Performance of Nano- Composite Modified Asphalt
Publication: Journal of Materials in Civil Engineering
Volume 35, Issue 11
Abstract
In this research, nano- and graphene composite were added to asphalt to enhance the performance of asphalt by synergistically improving the dispersion of each other. The physical properties of the modified asphalt were assessed using penetration, softening point, and ductility tests, and the rheological performance of the asphalt was studied using dynamic shear rheometric (DSR) and bending beam rheometric (BBR) tests. In addition, scanning electron microscopy (SEM), Fourier-transform infrared (FTIR) spectroscopy, and nanoparticle size analyzer (DLS) were used for microscopic analysis of asphalt. The results demonstrated that the incorporation of nano- and graphene in asphalt could improve the high-temperature properties and the aging resistance of base asphalt. In terms of low temperature performance, the composite of nano- with graphene improves the negative effects of the single addition of nano- or graphene. Microscopic analysis indicated that the dispersion of the nano- and graphene in the asphalt synergistically was improved significantly. The optimum amount of 1% nano- and 0.04% graphene is recommended for the composite. This study provides a basis for the diversified application and development of nanomaterial modified asphalt in the future.
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Data Availability Statement
Some or all data, models, or code that support the findings of this study are available from the corresponding author upon reasonable request.
Acknowledgments
The authors are grateful to the National Natural Science Foundation of China (Youth Program), Grant No. 52208435.
References
AASHTO. 2016. Standard method of test for determining the rheological properties of asphalt binder using a dynamic shear rheometer (DSR). AASHTO M 320-05. Washington, DC: AASHTO.
Ahmad Nazki, M., T. Chopra, and A. K. Chandrappa. 2020. “Rheological properties and thermal conductivity of bitumen binders modified with graphene.” Constr. Build. Mater. 238 (Mar): 117693. https://doi.org/10.1016/j.conbuildmat.2019.117693.
ASTM. 2001. Standard test method for determining the flexural creep stiffness of asphalt binder using the bending beam rheometer (BBR). ASTM D6648. West Conshohocken: ASTM.
ASTM. 2011. Standard test method for determining the rheological properties of asphalt binder using a dynamic shear rheometer. ASTM D7175. West Conshohocken: ASTM.
Atout, H., M. G. Álvarez, D. Chebli, A. Bouguettoucha, D. Tichit, J. Llorca, and F. Medina. 2017. “Enhanced photocatalytic degradation of methylene blue: Preparation of TiO2/reduced graphene oxide nanocomposites by direct sol-gel and hydrothermal methods.” Mater. Res. Bull. 95 (Apr): 578–587. https://doi.org/10.1016/j.materresbull.2017.08.029.
Azarhoosh, A., F. Moghaddas Nejad, and A. Khodaii. 2016. “Evaluation of the effect of nano- on the adhesion between aggregate and asphalt binder in hot mix asphalt.” Eur. J. Environ. Civ. Eng. 22 (8): 946–961. https://doi.org/10.1080/19648189.2016.1229227.
FHWA (Federal Highway Administration). 1994. U.S. strategic highway research program. Washington, DC: FHWA.
Ghayoor, R., A. Keshavarz, and M. N. Soltani Rad. 2019. “Facile preparation of TiO2 nanoparticles decorated by the graphene for enhancement of dye-sensitized solar cell performance.” J. Mater. Res. 34 (12): 2014–2023. https://doi.org/10.1557/jmr.2019.142.
Günay, T., and P. Ahmedzade. 2020. “Physical and rheological properties of nano-TiO2 and nanocomposite modified bitumens.” Constr. Build. Mater. 243 (May): 118208. https://doi.org/10.1016/j.conbuildmat.2020.118208.
Hao, G., and Y. Wang. 2021. “3D reconstruction of polymer phase in polymer-modified asphalt using confocal fluorescence microscopy.” J. Mater. Civ. Eng. 33 (1): 04020400. https://doi.org/10.1061/(ASCE)MT.1943-5533.0003485.
Jin, J., T. Xiao, Y. Tan, J. Zheng, R. Liu, G. Qian, H. Wei, and J. Zhang. 2018. “Effects of TiO2 pillared montmorillonite nanocomposites on the properties of asphalt with exhaust catalytic capacity.” J. Cleaner Prod. 205 (5): 339–349. https://doi.org/10.1016/j.jclepro.2018.08.251.
Jyothirmai, B., M. H. Kiranmai, and K. Vagdevi. 2020. “Graphene reinforces asphalt—Doubles durability of road.” In Proc., Int. Conf. on Multifunctional Materials (Icmm-2019). https://doi.org/10.1063/5.0019643.
Li, J., S. Duan, Y. Muhammad, Y. Liu, D. Hou, S. Yang, Y. Yin, S. Subhan, T. Hao, and Y. Meng. 2019. “Synthesis and performance evaluation of modified asphalt–based trackless tack coat material.” J. Mater. Civ. Eng. 31 (9): 04019202. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002812.
Li, X., Y.-M. Wang, Y.-L. Wu, H.-R. Wang, M. Chen, H.-D. Sun, and L. Fan. 2021a. “Properties and modification mechanism of asphalt with graphene as modifier.” Constr. Build. Mater. 272 (Feb): 121919.
Li, Y., S. Wu, and S. Amirkhanian. 2018. “Investigation of the graphene oxide and asphalt interaction and its effect on asphalt pavement performance.” Constr. Build. Mater. 165 (14): 572–584. https://doi.org/10.1016/j.conbuildmat.2018.01.068.
Li, Z., T. Guo, Y. Chen, Q. Liu, and Y. Chen. 2021b. “The properties of nano-/nano-ZnO/SBR composite-modified asphalt.” Nanotechnol. Rev. 10 (1): 1253–1265. https://doi.org/10.1515/ntrev-2021-0082.
Liu, J., K. Yan, and J. Liu. 2018. “Rheological characteristics of polyphosphoric acid–modified asphalt mastic.” J. Mater. Civ. Eng. 30 (12): 06018021. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002555.
MOT (Ministry of Transport of the People’s Republic of China). 2011. Standard test methods of bitumen and bituminous mixtures for highway engineering. [In Chinese.] JTG E20-2011. Beijing: MOT.
Nie, F., W. Jian, and D. Lau. 2021. “An atomistic study on the thermomechanical properties of graphene and functionalized graphene sheets modified asphalt.” Carbon 182 (6): 615–627. https://doi.org/10.1016/j.carbon.2021.06.055.
Saltan, M., S. Terzi, and S. Karahancer. 2019. “Mechanical behavior of bitumen and hot-mix asphalt modified with zinc oxide nanoparticle.” J. Mater. Civ. Eng. 31 (3): 04018399. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002621.
Shafabakhsh, G. A., M. Sadeghnejad, B. Ahoor, and E. Taheri. 2020. “Laboratory experiment on the effect of nano SiO2 and TiO2 on short and long-term aging behavior of bitumen.” Constr. Build. Mater. 237 (Mar): 117640. https://doi.org/10.1016/j.conbuildmat.2019.117640.
Sun, X., S. Ji, M. Wang, J. Dou, Z. Yang, H. Qiu, S. Kou, Y. Ji, and H. Wang. 2020. “Fabrication of porous TiO2-RGO hybrid aerogel for high-efficiency, visible-light photodegradation of dyes.” J. Alloys Compd. 819 (Apr): 153033. https://doi.org/10.1016/j.jallcom.2019.153033.
Tibodee, A., P. Pannak, K. Akkarachaneeyakorn, T. Thaweechai, and W. Sirisaksoontorn. 2019. “Use of the graphite intercalation compound to produce low-defect graphene sheets for the photocatalytic enhancement of graphene/TiO2 composites.” Mater. Chem. Phys. 235 (Sep): 121755. https://doi.org/10.1016/j.matchemphys.2019.121755.
Wang, G., D. Rao, K. Li, and Y. Lin. 2014. “UV Blocking by Mg–Zn–Al layered double hydroxides for the protection of asphalt road surfaces.” Ind. Eng. Chem. Res. 53 (11): 4165–4172. https://doi.org/10.1021/ie403901n.
Wang, Q. E., K. Zheng, H. Yu, L. Zhao, X. Zhu, and J. Zhang. 2020. “Laboratory experiment on the nano-TiO2 photocatalytic degradation effect of road surface oil pollution.” Nanotechnol. Rev. 9 (1): 922–933. https://doi.org/10.1515/ntrev-2020-0072.
Wei, Y., Y. Liu, Y. Muhammad, S. Subhan, F. Meng, D. Ren, M. Han, and J. Li. 2020. “Study on the properties of GNPs/PS and GNPs/ODA composites incorporated SBS modified asphalt after short-term and long-term aging.” Constr. Build. Mater. 261 (Nov): 119682. https://doi.org/10.1016/j.conbuildmat.2020.119682.
Xu, J., H. Chen, Y. Wen, B. Xue, R. Li, and J. Pei. 2021. “Aging property of oil recycled asphalt binders with reclaimed asphalt materials.” J. Mater. Civ. Eng. 33 (9): 04021246. https://doi.org/10.1061/(ASCE)MT.1943-5533.0003663.
Yang, J., Y. Muhammad, C. Yang, Y. Liu, Z. Su, Y. Wei, and J. Li. 2021. “Preparation of TiO2/PS-rGO incorporated SBS modified asphalt with enhanced resistance against ultraviolet aging.” Constr. Build. Mater. 276 (Mar): 121461. https://doi.org/10.1016/j.conbuildmat.2020.121461.
Yang, Q., X. Li, L. Zhang, Y. Qian, Y. Qi, H. S. Kouhestani, X. Shi, X. Gui, D. Wang, and J. Zhong. 2020. “Performance evaluation of bitumen with a homogeneous dispersion of carbon nanotubes.” Carbon 158 (Mar): 465–471. https://doi.org/10.1016/j.carbon.2019.11.013.
Yang, S., Y. Li, J. Sun, and B. Cao. 2019. “Laser induced oxygen-deficient TiO2/graphene hybrid for high-performance supercapacitor.” J. Power Sources 431 (Aug): 220–225. https://doi.org/10.1016/j.jpowsour.2019.05.016.
Zeng, J., C. Peng, X. Wang, R. Wang, N. Zhang, and S. Xiong. 2019. “One-pot self-assembled TiO2/graphene/poly(acrylamide) superporous hybrid for photocatalytic degradation of organic pollutants.” J. Appl. Polym. Sci. 136 (5): 47033. https://doi.org/10.1002/app.47033.
Zhang, Y., H. M. Yang, and S.-J. Park. 2018. “Synthesis and characterization of nitrogen-doped TiO2 coatings on reduced graphene oxide for enhancing the visible light photocatalytic activity.” Curr. Appl Phys. 18 (2): 163–169. https://doi.org/10.1016/j.cap.2017.12.001.
Zhu, C., H. Zhang, C. Shi, and S. Li. 2017. “Effect of nano-zinc oxide and organic expanded vermiculite on rheological properties of different bitumens before and after aging.” Constr. Build. Mater. 146 (Aug): 30–37. https://doi.org/10.1016/j.conbuildmat.2017.04.062.
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© 2023 American Society of Civil Engineers.
History
Received: Oct 31, 2022
Accepted: Apr 3, 2023
Published online: Aug 24, 2023
Published in print: Nov 1, 2023
Discussion open until: Jan 24, 2024
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