Journal of Environmental Engineering

This study examined the effects of COD:N:P ratio on nitrogen and phosphorus removal in a single upflow fixed-bed filter provided with anaerobic, anoxic, and aerobic conditions through effluent and sludge recirculation and diffused air aeration. A high-strength wastewater mainly made of peptone, ammonium chloride, monopotassium phosphate, and sodium bicarbonate with varying COD, N, and P concentrations (COD: 2,500–6,000, N: 25–100, and P: 20–50 mg/L) was used as a substrate feed. Sodium acetate provided about 1,500 mg/L of the wastewater COD while the remainder was provided by glucose and peptone. A series of orthogonal tests using three factors, namely, COD, N, and P concentrations, at three different concentration levels were carried out. The experimental results obtained revealed that phosphorus removal efficiency was affected more by its own concentration than that of COD and N concentrations; while nitrogen removal efficiency was unaffected by different phosphorus concentrations. At a COD:N:P ratio of 300:5:1, both nitrogen and phosphorus were effectively removed using the filter, with removal efficiencies at 87 and 76%, respectively, under volumetric loadings of $0.1\mathrm{kg} N/m^3 d$ and $0.02\mathrm{kg} P/m^3 d\text{.}$

This paper presents a theoretical investigation on excess sludge production in membrane bioreactors for municipal wastewater treatment. Based on mass balances of sludge and substrate, a formula to predict the excess sludge production in membrane bioreactors is introduced and verified by experimental data. The effects of kinetic parameters and operating conditions on excess sludge production are discussed for strong-, medium-, and low-strength municipal wastewaters, respectively. The strategy for reducing excess sludge production is recommended in order of priority, as sludge retention time$\to k_d\to Y\to$hydraulic retention time. Furthermore, the differences between membrane bioreactors and activated sludge processes are analyzed from the viewpoint of excess sludge production.

Commensurate with development of in situ storm-water control and treatment is the need to quantify the delivery and granulometry of the suspended particulate fraction in storm water. Consistent with this need, this study examined the so-called “first flush” phenomenon for suspended particles with a measured range from 2 to 75 μm (typically <50 μm), the appropriateness of a single- versus multiple-power-law model of particle-number density (PND), and the application of process selection diagrams for particle separation. In comparison to a defined concentration “first flush” during the early portion of the examined rainfall-runoff events, results indicate that a disproportionately high and in some cases a continuous suspended particle delivery phenomenon that followed the hydrology of the event occurred. Such results suggest that the entire event may require treatment, not solely the commonly designated “first flush” based on indices such as suspended solids. While a single-power law reasonably represented granulometric characteristics of suspended storm-water particulates, and in theory a continuously size-based power law is the most accurate representation; within the given suspended particle-size range a multiple-power law provided reasonable simplicity and accuracy for total PND, surface area, and particulate volume. Despite a wide range of hydrologic conditions for a series of nine rainfall-runoff events examined, process selection diagrams based on the number-volume mean size $\left(l_{\mathrm{nv}}\right)$ and total PND led to a similar conclusion. Based on the combination of $l_{\mathrm{nv}}$ and PND in the urban catchment sedimentation in a typical transportation land use drainage facility is capable of removing 90% of particulate matter by mass within a detention time of 120 min.

Storm water runoff is perceived as a major source of pollutants that results in adverse environmental effects, but large-scale assessments are rarely conducted. The problem is particularly pronounced in southern California where 17 million people have rapidly developed coastal watersheds. The goal of this study was to make regionwide estimates of mass emissions, assess the relative contribution from urbanized watersheds, and compare pollutant flux from different land uses. A geographic information system-based storm water runoff model was used to estimate pollutant mass emissions based on land use, rainfall, runoff volume, and local water-quality information. Local monitoring data were used to derive runoff coefficients; over 1,700 storm water sampling events were used to calibrate and validate annual loadings. An average rainfall year produced $1\text{,}073\times {10}^9 L$ of runoff, 118,000 metric tons (MT) of suspended solids, 1,940 MT of nitrate-N, 108 MT of zinc, and 15 kg of diazinon. The majority of mass emissions were from urbanized watersheds except for suspended solids, total DDT, and chlorpyrifos. Agricultural areas had the greatest fluxes for pesticides, including total DDT and chlorpyrifos while open areas typically had the smallest.

The San Juan Bay Estuary is a tropical lagoon system severely impacted by eutrophication and by elevated pathogen concentrations. This investigation examined alternatives for pollution abatement primarily through physical modifications to the system. The investigation included field surveys, computation of pollutant loads, and application of hydrodynamic and eutrophication models. A eutrophication model developed for temperate estuaries was successfully transferred to San Juan Bay Estuary. Results indicate two primary modifications reduce eutrophication. The first clears a constricted channel to the interior of the system and promotes flushing. The second fills deep holes in which anoxic conditions promote sediment nutrient release to the water column. Major reductions in pathogen concentration require regional controls on sources.

Phenolic compounds are environmentally important due to their extensive use in various industries, presence in wastewaters, and potential toxicity. When phenolic compounds reach the activated sludge processes of publicly owned treatment works, they can cause upsets in the operations of the treatment plants. A continuous toxicity testing system was developed based on the bioluminescent bacterium Shk1. The toxicities of 23 phenolic compounds to Shk1 were studied and the 5 min ${\mathrm{EC}}_{50}$ values were obtained. Quantitative structure-activity relationship models based on the logarithm of the octanol-water partitioning coefficient $\left[\log \right(K_{\mathrm{ow}}\left)\right]$ were established for estimating the toxicity of phenolic compounds and the model validity was verified.

Numerous sites have been contaminated with polycyclic aromatic hydrocarbons (PAHs), and these sites pose a significant risk to public health and the environment because PAHs are often toxic, mutagenic, and/or carcinogenic. Furthermore, these sites are often difficult or costly to remediate because PAHs are hydrophobic and highly resistant to degradation. The in situ flushing process using surfactants and/or cosolvents has shown great promise for sites possessing uniform and high-permeability soils, but it is generally ineffective for sites containing heterogeneous and/or low-permeability soils. Thus, for difficult soil conditions, electrokinetics can be integrated with the in situ flushing process to improve soil-solution-contaminant interaction. This investigation was conducted to evaluate the effects of two different low-permeability soils, kaolin and glacial till, on electrokinetically enhanced flushing. Each soil type was used in three bench-scale electrokinetic experiments, where each test employed a different flushing solution, deionized water, a surfactant, or a cosolvent. The results indicated that the contaminant was more strongly bound to the glacial till than the kaolin, and this was attributed to its higher-organic content. The glacial till also generated a greater electrical current and electro-osmotic flow, and this was probably a result of its higher-carbonate content and more diverse mineralogy. Based on the contaminant mass remaining in the soil, it was apparent that the surfactant or cosolvent solution caused contaminant desorption, solubilization, and/or migration in both soils, but additional research is required to improve PAH removal efficiency.

The dielectric permittivity of soils can be significantly modified by the presence of organic contaminant in the pore fluid. Thus, nondestructive techniques based on the propagation of electromagnetic waves may be used to detect contaminant plumes and to evaluate decontamination processes. Ground penetrating radar (GPR) and time domain reflectometry are two of the most relevant geophysical tools working in the frequency range of interest here. In this work, the complex dielectric permittivity of some soil–organic mixtures are measured in the frequency range of 20 MHz to 1.3 GHz. Tests are conducted in samples of silica sand, loess, and kaolinite mixed with varied amount of paraffin oil and lubricant oil. Additional tests are performed in soil–water samples for comparison. Mixtures formulas reported in the literature are extended from two to three and four phases in order to model the measured dielectric response of the contaminated soil samples. The results allow us to study the effect of the volumetric liquid content, organic type, mineral composition, and specific surface of soil particles on the dielectric permittivity of the mixtures. It is concluded in this work that the value of dielectric permittivity in soils is sensitive to the detection of contaminants when the organic concentration is high. On the other hand, the organic content can be determined providing that the total volume of fluid in the pores is known. The detection limits of organics in soils are discussed. Finally, a contamination process is monitored with GPR at the frequency of 1 GHz in a laboratory cell. The results show that organic contaminants are easily detected in dry sand, yet detection becomes very difficult in wet sand.

The construction of mixture designs and the methods of response surface analysis of mixture data are discussed and applied for determining the optimum ingredients for stabilized phosphogypsum (PG) composites conducive to marine application. Of particular importance is the ability of the composites to maintain physical integrity when submerged. Therefore, potential indicators for the survivability of the stabilized PG composites were also screened. The triangular coordinate system was used to present the three ingredient components of the PG composites as well as their dependent variables. The augmented simplex centroid design with pseudocomponents was used in determining mixture ingredient composition. A quadratic model with two process variables was used to analyze the experimental results and predict the optimum ingredient composition. The model predicts that a series of PG: class C fly ash:portland type II cement ingredients, such as 62%:35%:3% PG:class C fly ash:portland type II cement and 65%:31%:4% PG:class C fly ash:portland type II cement composites with class C fly ash content (30.7–36.6%) and portland type II cement content (2.7–4.2%), can survive in marine environments for more than two years. The indicator screening for the survivability of the stabilized PG composites in the marine environment showed that the minimum wet leached surface hardness, minimum wet control surface hardness, and maximum effective diffusion coefficient may serve as indicators.

The potential of solidification/stabilization (S/S) technology for the safe disposal of hazardous wastes has wide spread recognition. The purpose of this study was to investigate the effectiveness of portland cement-based S/S technology for the safe disposal of hazardous wastes containing toxic metals and organic contaminants. As hazardous wastes, metal enriched mining residue, adsorbable organic halogens (AOX) containing pulp and paper sludge, and polychlorinated biphenyl (PCB) oil-contaminated soil were used. For S/S of waste, portland cement as a binding agent was mixed with wastes at different ratios. For initial waste characterization, contaminant concentrations and some physical waste characteristics such as particle-size distribution, Atterberg limits, specific gravity, and moisture content yielding the maximum compacted dry density were determined. Waste and cement mixtures were cured for 28 days after compacting the desired waste-cement mixtures at their predetermined optimum moisture contents yielding the corresponding maximum dry densities in cylindrical molds having a height of 71 mm and a diameter of 36 mm. At the end of the 28-day cure period, unconfined compressive strength and hydraulic conductivity measurements were conducted on the solidified samples. Subsequently, solidified samples were crushed for fractionation into two different aggregate sizes (between 1–2 and >2 mm) and subjected to the U.S. Environmental Protection Agency Toxicity Characteristic Leaching Procedure (TCLP). The effectiveness of S/S was assessed by comparing the chemical composition of leachates obtained from TCLP tests of untreated and treated, i.e., S/S waste samples, and comparing values of strength and hydraulic conductivity of solidified waste samples with regulatory requirements. For mining waste, effective application of S/S was achieved for most cases. AOX containing sludge yielded acceptable results in terms of strength and hydraulic conductivity but leachate AOX concentrations were above regulatory levels. The effectiveness of S/S for coarse textured-soils contaminated with a PCB oil was not satisfactory, especially at a cement:soil ratio less than 35%.

The Massachusetts Water Resources Authority (MWRA) supplies unfiltered water from two large surface water reservoirs to the metropolitan Boston area, as well as to three smaller communities in central Massachusetts [the Chicopee Valley Aqueduct (CVA) communities]. Quabbin Reservoir is larger than Wachusett Reservoir, and has traditionally been used to supplement the Wachusett during the summer period. Quabbin water is also of better quality, with lower reactive natural organic matter (NOM). The MWRA began to add chlorine at Wachusett in 1997, and a new facility for adding chlorine at Quabbin for the CVA was also started up in 2000 to meet primary disinfection regulations to meet pathogen inactivation. The reaction of chlorine with NOM produces undesirable disinfection by-products (DBPs). The absorption of ultraviolet light at a wavelength of 254 nm was identified in chlorine decay studies to be the most important raw water quality parameter for predicting chlorine decay and DBP formation. This technical note summarizes the chlorine decay model for Wachusett and Quabbin water. The model is extended to ozonation of Wachusett water for the future Walnut Hill treatment plant. The models allowed the development of a trigger using UV-254 to time the Quabbin transfer to optimize treatment results. It is believed that the model for disinfectant decay and the use of UV-254 as a trigger for water treatment decisions are generalized and applicable to other water utilities.

The effects of oxygen on the pyrolysis of tetra pack, a principal component of municipal solid wastes in Taiwan, were investigated with a thermal gravimetric analysis (TGA) reaction system. The pyrolysis experiments of tetra pack were carried out in four different oxygen concentrations $(C_{O2}\text{,}$ 5.37, 10.40, 14.82, and 20.95%) at the heating rates of 5.25, 10.36, and 15.06 K/min. The TGA curves indicated two principal reactions, distinguished by significant and distinct mass changes over the experimental range. Oxygen enhanced the pyrolysis reaction of tetra pack. A kinetic model was proposed for the pyrolysis of the tetra pack in an oxygen environment. The corresponding activation energies, preexponential factors, and reaction orders were determined. The experimental results were satisfactorily fitted by the proposed kinetic model.