Abstract

The long-term aging of bitumens and its effect on low-temperature performance is a detrimental phenomenon. In order to investigate the effects of the aging phenomenon on the low-temperature performance of bitumens, it is very important to accurately simulate the behavior of bitumens in repeated aging cycles and to investigate related viscoelastic, chemical, and microstructural changes. In this research, three types of bitumen with penetration grades of 40/50, 60/70, and 85/100 were subjected to one to three cycles of pressure aging vessel (PAV) aging. Comprehensive data on the bitumen’s behavior were obtained by conducting bending beam rheometer, Fourier transform infrared spectroscopy, and atomic force microscopy tests. Using the results of the conducted tests, an attempt was made to find precise relationships between different indicators of bitumen aging in terms of chemistry and viscoelasticity. The results revealed a linear correlation between the aging index and the ΔTc and dissipated energy ratio (DER) values, as well as the aging index and the vertical shift factor of the stiffness-time curve. The fitting coefficients of these linear relationships were R2=0.8 and above, indicating a strong linear relationship between these parameters. Furthermore, the viscoelastic indices DER and the derivation of creep compliance (J) exhibited a fairly good linear relationship.

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Data Availability Statement

Some or all data, models, or code that support the findings of this study are available from the corresponding author upon reasonable request.

References

AASHTO. 2013a. Standard method of test for effect of heat and air on a moving film of asphalt (rolling thin-film oven test). AASHTO T 240-09. Washington, DC: AASHTO.
AASHTO. 2013b. Standard practice for accelerated aging of asphalt binder using a pressurized aging vessel (PAV). AASHTO R 28. Washington, DC: AASHTO.
Aflaki, S., and P. Hajikarimi. 2012. “Implementing viscoelastic rheological methods to evaluate low temperature performance of modified asphalt binders.” Constr. Build. Mater. 36 (Nov): 110–118. https://doi.org/10.1016/j.conbuildmat.2012.04.076.
Ahmedzade, P., K. Demirelli, T. Günay, F. Biryan, and O. Alqudah. 2015. “Effects of waste polypropylene additive on the properties of bituminous binder.” Procedia Manuf. 2 (Feb): 165–170. https://doi.org/10.1016/j.promfg.2015.07.029.
Allen, R. G., D. N. Little, A. Bhasin, and C. J. Glover. 2014. “The effects of chemical composition on asphalt microstructure and their association to pavement performance.” Int. J. Pavement Eng. 15 (1): 9–22. https://doi.org/10.1080/10298436.2013.836192.
Anderson, R. M., G. N. King, D. I. Hanson, and P. B. Blankenship. 2011. “Evaluation of the relationship between asphalt binder properties and non-load related cracking.” J. Assoc. Asphalt Paving Technol. 80 (Apr): 615–664.
ASTM. 2001. Standard test method for determining the flexural creep stiffness of asphalt binder using the bending beam rheometer (BBR). ASTM D6648-08. West Conshohocken, PA: ASTM.
ASTM. 2010. Standard test method for softening point of bitumen (ring-and-ball apparatus). ASTM D36. West Conshohocken, PA: ASTM.
ASTM. 2012. Standard test method for effect of heat and air on a moving film of asphalt (rolling thin-film oven test). ASTM D2872. West Conshohocken, PA: ASTM.
ASTM. 2017a. Standard test method for ductility of asphalt materials. ASTM D113. West Conshohocken, PA: ASTM.
ASTM. 2017b. Standard test method for penetration of bituminous materials. ASTM D5/D5M. West Conshohocken, PA: ASTM.
ASTM. 2018. Standard test method for flash and fire points by cleveland open cup tester. ASTM D92. West Conshohocken, PA: ASTM.
Braswell, E., N. F. Saleh, M. Elwardany, F. Yousefi Rad, C. Castorena, B. S. Underwood, and Y. R. Kim. 2020. “Refinement of climate-, depth-, and time-based laboratory aging procedure for asphalt mixtures.” Transp. Res. Rec. 2675 (2): 207–218. https://doi.org/10.1177/0361198120957316.
Brown, E. R., P. S. Kandhal, F. L. Roberts, Y. R. Kim, D.-Y. Lee, and T. W. Kennedy. 2009. “Hot mix asphalt materials, mixture design, and construction.” In NAPA research and education foundation. Lanham, MD: National Asphalt Pavement Association Research and Education Foundation.
Czajkowski, P., A. Przyjazny, and G. Boczkaj. 2023. “Bitumen aging—Laboratory simulation methods used in practice and selected directions of research on new methods.” Materials 16 (2): 853. https://doi.org/10.1039/C9RA00645A.
Elwardany, M. D., F. Y. Rad, C. Castorena, and R. Y. Kim. 2018. “Climate-, depth-, and time-based laboratory aging procedure for asphalt mixtures.” J. Assoc. Asphalt Paving Technol. 87 (Mar): 467–511. https://doi.org/10.12783/aapt2018/33815.
Eurobitume. 2015. The bitumen industry—A global perspective: Production, chemistry, use, specification and occupational exposure. Brussels, Belgium: European Association of Bitumen Producers.
Hajikarimi, P., and F. Moghadas Nejad. 2021. Applications of viscoelasticity: Bituminous materials characterization and modeling. Amsterdam, Netherlands: Elsevier.
Hofer, K., J. Mirwald, A. Bhasin, and B. Hofko. 2023. “Low-temperature characterization of bitumen and correlation to chemical properties.” Constr. Build. Mater. 366 (Feb): 130202. https://doi.org/10.1016/j.conbuildmat.2022.130202.
Hofko, B., D. Maschauer, D. Steiner, J. Mirwald, and H. Grothe. 2020. “Bitumen ageing–Impact of reactive oxygen species.” Case Stud. Constr. Mater. 13 (Dec): e00390. https://doi.org/10.1016/j.cscm.2020.e00390.
Hofko, B., L. Porot, A. Falchetto Cannone, L. Poulikakos, L. Huber, X. Lu, K. Mollenhauer, and H. Grothe. 2018. “FTIR spectral analysis of bituminous binders: Reproducibility and impact of ageing temperature.” Mater. Struct. 51 (2): 1–16.
Hossain, R., S. Arafat, D. Salomon, and N. M. Wasiuddin. 2022. “A comparative study of RTFO, PAV and UV aging using FT-IRS and DSR tests.” In RILEM bookseries. New York: Springer.
Huang, Y. H. 2004. Pavement analysis and design. Hoboken, NJ: Prentice Hall.
Kennedy, T. W., G. A. Huber, E. T. Harrigan, R. J. Cominsky, C. S. Hughes, H. Von Quintus, and J. S. Moulthrop. 1994. Superior performing asphalt pavements (Superpave): The product of the SHRP asphalt research program. Washington, DC: Strategic Highway Research Program, National Research Council.
Kim, Y. S., J. Büchner, M. P. Wistuba, J. R. Agudo, M. Rochlani, and M. Schäffler. 2022. “Asphalt binder testing at low temperature: Three-point bending beam test in dynamic shear rheometer.” Front. Mater. 9 (Feb): 831443.
Koyun, A., J. Büchner, M. P. Wistuba, and H. Grothe. 2022. “Rheological, spectroscopic and microscopic assessment of asphalt binder ageing.” Road Mater. Pavement Des. 23 (1): 80–97. https://doi.org/10.1080/14680629.2020.1820891.
Lewis, R. H., and J. Y. Welborn. 1940. “Report on the properties of the residues of 50-60 and 85-100 penetration asphalts from oven tests and exposure.” In Proc., Association of Asphalt Paving Technologists, 86–157. Washington, DC: Federal Highway Administration.
Li, Y., S. Liu, Z. Xue, and W. Cao. 2014. “Experimental research on combined effects of flame retardant and warm mixture asphalt additive on asphalt binders and bituminous mixtures.” Constr. Build. Mater. 54 (Mar): 533–540. https://doi.org/10.1016/j.conbuildmat.2013.12.058.
Lin, P., W. Huang, X. Liu, P. Apostolids, H. Wang, and C. Yan. 2020. “Laboratory evaluation of the effects of long-term aging on high-content polymer-modified asphalt binder.” J. Mater. Civ. Eng. 32 (7): 1–12. https://doi.org/10.1061/(ASCE)MT.1943-5533.0003208.
Liu, L., Y. Lu, A. Liu, Y. Li, and R. Guo. 2021. “Analysis of asphalt aging behavior evaluation method based on infrared spectrum.” IOP Conf. Ser.: Earth Environ. Sci. 787 (1): 012044. https://doi.org/10.1016/j.conbuildmat.2009.10.015.
Liu, S., W. Cao, S. Shang, H. Qi, and J. Fang. 2010. “Analysis and application of relationships between low-temperature rheological performance parameters of asphalt binders.” Constr. Build. Mater. 24 (4): 471–478. https://doi.org/10.1016/j.conbuildmat.2009.10.015.
Ma, J., P. Singhvi, H. Ozer, I. L. Al-Qadi, and B. K. Sharma. 2021. “Brittleness progression for short- and long-term aged asphalt binders with various levels of recycled binders.” Int. J. Pavement Eng. 22 (11): 1399–1409. https://doi.org/10.1080/10298436.2019.1694677.
Marsac, P., et al. 2014. “Potential and limits of FTIR methods for reclaimed asphalt characterisation.” Mater. Struct. 47 (8): 1273–1286. https://doi.org/10.1617/s11527-014-0248-0.
Masson, J., V. Leblond, and J. Margeson. 2006. “Bitumen morphologies by phase-detection atomic force microscopy.” J. Microsc. 221 (1): 17–29. https://doi.org/10.1111/j.1365-2818.2006.01540.x.
Menapace, I., E. Masad, A. Bhasin, and D. Little. 2015. “Microstructural properties of warm mix asphalt before and after laboratory-simulated long-term ageing.” Road Mater. Pavement Des. 16 (Apr): 2–20. https://doi.org/10.1080/14680629.2015.1029692.
Mirwald, J., D. Nura, and B. Hofko. 2022. “Recommendations for handling bitumen prior to FTIR spectroscopy.” Mater. Struct. 55 (2): 26. https://doi.org/10.1617/s11527-022-01884-1.
Ouyang, Q., Z. Xie, J. Liu, M. Gong, and H. Yu. 2022. “Application of atomic force microscopy as advanced asphalt testing technology: A comprehensive review.” Polymers 14 (4): 2851. https://doi.org/10.3390/polym14142851.
Petersen, J. C. 2009. “A review of the fundamentals of asphalt oxidation: Chemical, physicochemical, physical property, and durability relationships.” In Transportation research circular, E-C140. Washington, DC: Transportation Research Board.
Poulikakos, L. D., C. A. Falchetto, D. Wang, L. Porot, and B. Hofko. 2019. “Impact of asphalt aging temperature on chemo-mechanics.” RSC Adv. 9 (21): 11602–11613. https://doi.org/10.1039/C9RA00645A.
Rebelo, L. M., J. S. De Sousa, A. S. Abreu, M. Baroni, A. E. V. Alencar, S. A. Soares, J. Mendes Filho, and J. B. Soares. 2014. “Aging of asphaltic binders investigated with atomic force microscopy.” Fuel 117 (Mar): 15–25. https://doi.org/10.1016/j.fuel.2013.09.018.
Ren, H., Z. Qian, W. Huang, H. Li, and Y. Liu. 2022. “Low-temperature thermal cracking performance of waterborne epoxy asphalt emulsion mastic based on bending beam rheometer (BBR).” Constr. Build. Mater. 334 (Jun): 127461. https://doi.org/10.1016/j.conbuildmat.2022.127461.
Ren, S., X. Liu, P. Lin, S. Erkens, and Y. Xiao. 2021. “Chemo-physical characterization and molecular dynamics simulation of long-term aging behaviors of bitumen.” Constr. Build. Mater. 302 (Jun): 124437. https://doi.org/10.1016/j.conbuildmat.2021.124437.
Shan, L., Y. Tan, H. Zhang, and Y. Xu. 2016. “Analysis of linear viscoelastic response function model for asphalt binders.” J. Mater. Civ. Eng. 28 (6): 4016010. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001497.
Singhvi, P., J. J. García Mainieri, H. Ozer, B. K. Sharma, and I. L. Al-Qadi. 2020. “Effect of chemical composition of Bio- and petroleum-based modifiers on asphalt binder rheology.” Appl. Sci. 10 (9): 3249.
Singhvi, P., A. Karakas, H. Ozer, I. L. Al-Qadi, and K. Hossain. 2019. “Impact of asphalt modifier dosage on modified binder rheology and chemistry with long-term aging.” In Proc., Int. Airfield and Highway Pavements Conf. 2019, 274–284. Reston, VA: ASCE.
Sirin, O., D. K. Paul, and E. Kassem. 2018. “State of the art study on aging of asphalt mixtures and use of antioxidant additives.” Adv. Civ. Eng. 2018 (Mar): 18. https://doi.org/10.1155/2018/3428961.
Soenen, H., S. Heyrman, X. Lu, P. Redelius, and J. C. Edwards. 2016. “The interaction of polyphosphoric acid with bituminous binders.” In Proc., 8th RILEM Int. Symp. on Testing and Characterization of Sustainable and Innovative Bituminous Materials, edited by F. Canestrari and M. N. Partl, 103–114. Dordrecht, Netherlands: Springer.
Wang, H., X. Liu, P. Apostolidis, M. van de Ven, S. Erkens, and A. Skarpas. 2020. “Effect of laboratory aging on chemistry and rheology of crumb rubber modified bitumen.” Mater. Struct. 53 (Apr): 1–15.
Wang, M., and L. Liu. 2017. “Investigation of microscale aging behavior of asphalt binders using atomic force microscopy.” Constr. Build. Mater. 135 (Mar): 411–419. https://doi.org/10.1016/j.conbuildmat.2016.12.180.
Wu, S., L. Pang, L. Mo, Y. Chen, and G. Zhu. 2009. “Influence of aging on the evolution of structure, morphology and rheology of base and SBS modified bitumen.” Constr. Build. Mater. 23 (2): 1005–1010. https://doi.org/10.1016/j.conbuildmat.2008.05.004.
Xu, J., Z. Fan, J. Lin, X. Yang, D. Wang, and M. Oeser. 2021. “Predicting the low-temperature performance of asphalt binder based on rheological model.” Constr. Build. Mater. 302 (Oct): 124401. https://doi.org/10.1016/j.conbuildmat.2021.124401.
Xu, S., J. Huang, S. Tighe, C. Zhang, H. Ma, X. Jia, and X. Zhou. 2022. “Aging evaluation of base and SBS modified bitumens under the coupling effect of multiple aging factors.” Constr. Build. Mater. 348 (Sep): 128670. https://doi.org/10.1016/j.conbuildmat.2022.128670.
Yan, T., M. Marasteanu, and M. Turos. 2021. “Obtaining asphalt binder rheological properties from BBR strength test–The effect of loading rate.” Mech. Time-Depend. Mater. 25 (4): 617–630. https://doi.org/10.1007/s11043-020-09464-y.
Yang, J., X. Zhu, Y. Yuan, and L. Li. 2020. “Effects of aging on micromechanical properties of asphalt binder using AFM.” J. Mater. Civ. Eng. 32 (5): 4020081. https://doi.org/10.1061/(ASCE)MT.1943-5533.0003030.
Yang, Z., X. Zhang, Z. Zhang, B. Zou, Z. Zhu, G. Lu, W. Xu, J. Yu, and H. Yu. 2018. “Effect of aging on chemical and rheological properties of bitumen.” Polymers 10 (12): 1345.
Zhang, E., L. Shan, X. Qi, X. Wang, and Y. Fan. 2022. “Investigating the relationship between chemical composition and mechanical properties of asphalt binders using atomic force microscopy (AFM).” Constr. Build. Mater. 343 (Aug): 128001. https://doi.org/10.1016/j.conbuildmat.2022.128001.
Zhang, H., Y. Wang, T. Yu, and Z. Liu. 2020a. “Microstructural characteristics of differently aged asphalt samples based on atomic force microscopy (AFM).” Constr. Build. Mater. 255 (Sep): 119388. https://doi.org/10.1016/j.conbuildmat.2020.119388.
Zhang, H. L., J. Y. Yu, Z. G. Feng, L. H. Xue, and S. P. Wu. 2012. “Effect of aging on the morphology of bitumen by atomic force microscopy.” J. Microsc. 246 (1): 11–19. https://doi.org/10.1111/j.1365-2818.2011.03578.x.
Zhang, K., and J. Kevern. 2021. “Review of porous asphalt pavements in cold regions: The state of practice and case study repository in design, construction, and maintenance.” J. Infrastruct. Preserv. Resilience 2 (Dec): 1–17.
Zhang, R., J. E. Sias, and E. V. Dave. 2020b. “Correlating laboratory conditioning with field aging for asphalt using rheological parameters.” Transp. Res. Rec. 2674 (5): 393–404. https://doi.org/10.1177/0361198120915894.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 36Issue 5May 2024

History

Received: May 12, 2023
Accepted: Oct 23, 2023
Published online: Feb 22, 2024
Published in print: May 1, 2024
Discussion open until: Jul 22, 2024

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Mohammad Mehdi Dadaei [email protected]
Master’s Student, Dept. of Civil and Environmental Engineering, Amirkabir Univ. of Technology (Tehran Polytechnic), Tehran 1591634311, Iran. Email: [email protected]
Assistant Professor, Dept. of Civil and Environmental Engineering, Amirkabir Univ. of Technology (Tehran Polytechnic), Tehran 1591634311, Iran (corresponding author). ORCID: https://orcid.org/0000-0001-5621-7274. Email: [email protected]
Masoud Esfandiar [email protected]
Lecturer, Dept. of Management, Islamic Azad Univ., Shahr-e-Ghods Branch, Tehran 1311537541, Iran. Email: [email protected]
Mohammad Rahi [email protected]
Director, Dept. of Research and Development, Pasargad Oil Company, Tehran 1998873665, Iran. Email: [email protected]
Mehdi Dastoori Razaz [email protected]
Manager, Dept. of Research and Development, Pasargad Oil Company, Abadan 1998873665, Iran. Email: [email protected]
Behnoosh Tahmasbi [email protected]
Laboratory Expert, Dept. of Research and Development, Pasargad Oil Company, Abadan 1998873665, Iran. Email: [email protected]
Professor and Head of Transportation Group, Dept. of Civil and Environmental Engineering, Amirkabir Univ. of Technology (Tehran Polytechnic), Tehran 1591634311, Iran. ORCID: https://orcid.org/0000-0003-3830-4555. Email: [email protected]

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