Technical Papers
May 18, 2017

Adhesion Evaluation of Duplex Paint System for Sustainable Infrastructure

Publication: Journal of Materials in Civil Engineering
Volume 29, Issue 9

Abstract

Organic paints are applied to galvanized or metalized steel surfaces in a duplex system, which is potentially more sustainable than the zinc-rich primer/steel system. A series of experimental tests were performed to measure and investigate adhesion strengths on three different types of roughened zinc surfaces. The contact angles were also measured for freshly formulated liquid paints on the roughened zinc surfaces to test if there is a correlation between the paint wetting property and the adhesive strengths. By comparing duplex system and zinc-rich primer/steel qualified North East Protective Coating (NEPCOAT) panels, it was found that the paint adhesion of the duplex system is as strong as the zinc primer/steel panels test results. The results also showed that adhesive strengths depend on the match between the paint and type of roughened zinc surfaces. The measurement of liquid paint wetting properties indicates small contact angles correlate with stronger pull-off adhesive strength. The authors of this study suggest that contact angle/strength correlation could be useful as a tool for optimizing the match between the paints and the profiled zinc surface.

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Acknowledgments

This research project was sponsored by NETC under project 05-5 administered by FHWA CT Division Office. Details of the experimental data and the full report are available from NETC (http://www.uvm.edu/trc/netc/). The authors thank the NETC05-5 technical committee members for their guidance throughout the research project: Jerry McMahan, Vermont Agency of Transportation, Chairperson; Jerry Zoller, New Hampshire DOT; Denis Dubois, Maine DOT; Andrew J. Mroczkowski, Connecticut DOT; Willie Feliciano, New York DOT; Mary Grieco, Massachusetts Highway Department; and Colin Franco, Rhode Island DOT. The authors thank the following persons for their generous help: Michael Hewins, Massachusetts Highway Department; Michael Sock, Rhode Island DOT; and Richard Brown, Department of Chemical Engineering, URI. The authors also thank the anonymous reviewers who suggested useful clarifications including the threshold model discussed in the main text.

References

American Welding Society. (2003). “Specification for the application of thermal spray coatings (metallizing) of aluminum, zinc, and their alloys and composites for the corrosion protection of steel.”, Miami.
ASTM. (2009). “Standard test method for pull-off strength of coatings using portable adhesion testers.” ASTM D4541, West Conshohocken, PA.
ASTM. (2015). “Standard specification for Zinc (Hot-Dip Galvanized) coatings on iron and steel.” ASTM A123, West Conshohocken, PA.
ASTM. (2017). “Standard test methods for rating adhesion by tape test.” ASTM D3359, West Conshohocken, PA.
Bonn, D. J., Eggers, J., Indekeu, J., Meunier, E., and Rolley, E., E. (2009). “Wetting and spreading.” Rev. Mod. Phys., 81(2), 739–805.
Cassie, A. B. D., and Baxter, S. (1944). “Wettability of porous surfaces.” Trans. Faraday Soc., 40, 546–551.
Chow, T. S. (1998). “Wetting of rough surfaces.” J. Phys. Condens. Matter, 10(27), L445.
de Gennes, P. G. (1985). “Wetting: Statics and dynamics.” Rev. Mod. Phys., 57(3), 827–863.
DROP [Computer software]. Ramé-Hart Instrument Co., Succasunna, NJ.
NEPCOAT (North East Protective Coating Committee). (2017). “Qualified products for protective coatings for new and 100% bare existing steel for bridges.” ⟨http://www.nepcoat.org/qualprod.htm⟩ (Apr. 20, 2017).
Petrie, E. (2012). “Fundamentals of paint adhesion.” ⟨http://www.materialstoday.com/metal-finishing/features/fundamentals-of-paint-adhesion/⟩ (May 22, 2012).
Spori, D. M., et al. (2008). “Beyond the lotus effect: Roughness influences on wetting over a wide surface-energy range.” Langmuir, 24(10), 5411–5417.
Wan, Y., Wang, Z., Xu, Z., Liu, C., and Zhang, J. (2011). “Fabrication and wear protection performance of superhydrophobic surface on zinc.” Appl. Surf. Sci., 257(17), 7486–7489.
Wenzel, R. N. (1936). “Resistance of solid surfaces to wetting by water.” Ind. Eng. Chem., 28(8), 988–994.
Yang, S. C., Lee, K. W., Mirville, M., Lu, C., and Pahram, A. (2013). “Measurement of adhesion properties between topcoat paint and metallized/galvanized steel with surface energy measurement equipment.” ⟨http://www.uvm.edu/~transctr/pdf/netc/NETCR93_05-5_with_bookmarks.pdf⟩ (Apr. 20, 2017).
Zisman, W. A. (1964). “Relation of the equilibrium contact angle to liquid and solid constitution.” ACS Symp. Series: Advances in Chemistry, topic “Conact Angle, Wettability and Adhesion,” Vol. 43, American Chemical Society, Washington, DC, 1–51.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 29Issue 9September 2017

History

Received: Jun 7, 2016
Accepted: Dec 6, 2016
Published online: May 18, 2017
Published in print: Sep 1, 2017
Discussion open until: Oct 18, 2017

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Authors

Affiliations

Sze Yang, Ph.D. [email protected]
Professor of Chemistry, Univ. of Rhode Island, Kingston, RI 02881. E-mail: [email protected]
K. Wayne Lee, Ph.D., F.ASCE [email protected]
P.E.
Professor and Director of RI Transportation Research Center, Dept. of Civil and Environment Engineering, Univ. of Rhode Island, Kingston, RI 02881 (corresponding author). E-mail: [email protected]
Graduate Student, Dept. of Chemistry, Univ. of Rhode Island, Kingston, RI 02881. E-mail: [email protected]
Maureen Mirville [email protected]
Research Assistant, Dept. of Chemistry, Univ. of Rhode Island, Kingston, RI 02881. E-mail: [email protected]
Anthony Parham [email protected]
Graduate Student, Dept. of Chemistry, Univ. of Rhode Island, Kingston, RI 02881. E-mail: [email protected]

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