Technical Papers
Aug 25, 2023

Microscopic Analysis of Aging Characteristics of SBS-Modified Asphalt Based on FTIR Technology

Publication: Journal of Materials in Civil Engineering
Volume 35, Issue 11

Abstract

Thermal-photo-oxidative coupled aging, anaerobic and thermal-oxidative aging testing were conducted on styrene-butadiene-styrene (SBS) type copolymer -modified asphalt at different aging temperatures. The changes in functional group index before and after aging of modified asphalt were deeply analyzed by the attenuated total reflection (ATR) method of Fourier transform infrared (FTIR) spectroscopy. The results show that the carbonyl index IC=O, the sulfoxide index IS=O, the polybutadiene index IPB, and the polystyrene index IPS can properly characterize the changes in the microscopic chemical structure of SBS-modified asphalt during aging, and can accurately quantify the degree of aging of SBS-modified asphalt at the microscopic level.

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Data Availability Statement

All data, models, or code that support the findings of this study are available from the corresponding author upon reasonable request.

Acknowledgments

No funding was received for this research.

References

Abouelsaad, A., and G. White. 2022. “The combined effect of ultraviolet irradiation and temperature on hot mix asphalt mixture aging.” Sustainability 14 (10): 5942. https://doi.org/10.3390/su14105942.
Chang, R., and H. Wang. 2020. “Study on aging behavior and aging mechanism of asphalt.” China Sciencepaper 15 (4): 420–424. https://doi.org/10.3969/j.issn.2095-2783.2020.04.008.
Chen, Z., H. Zhang, and H. Duan. 2020. “Investigation of ultraviolet radiation aging gradient in asphalt binder.” Constr. Build. Mater. 246 (Jun): 118501. https://doi.org/10.1016/j.conbuildmat.2020.118501.
Cheng, X., X. Li, and H. Huang. 2018. “Study on rapid determination of SBS content in modified asphalt by attenuated total reflection fourier transform infrared spectroscopy.” Shandong Transp. Technol. (5): 39–41. https://doi.org/10.3969/j.issn.1673-8942.2018.05.010.
Chinese Standard. 2011. Standard test methods of bitumen and bituminous mixtures for highway engineering. Beijing: China Communications Press.
Ding, Y., D. Li, H. Zhang, M. Deng, X. Mao, and X. Cao. 2022. “Investigation of aging behavior of asphalt under multiple environmental conditions.” J. Mater. Civ. Eng. 34 (2): 04021419. https://doi.org/10.1061/(ASCE)MT.1943-5533.0004048.
Gao, Y., F. Gu, and Y. Zhao. 2013. “Thermal oxidative aging characterization of SBS modified asphalt.” J. Wuhan Univ. Technol.-Mater. Sci. Ed. 28 (1): 88–91. https://doi.org/10.1007/s11595-013-0646-0.
Hao, Z., X. Zhang, X. Sheng, and J. Wang. 2009. “Aging mechanism of modified under epithermal conditions.” J. Build. Mater. 12 (4): 433–437. https://doi.org/10.3969/j.issn.1007-9629.2009.04.012.
Lamontagne, J., P. Dumas, V. Mouillet, and J. Kister. 2001. “Comparison by Fourier transform infrared (FTIR) spectroscopy of different ageing techniques: Application to road bitumens.” Fuel 80 (4): 483–488. https://doi.org/10.1016/S0016-2361(00)00121-6.
Li, N., X. Zhao, J. Sun, and Q. Xiao. 2015. “Study on aging mechanism of rubber-modified asphalt.” J. Highway Transp. Res. Dev. 32 (7): 22–27. https://doi.org/10.3969/j.issn.1002-0268.2015.07.004.
Li, P., T. Nian, D. Wei, and M. Lin. 2018. “Quantitative analysis method for FTIR and exploration on rheological parameters of aging asphalt binders.” J. Huazhong Univ. Sci. Technol. (Natl. Sci. Ed.) 46 (2): 34–39. https://doi.org/10.13245/j.hust.180207.
Liu, B., J. Shen, and P. Shi. 2016. “Nano-scale microscopic characteristics and functional groups of aged asphalt.” J. Highway Transp. Res. Dev. 33 (2): 33 (2): 6–13. https://doi.org/10.3969/j.issn.1002-0268.2016.02.002.
Lopes, M., V. Mouillet, L. Bernucci, and T. Gabet. 2016. “The potential of attenuated total reflection imaging in the mid-infrared for the study of recycled asphalt mixtures.” Constr. Build. Mater. 124 (Oct): 1120–1131. https://doi.org/10.1016/j.conbuildmat.2016.08.108.
Seitllari, A., Y. S. Kumbargeri, K. P. Biligiri, and I. Boz. 2019. “A soft computing approach to predict and evaluate asphalt mixture aging characteristics using asphaltene as a performance indicator.” Mater. Struct. 52 (5): 1–11. https://doi.org/10.1617/s11527-019-1402-5.
Smith, B. T., R. W. Bazuhair, C. Daranga, G. L. Baumgardner, and I. L. Howard. 2019. “Comparing laboratory pressure aging vessel conditioning to field aging of asphalt binder within compacted mixtures.” J. Mater. Civ. Eng. 31 (11): 04019271. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002926.
Song, J., L. He, X. Wang, L. Luo, and W. Li. 2020. “Microscopic aging mechanism of SBS modified asphalt in RTFOT.” J. Highway Transp. Res. Dev. 37 (2): 1–7.
Sugano, M., Y. Iwabuchi, T. Watanabe, J. Kajita, K. Iwata, and K. Hirano. 2010. “Relations between thermal degradations of SBS copolymer and asphalt substrate in polymer modified asphalt.” Clean Technol. Environ. Policy 12 (6): 653–659. https://doi.org/10.1007/s10098-010-0301-9.
Tang, J., Q. Ma, J. Shi, H. Yuan, C. Song, J. Xie, and X. Li. 2016. “Study on rapid detection of asphalt properties by attenuated total reflection infrared spectroscopy.” Spectrosc. Spectral Anal. 36 (3): 4.
Wang, C., Z. Liu, L. Ceng, and W. Li. 2020a. “Study on asphalt aging based on FTIR technology.” Highways Autom. Appl. 199 (4): 5.
Wang, L., M. Shan, and C. Li. 2020b. “The cracking characteristics of the polymer-modified asphalt mixture before and after aging based on the digital image correlation technology.” Constr. Build. Mater. 260 (Nov): 119802. https://doi.org/10.1016/j.conbuildmat.2020.119802.
Wang, S., W. Huang, P. Lin, Z. Wu, C. Kou, and B. Wu. 2021. “Chemical, physical, and rheological evaluation of aging behaviors of terminal blend rubberized asphalt binder.” J. Mater. Civ. Eng. 33 (11): 33. https://doi.org/10.1061/(ASCE)MT.1943-5533.0003931.
Wu, S., L. Pang, G. Liu, and J. Zhu. 2010. “Laboratory study on ultraviolet radiation aging of bitumen.” J. Mater. Civ. Eng. 22 (8): 767–772. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000010.
Wu, S., L. Pang, L. Mo, J. Qiu, G. Zhu, and Y. Xiao. 2008. “UV and thermal aging of pure bitumen-comparison between laboratory simulation and natural exposure aging.” Road Mater. Pavem. Des. 9 (Supp 1): 103–113. https://doi.org/10.1080/14680629.2008.9690161.
Xu, S., J. Huang, S. Tighe, C. Zhang, H. Ma, X. Jia, and X. Zhou. 2022. “Aging evaluation of base and SBS modified bitumens under the coupling effect of multiple aging factors.” Constr. Build. Mater. 348 (Sep): 128670. https://doi.org/10.1016/j.conbuildmat.2022.128670.
Xuelian, L., J. Guo, Z. Cui, J. Ye, X. Zhang, and J. Tian. 2022. “Creep and relaxation performance of reclaimed asphalt using SBS modified.” J. Transp. Sci. Eng. 38 (2): 53. https://doi.org/10.3969/j.issn.1674-599X.2022.02.002.
Yan, C., W. Huang, F. Xiao, L. Wang, and Y. Li. 2018. “Proposing a new infrared index quantifying the aging extent of SBS-modified asphalt.” Road Mater. Pavement Des. 19 (6): 1406–1421. https://doi.org/10.1080/14680629.2017.1318082.
Ye, F., and P. Huang. 2005. “Effects of intensive ultraviolet radiation on asphalt performance.” J. Tongji Univ. (Natl. Sci.) 33 (7): 5.
Ye, F., D. Sun, P. Huang, J. Zhu, and Z. Zhou. 2006. “Analysis of asphalt photooxidation aging property under intensive ultraviolet.” [In Chinese.] China J. Highway Transp. 19 (6): 5. https://doi.org/10.19721/j.cnki.1001-7372.2006.06.007.
Zhang, Z., S. Han, X. Han, X. Cheng, and T. Yao. 2020. “Comparison of SBS-modified asphalt rheological properties during simple-aging test.” J. Mater. Civ. Eng. 32 (9): 04020241. https://doi.org/10.1061/(ASCE)MT.1943-5533.0003316.
Zhang, Z., S. Han, X. Han, S. Dong, and T. Yao. 2021. “Performance changes of hot recycled asphalt mixture in different layers under coupling of multiple aging factors.” Constr. Build. Mater. 269 (Feb): 121343. https://doi.org/10.1016/j.conbuildmat.2020.121343.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 35Issue 11November 2023

History

Received: Sep 1, 2022
Accepted: Apr 5, 2023
Published online: Aug 25, 2023
Published in print: Nov 1, 2023
Discussion open until: Jan 25, 2024

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Authors

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Associate Professor, School of Traffic and Transportation Engineering, Changsha Univ. of Science and Technology, Changsha, Hunan 410114, China; Associate Professor, National Engineering Laboratory for Highway Maintenance Technology, Changsha Univ. of Science & Technology, Changsha, Hunan 410114, China. ORCID: https://orcid.org/0000-0002-3202-9815. Email: [email protected]
School of Traffic and Transportation Engineering, Changsha Univ. of Science and Technology, Changsha, Hunan 410114, China (corresponding author). ORCID: https://orcid.org/0000-0002-2769-9590. Email: [email protected]
ChaoSheng Yuan [email protected]
Research Fellow, Jiangxi Academy of Transportation Sciences Co., Ltd., No. 809 Jinsha Ave., Xiaolan Economic and Technological Development Zone, Nanchang, Jiangxi 330200, China. Email: [email protected]

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