TECHNICAL PAPERS
Mar 1, 2006

Bioavailability Prediction of Polycyclic Aromatic Hydrocarbons in Field-Contaminated Sediment by Mild Extractions

Publication: Journal of Environmental Engineering
Volume 132, Issue 3

Abstract

Assessing the bioavailability of a group of polycyclic aromatic hydrocarbons (PAHs) coexisting in a field-aged contaminated sediment was examined using mild extractions by isopropanol- and ethanol-water solutions at concentrations of 5–100%, using extraction durations from 1hto7days . At a given solvent concentration, an initial rapid phase of PAH desorption was generally observed during the first 12h , followed by a subsequent slower phase of desorption. A similar biphasic desorption was evident with increases in solvent concentration. PAH removal by various mild extractions was compared with PAH biodegradation by indigenous microorganisms. The removal of individual PAHs using 1-day 70% ethanol extraction was closely correlated to corresponding PAH removal via biodegradation, suggesting the possibility of using alcohol-water solution to simultaneously predict the bioavailability of multiple PAHs in aged sediments to indigenous microorganisms.

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Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 132Issue 3March 2006
Pages: 384 - 391

History

Received: Sep 15, 2003
Accepted: May 23, 2005
Published online: Mar 1, 2006
Published in print: Mar 2006

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Authors

Affiliations

Process Engineer, Damon S. Williams Associates, 2355 E. Camelback Rd., Suite 700, Phoenix, AZ, 85249 (corresponding author). E-mail: [email protected]
Rajesh Bagchi [email protected]
MS Student, Dept. of Civil and Environmental Engineering, Univ. of Cincinnati, Cincinnati, OH 45221-0071. E-mail: [email protected]
Amid P. Khodadoust [email protected]
Professor, Dept. of Civil & Materials Engineering, Univ. of Illinois at Chicago, 842 West Taylor Street, Chicago, IL 60607. E-mail: [email protected]
Makram T. Suidan [email protected]
Professor, 701 ERC, Dept. of Civil & Environmental Engineering, Univ. of Cincinnati, Cincinnati, OH 45221-0071. E-mail: [email protected]
Henry H. Tabak [email protected]
Senior Chemist, Environment Research Center, National Risk Management Research Laboratory, EPA, 26 West Martin Luther King Drive, Cincinnati, OH 45268. E-mail: [email protected]

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