TECHNICAL PAPERS
May 29, 2010

Simultaneous Desulfurization and Denitrification by Microwave Catalytic over FeCoCu/Zeolite 5A Catalyst

Publication: Journal of Environmental Engineering
Volume 136, Issue 12

Abstract

FeCoCu/zeolite 5A was used as a catalyst for microwave catalytic desulfurization and denitrification and for microwave catalytic reduction of SO2 and NOx with ammonium bicarbonate (NH4HCO3) as a reducing agent. Microwave catalytic desulfurization and denitrification efficiency attained 99.5 and 86.1%, respectively. The reaction efficiencies of microwave catalytic reduction of SO2 and NOx could be up to 95.8 and 95.1% separately; the optimal microwave power and empty bed residence time on microwave catalytic reduction of SO2 and NOx simultaneously are 280 W and 0.358 s, respectively. Microwave accentuates catalytic reduction treatment, and microwave addition can increase the SO2 and NOx removal efficiency. The microwave catalytic SO2 and NOx removal follows the Langmuir-Hinshelwood model.

Get full access to this article

View all available purchase options and get full access to this article.

Acknowledgments

The writers gratefully acknowledge the financial support from the Research Fund Program of Guangdong Provincial Key Laboratory of Environmental Pollution Control and Remediation Technology (Grant No. UNSPECIFIED2006K0013).

References

Bennici, S., Gervasini, A., Lazzarin, M., and Ragaini, V. (2005). “CuO based catalysts on modified acidic silica supports tested in the de-NOx reduction.” Ultrason. Sonochem., 12(4), 307–312.
Carja, G., Kameshima, Y., Okada, K., and Madhusoodana, C. D. (2007). “Mn–Ce/ZSM5 as a new superior catalyst for NO reduction with NH3 .” Appl. Catal., B, 73(1–2), 60–64.
Chang, Y. C., and Dong, S. K. (2001). “Microwave induced reactions of sulfur dioxide and nitrogen oxides in char and anthracite bed.” Carbon, 39(8), 1159–1166.
Han, G. B., Park, N. K., Lee, J. D., Ryu, S. O., and Lee, T. J. (2006). “A study on the characteristics of the SO2 reduction using coal gas over SnO2ZrO2 catalysts.” Catal. Today, 111(3–4), 205–211.
Ighigeanu, D., et al. (2005). “ SO2 and NOx removal by electron beam and electrical discharge induced non-thermal plasmas.” Vacuum, 77(4), 493–500.
Kim, S. B., and Hong, S. C. (2002). “Kinetic study for photocatalytic degradation of volatile organic compounds in air using thin film TiO2 photocatalyst.” Appl. Catal., B, 35(4), 305–315.
Krishna, K., and Makkee, M. (2005). “Coke formation over zeolites and CeO2 -zeolites and its influence on selective catalytic reduction of NOx .” Appl. Catal., B, 59(1–2), 35–44.
Marilena, T. R., Diana, I. M., and Ioan, C. (2003). “Emission control of SO2 and NOx by irradiation methods.” J. Hazard. Mater., 97(1–3), 145–158.
Nimmo, W., Patsias, A. A., and Hampartsoumian, E. (2004). “Simultaneous reduction of NOx and SO2 emissions from coal combustion by calcium magnesium acetate.” Fuel, 83(2), 149–155.
Pillai, K. C., Chung, S. J., Raju, T., and Moon, I. S. (2009). “Experimental aspects of combined NOx and SO2 removal from flue-gas mixture in an integrated wet scrubber-electrochemical cell system.” Chemosphere, 76(5), 657–664.
Sepúlveda-Escribano, A., Márquez-Alvarez, C., Rodríguez-Ramos, I., Guerrero-Ruiz, A., and Fierro, J. L. G. (1993). “Decomposition of NO on Cu-loaded zeolites.” Catal. Today, 17(1–2), 167–174.
Shang, K. F., et al. (2004). “Investigation on simultaneously desulphurization and denitrification from flue gas by pulsed corona discharge plasma and additives.” Recent developments in applied electrostatics, S. Keping and Y. Gefei, eds., 61–64.
Vicente, S. E., Montanari, T., and Busca, G. (2005). “Low temperature selective catalytic reduction of NOx by ammonia over H-ZSM-5: An IR study.” Appl. Catal., B, 58(1–2), 19–23.
Wallin, M., Karlsson, C. J., Skoglundh, M., and Anders, P. (2003). “Selective catalytic reduction of NOx with NH3 over zeolite H–ZSM-5: Influence of transient ammonia supply.” J. Catal., 218(2), 354–364.
Wang, C. H., Lin, S. S., Sung, P. C., and Weng, H. S. (2003). “Catalytic reduction of SO2 over supported transition-metal oxide catalysts with C2H4 as a reducing agent.” Appl. Catal., B, 40(4), 331–345.
Wei, Z. S., Zeng, G. H., and Xie, Z. R. (2009). “Microwave catalytic desulfurization and denitrification simultaneously on Fe/Ca-5A zeolite catalyst.” Energy Fuels, 23(6), 2947–2951.
Xie, G. Y., Liu, Z. Y., Zhu, Z. P., Liu, Q. Y., Ge, J., and Huang, Z. G. (2004). “Simultaneous removal of SO2 and NOx from flue gas using a CuO/Al2O3 catalyst sorbent. II: Promotion of SCR activity by SO2 at high temperatures.” J. Catal., 224(1), 42–49.
Xing, N., Wang, X. P., Zhang, A. F., Liu, Z. G., and Guo, X. W. (2008). “Eley-Rideal mode of formamide species formation in selective catalytic reduction of NOx by C2H2 over ferrierite based catalysts.” Catal. Commun., 9(11–12), 2117–2120.
Yu, Q., Yang, H. M., Zeng, K. S., Zhang, Z. W., and Yu, G. (2007). “Simultaneous removal of NO and SO2 from dry gas stream using non-thermal plasma.” J. Environ. Sci. (China), 19(11), 1393–1397.
Zhang, D. X., Yu, A. M., and Jin, Q. H. (1997). “Studies on microwave-carbon reduction method for the treatment of nitric oxide.” Chem. J. Chin. Univ., 18(8), 1271–1274.

Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 136Issue 12December 2010
Pages: 1403 - 1408

History

Received: Aug 21, 2009
Accepted: May 26, 2010
Published online: May 29, 2010
Published in print: Dec 2010

Permissions

Request permissions for this article.

Authors

Affiliations

Zaishan Wei [email protected]
Associate Professor, School of Environmental Science and Engineering, Sun Yat-sen Univ., Guangzhou 510275, People’s Republic of China (corresponding author). E-mail: [email protected]
Guihua Zeng
MS Student, School of Environmental Science and Engineering, Sun Yat-sen Univ., Guangzhou 510275, People’s Republic of China.
Zhirong Xie
MS Student, School of Environmental Science and Engineering, Sun Yat-sen Univ., Guangzhou 510275, People’s Republic of China.
Jianliang Sun
MS Student, School of Environmental Science and Engineering, Sun Yat-sen Univ., Guangzhou 510275, People’s Republic of China.

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share