TECHNICAL PAPERS
Jan 7, 2011

Preparation of TiO2/Hydroxyapatite Composite and Its Photocatalytic Degradation of Methyl Orange

Publication: Journal of Environmental Engineering
Volume 137, Issue 7

Abstract

A TiO2/hydroxyapatite composite (Ti-HAP) was prepared by a hydrothermal method with hydroxyapatite and titanium sulfate and tested for photocatalytic degradation of methyl orange with an 8 W ultraviolet (UV) lamp irradiation. The properties of Ti-HAP were characterized by X-ray diffraction, scanning electron microscope, and Fourier transform infrared spectroscopy (FT-IR) analysis. The effect of the Ti/(Ca+Ti) mole ratio on the photocatalytic degradation efficiency of methyl orange by Ti-HAP and the photocatalytic degradation dynamics were investigated. The results show that the addition of Ti slightly changes the structure of HAP. A higher Ti/(Ca+Ti) mole ratio results in the generation of anatase in Ti-HAP and higher removal efficiency of methyl orange by Ti-HAP under UV irradiation. The removal efficiency decreases with the initial content of methyl orange increasing from 10200mg/L. The photocatalytic degradation process of methyl orange by Ti-HAP and HAP follow the Langmuir-Hinshelwood kinetics model.

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Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 137Issue 7July 2011
Pages: 611 - 616

History

Received: May 9, 2010
Accepted: Jan 5, 2011
Published online: Jan 7, 2011
Published in print: Jul 1, 2011

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Guanghong Sheng [email protected]
Associate Professor, School of Architecture and Civil Engineering, Anhui Univ. of Technology, Maanshan 243002, Anhui, China (corresponding author). E-mail: address: [email protected]
Lili Qiao
Graduate Student, School of Architecture and Civil Engineering, Anhui Univ. of Technology, Maanshan 243002, Anhui, China.
Yaqin Mou
Graduate Student, School of Architecture and Civil Engineering, Anhui Univ. of Technology, Maanshan 243002, Anhui, China.

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