TECHNICAL PAPERS
Nov 15, 2010

Removal of Trichlorobenzene from Flue Gas Using Complex Absorbent

Publication: Journal of Environmental Engineering
Volume 136, Issue 12

Abstract

The present study attempts to clean up 1,2,4-trichlorobenzene (TCB) vapor of the flue gas from the laboratory-scale bubbling reactor. Experiments were carried out to examine the effects of input TCB vapor concentration, pH of reaction medium, reaction temperature, and the other experimental conditions on TCB removal efficiency. The optimum experimental conditions for removing 1,2,4-TCB are that the ratio of NaClO2/NaClO in complex absorbent is 2, reaction temperature is 50°C , and pH of reaction medium is 8. TCB removal efficiency above 90% was achieved under the optimized conditions. The reaction products were determined by gas chromatograph/mass spectrometer, as such, the reaction route was revealed, 4-methyl-1-pentanol and succinic acid are considered to be the major intermediate products.

Get full access to this article

View all available purchase options and get full access to this article.

References

Addink, R., Govers, H. A. J., and Olie, K. (1995). “Desorption behaviour of polychlorinated dibenzo-p-dioxins/dibenzofurans on a packed fly ash bed.” Chemosphere, 31, 3945–3950.
Buekens, A., and Huang, H. (1998). “Comparative evaluation of techniques for controlling the formation and emission of chlorinated dioxins/furans in municipal waste incineration.” J. Hazard. Mater., 62, 1–33.
Chang, J. S. (2003). “Next generation integrated electrostatic gas cleaning systems.” J. Electrost., 57, 273–291.
Chang, M. B., Lin, J. J., and Chang, S. H. (2002). “Characterization of dioxin emissions from two municipal solid waste incinerators in Taiwan.” Atmos. Environ., 36(2), 279–286.
Cudahy, J. J., and Helsel, R. W. (2000). “Removal of products of incomplete combustion with carbon.” Waste Manage., 20, 339–345.
Eduljee, G. H., and Dyke, P. (1996). “An updated inventory of PCDD and PCDF emissions sources in the UK.” Sci. Total Environ., 177, 303–321.
Gu, X. R. (1994). Surface chemistry, Science Publishing Company, Beijing, 15–20.
He, Q. H., Ji, Z. Y., and Suo, N. (2004). “The development in solid ClO2 preparation.” Chemical Industry Standardization & Quality Supervision, 9, 25–29.
Jianqiang, Z. (2003). “Microbial decomposition of dioxins.” Chongqing Environmental Science, 25(10), 70–73.
Kim, M. K., and Okeefe, P. (2000). “Photodegradation of polychlorinated dibenzo-p-dioxins and dibenzofurans in aqueous solutions and in organic solvents.” Chemosphere, 41, 793–800.
Kim, S. C., et al. (2001). “Removal efficiencies of PCDD/Fs by air pollution control devices in municipal solid waste incinerators.” Chemosphere, 43, 733–776.
Lin, H. F., Ravikrishna, R., and Valsaraj, K. T. (2002). “Reusable adsorbents for dilute solution separation. 6. Batch and continuous reactors for the adsorption and degradation of 1,2-dichlorobenzene from dilute wastewater streams using titania as a photocatalyst.” Sep. Purif. Technol., 28, 87–102.
Pimentel, M., Oturan, N., Dezotti, M., and Oturan, M. A. (2008). “Phenol degradation by advanced electrochemical oxidation process electro-Fenton using a carbon felt cathode.” Appl. Catal., B, 83, 140–149.
Shen, B. X., and Yao, Q. (2002). “Formation mechanism and control of dioxins in waste incineration.” Power System Engineering, 18(5), 8–10.
Singh S. B., and Kulshrestha G. (1997). “Chromatographic analysis of polychlorinated dibenzo-p-dioxins and dibenzofurans.” J. Chromatogr., A, 774, 97–109.
Wang, L. C., et al. (2003). “Emissions of polychlorinated dibenzo-p-dioxins and dibenzofurans from stack flue gases of sinter plants.” Chemosphere, 50, 1123–1129.
Zhang, J. C., Yao, Q., and Liu, Z. A. (2001). “Formation mechanism and control of secondary pollution in waste incineration.” Environ. Prot., 5, 17–18.

Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 136Issue 12December 2010
Pages: 1398 - 1402

History

Received: Dec 5, 2009
Accepted: Jun 1, 2010
Published online: Nov 15, 2010
Published in print: Dec 2010

Permissions

Request permissions for this article.

Authors

Affiliations

Professor, School of Environmental Science and Engineering, North China Electric Power Univ., Baoding 071003, China (corresponding author). E-mail: [email protected]
Ph.D. Student, School of Environmental Science and Engineering, North China Electric Power Univ., Baoding 071003, China. E-mail: [email protected]
Tian-Xiang Guo [email protected]
Ph.D. Student, School of Environmental Science and Engineering, North China Electric Power Univ., Baoding 071003, China. E-mail: [email protected]
Bing-Jian Zhang [email protected]
Graduate Student, School of Environmental Science and Engineering, North China Electric Power Univ., Baoding 071003, China. E-mail: [email protected]
Ying-Hui Han [email protected]
Ph.D. Student, School of Environmental Science and Engineering, North China Electric Power Univ., Baoding 071003, China. E-mail: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share