Simultaneous Desulfurization and Denitrification by Microwave Catalytic over FeCoCu/Zeolite 5A Catalyst
Publication: Journal of Environmental Engineering
Volume 136, Issue 12
Abstract
FeCoCu/zeolite 5A was used as a catalyst for microwave catalytic desulfurization and denitrification and for microwave catalytic reduction of and with ammonium bicarbonate as a reducing agent. Microwave catalytic desulfurization and denitrification efficiency attained 99.5 and 86.1%, respectively. The reaction efficiencies of microwave catalytic reduction of and could be up to 95.8 and 95.1% separately; the optimal microwave power and empty bed residence time on microwave catalytic reduction of and simultaneously are 280 W and 0.358 s, respectively. Microwave accentuates catalytic reduction treatment, and microwave addition can increase the and removal efficiency. The microwave catalytic and removal follows the Langmuir-Hinshelwood model.
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Acknowledgments
The writers gratefully acknowledge the financial support from the Research Fund Program of Guangdong Provincial Key Laboratory of Environmental Pollution Control and Remediation Technology (Grant No. UNSPECIFIED2006K0013).
References
Bennici, S., Gervasini, A., Lazzarin, M., and Ragaini, V. (2005). “CuO based catalysts on modified acidic silica supports tested in the reduction.” Ultrason. Sonochem., 12(4), 307–312.
Carja, G., Kameshima, Y., Okada, K., and Madhusoodana, C. D. (2007). “Mn–Ce/ZSM5 as a new superior catalyst for NO reduction with .” Appl. Catal., B, 73(1–2), 60–64.
Chang, Y. C., and Dong, S. K. (2001). “Microwave induced reactions of sulfur dioxide and nitrogen oxides in char and anthracite bed.” Carbon, 39(8), 1159–1166.
Han, G. B., Park, N. K., Lee, J. D., Ryu, S. O., and Lee, T. J. (2006). “A study on the characteristics of the reduction using coal gas over catalysts.” Catal. Today, 111(3–4), 205–211.
Ighigeanu, D., et al. (2005). “ and removal by electron beam and electrical discharge induced non-thermal plasmas.” Vacuum, 77(4), 493–500.
Kim, S. B., and Hong, S. C. (2002). “Kinetic study for photocatalytic degradation of volatile organic compounds in air using thin film photocatalyst.” Appl. Catal., B, 35(4), 305–315.
Krishna, K., and Makkee, M. (2005). “Coke formation over zeolites and -zeolites and its influence on selective catalytic reduction of .” Appl. Catal., B, 59(1–2), 35–44.
Marilena, T. R., Diana, I. M., and Ioan, C. (2003). “Emission control of and by irradiation methods.” J. Hazard. Mater., 97(1–3), 145–158.
Nimmo, W., Patsias, A. A., and Hampartsoumian, E. (2004). “Simultaneous reduction of and emissions from coal combustion by calcium magnesium acetate.” Fuel, 83(2), 149–155.
Pillai, K. C., Chung, S. J., Raju, T., and Moon, I. S. (2009). “Experimental aspects of combined and removal from flue-gas mixture in an integrated wet scrubber-electrochemical cell system.” Chemosphere, 76(5), 657–664.
Sepúlveda-Escribano, A., Márquez-Alvarez, C., Rodríguez-Ramos, I., Guerrero-Ruiz, A., and Fierro, J. L. G. (1993). “Decomposition of NO on Cu-loaded zeolites.” Catal. Today, 17(1–2), 167–174.
Shang, K. F., et al. (2004). “Investigation on simultaneously desulphurization and denitrification from flue gas by pulsed corona discharge plasma and additives.” Recent developments in applied electrostatics, S. Keping and Y. Gefei, eds., 61–64.
Vicente, S. E., Montanari, T., and Busca, G. (2005). “Low temperature selective catalytic reduction of by ammonia over H-ZSM-5: An IR study.” Appl. Catal., B, 58(1–2), 19–23.
Wallin, M., Karlsson, C. J., Skoglundh, M., and Anders, P. (2003). “Selective catalytic reduction of with over zeolite H–ZSM-5: Influence of transient ammonia supply.” J. Catal., 218(2), 354–364.
Wang, C. H., Lin, S. S., Sung, P. C., and Weng, H. S. (2003). “Catalytic reduction of over supported transition-metal oxide catalysts with as a reducing agent.” Appl. Catal., B, 40(4), 331–345.
Wei, Z. S., Zeng, G. H., and Xie, Z. R. (2009). “Microwave catalytic desulfurization and denitrification simultaneously on Fe/Ca-5A zeolite catalyst.” Energy Fuels, 23(6), 2947–2951.
Xie, G. Y., Liu, Z. Y., Zhu, Z. P., Liu, Q. Y., Ge, J., and Huang, Z. G. (2004). “Simultaneous removal of and from flue gas using a catalyst sorbent. II: Promotion of SCR activity by at high temperatures.” J. Catal., 224(1), 42–49.
Xing, N., Wang, X. P., Zhang, A. F., Liu, Z. G., and Guo, X. W. (2008). “Eley-Rideal mode of formamide species formation in selective catalytic reduction of by over ferrierite based catalysts.” Catal. Commun., 9(11–12), 2117–2120.
Yu, Q., Yang, H. M., Zeng, K. S., Zhang, Z. W., and Yu, G. (2007). “Simultaneous removal of NO and from dry gas stream using non-thermal plasma.” J. Environ. Sci. (China), 19(11), 1393–1397.
Zhang, D. X., Yu, A. M., and Jin, Q. H. (1997). “Studies on microwave-carbon reduction method for the treatment of nitric oxide.” Chem. J. Chin. Univ., 18(8), 1271–1274.
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© 2010 ASCE.
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Received: Aug 21, 2009
Accepted: May 26, 2010
Published online: May 29, 2010
Published in print: Dec 2010
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