Technical Papers
Sep 5, 2023

Effect of Cement Type and Water-to-Binder Ratio on k-value of Low-Calcium Fly Ash for Concrete Compressive Strength

Publication: Journal of Materials in Civil Engineering
Volume 35, Issue 11

Abstract

The present study assessed the effect of cement type and water-to-binder ratio (W/B) on the cementing efficiency factor (k-value) of low-calcium fly ash (FA) for the compressive strength of concrete in a chemical approach. The results indicated that the k-values increased with an increase in the FA reaction degree for each cement type. Despite the higher FA reaction degree in high-early-strength Portland cement (HSPC) paste, the k-value in the HSPC concrete was lower than that in OPC (ordinary Portland cement) concrete. For OPC concrete, a lower W/B has a higher k-value at the early ages mainly because of cement hydration that is enhanced by FA, and all the k-values increased significantly after 28 days due to the pozzolanic reaction of FA. A modified equation of portlandite consumption for the FA reaction assessment that considers the cement-hydration-enhancement effect was proposed to assess the FA reaction degree more appropriately than the conventional one.

Get full access to this article

View all available purchase options and get full access to this article.

Data Availability Statement

All data, models, and code generated or used during the study appear in the published article.

Acknowledgments

The authors are grateful to Mr. Yuki Miyoshi, former master’s student, and other students of the Structural Materials and Concrete Structures Laboratory of Hiroshima University for their assistance during the experimental campaign. This research was partially supported by JSPS KAKENHI Grant, Grant-in-Aid for Young Scientists (B) No. JP17K14708.

References

ASTM. 2003. Standard specification for coal fly ash and raw or calcined natural pozzolan for use in concrete. ASTM C618. West Conshohocken, PA: ASTM.
Babu, K. G., and G. S. N. Rao. 1996. “Efficiency of fly ash in concrete with age.” Cem. Concr. Res. 26 (3): 465–474. https://doi.org/10.1016/0008-8846(96)00011-7.
Berry, E. E., R. T. Hemmings, and B. J. Cornelius. 1990. “Mechanisms of hydration reactions in high volume fly ash pastes and mortars.” Cem. Concr. Compos. 12 (4): 253–261. https://doi.org/10.1016/0958-9465(90)90004-H.
Bijen, J. 1996. “Benefits of slag and fly ash.” Constr. Build. Mater. 10 (5): 309–314. https://doi.org/10.1016/0950-0618(95)00014-3.
Bijen, J., and R. V. Selst. 1993. “Cement equivalence factors for fly ash.” Cem. Concr. Res. 23 (5): 1029–1039. https://doi.org/10.1016/0008-8846(93)90162-3.
Bostanci, S. C., M. Limbachiya, and H. Kew. 2016. “Portland slag and composites cement concretes: Engineering and durability properties.” J. Cleaner Prod. 112 (Jan): 542–552. https://doi.org/10.1016/j.jclepro.2015.08.070.
Bui, P. T., Y. Ogawa, and K. Kawai. 2018. “Long-term pozzolanic reaction of fly ash in hardened cement-based paste internally activated by natural injection of saturated Ca(OH)2 solution.” Mater. Struct. 51 (6): 1–14. https://doi.org/10.1617/s11527-018-1274-0.
Bui, P. T., Y. Ogawa, K. Nakarai, and K. Kawai. 2015. “A study on pozzolanic reaction of fly ash cement paste activated by an injection of alkali solution.” Constr. Build. Mater. 94 (Sep): 28–34. https://doi.org/10.1016/j.conbuildmat.2015.06.046.
CEN (European Committee for Standardization). 2000. Concrete—Part 1: Specification, performance, production and conformity. EN 206-1. Brussels, Belgium: CEN.
Chen, C., G. Habert, Y. Bouzidi, and A. Jullien. 2010. “Environmental impact of cement production: Detail of the different processes and cement plant variability evaluation.” J. Cleaner Prod. 18 (5): 478–485. https://doi.org/10.1016/j.jclepro.2009.12.014.
De la Varga, I., J. Castro, D. P. Bentz, F. Zunino, and J. Weiss. 2018. “Evaluating the hydration of high volume fly ash mixtures using chemically inert fillers.” Constr. Build. Mater. 161 (Feb): 221–228. https://doi.org/10.1016/j.conbuildmat.2017.11.132.
De Weerdt, K., M. Ben Haha, G. Le Saout, K. O. Kjellsen, H. Justnes, and B. Lothenbach. 2011. “Hydration mechanisms of ternary Portland cements containing limestone powder and fly ash.” Cem. Concr. Res. 41 (3): 279–291. https://doi.org/10.1016/j.cemconres.2010.11.014.
Durdzinski, P. T., et al. 2017. “Outcomes of the RILEM round robin on degree of reaction of slag and fly ash in blended cements.” Mater. Struct. 50 (Apr): 135. https://doi.org/10.1617/s11527-017-1002-1.
Evi Aprianti, S. 2017. “A huge number of artificial waste material can be supplementary cementitious material (SCM) for concrete production—A review part II.” J. Cleaner Prod. 142 (Jan): 4178–4194. https://doi.org/10.1016/j.jclepro.2015.12.115.
Feldman, R. F., G. G. Carette, and V. M. Malhotra. 1990. “Studies on mechanics of development of physical and mechanical properties of high-volume fly ash-cement pastes.” Cem. Concr. Compos. 12 (4): 245–251. https://doi.org/10.1016/0958-9465(90)90003-G.
Fraay, A. L. A., J. M. Bijen, and Y. M. de Haan. 1989. “The reaction of fly ash in concrete a critical examination.” Cem. Concr. Res. 19 (2): 235–246. https://doi.org/10.1016/0008-8846(89)90088-4.
Hanehara, S., F. Tomosawa, M. Kobayakawa, and K. Hwang. 2001. “Effects of water/powder ratio, mixing ratio of fly ash, and curing temperature on pozzolanic reaction of fly ash in cement paste.” Cem. Concr. Res. 31 (1): 31–39. https://doi.org/10.1016/S0008-8846(00)00441-5.
Hedegaard, S. E., and T. C. Hansen. 1992. “Modified water/cement ratio law for compressive strength of fly ash concretes.” Mater. Struct. 25 (5): 273–283. https://doi.org/10.1007/BF02472668.
Hemalatha, T., and A. Ramaswamy. 2017. “A review on fly ash characteristics—Towards promoting high volume utilization in developing sustainable concrete.” J. Cleaner Prod. 147 (Mar): 546–559. https://doi.org/10.1016/j.jclepro.2017.01.114.
Hwang, K., T. Noguchi, and F. Tomosawa. 2004. “Prediction model of compressive strength development of fly-ash concrete.” Cem. Concr. Res. 34 (12): 2269–2276. https://doi.org/10.1016/j.cemconres.2004.04.009.
JSA (Japanese Standards Association). 1999. Fly ash for concrete. JIS A 6201. Tokyo: JSA.
JSA (Japanese Standards Association). 2009. Portland cement. JIS R 5210. Tokyo: JSA.
JSA (Japanese Standards Association). 2013. Method of test for compressive strength of concrete. JIS A 1108. Tokyo: JSA.
JSA (Japanese Standards Association). 2014a. Method of test for air content of fresh concrete by pressure method. JIS A 1128. Tokyo: JSA.
JSA (Japanese Standards Association). 2014b. Method of test for slump of concrete. JIS A 1101. Tokyo: JSA.
JSCE (Japan Society of Civil Engineers). 2009. New utilization technologies of fly ash concrete suitable for recycle oriented society. [In Japanese.]. Tokyo: JSCE.
Kuder, K., D. Lehman, J. Berman, G. Hannesson, and R. Shogren. 2012. “Mechanical properties of self consolidating concrete blended with high volumes of fly ash and slag.” Constr. Build. Mater. 34 (Sep): 285–295. https://doi.org/10.1016/j.conbuildmat.2012.02.034.
Lam, L., Y. Wong, and C. Poon. 2000. “Degree of hydration and gel/space ratio of high-volume fly ash/cement systems.” Cem. Concr. Res. 30 (5): 747–756. https://doi.org/10.1016/S0008-8846(00)00213-1.
Li, S., D. M. Roy, and A. Kumar. 1985. “Quantatative determination of pozzolanas in hydrated systems of cement or Ca(OH)2 with fly ash or silica fume.” Cem. Concr. Res. 15 (6): 1079–1086. https://doi.org/10.1016/0008-8846(85)90100-0.
Lollini, F., E. Redaelli, and L. Bertolini. 2016. “A study on the applicability of the efficiency factor of supplementary cementitious materials to durability properties.” Constr. Build. Mater. 120 (Sep): 284–292. https://doi.org/10.1016/j.conbuildmat.2016.05.031.
Lothenbach, B., G. Le Saout, E. Gallucci, and K. Scrivener. 2008. “Influence of limestone on the hydration of portland cements.” Cem. Concr. Res. 38 (6): 848–860. https://doi.org/10.1016/j.cemconres.2008.01.002.
Malhotra, V. M. 1990. “Durability of concrete incorporating high-volume of low-calcium (ASTM Class F) fly ash.” Cem. Concr. Compos. 12 (4): 271–277. https://doi.org/10.1016/0958-9465(90)90006-J.
Martin, L. H. J., F. Winnefeld, E. Tschopp, C. J. Müller, and B. Lothenbach. 2017. “Influence of fly ash on the hydration of calcium sulfoaluminate cement.” Cem. Concr. Res. 95 (May): 152–163. https://doi.org/10.1016/j.cemconres.2017.02.030.
Matschei, T., B. Lothenbach, and F. P. Glasser. 2007. “The role of calcium carbonate in cement hydration.” Cem. Concr. Res. 37 (4): 551–558. https://doi.org/10.1016/j.cemconres.2006.10.013.
Moon, G. D., S. Oh, and Y. C. Choi. 2016. “Effects of the physicochemical properties of fly ash on the compressive strength of high-volume fly ash mortar.” Constr. Build. Mater. 124 (Oct): 1072–1080. https://doi.org/10.1016/j.conbuildmat.2016.08.148.
Ogawa, Y., K. Uji, A. Ueno, and K. Kawai. 2021. “Contribution of fly ash to the strength development of mortars cured at different temperatures.” Const. Build. Mater. 276 (Mar): 122191. https://doi.org/10.1016/j.conbuildmat.2020.122191.
Ohsawa, S., K. Asaga, S. Goto, and M. Daimon. 1985. “Quantitative determination of fly ash in the hydrated fly ash—CaSO4·2H2O-Ca(OH)2 system.” Cem. Concr. Res. 15 (2): 357–366. https://doi.org/10.1016/0008-8846(85)90047-X.
Oner, A., S. Akyuz, and R. Yildiz. 2005. “An experimental study on strength development of concrete containing fly ash and optimum usage of fly ash in concrete.” Cem. Concr. Res. 35 (6): 1165–1171. https://doi.org/10.1016/j.cemconres.2004.09.031.
Papadakis, V. G., and S. Tsimas. 2002a. “Supplementary cementing materials in concrete: Part I: Efficiency and design.” Cem. Concr. Res. 32 (10): 1525–1532. https://doi.org/10.1016/S0008-8846(02)00827-X.
Papadakis, V. G., and S. Tsimas. 2002b. “Supplementary cementing materials in concrete: Part II: A fundamental estimation of the efficiency factor.” Cem. Concr. Res. 32 (10): 1533–1538. https://doi.org/10.1016/S0008-8846(02)00829-3.
Rajamane, N. P., J. A. Peter, and P. S. Ambily. 2007. “Prediction of compressive strength of concrete with fly ash as sand replacement material.” Cem. Concr. Compos. 29 (3): 218–223. https://doi.org/10.1016/j.cemconcomp.2006.10.001.
Sakai, E., S. Miyahara, S. Ohsawa, S. H. Lee, and M. Daimon. 2005. “Hydration of fly ash cement.” Cem. Concr. Res. 35 (6): 1135–1140. https://doi.org/10.1016/j.cemconres.2004.09.008.
Schöler, A., B. Lothenbach, F. Winnefeld, and M. Zajac. 2015. “Hydration of quaternary Portland cement blends containing blast-furnace slag, siliceous fly ash and limestone powder.” Cem. Concr. Compos. 55 (Jan): 374–382. https://doi.org/10.1016/j.cemconcomp.2014.10.001.
Scrivener, K., R. Snellings, and B. Lothenbach. 2016. A practical guide to microstructural analysis of cementitious materials. 1st ed. Boca Raton, FL: CRC Press.
Smith, I. A. 1967. “The design of fly-ash concretes.” Proc. Inst. Civ. Eng. 36 (4): 769–790. https://doi.org/10.1680/iicep.1967.8472.
Supit, S. W. M., and F. U. A. Shaikh. 2015. “Durability properties of high volume fly ash concrete containing nano-silica.” Mater. Struct. 48 (Aug): 2431–2445. https://doi.org/10.1617/s11527-014-0329-0.
Termkhajornkit, P., T. Nawa, M. Nakai, and T. Saito. 2005. “Effect of fly ash on autogenous shrinkage.” Cem. Concr. Res. 35 (3): 473–482. https://doi.org/10.1016/j.cemconres.2004.07.010.
Yang, K.-H., Y.-B. Jung, M.-S. Cho, and S.-H. Tea. 2015. “Effect of supplementary cementitious materials on reduction of CO2 emissions from concrete.” J. Cleaner Prod. 103 (Sep): 774–783. https://doi.org/10.1016/j.jclepro.2014.03.018.
Zeng, Q., and K. Li. 2015. “Reaction and microstructure of cement–fly-ash system.” Mater. Struct. 48 (Jun): 1703–1716. https://doi.org/10.1617/s11527-014-0266-y.
Zeng, Q., K. Li, T. Fen-chong, and P. Dangla. 2012. “Determination of cement hydration and pozzolanic reaction extents for fly-ash cement pastes.” Constr. Build. Mater. 27 (1): 560–569. https://doi.org/10.1016/j.conbuildmat.2011.07.007.
Zhang, Y. M., W. Sun, and H. D. Yan. 2000. “Hydration of high-volume fly ash cement pastes.” Cem. Concr. Compos. 22 (6): 445–452. https://doi.org/10.1016/S0958-9465(00)00044-5.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 35Issue 11November 2023

History

Received: Sep 7, 2022
Accepted: Apr 21, 2023
Published online: Sep 5, 2023
Published in print: Nov 1, 2023
Discussion open until: Feb 5, 2024

Permissions

Request permissions for this article.

Authors

Affiliations

Ph.D. Student, Dept. of Civil and Environmental Engineering, Graduate School of Engineering, Hiroshima Univ., 1-4-1, Kagamiyama, Higashi-Hiroshima City 739-8527, Japan; Lecturer, Faculty of Civil Engineering, Ho Chi Minh City Univ. of Technology (HCMUT), 268 Ly Thuong Kiet St., District 10, Ho Chi Minh City 700000, Vietnam; Vietnam National Univ. Ho Chi Minh City, Linh Trung Ward, Thu Duc City, Ho Chi Minh City 700000, Vietnam. ORCID: https://orcid.org/0000-0002-6887-0091
Assistant Professor, Civil and Environmental Engineering Program, Graduate School of Advanced Science and Engineering, Hiroshima Univ., 1-4-1, Kagamiyama, Higashi-Hiroshima City 739-8527, Japan (corresponding author). ORCID: https://orcid.org/0000-0003-0581-1139. Email: [email protected]
Professor, Civil and Environmental Engineering Program, Graduate School of Advanced Science and Engineering, Hiroshima Univ., 1-4-1, Kagamiyama, Higashi-Hiroshima City 739-8527, Japan. ORCID: https://orcid.org/0000-0002-3752-4161
Lecturer, Faculty of Civil Engineering, Ho Chi Minh City Univ. of Technology (HCMUT), 268 Ly Thuong Kiet St., District 10, Ho Chi Minh City 700000, Vietnam; Vietnam National Univ. Ho Chi Minh City, Linh Trung Ward, Thu Duc City, Ho Chi Minh City 700000, Vietnam. ORCID: https://orcid.org/0000-0001-9443-2397

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share