Synthesis of Quaternary Hydrotalcite-Carbon Nanotube Composite and Its Sulfate Adsorption Performance in Cement Paste
Publication: Journal of Materials in Civil Engineering
Volume 35, Issue 11
Abstract
In this paper, quaternary hydrotalcite [layered double hydroxide (LDH)] (CoFeMgAl-LDH) was first fabricated based on the coprecipitation method, and then, CoFeMgAl-LDH/carbon nanotubes (CNTs) composite was synthesized by CNTs and CoFeMgAl-LDH through the solid phase mixing method. Subsequently, the physical-chemical properties of CoFeMgAl-LDH/CNT composite were investigated by scanning electron microscope (SEM), X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, energy dispersive spectroscopy (EDS), and Brunauer-Emmett-Teller (BET) analysis. Meanwhile, the performance of CoFeMgAl-LDH/CNT composite for adsorption was evaluated under different conditions, including different initial concentration, contact time, adsorbent dosage, solution pH, temperature, and coexisting ions. Afterward, the adsorption capacity of CoFeMgAl-LDH/CNT in cement paste was further studied. The results showed that the CoFeMgAl-LDH/CNT composite exhibited a three-dimensional structure with high specific surface area. The maximum adsorption amount of the CoFeMgAl-LDH/CNT composite was , which was significantly higher compared with other absorbents of the same type. Pseudosecond-order kinetic model could reasonably describe the adsorption kinetics, and Freundlich isotherm could fit the adsorption data accurately. The results also suggest that the synthesized CoFeMgAl-LDH/CNT composite can serve as a potential material for the sulfate binding in cementitious materials.
Get full access to this article
View all available purchase options and get full access to this article.
Data Availability Statement
Some or all data, models, or code that support the findings of this study are available from the corresponding author upon reasonable request.
Acknowledgments
All authors appreciate the supports from the Natural Science Foundation of Hunan Province (2019JJ60003 and 2022JJ40615), Changsha Municipal Natural Science Foundation (kq2202099), the China Scholarship Council (CSC) scholarship (No.202108410138), and Australian Research Council (ARC), Australia.
References
ASTM. 1997. Powder diffraction file, joint committee on powder diffraction standards (JCPDS). West Conshohocken, PA: ASTM.
Chen, Y., Z. Shui, W. Chen, and G. Chen. 2015. “Chloride binding of synthetic Ca–Al–NO3 LDHs in hardened cement paste.” Constr. Build. Mater. 93 (Sep): 1051–1058. https://doi.org/10.1016/j.conbuildmat.2015.05.047.
Chinese National Standard. 2008. Chemical analysis methods of lithium fluoride—Part 8: Determination of sulphate content—Barium sulphate gravimetric method. GB/T 22660.8-2008. Beijing: Chinese National Standard.
Chiron, N., R. Guilet, and E. Deydier. 2003. “Adsorption of Cu(II) and Pb(II) onto a grafted silica: Isotherms and kinetic models.” Water Res. 37 (13): 3079–3086. https://doi.org/10.1016/S0043-1354(03)00156-8.
Diab, A. M., H. E. Elyamany, M. Abd Elmoaty, and M. M. Sreh. 2019. “Effect of nanomaterials additives on performance of concrete resistance against magnesium sulfate and acids.” Constr. Build. Mater. 210 (Jun): 210–231. https://doi.org/10.1016/j.conbuildmat.2019.03.099.
Dinari, M., H. Allami, and M. M. Momeni. 2020. “Construction of Ce-Doped NiCo-LDH@ CNT nanocomposite electrodes for high-performance supercapacitor application.” Energy Fuels 35 (2): 1831–1841. https://doi.org/10.1021/acs.energyfuels.0c03764.
Duan, P., W. Chen, J. Ma, and Z. Shui. 2013. “Influence of layered double hydroxides on microstructure and carbonation resistance of sulphoaluminate cement concrete.” Constr. Build. Mater. 48 (Aug): 601–609. https://doi.org/10.1016/j.conbuildmat.2013.07.049.
Elahi, M. M. A., C. R. Shearer, A. N. R. Reza, A. K. Saha, M. N. N. Khan, M. M. Hossain, and P. K. Sarker. 2021. “Improving the sulfate attack resistance of concrete by using supplementary cementitious materials (SCMs): A review.” Constr. Build. Mater. 281 (Apr): 122628. https://doi.org/10.1016/j.conbuildmat.2021.122628.
Foo, K. Y., and B. H. Hameed. 2010. “Insights into the modeling of adsorption isotherm systems.” Chem. Eng. J. 156 (1): 2–10. https://doi.org/10.1016/j.cej.2009.09.013.
Geng, J., C. Pan, Y. Wang, W. Chen, and Y. Zhu. 2021. “Chloride binding in cement paste with calcined Mg-Al-CO3 LDH (CLDH) under different conditions.” Constr. Build. Mater. 273 (Mar): 121678. https://doi.org/10.1016/j.conbuildmat.2020.121678.
Goh, K.-H., T.-T. Lim, and Z. Dong. 2008. “Application of layered double hydroxides for removal of oxyanions: A review.” Water Res. 42 (6–7): 1343–1368. https://doi.org/10.1016/j.watres.2007.10.043.
Gomes, C., Z. Mir, R. Sampaio, A. Bastos, J. Tedim, F. Maia, C. Rocha, and M. Ferreira. 2020. “Use of ZnAl-layered double hydroxide (LDH) to extend the service life of reinforced concrete.” Materials (Basel) 13 (7): 1769. https://doi.org/10.3390/ma13071769.
Guo, J.-J., K. Wang, and C.-G. Qi. 2021. “Determining the mineral admixture and fiber on mechanics and fracture properties of concrete under sulfate attack.” J. Mar. Sci. Eng. 9 (3): 251. https://doi.org/10.3390/jmse9030251.
Guo, J. K., Z. Zhou, F. Y. Peng, and X. S. Bai. 2019. “Preparation of CNTs/MgAl-LDHs composites and their adsorption properties for chloride ions.” Mater. Sci. Forum 956 (Feb): 305–313. https://doi.org/10.4028/www.scientific.net/MSF.956.305.
Guo, L., Y. Wu, P. Duan, and Z. Zhang. 2020. “Improving sulfate attack resistance of concrete by using calcined Mg-Al-CO3 LDHs: Adsorption behavior and mechanism.” Constr. Build. Mater. 232 (Jan): 117256. https://doi.org/10.1016/j.conbuildmat.2019.117256.
Haghseresht, F., and G. Q. Lu. 1998. “Adsorption characteristics of phenolic compounds onto coal-reject-derived adsorbents.” Energy Fuels 12 (6): 1100–1107. https://doi.org/10.1021/ef9801165.
Higgins, D. 2003. “Increased sulfate resistance of ggbs concrete in the presence of carbonate.” Cem. Concr. Compos. 25 (8): 913–919. https://doi.org/10.1016/S0958-9465(03)00148-3.
Ho, Y.-S. 2006. “Review of second-order models for asorption systems.” J. Hazard. Mater. 136 (3): 681–689. https://doi.org/10.1016/j.jhazmat.2005.12.043.
Huang, S., H. Peng, W. W. Tjiu, Z. Yang, H. Zhu, T. Tang, and T. Liu. 2010. “Assembling exfoliated layered double hydroxide (LDH) nanosheet/carbon nanotube (CNT) hybrids via electrostatic force and fabricating nylon nanocomposites.” J. Phys. Chem. B 114 (50): 16766–16772. https://doi.org/10.1021/jp1087256.
Jaturapitakkul, C., K. Kiattikomol, W. Tangchirapat, and T. Saeting. 2007. “Evaluation of the sulfate resistance of concrete containing palm oil fuel ash.” Constr. Build. Mater. 21 (7): 1399–1405. https://doi.org/10.1016/j.conbuildmat.2006.07.005.
Kamble, S. P., G. Deshpande, P. P. Barve, S. Rayalu, N. K. Labhsetwar, A. Malyshew, and B. D. Kulkarni. 2010. “Adsorption of fluoride from aqueous solution by alumina of alkoxide nature: Batch and continuous operation.” Desalination 264 (1–2): 15–23. https://doi.org/10.1016/j.desal.2010.07.001.
Kayali, O., M. S. H. Khan, and M. Sharfuddin Ahmed. 2012. “The role of hydrotalcite in chloride binding and corrosion protection in concretes with ground granulated blast furnace slag.” Cem. Concr. Compos. 34 (8): 936–945. https://doi.org/10.1016/j.cemconcomp.2012.04.009.
Kunther, W., B. Lothenbach, and J. Skibsted. 2015. “Influence of the Ca/Si ratio of the C–S–H phase on the interaction with sulfate ions and its impact on the ettringite crystallization pressure.” Cem. Concr. Res. 69 (Aug): 37–49. https://doi.org/10.1016/j.cemconres.2014.12.002.
Li, W., P. Wu, S. Yang, Y. Zhu, C. Kang, L. T. Tran, and B. Zeng. 2015. “3D hierarchical honeycomb structured MWCNTs coupled with CoMnAl–LDO: Fabrication and application for ultrafast catalytic degradation of bisphenol A.” RSC Adv. 5 (12): 8859–8867. https://doi.org/10.1039/C4RA15339A.
Li, Y., X. Yang, P. Lou, R. Wang, Y. Li, and Z. Si. 2021. “Sulfate attack resistance of recycled aggregate concrete with NaOH-solution-treated crumb rubber.” Constr. Build. Mater. 287 (Jun): 123044. https://doi.org/10.1016/j.conbuildmat.2021.123044.
Liu, P., Y. Chen, Z. Yu, and Z. Lu. 2019. “Effect of sulfate solution concentration on the deterioration mechanism and physical properties of concrete.” Constr. Build. Mater. 227 (Aug): 116641. https://doi.org/10.1016/j.conbuildmat.2019.08.022.
Mehta, P. K. 1973. “Mechanism of expansion associated with ettringite formation.” Cem. Concr. Res. 3 (1): 1–6. https://doi.org/10.1016/0008-8846(73)90056-2.
Mehta, P. K. 1983. “Mechanism of sulfate attack on portland cement concrete—Another look.” Cem. Concr. Res. 13 (3): 401–406. https://doi.org/10.1016/0008-8846(83)90040-6.
Nehdi, M., A. Suleiman, and A. Soliman. 2014. “Investigation of concrete exposed to dual sulfate attack.” Cem. Concr. Res. 64 (Oct): 42–53. https://doi.org/10.1016/j.cemconres.2014.06.002.
Ogata, F., N. Nagai, Y. Kariya, E. Nagahashi, Y. Kobayashi, T. Nakamura, and N. Kawasaki. 2018. “Adsorption of nitrite and nitrate ions from an aqueous solution by Fe–mg-type hydrotalcites at different molar ratios.” Chem. Pharm. Bull. 66 (4): 458–465. https://doi.org/10.1248/cpb.c17-01044.
Qu, J., Q. Zhang, X. Li, X. He, and S. Song. 2016. “Mechanochemical approaches to synthesize layered double hydroxides: A review.” Appl. Clay Sci. 119 (Aug): 185–192. https://doi.org/10.1016/j.clay.2015.10.018.
Rudzinski, W., and T. Panczyk. 2000. “Kinetics of isothermal adsorption on energetically heterogeneous solid surfaces: A new theoretical description based on the statistical rate theory of interfacial transport.” J. Phys. Chem. B 104 (39): 9149–9162. https://doi.org/10.1021/jp000045m.
Tang, Z., W. Li, G. Ke, J. L. Zhou, and V. W. Y. Tam. 2019. “Sulfate attack resistance of sustainable concrete incorporating various industrial solid wastes.” J. Cleaner Prod. 218 (Feb): 810–822. https://doi.org/10.1016/j.jclepro.2019.01.337.
Wang, D., X. Zhou, Y. Meng, and Z. Chen. 2017. “Durability of concrete containing fly ash and silica fume against combined freezing-thawing and sulfate attack.” Constr. Build. Mater. 147 (Aug): 398–406. https://doi.org/10.1016/j.conbuildmat.2017.04.172.
Wei, J., J. Xu, Y. Mei, and Q. Tan. 2020. “Chloride adsorption on aminobenzoate intercalated layered double hydroxides: Kinetic, thermodynamic and equilibrium studies.” Appl. Clay Sci. 187 (Mar): 105495. https://doi.org/10.1016/j.clay.2020.105495.
Xiao, L., W. Ma, M. Han, and Z. Cheng. 2011. “The influence of ferric iron in calcined nano-Mg/Al hydrotalcite on adsorption of Cr (VI) from aqueous solution.” J. Hazard. Mater. 186 (1): 690–698. https://doi.org/10.1016/j.jhazmat.2010.11.052.
Yang, H., C. Xiong, X. Liu, A. Liu, T. Li, R. Ding, S. P. Shah, and W. Li. 2021. “Application of layered double hydroxides (LDHs) in corrosion resistance of reinforced concrete-state of the art.” Constr. Build. Mater. 307 (Jun): 124991. https://doi.org/10.1016/j.conbuildmat.2021.124991.
Yang, W., Z. Gao, J. Wang, J. Ma, M. Zhang, and L. Liu. 2013. “Solvothermal one-step synthesis of Ni-Al layered double hydroxide/carbon nanotube/reduced graphene oxide sheet ternary nanocomposite with ultrahigh capacitance for supercapacitors.” ACS Appl. Mater. Interfaces 5 (12): 5443–5454. https://doi.org/10.1021/am4003843.
Yang, Z., H. Fischer, and R. Polder. 2012. “Possibilities for improving corrosion protection of reinforced concrete by modified hydrotalcites—A literature review.” In Advances in modeling concrete service life, 95–105. Dordrecht, Netherlands: Springer Netherlands.
Yang, Z., F. Wang, C. Zhang, G. Zeng, X. Tan, Z. Yu, Y. Zhong, H. Wang, and F. Cui. 2016. “Utilization of LDH-based materials as potential adsorbents and photocatalysts for the decontamination of dyes wastewater: A review.” RSC Adv. 6 (83): 79415–79436. https://doi.org/10.1039/C6RA12727D.
Yang, Z.-Z., C. Zhang, G.-M. Zeng, X.-F. Tan, H. Wang, D.-L. Huang, K.-H. Yang, J.-J. Wei, C. Ma, and K. Nie. 2020. “Design and engineering of layered double hydroxide based catalysts for water depollution by advanced oxidation processes: A review.” J. Mater. Chem. A 8 (8): 4141–4173. https://doi.org/10.1039/C9TA13522G.
Yasaei, M., M. Khakbiz, A. Zamanian, and E. Ghasemi. 2019. “Synthesis and characterization of Zn/Al-LDH@SiO2 nanohybrid: Intercalation and release behavior of vitamin C.” Mater. Sci. Eng. C Mater. Biol. Appl. 103 (Oct): 109816. https://doi.org/10.1016/j.msec.2019.109816.
Yu, C., J. Yang, C. Zhao, X. Fan, G. Wang, and J. Qiu. 2014. “Nanohybrids from NiCoAl-LDH coupled with carbon for pseudocapacitors: Understanding the role of nano-structured carbon.” Nanoscale 6 (6): 3097–3104. https://doi.org/10.1039/C3NR05477B.
Zubair, M., M. Daud, G. McKay, F. Shehzad, and M. A. Al-Harthi. 2017. “Recent progress in layered double hydroxides (LDH)-containing hybrids as adsorbents for water remediation.” Appl. Clay Sci. 143 (Jul): 279–292. https://doi.org/10.1016/j.clay.2017.04.002.
Information & Authors
Information
Published In
Copyright
© 2023 American Society of Civil Engineers.
History
Received: Jul 20, 2022
Accepted: Apr 4, 2023
Published online: Aug 26, 2023
Published in print: Nov 1, 2023
Discussion open until: Jan 26, 2024
Authors
Metrics & Citations
Metrics
Citations
Download citation
If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.