Abstract

A new cement based on belitic calcium sulfoaluminate (BCSA) was investigated, which featured a unique combination of advantages such as fast setting time, increased tensile strength, and net positive expansion over conventional, commercial BCSA and portland cements. These advantages are achieved by combining commercially available BCSA and mixing the cement with pure, finely ground anhydrite. Mortar bars prepared using this new cement (referred to as supersulfated BCSA or SBCSA) achieve nearly seven times the expansion of conventional BCSA at 28 days. SBCSA concrete exhibits restrained and unrestrained expansions greater by nearly eight times compared with standard BCSA concrete at 28 days. The compressive and flexural strengths of SBCSA concretes are nearly 50% and up to 25% higher compared with BCSA, according to standard test methods. The use of cut-sheet continuously deformed steel fibers in the SBCSA concrete mixes at a dosage of 0.75% shows only minor improvements in terms of restrained expansions and flexural strengths. X-ray diffraction (XRD) analysis showed that the amount of ettringite increased by nearly 30%, and the hydration of belite is enhanced in SBCSA at 28 days compared with BCSA. Due to the unique combination of expansive and fast-setting characteristics, SBCSA offers a potential opportunity to improve the structural design of portland cement concrete. For example, the combination of high early strength and expansion allows the concrete to sustain expansions typically destructive in portland-based expansive cements.

Get full access to this article

View all available purchase options and get full access to this article.

Data Availability Statement

All data, models, and code generated or used during the study appear in the published article.

Acknowledgments

The authors would like to thank Danny Chung for his help with designing mixture proportions, preparing mortar and concrete mixes, and testing physical and mechanical properties of several concrete mixtures consisting of BCSA and the SBCSA cements.

References

ASTM. 2021a. Standard specification for concrete aggregates. ASTM C33. West Conshohocken, PA: ASTM.
ASTM. 2021b. Standard specification for expansive hydraulic cement. ASTM C845. West Conshohocken, PA: ASTM.
ASTM. 2021c. Standard specification for mixing rooms, moist cabinets, moist rooms, and water storage tanks used in the testing of hydraulic cements and concretes. ASTM C511. West Conshohocken, PA: ASTM.
ASTM. 2021d. Standard specification for rapid hardening hydraulic cement. ASTM C1600. West Conshohocken, PA: ASTM.
ASTM. 2021e. Standard specification for standard sand. ASTM C778. West Conshohocken, PA: ASTM.
ASTM. 2021f. Standard test method for compressive strength of cylindrical concrete specimens. ASTM C39. West Conshohocken, PA: ASTM.
ASTM. 2021g. Standard test method for compressive strength of hydraulic cement mortars (using 2-in. or [50 mm] cube specimens). ASTM C109. West Conshohocken, PA: ASTM.
ASTM. 2021h. Standard test method for flexural strength of concrete (using simple beam with third-point loading). ASTM C78. West Conshohocken, PA: ASTM.
ASTM. 2021i. Standard test method for length change of hardened hydraulic-cement mortar and concrete. ASTM C157. West Conshohocken, PA: ASTM.
ASTM. 2021j. Standard test method for restrained expansion of expansive cement mortar. ASTM C806. West Conshohocken, PA: ASTM.
ASTM. 2021k. Standard test method for restrained expansion of shrinkage-compensating concrete. ASTM C878. West Conshohocken, PA: ASTM.
ASTM. 2021l. Standard test methods for fineness of hydraulic cement by air-permeability apparatus. ASTM C204. West Conshohocken, PA: ASTM.
ASTM. 2021m. Standard test methods for mechanical mixing of hydraulic cement pastes and mortars of plastic consistency. ASTM C305. West Conshohocken, PA: ASTM.
Bescher, E., and J. Kim. 2019. “Belitic calcium sulfoaluminate cement: History, chemistry, performance, and use in the United States.” In Proc., 1st Int. Conf. on Innovation in Low-Carbon Cement and Concrete Technology. Garden Grove, CA: CTS Cement Manufacturing Corporation.
Bescher, E. P., J. Kim, and M. McNerney. 2020. “On the differences in chemistry and performance between types of rapid strength concretes (RSCs).” In Proc., 120th Int. Conf. on Concrete Pavement. Garden Grove, CA: CTS Cement Manufacturing Corporation.
Bizzozero, J., C. Gosselin, and K. Scrivener. 2014. “Expansion mechanisms in calcium aluminate and sulfoaluminate systems with calcium sulfate.” Cem. Concr. Res. 56 (Aug): 190–202. https://doi.org/10.1016/j.cemconres.2013.11.011.
Chaunsali, P. 2015. “Early-age hydration and volume change of calcium sulfoaluminate cement-based binders.” Ph.D. thesis, Dept. of Civil and Environmental Engineering, Univ. of Illinois at Urbana–Champaign.
Chen, I. A., C. W. Hargis, and M. C. G. Juenger. 2012. “Understanding expansion in calcium sulfoaluminate-belite cements.” Cem. Concr. Res. 42 (1): 51–60. https://doi.org/10.1016/j.cemconres.2011.07.010.
Chen, I. A., and M. C. G. Juenger. 2011. “Synthesis and hydration of calcium sulfoaluminate-belite cements with varied phase compositions.” J. Mater. Sci. 46 (8): 2568–2577. https://doi.org/10.1007/s10853-010-5109-9.
Damtoft, J. S., J. Lukasik, D. Herfort, D. Sorrentino, and E. M. Gartner. 2008. “Sustainable development and climate change initiatives.” Cem. Concr. Res. 38 (2): 115–127. https://doi.org/10.1016/j.cemconres.2007.09.008.
Desbois, T., R. Le-Roy, A. Pavoine, G. Platret, A. Feraille, and A. Alaoui. 2010. “Effect of gypsum content on sulfoaluminate mortars stability.” Eur. J. Environ. Civ. Eng. 14 (5): 579–597. https://doi.org/10.1080/19648189.2010.9693248.
Glasser, F. P., and L. Zhang. 2001. “High-performance cement matrices based on calcium sulfoaluminate-belite compositions.” Cem. Concr. Res. 31 (12): 1881–1886. https://doi.org/10.1016/S0008-8846(01)00649-4.
Han, J., D. Jia, and P. Yan. 2016. “Understanding the shrinkage compensating ability of type K expansive agent in concrete.” Constr. Build. Mater. 116 (Jul): 36–44. https://doi.org/10.1016/j.conbuildmat.2016.04.092.
Juenger, M. C. G., F. Winnefeld, J. L. Provis, and J. H. Idekar. 2011. “Advances in alternative cementitious binders.” Cem. Concr. Res. 41 (12): 1232–1243. https://doi.org/10.1016/j.cemconres.2010.11.012.
Kasselouri, V., P. Tsakiridis, B. MalamiGeorgaliGeorgali, and C. Alexandridou. 1995. “A study on the hydration products of a non-expansive sulfoaluminate cement.” Cem. Concr. Res. 25 (8): 1726–1736. https://doi.org/10.1016/0008-8846(95)00168-9.
Klein, A., T. Karby, and M. Polivka. 1961. “Properties of an expansive cement for chemical prestressing.” ACI J. Proc. 58 (Mar): 59–62. https://doi.org/10.14359/7974.
Le Saout, G., B. Lothenbach, A. Hori, T. Higuchi, and F. Winnefeld. 2013. “Hydration of portland cement with additions of calcium sulfoaluminates.” Cem. Concr. Res. 43 (Feb): 81–94. https://doi.org/10.1016/j.cemconres.2012.10.011.
Liu, Y. J., Y. M. Xu, and C. L. Geng. 2011. “Sulfoaluminate cement: An alternative to portland cement.” Adv. Mater. Res. 368–373 (Oct): 478–484. https://doi.org/10.4028/www.scientific.net/AMR.368-373.478.
Mehta, P. K., and A. Klein. 1966. Investigations on the hydration products in system 4CaO.3Al2O3.SO3-CaSO4-CaO-H2O, 328–352. Washington, DC: Highway Research Board.
Miller, S. A., A. Horvath, and P. J. M. Monteiro. 2016. “Readily implementable techniques can cut annual CO2 emissions from the production of concrete by over 20%.” Environ. Res. Lett. 11 (7): 074029. https://doi.org/10.1088/1748-9326/11/7/074029.
Ogawa, K., and D. M. Roy. 1982. “C4A3S hydration, ettringite formation, and its expansion mechanisms: III, Effect of CaO, NaOH, and NaCl; conclusions.” Cem. Concr. Res. 12 (2): 247–256. https://doi.org/10.1016/0008-8846(82)90011-4.
Roswurn, S. J., and C. Ramseyer. 2019. “Developing large slab airport runways for the next century.” Transp. Res. Rec. 2673 (6): 525–535. https://doi.org/10.1177/0361198119849577.
Sahu, S., J. Havlica, V. Tomková, and J. Majling. 1991. “Hydration behaviour of sulphoaluminate belite cement in the presence of various calcium sulphates.” Thermochem. Acta 175 (1): 45–52. https://doi.org/10.1016/0040-6031(91)80244-D.
Winnefeld, F., and S. Barlag. 2010. “Calorimetric and thermogravimetric study on the influence of calcium sulfate on the hydration of ye’elimite.” J. Therm. Anal. Calorim. 101 (3): 949–957. https://doi.org/10.1007/s10973-009-0582-6.
Zhang, J., X. Guan, X. Wang, X. Ma, Z. Li, Z. Xu, and B. Jin. 2020. “Microstructure and properties of sulfoaluminate cement-based grouting materials: Effect of calcium sulfate variety.” Adv. Mater. Sci. Eng. 2020 (Apr): 7564108. https://doi.org/10.1155/2020/7564108.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 35Issue 11November 2023

History

Received: Nov 10, 2022
Accepted: Apr 21, 2023
Published online: Sep 4, 2023
Published in print: Nov 1, 2023
Discussion open until: Feb 4, 2024

Permissions

Request permissions for this article.

Authors

Affiliations

Research Manager, Pavement and Infrastructure, CTS Cement Manufacturing Corp., 12422 Knott St., Garden Grove, CA 92841 (corresponding author). ORCID: https://orcid.org/0000-0003-0588-6552. Email: [email protected]
Neel Bhuskute [email protected]
Research Engineer, Pavement and Infrastructure, CTS Cement Manufacturing Corp., 12422 Knott St., Garden Grove, CA 92841. Email: [email protected]
Pavement Engineer, Pavement and Infrastructure, CTS Cement Manufacturing Corp., 12422 Knott St., Garden Grove, CA 92841. ORCID: https://orcid.org/0000-0003-4062-5454. Email: [email protected]
Javier Guijosa [email protected]
Laboratory Analyst, CTS Cement Manufacturing Corp., 12422 Knott St., Garden Grove, CA 92841. Email: [email protected]
Janeth Rivera [email protected]
Laboratory Analyst, CTS Cement Manufacturing Corp., 12422 Knott St., Garden Grove, CA 92841. Email: [email protected]
Adjunct Professor, Dept. of Materials Science and Engineering, Univ. of California, Los Angeles, CA 90024. ORCID: https://orcid.org/0000-0001-5079-6279. Email: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share