Technical Papers
Aug 24, 2023

Freeze–Thaw Characteristics of Slaking Marl Clay Stabilized with a Binder Based on Alkali-Activated Recycled Glass Powder

Publication: Journal of Materials in Civil Engineering
Volume 35, Issue 11

Abstract

Marl soils with different carbonate contents usually show more unpredictable behavior than other problematic soils. In some marl soil groups, freezing–thawing (F-T) cycles can result in slaking and detrimental effects on the soil mechanical properties. However, up to now, studies on the performance of stabilized marl with alkali-activated materials under F-T cycles have been noticed to be quite limited. Moreover, the filled pores in the marl layered matrix and cementing materials bonded particles during the formation mechanism have not been clearly explored yet. This study investigated the improvement of slaking marl soil with a geopolymer based on recycled glass powder (RGP) activated with sodium hydroxide (NaOH) for complete replacement of industrial cement. The study evaluated the effects of the changes of the curing times (7, 28, and 90 days), RGP content (5%, 10%, and 15%), alkali concentration (2, 4, and 6M), curing temperatures as close to research conditions as possible (20°C and 50°C), volumetric strain, and 12 cycles of F-T for the unconfined compression strength (UCS) and consolidation test results. The control sets, comprising natural and cement-stabilized samples, were prepared and examined to provide a reference baseline. The mineralogical and microstructural characteristics were determined through X-ray diffractometer (XRD) and scanning electron microscopy (SEM) techniques. The results revealed that the cyclic F-T actions damaged the bonding between marl layers and made an irreversible structure with a lower UCS value. The results indicated that after conducting F-T cycles, the UCS of stabilized samples (15% RGP content, 2 M NaOH, 90 days curing) diminished from 3,667 to 2,668 kPa (27% reduction) after 12 F-T cycles. The one-dimensional consolidation test results confirmed a considerable reduction (92% for 90-day cured samples) in the settlement.

Get full access to this article

View all available purchase options and get full access to this article.

Data Availability Statement

All data, models, and code generated or used during the study appear in the published article.

References

Alonso, S., and A. Palomo. 2001. “Alkaline activation of metakaolin and calcium hydroxide mixtures: Influence of temperature, activator concentration and solids ratio.” Mater. Lett. 47 (1–2): 55–62. https://doi.org/10.1016/S0167-577X(00)00212-3.
Arifuzzaman, M., M. Najjar, M. N. Mahmud, A. B. M. S. Islam, M. Khan, and M. M. Ali. 2017. “Enhancing the properties of marl soils for effective construction in Saudi Arabian region.” Eng. J. 21 (4): 111–126. https://doi.org/10.4186/ej.2017.21.4.111.
ASTM. 2003. Standard test method for unconfined compressive strength of cohesive soil. ASTM D2166-87. West Conshohocken, PA: ASTM.
ASTM. 2009. Standard specification for portland cement. ASTM C 150. West Conshohocken, PA: ASTM.
ASTM. 2011. Standard practice for classification of soils for engineering purposes (unified soil classification system). ASTM D2487-11. West Conshohocken, PA: ASTM.
ASTM. 2012. Standard test method for one-dimensional consolidation properties of saturated cohesive soils using controlled-strain loading. ASTM D4186. West Conshohocken, PA: ASTM.
ASTM. 2015. Standard test methods for specific gravity of soil solids by water pycnometer method. ASTM D854. West Conshohocken, PA: ASTM.
ASTM. 2018. Standard test methods for liquid limit, plastic limit, and plasticity index of soils. ASTM D4318-17e1. West Conshohocken, PA: ASTM.
ASTM. 2019. Standard test method for pH of soils. ASTM D 4972-19. West Conshohocken, PA: ASTM.
ASTM. 2021. Standard test methods for laboratory compaction characteristics of soil using standard effort (12,400 ft-lbf/ft3 (600 kN-m/m3)). ASTM D698-12. West Conshohocken, PA: ASTM.
Bahadori, H., A. Hasheminezhad, and F. Taghizadeh. 2019. “Experimental study on marl soil stabilization using natural pozzolans.” J. Mater. Civ. Eng. 31 (2): 4018363. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002577.
Bahmyari, H., M. Ajdari, and H. Nabizadeh. 2021a. “Effect of wetting-drying on a stabilized expansive soil.” In Proc., IFCEE 2021, 243–263. Reston, VA: ASCE.
Bahmyari, H., M. Ajdari, A. Vakili, and M. H. Ahmadi. 2021b. “The role of the cement, lime, and natural pozzolan stabilizations on the mechanical response of a collapsible soil.” Transp. Infrastruct. Geotechnol. 8 (3): 452–472. https://doi.org/10.1007/s40515-020-00146-3.
Bhattacharja, S., J. I. Bhatty, and H. A. Todres. 2003. “Stabilization of clay soils by Portland cement or lime–a critical review of literature.” PCA R&D Ser. 60 (1): 124–133.
Brigatti, M. F., and A. Mottana. 2011. Layered mineral structures and their application in advanced technologies. London: Mineralogical Society of Great Britain and Ireland.
Chand, G., S. K. Happy, and S. Ram. 2021. “Assessment of the properties of sustainable concrete produced from quaternary blend of portland cement, glass powder, metakaolin and silica fume.” Cleaner Eng. Technol. 4 (Jan): 100179. https://doi.org/10.1016/j.clet.2021.100179.
Cherian, C., and S. Siddiqua. 2021. “Engineering and environmental evaluation for utilization of recycled pulp mill fly ash as binder in sustainable road construction.” J. Cleaner Prod. 298 (May): 126758. https://doi.org/10.1016/j.jclepro.2021.126758.
Christiansen, M. U. 2013. An investigation of waste glass-based geopolymers supplemented with alumina. Houghton, MI: Michigan Technological Univ.
Clark, H., and H. Wu. 2016. The sustainable development goals: 17 goals to transform our world, 36–54. New York: Furthering Work United Nations.
Cyr, M., R. Idir, and T. Poinot. 2012. “Properties of inorganic polymer (geopolymer) mortars made of glass cullet.” J. Mater. Sci. 47 (6): 2782–2797. https://doi.org/10.1007/s10853-011-6107-2.
Dash, S. K., and M. Hussain. 2012. “Lime stabilization of soils: Reappraisal.” J. Mater. Civ. Eng. 24 (6): 707–714. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000431.
de Jesús Arrieta Baldovino, J., R. dos Santos Izzo, J. L. Rose, and M. A. Avanci. 2020. “Geopolymers based on recycled glass powder for soil stabilization.” Geotech. Geol. Eng. 38 (4): 4013–4031. https://doi.org/10.1007/s10706-020-01274-w.
El Howayek, A., M. C. Santagata, A. Bobet, and N. Zia-Siddiki. 2015. Engineering properties of marls. West Lafayette, IN: Purdue Univ.
Fernández-Jiménez, A., F. Puertas, I. Sobrados, and J. Sanz. 2003. “Structure of calcium silicate hydrates formed in alkaline-activated slag: influence of the type of alkaline activator.” J. Am. Ceram. Soc. 86 (8): 1389–1394.
Grim, R. E. 1968. Clay mineralogy. 2nd ed. New York: McGraw-Hill Book Company.
Günther, C., R. Kauther, and C. Lempp. 2018. “Evaluation of effective strength parameters in mudrocks.” Vol. 2 of Proc., ISRM European Rock Mechanics Symp.-EUROCK 2018, 1179–1184. Boca Raton, FL: CRC Press.
Haha, M. B., G. Le Saout, F. Winnefeld, and B. Lothenbach. 2011. “Influence of activator type on hydration kinetics, hydrate assemblage and microstructural development of alkali activated blast-furnace slags.” Cem. Concr. Res. 41 (3): 301–310. https://doi.org/10.1016/j.cemconres.2010.11.016.
Han, Z., and S. K. Vanapalli. 2016. “Stiffness and shear strength of unsaturated soils in relation to soil-water characteristic curve.” Géotechnique 66 (8): 627–647. https://doi.org/10.1680/jgeot.15.P.104.
Henry, K. S. 2000. A review of the thermodynamics of frost heave. Vicksburg, MS: Engineer Research and Development Center.
Hoy, M., R. Rachan, S. Horpibulsuk, A. Arulrajah, and M. Mirzababaei. 2017. “Effect of wetting–drying cycles on compressive strength and microstructure of recycled asphalt pavement–fly ash geopolymer.” Constr. Build. Mater. 144 (Aug): 624–634. https://doi.org/10.1016/j.conbuildmat.2017.03.243.
Hunter, D. 1988. “Lime-induced heave in sulfate-bearing clay soils.” J. Geotech. Eng. 114 (2): 150–167. https://doi.org/10.1061/(ASCE)0733-9410(1988)114:2(150).
Khalifa, A. Z., Ö. Cizer, Y. Pontikes, A. Heath, P. Patureau, S. A. Bernal, and A. T. M. Marsh. 2020. “Advances in alkali-activation of clay minerals.” Cem. Concr. Res. 132 (Mar): 106050. https://doi.org/10.1016/j.cemconres.2020.106050.
Khoshbakht, E. B., A. H. Vakili, M. S. Farhadi, and M. Salimi. 2019. “Reducing the negative impact of freezing and thawing cycles on marl by means of the electrokinetical injection of calcium chloride.” Cold Reg. Sci. Technol. 157 (Feb): 196–205. https://doi.org/10.1016/j.coldregions.2018.10.010.
Khoury, N. N., and R. Brooks. 2010. “Performance of a stabilized aggregate base subject to different durability procedures.” J. Mater. Civ. Eng. 22 (5): 506–514. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000055.
Lamas, F., C. Irigaray, and J. Chacón. 2002. “Geotechnical characterization of carbonate marls for the construction of impermeable dam cores.” Eng. Geol. 66 (3–4): 283–294. https://doi.org/10.1016/S0013-7952(02)00048-0.
Lamas, F., C. Irigaray, C. Oteo, and J. Chacon. 2005. “Selection of the most appropriate method to determine the carbonate content for engineering purposes with particular regard to marls.” Eng. Geol. 81 (1): 32–41. https://doi.org/10.1016/j.enggeo.2005.07.005.
Lu, N., and W. J. Likos. 2006. “Suction stress characteristic curve for unsaturated soil.” J. Geotech. Geoenviron. Eng. 132 (2): 131–142. https://doi.org/10.1061/(ASCE)1090-0241(2006)132:2(131).
Lu, Y., S. Liu, E. Alonso, L. Wang, L. Xu, and Z. Li. 2019. “Volume changes and mechanical degradation of a compacted expansive soil under freeze–thaw cycles.” Cold Reg. Sci. Technol. 157 (Jan): 206–214. https://doi.org/10.1016/j.coldregions.2018.10.008.
Ma, H., H. Zhu, C. Yi, J. Fan, H. Chen, X. Xu, and T. Wang. 2019. “Preparation and reaction mechanism characterization of alkali-activated coal gangue–slag materials.” Materials 12 (14): 2250. https://doi.org/10.3390/ma12142250.
Manaenkov, A., M. Steinerova, and E. Kukleva. 2021. “Effect of kaolin addition into metakaolin geopolymer composite.” J. Mater. Civ. Eng. 33 (1): 6020022. https://doi.org/10.1061/(ASCE)MT.1943-5533.0003498.
Mansour, Z. M., Z. Chik, and M. R. Taha. 2008. “On the procedures of soil collapse potential evaluation.” J. Appl. Sci. 8 (23): 4434–4439. https://doi.org/10.3923/jas.2008.4434.4439.
Moghadam, M. J., R. Ajalloeian, and A. Hajiannia. 2019. “Preparation and application of alkali-activated materials based on waste glass and coal gangue: A review.” Constr. Build. Mater. 221 (Oct): 84–98. https://doi.org/10.1016/j.conbuildmat.2019.06.071.
Mohamed, A. M. O. 2000. “The role of clay minerals in marly soils on its stability.” Eng. Geol. 57 (3–4): 193–203. https://doi.org/10.1016/S0013-7952(00)00029-6.
Moriwaki, Y., and J. K. Mitchell. 1977. “The role dispersion in the slaking of intactclay.” In Dispersive clays, related piping and erosion in geotechnical properties, edited by J. L. Sherard and R. S. Decker, 287–302. West Conshohocken, PA: ASTM.
Mutlutürk, M., R. Altindag, and G. Türk. 2004. “A decay function model for the integrity loss of rock when subjected to recurrent cycles of freezing–thawing and heating–cooling.” Int. J. Rock Mech. Min. Sci. 41 (2): 237–244. https://doi.org/10.1016/S1365-1609(03)00095-9.
Olufowobi, J., A. Ogundoju, B. Michael, and O. Aderinlewo. 2014. “Clay soil stabilisation using powdered glass.” J. Eng. Sci. Technol. 9 (5): 541–558.
Onyelowe, K. C., D. Bui Van, and M. Nguyen Van. 2021. “Swelling potential, shrinkage and durability of cemented and uncemented lateritic soils treated with CWC base geopolymer.” Int. J. Geotech. Eng. 15 (4): 389–404. https://doi.org/10.1080/19386362.2018.1462606.
Parghi, A., and M. S. Alam. 2016. “Physical and mechanical properties of cementitious composites containing recycled glass powder (RGP) and styrene butadiene rubber (SBR).” Constr. Build. Mater. 104 (Jun): 34–43. https://doi.org/10.1016/j.conbuildmat.2015.12.006.
Perfect, E., W. V. Van Loon, B. D. Kay, and P. H. Groenevelt. 1990. “Influence of ice segregation and solutes on soil structural stability.” Can. J. Soil Sci. 70 (4): 571–581. https://doi.org/10.4141/cjss90-060.
Pettijohn, F. J. 1975. Sedimentary rocks. New York: Harper & Row.
Post, J. L., and S. Crawford. 2007. “Varied forms of palygorskite and sepiolite from different geologic systems.” Appl. Clay Sci. 36 (4): 232–244. https://doi.org/10.1016/j.clay.2006.10.003.
Scheuermann Filho, H. C., R. Beck Saldanha, C. Gravina da Rocha, and N. Cesar Consoli. 2021. “Sustainable binders stabilizing dispersive clay.” J. Mater. Civ. Eng. 33 (3): 6020026. https://doi.org/10.1061/(ASCE)MT.1943-5533.0003595.
Shang, H.-S., Y.-P. Song, and L.-K. Qin. 2008. “Experimental study on strength and deformation of plain concrete under triaxial compression after freeze-thaw cycles.” Build. Environ. 43 (7): 1197–1204. https://doi.org/10.1016/j.buildenv.2006.08.027.
Shariatmadari, N., H. Mohebbi, and A. A. Javadi. 2021. “Surface stabilization of soils susceptible to wind erosion using volcanic ash–based geopolymer.” J. Mater. Civ. Eng. 33 (12): 4021345. https://doi.org/10.1061/(ASCE)MT.1943-5533.0003981.
Tan, T., B. B. K. Huat, V. Anggraini, and S. K. Shukla. 2021. “Improving the engineering behaviour of residual soil with fly ash and treated natural fibres in alkaline condition.” Int. J. Geotech. Eng. 15 (3): 313–326. https://doi.org/10.1080/19386362.2018.1564854.
Vindula, S. K., R. V. P. Chavali, P. H. P. Reddy, and T. Srinivas. 2019. “Ground granulated blast furnace slag to control alkali induced swell in kaolinitic soils.” Int. J. Geotech. Eng. 13 (4): 377–384. https://doi.org/10.1080/19386362.2017.1359901.
Vossberg, C., K. Mason-Jones, and B. Cohen. 2014. “An energetic life cycle assessment of C&D waste and container glass recycling in Cape Town, South Africa.” Resour. Conserv. Recycl. 88 (Jul): 39–49. https://doi.org/10.1016/j.resconrec.2014.04.009.
Wattez, T., C. Patapy, L. Frouin, J. Waligora, and M. Cyr. 2021. “Interactions between alkali-activated ground granulated blastfurnace slag and organic matter in soil stabilization/solidification.” Transp. Geotech. 26 (Jun): 100412. https://doi.org/10.1016/j.trgeo.2020.100412.
Xiao, R., P. Polaczyk, M. Zhang, X. Jiang, Y. Zhang, B. Huang, and W. Hu. 2020. “Evaluation of glass powder-based geopolymer stabilized road bases containing recycled waste glass aggregate.” Transp. Res. Rec. 2674 (1): 22–32. https://doi.org/10.1177/0361198119898695.
Yao, J., H. Qiu, H. He, X. Chen, and G. Hao. 2021. “Application of a soft soil stabilized by composite geopolymer.” J. Perform. Constr. Facil. 35 (4): 4021018. https://doi.org/10.1061/(ASCE)CF.1943-5509.0001586.
Yavuz, H. 2011. “Effect of freeze–thaw and thermal shock weathering on the physical and mechanical properties of an andesite stone.” Bull. Eng. Geol. Environ. 70 (2): 187–192. https://doi.org/10.1007/s10064-010-0302-2.
Yliniemi, J., B. Walkley, J. L. Provis, P. Kinnunen, and M. Illikainen. 2020. “Nanostructural evolution of alkali-activated mineral wools.” Cem. Concr. Compos. 106 (Mar): 103472. https://doi.org/10.1016/j.cemconcomp.2019.103472.
Yong, R. N., and V. R. Ouhadi. 2007. “Experimental study on instability of bases on natural and lime/cement-stabilized clayey soils.” Appl. Clay Sci. 35 (3–4): 238–249. https://doi.org/10.1016/j.clay.2006.08.009.
Zhang, T., G. Cai, and S. Liu. 2017. “Application of lignin-based by-product stabilized silty soil in highway subgrade: A field investigation.” J. Cleaner Prod. 142 (Aug): 4243–4257. https://doi.org/10.1016/j.jclepro.2016.12.002.
Zhang, T., G. Cai, and S. Liu. 2018. “Application of lignin-stabilized silty soil in highway subgrade: A macroscale laboratory study.” J. Mater. Civ. Eng. 30 (4): 4018034. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002203.
Zhang, T., Y.-L. Yang, and S.-Y. Liu. 2020. “Application of biomass by-product lignin stabilized soils as sustainable geomaterials: A review.” Sci. Total Environ. 728 (May): 138830. https://doi.org/10.1016/j.scitotenv.2020.138830.
Zheng, C., Q. Yang, and J. Huang. 2019. “Lignin with and without polymerization for soil stabilization.” J. Mater. Civ. Eng. 31 (12): 4019292. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002935.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 35Issue 11November 2023

History

Received: Aug 23, 2022
Accepted: Apr 4, 2023
Published online: Aug 24, 2023
Published in print: Nov 1, 2023
Discussion open until: Jan 24, 2024

Permissions

Request permissions for this article.

Authors

Affiliations

Mohammad Jamalimoghadam, Ph.D. [email protected]
Adjacent Research Assistant Professor, Dept. of Civil Engineering, Beyza Branch, Islamic Azad Univ., Beyza 7363111341, Iran (corresponding author). Email: [email protected]
Hossein Bahmyari, Ph.D., M.ASCE [email protected]
P.E.
D.GE
Lead Geotechnical Engineer, Twining Inc., 15950 Bernardo Center Dr., Suite J, San Diego, CA 92127. Email: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share