Properties and Mechanism of Fe–Cu–AC Microelectrolysis for Treatment of Typical Dye Wastewater
Publication: Journal of Environmental Engineering
Volume 149, Issue 12
Abstract
The degradation of typical dye wastewater has always been a continuous concern in wastewater treatment. Microelectrolysis is a technology that offers the advantages of being green and highly efficient in treating wastewater. However, traditional binary microelectrolysis has problems, such as low applicability and high dependence on acidic environments. This study prepared ternary microelectrolytic materials, optimized the key conditions of material preparation and wastewater treatment, explored the removal mechanism of ternary microelectrolytic materials for dye wastewater, and quantitatively analyzed the contribution of different removal paths in the removal process of dye. For chemical oxygen demand (COD), the removal contributions of adsorption, flocculation, , , and reduction were 22.23%, 20.35%, 15.43%, 6.62%, and 0.71%, respectively. For the chorma removal of vital red, the removal contributions of adsorption, flocculation, , , and reduction were 21.07%, 55.97%, 14.57%, 4.62%, and 0.91%, respectively. For the chorma removal of disperse blue, the removal contributions of adsorption, flocculation, , , and reduction were 7.81%, 72.36%, 11.52%, 6.10%, and 0.70%, respectively. Ternary microelectrolysis can achieve an ideal removal effect in a neutral treatment environment. The material structure, produced in the system, and pH regulation of effluent are crucial in the removal process of dye wastewater. Ternary microelectrolysis materials are superior to traditional binary microelectrolysis materials due to their double cathode characteristics, strong applicability, and ability to operate in a neutral treatment environment. This study can serve as guide for ternary microelectrolysis technology in the treatment of typical dye wastewater.
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Data Availability Statement
All data, models, and code generated or used during the study appear in the published article.
Acknowledgments
This work was supported by the State Key Laboratory of Eco-Hydraulics in Northwest Arid Region, Xi’an University of Technology, under (Grant No. 2020KFKT-11) and the Science and Technology Department of Shaanxi Province, China, under (Grant Nos. 2021JQ-670 and 2023-YBSF-531).
References
Agrawal, K., and P. Verma. 2020. “Myco-valorization approach using entrapped Myrothecium verrucaria ITCC-8447 on synthetic and natural support via column bioreactor for the detoxification and degradation of anthraquinone dyes.” Int. Biodeterior. Biodegrad. 153 (Sep): 105052. https://doi.org/10.1016/j.ibiod.2020.105052.
Cai, F., L. Lei, Y. Li, and Y. Chen. 2021. “A review of aerobic granular sludge (AGS) treating recalcitrant wastewater: Refractory organics removal mechanism, application and prospect.” Sci. Total Environ. 782 (Aug): 146852. https://doi.org/10.1016/j.scitotenv.2021.146852.
Chao, H.-J., D. Xue, W. Jiang, D. Li, Z. Hu, J. Kang, and D. Liu. 2020. “A low-voltage pulse electrolysis method for the degradation of anthraquinone and azo dyes in chloride medium by anodic oxidation on electrodes.” Water Environ. Res. 92 (5): 779–788. https://doi.org/10.1002/wer.1270.
Chaudhari, A. U., D. Paul, D. Dhotre, and K. M. Kodam. 2017. “Effective biotransformation and detoxification of anthraquinone dye reactive blue 4 by using aerobic bacterial granules.” Water Res. 122 (Oct): 603–613. https://doi.org/10.1016/j.watres.2017.06.005.
Che, J., J. Wan, X. Huang, R. Wu, and K. Liang. 2017. “Pretreatment of piggery digestate wastewater by ferric-carbon micro-electrolysis under alkalescence condition.” Korean J. Chem. Eng. 34 (Sep): 2397–2405. https://doi.org/10.1007/s11814-017-0144-8.
Du, X., W. Fu, P. Su, J. Cai, and M. Zhou. 2020. “Internal-micro-electrolysis-enhanced heterogeneous electro-Fenton process catalyzed by PC core–shell hybrid for sulfamethazine degradation.” Chem. Eng. J. 398 (Oct): 125681. https://doi.org/10.1016/j.cej.2020.125681.
Duan, C., X. Huan, J. Gao, Y. Zhou, N. Chen, and J. Zhu. 2022. “Iron-carbon (Fe-C) micro-electrolysis coupling with anaerobic-anoxic-oxic () process: Nitrogen and phosphorus removal performance and microbial characteristics.” J. Environ. Chem. Eng. 10 (2): 107235. https://doi.org/10.1016/j.jece.2022.107235.
Fatima, M., R. Farooq, R. W. Lindström, and M. Saeed. 2017. “A review on biocatalytic decomposition of azo dyes and electrons recovery.” J. Mol. Liq. 246 (Nov): 275–281. https://doi.org/10.1016/j.molliq.2017.09.063.
Gao, J.-F., Z.-L. Wu, W.-J. Duan, and W.-Z. Zhang. 2019. “Simultaneous adsorption and degradation of triclosan by Ginkgo biloba L. stabilized Fe/Co bimetallic nanoparticles.” Sci. Total Environ. 662 (Apr): 978–989. https://doi.org/10.1016/j.scitotenv.2019.01.194.
Gulkaya, I., G. Surucu, and F. Dilek. 2006. “Importance of ratio in Fenton’s treatment of a carpet dyeing wastewater.” J. Hazard. Mater. 136 (Apr): 763–769. https://doi.org/10.1016/j.jhazmat.2006.01.006.
Guo, J., Y. Zhang, H. Wen, H. Jia, and J. Wang. 2023. “A novel recycling way of blast furnace dust from steelworks: Electrocoagulation coupled micro-electrolysis system in indigo wastewater treatment.” Chemosphere 327 (Jun): 138416. https://doi.org/10.1016/j.chemosphere.2023.138416.
Han, Y., H. Li, M. Liu, Y. Sang, C. Liang, and J. Chen. 2016. “Purification treatment of dyes wastewater with a novel micro-electrolysis reactor.” Sep. Purif. Technol. 170 (Oct): 241–247. https://doi.org/10.1016/j.seppur.2016.06.058.
Han, Y., M. Qi, L. Zhang, Y. Sang, M. Liu, T. Zhao, J. Niu, and S. Zhang. 2019. “Degradation of nitrobenzene by synchronistic oxidation and reduction in an internal circulation microelectrolysis reactor.” J. Hazard. Mater. 365 (Jun): 448–456. https://doi.org/10.1016/j.jhazmat.2018.11.036.
Han, Y., C. Wu, Z. Su, X. Fu, and Y. Xu. 2020. “Micro-electrolysis biological fluidized bed process for coking wastewater treatment.” J. Water Process Eng. 38 (Mar): 101624. https://doi.org/10.1016/j.jwpe.2020.101624.
He, Y., H. Lin, Y. Dong, B. Li, L. Wang, S. Chu, M. Luo, and J. Liu. 2018. “Zeolite supported Fe/Ni bimetallic nanoparticles for simultaneous removal of nitrate and phosphate: Synergistic effect and mechanism.” Chem. Eng. J. 347 (Mar): 669–681. https://doi.org/10.1016/j.cej.2018.04.088.
Huang, C., F. Peng, H.-J. Guo, C. Wang, M.-T. Luo, C. Zhao, L. Xiong, X.-F. Chen, and X.-D. Chen. 2018. “Efficient COD degradation of turpentine processing wastewater by combination of Fe-C micro-electrolysis and Fenton treatment: Long-term study and scale up.” Chem. Eng. J. 351 (Nov): 697–707. https://doi.org/10.1016/j.cej.2018.06.139.
Kapoor, R. T., M. Danish, R. S. Singh, M. Rafatullah, and A. K. HPS. 2021. “Exploiting microbial biomass in treating azo dyes contaminated wastewater: Mechanism of degradation and factors affecting microbial efficiency.” J. Water Process Eng. 43 (Oct): 102255. https://doi.org/10.1016/j.jwpe.2021.102255.
Lai, B., Y. Zhou, P. Yang, J. Yang, and J. Wang. 2013. “Degradation of 3, 3′-iminobis-propanenitrile in aqueous solution by micro-electrolysis system.” Chemosphere 90 (4): 1470–1477. https://doi.org/10.1016/j.chemosphere.2012.09.040.
Li, H.-H., Y.-T. Wang, Y. Wang, H.-X. Wang, K.-K. Sun, and Z.-M. Lu. 2019. “Bacterial degradation of anthraquinone dyes.” J. Zhejiang Univ. Sci. B 20 (6): 528–540. https://doi.org/10.1631/jzus.B1900165.
Li, P., K. Lin, Z. Fang, and K. Wang. 2017. “Enhanced nitrate removal by novel bimetallic Fe/Ni nanoparticles supported on biochar.” J. Cleaner Prod. 151 (May): 21–33. https://doi.org/10.1016/j.jclepro.2017.03.042.
Li, X., Y. Jia, Y. Qin, M. Zhou, and J. Sun. 2021. “Iron-carbon micro-electrolysis for wastewater remediation: Preparation, performance and interaction mechanisms.” Chemosphere 278 (Sep): 130483. https://doi.org/10.1016/j.chemosphere.2021.130483.
Liu, L., D. He, F. Pan, R. Huang, H. Lin, and X. Zhang. 2020. “Comparative study on treatment of methylene blue dye wastewater by different internal electrolysis systems and COD removal kinetics, thermodynamics and mechanism.” Chemosphere 238 (Jan): 124671. https://doi.org/10.1016/j.chemosphere.2019.124671.
Liu, S., H. Xue, X. Feng, and S.-H. Pyo. 2022. “Electrostimulation for promoted microbial community and enhanced biodegradation of refractory azo dyes.” J. Environ. Chem. Eng. 10 (6): 108626. https://doi.org/10.1016/j.jece.2022.108626.
Liu, W.-J., T.-T. Qian, and H. Jiang. 2014. “Bimetallic Fe nanoparticles: Recent advances in synthesis and application in catalytic elimination of environmental pollutants.” Chem. Eng. J. 236 (Jan): 448–463. https://doi.org/10.1016/j.cej.2013.10.062.
Liu, Y., C. Wang, Z. Sui, and D. Zou. 2018. “Degradation of chlortetracycline using nano micro-electrolysis materials with loading copper.” Sep. Purif. Technol. 203 (Jun): 29–35. https://doi.org/10.1016/j.seppur.2018.03.064.
Ma, C., Z. Ran, Z. Yang, L. Wang, C. Wen, B. Zhao, and H. Zhang. 2019. “Efficient pretreatment of industrial estate wastewater for biodegradability enhancement using a micro-electrolysis-circulatory system.” J. Environ. Manage. 250 (Nov): 109492. https://doi.org/10.1016/j.jenvman.2019.109492.
Mahdizadeh, H., A. Nasiri, M. A. Gharaghani, and G. Yazdanpanah. 2020. “Hybrid UV/COP advanced oxidation process using ZnO as a catalyst immobilized on a stone surface for degradation of acid red 18 dye.” MethodsX 7 (Jan): 101118. https://doi.org/10.1016/j.mex.2020.101118.
Paździor, K., L. Bilińska, and S. Ledakowicz. 2019. “A review of the existing and emerging technologies in the combination of AOPs and biological processes in industrial textile wastewater treatment.” Chem. Eng. J. 376 (Nov): 120597. https://doi.org/10.1016/j.cej.2018.12.057.
Reyes, K. R. E., P.-W. Tsai, L. L. Tayo, C.-C. Hsueh, and B.-Y. Chen. 2021. “Biodegradation of anthraquinone dyes: Interactive assessment upon biodecolorization, biosorption and biotoxicity using dual-chamber microbial fuel cells (MFCs).” Process Biochem. 101 (Feb): 111–127. https://doi.org/10.1016/j.procbio.2020.11.006.
Selvaraj, V., T. S. Karthika, C. Mansiya, and M. Alagar. 2021. “An over review on recently developed techniques, mechanisms and intermediate involved in the advanced azo dye degradation for industrial applications.” J. Mol. Struct. 1224 (Jan): 129195. https://doi.org/10.1016/j.molstruc.2020.129195.
Song, N., J. Xu, Y. Cao, F. Xia, J. Zhai, H. Ai, D. Shi, L. Gu, and Q. He. 2020. “Chemical removal and selectivity reduction of nitrate from water by (nano) zero-valent iron/activated carbon micro-electrolysis.” Chemosphere 248 (Jun): 125986. https://doi.org/10.1016/j.chemosphere.2020.125986.
Sun, Z.-Z., Z.-H. Liu, L. Han, D.-L. Qin, G. Yang, and W.-H. Xing. 2019. “Study on the treatment of simulated azo dye wastewater by a novel micro-electrolysis filler.” Water Sci. Technol. 79 (12): 2279–2288. https://doi.org/10.2166/wst.2019.234.
Thommes, M., K. Kaneko, A. V. Neimark, J. P. Olivier, F. R. Reinoso, J. Rouquerol, and K. S. W. Sing. 2015. “Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC technical report).” Pure Appl. Chem. 87 (9–10): 1051–1069. https://doi.org/10.1515/pac-2014-1117.
Wang, G., L. Qian, X. Yong, Y. Wang, W. An, H. Jia, and J. Zhou. 2021a. “Synthesis of a ternary microscopic ball-shaped micro-electrolysis filler and its application in wastewater treatment.” Sep. Purif. Technol. 275 (Nov): 119131. https://doi.org/10.1016/j.seppur.2021.119131.
Wang, T. Z., W. J. Wang, H. Y. Hu, and S. T. Khu. 2021b. “Effect of coagulation on bio-treatment of textile wastewater: Quantitative evaluation and application.” J. Cleaner Prod. 312 (Aug): 127798. https://doi.org/10.1016/j.jclepro.2021.127798.
Wu, X., C. Lv, S. Yu, M. Li, J. Ye, X. Zhang, and Y. Liu. 2020. “Uranium (VI) removal from aqueous solution using iron-carbon micro-electrolysis packing.” Sep. Purif. Technol. 234 (Mar): 116104. https://doi.org/10.1016/j.seppur.2019.116104.
Xiong, M., S. Gu, H. Gu, D. Zhang, C. Ma, and Z. Xu. 2022. “New insights into iron/nickel-carbon ternary micro-electrolysis toward 4-nitrochlorobenzene removal: Enhancing reduction and unveiling removal mechanisms.” J. Colloid Interface Sci. 612 (Apr): 308–322. https://doi.org/10.1016/j.jcis.2021.12.116.
Xu, C., W. Yang, W. Liu, H. Sun, C. Jiao, and A.-J. Lin. 2018. “Performance and mechanism of Cr (VI) removal by zero-valent iron loaded onto expanded graphite.” J. Environ. Sci. 67 (May): 14–22. https://doi.org/10.1016/j.jes.2017.11.003.
Xu, Z., Y. Gao, H. Gu, S. Gu, M. Xiong, D. Zhang, R. Qi, and W. Chen. 2021. “Novel (IV) system: Toward the interaction between internal electrolysis and sulfite for p-nitrophenol degradation.” Sep. Purif. Technol. 268 (Aug): 118615. https://doi.org/10.1016/j.seppur.2021.118615.
Xu, Z., Z. Sun, Y. Zhou, D. Zhang, Y. Gao, Y. Huang, and W. Chen. 2020. “Enhanced hydrodechlorination of p-chloronitrobenzene by a GAC-Fe-Cu ternary micro-electrolysis system: Synergistic effects and removal mechanism.” Sep. Purif. Technol. 237 (Apr): 116391. https://doi.org/10.1016/j.seppur.2019.116391.
Yang, Z., Y. Ma, Y. Liu, Q. Li, Z. Zhou, and Z. Ren. 2017. “Degradation of organic pollutants in near-neutral pH solution by Fe-C micro-electrolysis system.” Chem. Eng. J. 315 (May): 403–414. https://doi.org/10.1016/j.cej.2017.01.042.
Yu, W., Y. Sun, M. Lei, S. Chen, T. Qiu, and Q. Tang. 2019. “Preparation of micro-electrolysis material from flotation waste of copper slag and its application for degradation of organic contaminants in water.” J. Hazard. Mater. 361 (Jan): 221–227. https://doi.org/10.1016/j.jhazmat.2018.08.098.
Zhang, D., B. Wang, X. Gong, Z. Yang, and Y. Liu. 2019a. “Selective reduction of nitrate to nitrogen gas by novel composite combined with HCOOH under UV radiation.” Chem. Eng. J. 359 (Mar): 1195–1204. https://doi.org/10.1016/j.cej.2018.11.058.
Zhang, H., Z. Wang, C. Liu, Y. Guo, N. Shan, C. Meng, and L. Sun. 2014. “Removal of COD from landfill leachate by an electro/Fe/peroxydisulfate process.” Chem. Eng. J. 250 (Aug): 76–82. https://doi.org/10.1016/j.cej.2014.03.114.
Zhang, L., Q. Yue, K. Yang, P. Zhao, and B. Gao. 2018. “Enhanced phosphorus and ciprofloxacin removal in a modified BAF system by configuring Fe-C micro electrolysis: Investigation on pollutants removal and degradation mechanisms.” J. Hazard. Mater. 342 (Jan): 705–714. https://doi.org/10.1016/j.jhazmat.2017.09.010.
Zhang, Q., D. Zhao, Y. Ding, Y. Chen, F. Li, A. Alsaedi, T. Hayat, and C. Chen. 2019b. “Synthesis of Fe–Ni/graphene oxide composite and its highly efficient removal of uranium (VI) from aqueous solution.” J. Cleaner Prod. 230 (Sep): 1305–1315. https://doi.org/10.1016/j.jclepro.2019.05.193.
Zhang, Z. 2017. “Treatment of oilfield wastewater by combined process of micro-electrolysis, Fenton oxidation and coagulation.” Water Sci. Technol. 76 (12): 3278–3288. https://doi.org/10.2166/wst.2017.486.
Zhou, Y., H. Lu, J. Wang, J. Zhou, X. Leng, and G. Liu. 2018. “Catalytic performance of quinone and graphene-modified polyurethane foam on the decolorization of azo dye Acid Red 18 by Shewanella sp. RQs-106.” J. Hazard. Mater. 356 (Aug): 82–90. https://doi.org/10.1016/j.jhazmat.2018.05.043.
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Received: Apr 29, 2023
Accepted: Jul 27, 2023
Published online: Oct 13, 2023
Published in print: Dec 1, 2023
Discussion open until: Mar 13, 2024
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