Technical Papers
Jan 31, 2023

Investigation on the Internal Relative Humidity of Superabsorbent Polymer–Modified Concrete Exposed to Various Ambient Humidities at Early Age

Publication: Journal of Materials in Civil Engineering
Volume 35, Issue 4

Abstract

The drop in internal relative humidity (IRH) affects the early-age cracking risk of concrete. Superabsorbent polymers (SAPs), an internal curing material, are usually used to decrease the drop rate of IRH in concrete and the shrinkage-induced cracking risk of concrete. This study investigated the changes in IRH and distribution of IRH in SAP-modified concrete under sealed conditions and exposed to various ambient humidities. The test results showed that the use of SAPs and additional internal curing water can compensate for water consumption caused by self-desiccation and moisture diffusion (MD) and increase the IRH of concrete exposed to various ambient humidities. However, the degree to which SAPs mitigated the drop in IRH of concrete exposed to outside ambient decreased with increasing ambient humidity. The IRH of SAP-modified concrete increased, and the MD coefficient decreased nonlinearly with increasing ambient humidity. A model for predicting IRH of SAP-modified concrete exposed to various ambient humidities under the influence of self-desiccation and MD was proposed.

Get full access to this article

View all available purchase options and get full access to this article.

Data Availability Statement

All data, models, and code generated or used during the study appear in the published article.

Acknowledgments

The financial support of the National Natural Science Foundation of China (Grant No. 51879092) is gratefully acknowledged. The support of the Fundamental Research Funds for the Central Universities (Grant No. B220203015) is also gratefully acknowledged.

References

Assmann, A., and H. W. Reinhardt. 2014. “Tensile creep and shrinkage of SAP modified concrete.” Cem. Concr. Res. 58 (Apr): 179–185. https://doi.org/10.1016/j.cemconres.2014.01.014.
ASTM. 2012. Standard practice for maintaining constant relative humidity by means of aqueous solutions. ASTM E104-02. West Conshohocken, PA: ASTM.
ASTM. 2017. Standard specification for lightweight aggregate for internal curing of concrete. ASTM C1761/C1761M-17. West Conshohocken, PA: ASTM.
Ayano, T., and F. H. Wittmann. 2002. “Drying, moisture distribution, and shrinkage of cement-based materials.” Mater. Struct. 35 (247): 134–140. https://doi.org/10.1617/13693.
Baroghel-Bouny, V., M. Mainguy, T. Lassabatere, and O. Coussy. 1999. “Characterization and identification of equilibrium and transfer moisture properties for ordinary and high-performance cementitious materials.” Cem. Concr. Res. 29 (8): 1225–1238. https://doi.org/10.1016/S0008-8846(99)00102-7.
Bažant, Z. P., and L. J. Najjar. 1972. “Nonlinear water diffusion in nonsaturated concrete.” Mater. Constr. 5 (1): 3–20. https://doi.org/10.1007/BF02479073.
Bentz, D. P., P. Lura, and J. W. Roberts. 2005. “Mixture proportioning for internal curing.” Concr. Int. 27 (2): 35–40.
Bissonnette, B., P. Pierre, and M. Pigeon. 1999. “Influence of key parameters on drying shrinkage of cementitious materials.” Cem. Concr. Res. 29 (10): 1655–1662. https://doi.org/10.1016/S0008-8846(99)00156-8.
Chen, S., H. T. Zhao, Y. Chen, D. H. Huang, Y. Z. Chen, and X. D. Chen. 2020. “Experimental study on interior relative humidity development in early-age concrete mixed with shrinkage-reducing and expansive admixtures.” Constr. Build. Mater. 232 (Jan): 117204. https://doi.org/10.1016/j.conbuildmat.2019.117204.
Craeye, B., M. Geirnaert, and G. De Schutter. 2011. “Super absorbing polymers as an internal curing agent for mitigation of early-age cracking of high-performance concrete bridge decks.” Constr. Build. Mater. 25 (1): 1–13. https://doi.org/10.1016/j.conbuildmat.2010.06.063.
Di Luzio, G., and G. Cusatis. 2009. “Hygro-thermo-chemical modeling of high performance concrete. I: Theory.” Cem. Concr. Compos. 31 (5): 301–308. https://doi.org/10.1016/j.cemconcomp.2009.02.015.
Ding, X. P., J. Zhang, and J. H. Wang. 2019. “Integrative modeling on self-desiccation and moisture diffusion in concrete based on variation of water content.” Cem. Concr. Compos. 97 (Mar): 322–340. https://doi.org/10.1016/j.cemconcomp.2019.01.008.
El-Dieb, A. S. 2007. “Self-curing concrete: Water retention, hydration and moisture transport.” Constr. Build. Mater. 21 (6): 1282–1287. https://doi.org/10.1016/j.conbuildmat.2006.02.007.
Gasch, T., R. Malm, and A. Ansell. 2016. “A coupled hygro-thermo-mechanical model for concrete subjected to variable environmental conditions.” Int. J. Solids Struct. 91 (Aug): 143–156. https://doi.org/10.1016/j.ijsolstr.2016.03.004.
Gawin, D., F. Pesavento, and B. A. Schrefler. 2006. “Hygro-thermo-chemo-mechanical modelling of concrete at early ages and beyond. Part I: Hydration and hygro-thermal phenomena.” Int. J Numer. Meth. Eng. 67 (3): 299–331. https://doi.org/10.1002/nme.1615.
Han, Y. D., J. Zhang, Y. M. Luosun, and T. Y. Hao. 2014. “Effect of internal curing on internal relative humidity and shrinkage of high strength concrete slabs.” Constr. Build. Mater. 61 (Jun): 41–49. https://doi.org/10.1016/j.conbuildmat.2014.02.060.
He, Z. M., A. Q. Shen, Y. C. Guo, Z. H. Lyu, D. S. Li, X. Qin, M. Zhao, and Z. L. Wang. 2019. “Cement-based materials modified with superabsorbent polymers: A review.” Constr. Build. Mater. 225 (Nov): 569–590. https://doi.org/10.1016/j.conbuildmat.2019.07.139.
Jendele, L., V. Šmilauer, and J. Červenka. 2014. “Multiscale hydro-thermo-mechanical model for early-age and mature concrete structures.” Adv. Eng. Software 72 (Jun): 134–146. https://doi.org/10.1016/j.advengsoft.2013.05.002.
Jensen, O. M., and P. F. Hansen. 2001. “Water-entrained cement-based materials: I. Principles and theoretical background.” Cem. Concr. Res. 31 (4): 647–654. https://doi.org/10.1016/S0008-8846(01)00463-X.
Jiang, Z. W., Z. P. Sun, and P. M. Wang. 2005. “Autogenous relative humidity change and autogenous shrinkage of high-performance cement pastes.” Cem. Concr. Res. 35 (8): 1539–1545. https://doi.org/10.1016/j.cemconres.2004.06.028.
Kang, S. T., J. S. Kim, Y. Lee, Y. D. Park, and J. K. Kim. 2012. “Moisture diffusivity of early age concrete considering temperature and porosity.” KSCE J. Civ. Eng. 16 (1): 179–188. https://doi.org/10.1007/s12205-012-1445-4.
Klausen, A. E., T. Kanstad, Ø. Bjøntegaard, and E. J. Sellevold. 2020. “The effect of curing temperature on autogenous deformation of fly ash concretes.” Cem. Concr. Compos. 109 (May): 103574. https://doi.org/10.1016/j.cemconcomp.2020.103574.
Kong, X. M., Z. L. Zhang, and Z. C. Lu. 2015. “Effect of pre-soaked superabsorbent polymer on shrinkage of high-strength concrete.” Mater. Struct. 48 (9): 2741–2758. https://doi.org/10.1617/s11527-014-0351-2.
Liu, J. H., N. Farzadnia, C. J. Shi, and X. W. Ma. 2019. “Effects of superabsorbent polymer on shrinkage properties of ultra-high strength concrete under drying condition.” Constr. Build. Mater. 215 (Aug): 799–811. https://doi.org/10.1016/j.conbuildmat.2019.04.237.
Ma, X. W., J. H. Liu, Z. M. Wu, and C. J. Shi. 2017. “Effects of SAP on the properties and pore structure of high performance cement-based materials.” Constr. Build. Mater. 131 (Jan): 476–484. https://doi.org/10.1016/j.conbuildmat.2016.11.090.
Maruyama, I., and P. Lura. 2019. “Properties of early-age concrete relevant to cracking in massive concrete.” Cem. Concr. Res. 123 (Sep): 105770. https://doi.org/10.1016/j.cemconres.2019.05.015.
Oh, B. H., and S. W. Cha. 2003. “Nonlinear analysis of temperature and moisture distributions in early-age concrete structures based on degree of hydration.” ACI Mater. J. 100 (5): 361–370. https://doi.org/10.14359/12811.
Pang, L. F. 2013. Study on the performance and mechanism of internal curing high-performance concrete with super absorbent polymer.” Ph.D. dissertation, School of Chemical & Environmental Engineering, China Univ. of Mining & Technology.
Pei, J. J., and J. S. S. Zhang. 2012. “Determination of adsorption isotherm and diffusion coefficient of toluene on activated carbon at low concentrations.” Build. Environ. 48 (Feb): 66–76. https://doi.org/10.1016/j.buildenv.2011.08.005.
Persson, B. 1998. “Experimental studies on shrinkage of high-performance concrete.” Cem. Concr. Res. 28 (7): 1023–1036. https://doi.org/10.1016/S0008-8846(98)00068-4.
Radlinska, A., F. Rajabipour, B. Bucher, R. Henkensiefken, G. Sant, and J. Weiss. 2008. “Shrinkage mitigation strategies in cementitious systems: A closer look at differences in sealed and unsealed behavior.” Transp. Res. Rec. 2070 (1): 59–67. https://doi.org/10.3141/2070-08.
Reis, P. F. O., F. Evangelista Jr., and E. F. Silva. 2020. “Profile of internal relative humidity and depth of drying in cementitious materials containing superabsorbent polymer and nano-silica particles.” Constr. Build. Mater. 237 (Mar): 117412. https://doi.org/10.1016/j.conbuildmat.2019.117412.
Schindler, A. K., and K. J. Folliard. 2005. “Heat of hydration models for cementitious materials.” ACI Mater. J. 102 (1): 24. https://doi.org/10.14359/14246.
Schroefl, C., V. Mechtcherine, P. Vontobel, J. Hovind, and E. Lehmann. 2015. “Sorption kinetics of superabsorbent polymers (SAPs) in fresh Portland cement-based pastes visualized and quantified by neutron radiography and correlated to the progress of cement hydration.” Cem. Concr. Res. 75 (Sep): 1–13. https://doi.org/10.1016/j.cemconres.2015.05.001.
Schröfl, C., K. A. Erk, W. Siriwatwechakul, M. Wyrzykowski, and D. Snoeck. 2022. “Recent progress in superabsorbent polymers for concrete.” Cem. Concr. Res. 151 (Jan): 106648. https://doi.org/10.1016/j.cemconres.2021.106648.
Schröfl, C., V. Mechtcherine, and M. Gorges. 2012. “Relation between the molecular structure and the efficiency of superabsorbent polymers (SAP) as concrete admixture to mitigate autogenous shrinkage.” Cem. Concr. Res. 42 (6): 865–873. https://doi.org/10.1016/j.cemconres.2012.03.011.
Šelih, J., and T. W. Bremner. 1996. “Drying of saturated lightweight concrete: An experimental investigation.” Mater. Struct. 29 (7): 401–405. https://doi.org/10.1007/BF02485989.
Shen, D. J., J. L. Jiang, M. Y. Zhang, P. P. Yao, and G. Q. Jiang. 2018. “Tensile creep and cracking potential of high performance concrete internally cured with super absorbent polymers at early age.” Constr. Build. Mater. 165 (Mar): 451–461. https://doi.org/10.1016/j.conbuildmat.2017.12.136.
Shen, D. J., C. Liu, Z. Z. Feng, S. S. Zhu, and C. Liang. 2019a. “Influence of ground granulated blast furnace slag on the early-age anti-cracking property of internally cured concrete.” Constr. Build. Mater. 223 (Oct): 233–243. https://doi.org/10.1016/j.conbuildmat.2019.06.149.
Shen, D. J., C. Liu, J. L. Jiang, J. C. Kang, and M. Li. 2020a. “Influence of super absorbent polymers on early-age behavior and tensile creep of internal curing high strength concrete.” Constr. Build. Mater. 258 (Oct): 120068. https://doi.org/10.1016/j.conbuildmat.2020.120068.
Shen, D. J., C. Liu, M. Wang, J. C. Kang, and M. Li. 2021. “Effect of polyvinyl alcohol fiber on the cracking risk of high strength concrete under uniaxial restrained condition at early age.” Constr. Build. Mater. 300 (Sep): 124206. https://doi.org/10.1016/j.conbuildmat.2021.124206.
Shen, D. J., C. Liu, M. L. Wang, X. C. Jin, and H. Tang. 2020b. “Prediction model for internal relative humidity in early-age concrete under different curing humidity conditions.” Constr. Build. Mater. 265 (Dec): 119987. https://doi.org/10.1016/j.conbuildmat.2020.119987.
Shen, D. J., M. L. Wang, Y. Chen, T. Wang, and J. Y. Zhang. 2017a. “Prediction model for relative humidity of early-age internally cured concrete with pre-wetted lightweight aggregates.” Constr. Build. Mater. 144 (Jul): 717–727. https://doi.org/10.1016/j.conbuildmat.2017.03.088.
Shen, D. J., M. L. Wang, Y. Chen, W. T. Wang, and J. Y. Zhang. 2017b. “Prediction of internal relative humidity in concrete modified with super absorbent polymers at early age.” Constr. Build. Mater. 149 (Sep): 543–552. https://doi.org/10.1016/j.conbuildmat.2017.05.121.
Shen, D. J., T. Wang, Y. Chen, M. L. Wang, and G. Q. Jiang. 2015. “Effect of internal curing with super absorbent polymers on the relative humidity of early-age concrete.” Constr. Build. Mater. 99 (Nov): 246–253. https://doi.org/10.1016/j.conbuildmat.2015.08.042.
Shen, D. J., B. Z. Zhou, M. L. Wang, Y. Chen, and G. Q. Jiang. 2019b. “Predicting relative humidity of early-age concrete under sealed and unsealed conditions.” Mag. Concr. Res. 71 (22): 1151–1166. https://doi.org/10.1680/jmacr.18.00068.
Sivakumar, A., and M. Santhanam. 2007. “A quantitative study on the plastic shrinkage cracking in high strength hybrid fibre reinforced concrete.” Cem. Concr. Compos. 29 (7): 575–581. https://doi.org/10.1016/j.cemconcomp.2007.03.005.
Standardization Administration of China. 2018. Common portland cement, quality supervision inspection and quarantine of the People’s Republic of China and Standardization Administration of China. GB 175-2007/XG3-2018. Beijing: Standards Press of China.
Standardization Administration of China. 2019. Standard for test methods of concrete physical and mechanical properties. GB/T 50081-2019. Beijing: Standards Press of China.
Urgessa, G., K. B. Choi, and J. H. Yeon. 2018. “Internal relative humidity, autogenous shrinkage, and strength of cement mortar modified with superabsorbent polymers.” Polymers (Basel) 10 (10): 1074. https://doi.org/10.3390/polym10101074.
Wang, F. Z., Y. Jin, C. Hua, W. Jing, and X. Y. Liang. 2015. “Study on mechanism of desorption behavior of saturated superabsorbent polymers in concrete.” ACI Mater. J. 112 (3): 463–469. https://doi.org/10.14359/51686996.
Wang, J. H., J. Zhang, X. P. Ding, and J. J. Zhang. 2018. “Effect of cementitious permanent formwork on moisture field of internal-cured concrete under drying.” Mech. Time-Depend. Mater. 22 (1): 95–127. https://doi.org/10.1007/s11043-017-9354-z.
Wei, Y., S. M. Liang, and X. Gao. 2017. “Numerical evaluation of moisture warping and stress in concrete pavement slabs with different water-to-cement ratio and thickness.” J. Eng. Mech. 143 (2): 04016111. https://doi.org/10.1061/(ASCE)EM.1943-7889.0001180.
Xu, F. M., X. S. Lin, and A. N. Zhou. 2021. “Performance of internal curing materials in high-performance concrete: A review.” Constr. Build. Mater. 311 (Dec): 125250. https://doi.org/10.1016/j.conbuildmat.2021.125250.
Yang, Q. B., and S. Q. Zhang. 2004. “Self-desiccation mechanism of high-performance concrete.” J. Zhejiang Univ. Sci. 5 (12): 1517–1523. https://doi.org/10.1631/jzus.2004.1517.
Ye, J. J., S. G. Hu, F. Z. Wang, Y. F. Zhou, and Z. C. Liu. 2006. “Effect of pre-wetted light-weight aggregate on internal relative humidity and autogenous shrinkage of concrete.” J. Wuhan Univ. Technol., Mater. Sci. Ed. 21 (1): 134–137. https://doi.org/10.1007/BF02861491.
Zhang, J., Y. Gao, and Y. D. Han. 2012. “Interior humidity of concrete under dry-wet cycles.” J. Mater. Civ. Eng. 24 (3): 289–298. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000382.
Zhang, J., Y. D. Han, Y. Gao, and Y. M. Luosun. 2013. “Integrative study on the effect of internal curing on autogenous and drying shrinkage of high-strength concrete.” Dry. Technol. 31 (5): 565–575. https://doi.org/10.1080/07373937.2012.745869.
Zhang, J., D. W. Hou, Y. Gao, and W. Sun. 2011. “Determination of moisture diffusion coefficient of concrete at early age from interior humidity measurements.” Dry. Technol. 29 (6): 689–696. https://doi.org/10.1080/07373937.2010.528106.
Zhang, J., K. Qi, and Y. Huang. 2009. “Calculation of moisture distribution in early-age concrete.” J. Eng. Mech. 135 (8): 871–880. https://doi.org/10.1061/(ASCE)0733-9399(2009)135:8(871.
Zhang, J., J. H. Wang, and X. P. Ding. 2018. “Test and simulation on moisture flow in early age concrete under drying.” Dry. Technol. 36 (2): 221–233. https://doi.org/10.1080/07373937.2017.1315588.
Zhang, J., J. H. Wang, and Y. Gao. 2016. “Moisture movement in early-age concrete under cement hydration and environmental drying.” Mag. Concr. Res. 68 (8): 391–408. https://doi.org/10.1680/jmacr.15.00293.
Zhang, J., J. H. Wang, and Y. D. Han. 2015. “Simulation of moisture field of concrete with pre-soaked lightweight aggregate addition.” Constr. Build. Mater. 96 (Oct): 599–614. https://doi.org/10.1016/j.conbuildmat.2015.08.058.
Zhong, P. H., Z. L. Hu, M. Griffa, M. Wyrzykowski, J. P. Liu, and P. Lura. 2021. “Mechanisms of internal curing water release from retentive and non-retentive superabsorbent polymers in cement paste.” Cem. Concr. Res. 147 (Sep): 106494. https://doi.org/10.1016/j.cemconres.2021.106494.
Zhutovsky, S., K. Kovler, and A. Bentur. 2011. “Revisiting the protected paste volume concept for internal curing of high-strength concretes.” Cem. Concr. Res. 41 (9): 981–986. https://doi.org/10.1016/j.cemconres.2011.05.007.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 35Issue 4April 2023

History

Received: Feb 14, 2022
Accepted: Aug 5, 2022
Published online: Jan 31, 2023
Published in print: Apr 1, 2023
Discussion open until: Jun 30, 2023

Permissions

Request permissions for this article.

Authors

Affiliations

Research Student, College of Civil and Transportation Engineering, Hohai Univ., No. 1, Xikang Rd., Nanjing 210024, China; Research Student, Jiangsu Engineering Research Center for Crack Control in Concrete, No. 1, Xikang Rd., Nanjing 210024, China. Email: [email protected]
Professor, College of Civil and Transportation Engineering, Hohai Univ., No. 1, Xikang Rd., Nanjing 210024, China; Deputy Director, Jiangsu Engineering Research Center for Crack Control in Concrete, No. 1, Xikang Rd., Nanjing 210024, China; Director, Nanjing Engineering Research Center for Prefabricated Construction, No. 1, Xikang Rd., Nanjing 210024, China (corresponding author). ORCID: https://orcid.org/0000-0002-0283-6835. Email: [email protected]
Research Student, College of Civil and Transportation Engineering, Hohai Univ., No. 1, Xikang Rd., Nanjing 210024, China; Research Student, Jiangsu Engineering Research Center for Crack Control in Concrete, No. 1, Xikang Rd., Nanjing 210024, China. ORCID: https://orcid.org/0000-0002-7419-9994. Email: [email protected]
Chengcai Li [email protected]
Research Student, College of Civil and Transportation Engineering, Hohai Univ., No. 1, Xikang Rd., Nanjing 210024, China; Research Student, Jiangsu Engineering Research Center for Crack Control in Concrete, No. 1, Xikang Rd., Nanjing 210024, China. Email: [email protected]
Jiacheng Kang [email protected]
Research Student, College of Civil and Transportation Engineering, Hohai Univ., No. 1, Xikang Rd., Nanjing 210024, China; Research Student, Jiangsu Engineering Research Center for Crack Control in Concrete, No. 1, Xikang Rd., Nanjing 210024, China. Email: [email protected]
Mingliang Wang [email protected]
Research Student, College of Civil and Transportation Engineering, Hohai Univ., No. 1, Xikang Rd., Nanjing 210024, China; Research Student, Jiangsu Engineering Research Center for Crack Control in Concrete, No. 1, Xikang Rd., Nanjing 210024, China. Email: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

  • Cracking failure behavior of high strength concrete containing nano-CaCO3 at early age, Cement and Concrete Composites, 10.1016/j.cemconcomp.2023.104996, 139, (104996), (2023).

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share