Technical Papers
Jan 17, 2018

Development and Characterization of Fly Ash–Slag Blended Geopolymer Mortar and Lightweight Concrete

Publication: Journal of Materials in Civil Engineering
Volume 30, Issue 4

Abstract

A synopsis of an experimental program on the development of a sustainable fly ash–slag blended geopolymer mortar (GPM) and lightweight geopolymer concrete (LGPC) is presented. Geopolymer mortar mixes were prepared incorporating industrial by-products and sustainable desert dune sand to study the effect of different mixing variables, including binding materials, curing temperature, and alkaline activator solution composition and content, on the rheological and mechanical performance. Optimum mix designs were then formulated into producing LGPC samples with different binding materials and curing temperature. Lightweight geopolymer concrete specimens exhibited a brittle behavior with a weakened structure due to low-strength lightweight aggregates. Lightweight geopolymer concrete made with dune sand and a fly ash to slag ratio of 31 resulted in the highest compressive strength when cured for 24 h at 60°C. Microstructure characterization of LGPC specimens was also conducted. Scanning electron microscopy and differential scanning calorimetry showed the coexistence of an aluminosilicate hydrate geopolymer gel and aluminum-modified CSH gel as the main polymerization reaction products in an amorphous geopolymeric microstructure.

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Acknowledgments

Financial support for this study was provided by the United Arab Emirates University (UAEU) under Grants 31N249 and 31N241. Participation of students and assistance of laboratory staff at UAEU is gratefully acknowledged. Ashtech International supplied the fly ash and Emirates Cement Factory provided the ground-granulated blast-furnace slag used in the study.

References

Abdulkareem, O. A., Al Bakri, A. M., Kamarudin, H., Nizar, I. K., and Ala’eddin, A. S. (2014). “Effects of elevated temperatures on the thermal behavior and mechanical performance of fly ash geopolymer paste, mortar and lightweight concrete.” Constr. Build. Mater., 50, 377–387.
ACI (American Concrete Institute). (1992a). “Prediction of creep, shrinkage, and temperature effects in concrete structures.” ACI 209, Farmington Hills, MI.
ACI (American Concrete Institute). (1992b). “State of the art report on high-strength concrete.” ACI 363, Farmington Hills, MI, 364–411.
ACI (American Concrete Institute). (2014). “Building code requirements for structural concrete and commentary.” ACI 318, Farmington Hills, MI.
Al-Harthy, A. S., Halim, M. A., Taha, R., and Al-Jabri, K. S. (2007). “The properties of concrete made with fine dune sand.” Constr. Build. Mater., 21(8), 1803–1808.
Al-Majidi, M. H., Lampropoulos, A., Cundy, A., and Meikle, S. (2016). “Development of geopolymer mortar under ambient temperature for in situ applications.” Constr. Build. Mater., 120, 198–211.
ASTM. (2011). “Standard test method for splitting tensile strength of cylindrical concrete specimens.” ASTM C496, West Conshohocken, PA.
ASTM. (2013). “Standard test methods for time of setting of hydraulic cement by Vicat needle.” ASTM C191, West Conshohocken, PA.
ASTM. (2014a). “Standard test method for sieve analysis of fine and coarse aggregates.” ASTM C136, West Conshohocken, PA.
ASTM. (2014b). “Standard test method for static modulus of elasticity and Poisson’s ratio of concrete in compression.” ASTM C469, West Conshohocken, PA.
ASTM. (2015a). “Standard specification for coal fly ash and raw or calcined natural pozzolan for use in concrete.” ASTM C618, West Conshohocken, PA.
ASTM. (2015b). “Standard test method for compressive strength of cylindrical concrete specimens.” ASTM C39, West Conshohocken, PA.
ASTM. (2015c). “Standard test method for flow of hydraulic cement mortar.” ASTM C1437, West Conshohocken, PA.
ASTM. (2015d). “Standard test method for relative density (specific gravity) and absorption of coarse aggregate.” ASTM C127, West Conshohocken, PA.
ASTM. (2016a). “Standard test method for compressive strength of hydraulic cement mortars (using 2-in. or [50-mm] cube specimens).” ASTM C109, West Conshohocken, PA.
ASTM. (2016b). “Standard test method for flexural strength of concrete (using simple beam with third-point loading).” ASTM C78, West Conshohocken, PA.
ASTM. (2017). “Standard test method for bulk density (‘unit weight’) and voids in aggregate.” ASTM C29, West Conshohocken, PA.
Bakharev, T. (2006). “Geopolymeric materials prepared using Class F fly ash and elevated temperature curing.” Cem. Concr. Res., 36(6), 1134–1147.
Brough, A. R., and Atkinson, A. (2002). “Sodium silicate-based, alkali-activated slag mortars. I: Strength, hydration and microstructure.” Cem. Concr. Res., 32(6), 865–879.
Chuah, S., et al. (2016). “The properties of fly ash based geopolymer mortars made with dune sand.” Mater. Des., 92, 571–578.
Colella, C. (1999). “Use of thermal analysis in zeolite research and application.” Characterization techniques of glasses and ceramics, J. M. Rincon, and M. Romero, eds., Springer, Berlin, 112–137.
Criado, M., Fernández-Jiménez, A., and Palomo, A. (2007). “Alkali activation of fly ash: Effect of the SiO2/Na2O ratio. I: FTIR study.” Microporous Mesoporous Mater., 106(1–3), 180–191.
Davidovits, J. (2008). Geopolymer: Chemistry and applications, Institut Géopolymère, Saint-Quentin, France.
Davidovits, J. (2013). “Geopolymer cement, a review.” Institut Géopolymère, Saint-Quentin, France.
Deb, P. S., Nath, P., and Sarker, P. K. (2014). “The effects of ground granulated blast-furnace slag blending with fly ash and activator content on the workability and strength properties of geopolymer concrete cured at ambient temperature.” Mater. Des. (1980–2015), 62, 32–39.
Dilli, M. E., Atahan, H. N., and Şengül, C. (2015). “A comparison of strength and elastic properties between conventional and lightweight structural concretes designed with expanded clay aggregates.” Constr. Build. Mater., 101, 260–267.
Ferone, C., et al. (2013). “Application-oriented chemical optimization of a metakaolin based geopolymer.” Materials, 6(5), 1920–1939.
Freedonia Group. (2014). “Bricks, blocks, and pavers.” Cleveland.
Guo, X., Shi, H., Chen, L., and Dick, W. A. (2010). “Alkali-activated complex binders from Class C fly ash and Ca-containing admixtures.” J. Hazard. Mater., 173(1–3), 480–486.
Izquierdo, M., Querol, X., Davidovits, J., Antenucci, D., Nugteren, H., and Fernández-Pereira, C. (2009). “Coal fly ash-slag-based geopolymers: Microstructure and metal leaching.” J. Hazard. Mater., 166(1), 561–566.
Kastiukas, G., Zhou, X., and Castro-Gomes, J. (2016). “Development and optimisation of phase change material-impregnated lightweight aggregates for geopolymer composites made from aluminosilicate rich mud and milled glass powder.” Constr. Build. Mater., 110, 201–210.
Ke, Y., Beaucour, A. L., Ortola, S., Dumontet, H., and Cabrillac, R. (2009). “Influence of volume fraction and characteristics of lightweight aggregates on the mechanical properties of concrete.” Constr. Build. Mater., 23(8), 2821–2828.
Lee, N. K., and Lee, H. K. (2013). “Setting and mechanical properties of alkali-activated fly ash/slag concrete manufactured at room temperature.” Constr. Build. Mater., 47, 1201–1209.
Li, C., Sun, H., and Li, L. (2010). “A review: The comparison between alkali-activated slag (Si+Ca) and metakaolin (Si+Al) cements.” Cem. Concr. Res., 40(9), 1341–1349.
Li, J., and Liu, S. (2007). “Influence of slag as additive on compressive strength of fly ash-based geopolymer.” J. Mater. Civ. Eng., 470–474.
Luo, F. J., He, L., Pan, Z., Duan, W. H., Zhao, X. L., and Collins, F. (2013). “Effect of very fine particles on workability and strength of concrete made with dune sand.” Constr. Build. Mater., 47, 131–137.
Mollah, M. Y. A., Yu, W., Schennach, R., and Cocke, D. L. (2000). “A Fourier transform infrared spectroscopic investigation of the early hydration of portland cement and the influence of sodium lignosulfonate.” Cem. Concr. Res., 30(2), 267–273.
Mouli, M., and Khelafi, H. (2008). “Performance characteristics of lightweight aggregate concrete containing natural pozzolan.” Build. Environ., 43(1), 31–36.
Nath, P., and Sarker, P. K. (2014). “Effect of GGBFS on setting, workability and early strength properties of fly ash geopolymer concrete cured in ambient condition.” Constr. Build. Mater., 66, 163–171.
Nath, S. K., and Kumar, S. (2013). “Influence of iron making slags on strength and microstructure of fly ash geopolymer.” Constr. Build. Mater., 38, 924–930.
Olivier, J. G. J., Janssens-Maenhout, G., Muntean, M., and Peters, J. A. H. W. (2015). “Trends in global CO2 emissions: 2015 report.”, PBL Netherlands Environmental Assessment Agency, Hague, Netherlands.
Palomo, A., Grutzeck, M. W., and Blanco, M. T. (1999). “Alkali-activated fly ashes: A cement for the future.” Cem. Concr. Res., 29(8), 1323–1329.
Perera, D. S., Vance, E. R., Finnie, K. S., Blackford, M. G., Hanna, J. V., and Cassidy, D. J. (2006). “Disposition of water in metakaolinite based geopolymers.” Advances in ceramic matrix composites XI, Vol. 175, Wiley, Hoboken, NJ.
Posi, P., et al. (2013). “Lightweight geopolymer concrete containing aggregate from recycle lightweight block.” Mater. Des., 52, 580–586.
Saavedra, W. G. V., Angulo, D. E., and Gutiérrez, R. M. D. (2016). “Fly ash slag geopolymer concrete: Resistance to sodium and magnesium sulfate attack.” J. Mater. Civ. Eng., 04016148.
Silva, P. D., Sagoe-Crenstil, K., and Sirivivatnanon, V. (2007). “Kinetics of geopolymerization: Role of Al2O3 and SiO2.” Cem. Concr. Res., 37(4), 512–518.
Standards Australia. (2009). “Concrete structures.” AS3600, Sydney, NSW, Australia.
Su, N., and Miao, B. (2003). “A new method for the mix design of medium strength flowing concrete with low cement content.” Cem. Concr. Compos., 25(2), 215–222.
Temuujin, J., Williams, R. P., and van Riessen, A. (2009). “Effect of mechanical activation of fly ash on the properties of geopolymer cured at ambient temperature.” J. Mater. Process. Technol., 209(12–13), 5276–5280.
Turner, L. K., and Collins, F. G. (2013). “Carbon dioxide equivalent (CO2-e) emissions: A comparison between geopolymer and OPC cement concrete.” Constr. Build. Mater., 43, 125–130.
van Deventer, J. S. J., Lukey, G. C., and Xu, H. (2006). “Effect of curing temperature and silicate concentration on fly-ash-based geopolymerization.” Ind. Eng. Chem. Res., 45(10), 3559–3568.
Wang, K., Shah, S. P., and Mishulovich, A. (2004). “Effects of curing temperature and NaOH addition on hydration and strength development of clinker-free CKD-fly ash binders.” Cem. Concr. Res., 34(2), 299–309.
Wu, H.-C., and Sun, P. (2007). “New building materials from fly ash-based lightweight inorganic polymer.” Constr. Build. Mater., 21(1), 211–217.
Yang, K.-H., Mun, J.-H., Sim, J.-I., and Song, J.-K. (2011). “Effect of water content on the properties of lightweight alkali-activated slag concrete.” J. Mater. Civ. Eng., 886–894.
Yang, K.-H., Song, J.-K., and Lee, J.-S. (2010). “Properties of alkali-activated mortar and concrete using lightweight aggregates.” Mater. Struct., 43(3), 403–416.
Yip, C. K., Lukey, G. C., and van Deventer, J. S. J. (2005). “The coexistence of geopolymeric gel and calcium silicate hydrate at the early stage of alkaline activation.” Cem. Concr. Res., 35(9), 1688–1697.
Yu, Q. L., Spiesz, P., and Brouwers, H. J. H. (2013). “Development of cement-based lightweight composites. 1: Mix design methodology and hardened properties.” Cem. Concr. Compos., 44, 17–29.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 30Issue 4April 2018

History

Received: May 16, 2017
Accepted: Sep 19, 2017
Published online: Jan 17, 2018
Published in print: Apr 1, 2018
Discussion open until: Jun 17, 2018

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Authors

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Najif Ismail, Ph.D.
Assistant Professor, Dept. of Civil and Environmental Engineering, United Arab Emirates Univ., P.O. Box 15551, Al Ain, United Arab Emirates.
Hilal El-Hassan, Ph.D., M.ASCE [email protected]
Assistant Professor, Dept. of Civil and Environmental Engineering, United Arab Emirates Univ., P.O. Box 15551, Al Ain, United Arab Emirates (corresponding author). E-mail: [email protected]

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