Technical Papers
Jan 31, 2023

Multifunctional Concrete with Graphene-Based Nanomaterials and Superabsorbent Polymer

Publication: Journal of Materials in Civil Engineering
Volume 35, Issue 4

Abstract

This study reports on the development of a multifunctional concrete using graphene nanoplatelet (GnP) and sodium polyacrylate (SP) superabsorbent polymer. A combination of concrete functionalities was convened to improve, i.e., high strength and durability along with smart properties such as self-healing and self-sensing. GnP (0.05% by weight of cement) and SP (0.11% by weight of cement) were dispersed in concrete. Compared to the control concrete mix (no GnP and SP), the compressive strength increased 14% by GnP and decreased 9% by SP, and their combination resulted in a 6% enhancement in strength. The durability performance of concrete samples under coupled degradation mechanisms of freeze-thaw and chloride ion ingress suggested that SP in concrete has a better performance than GnP in concrete. SP in concrete shows self-sealing abilities resulting in less chloride ion penetration. However, the combined effect of both GnP and SP in concrete resulted in the maximum reduction in chloride ion penetration depth under freeze-thaw, a 42% reduction compared to the control mix. Microstructural analysis was conducted and found to resist the effects of freeze-thaw and reduce chloride ion penetration in modified concrete compared to the control concrete mix. GnP developed self-sensing abilities in concrete, resulting in about 12.7% fractional change of electrical resistance under 10 KN of cyclic compressive loading. The synergic impact of GnP and SP possesses a new prospect for developing highly efficient multifunctional concrete.

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Data Availability Statement

Some or all data, models, or code that support the findings of this study are available from the corresponding author upon reasonable request.

Acknowledgments

The authors are grateful for Tanvir Qureshi’s Vice-Chancellor Early Career Research (VCECR) grant award and the IFA: New Starters (Faculty funded) award by the University of the West of England, Bristol, UK. The authors are also grateful for the graphene materials supply and collaboration with Zentec Ltd., Canada.

References

Al-Nasra, M. 2013. “Optimizing the use of sodium polyacrylate in plain concrete.” Int. J. Eng. Res. Appl. 3 (3): 1058–1062.
Anandkumar, M., M. Suriya, and P. Ravichandran. 2020. “Experimental study on effect of super absorption polymers in surface cracked concrete structures.” Int. J. Sci. Technol. Res. 9 (2): 812–815.
ASTM. 2012. Standard test method for bulk electrical conductivity of hardened concrete. West Conshohocken, PA: ASTM.
ASTM. 2015. Standard test method for resistance of concrete to rapid freezing and thawing. West Conshohocken, PA: ASTM.
ASTM. 2019. Standard practice for making and curing concrete test specimens in the laboratory. West Conshohocken, PA: ASTM.
BSI. 2019. Testing hardened concrete Part 3: Compressive strength of test specimens. BS EN 12390-3:2019. London: British Standard.
CEN. 2016. Testing hardened concrete - part 9: Freeze-thaw resistance with de-icing salts - scaling. CEN/TS 12390-9:2016. Brussels, Belgium: CEN.
Chen, G., M. Yang, L. Xu, Y. Zhang, and Y. Wang. 2019. “Graphene nanoplatelets impact on concrete in improving freeze-thaw resistance.” Appl. Sci. 9 (17): 3582. https://doi.org/10.3390/app9173582.
Chen, Y., X. Li, C. Li, N. Zhang, R. Liu, and C. Lu. 2021. “Improvement of flexural and compressive strength of cement mortar by graphene nanoplatelets.” Open J. Civ. Eng. 15 (1): 165–171. https://doi.org/10.2174/1874149502115010165.
Daoud, M., and M. Al-Nasra. 2014. “The use of super absorbent polymer as a sealing agent in plain concrete.” Am. J. Eng. Res. 3 (3): 132–137.
Ding, H., L. Zhang, and P. Zhang. 2017. “Factors influencing strength of super absorbent polymer (SAP) concrete.” Trans. Tianjin Univ. 23 (3): 245–257. https://doi.org/10.1007/s12209-017-0049-y.
Ding, S., Y. Xiang, Y.-Q. Ni, V. K. Thakur, X. Wang, B. Han, and J. Ou. 2022. “In-situ synthesizing carbon nanotubes on cement to develop self-sensing cementitious composites for smart high-speed rail infrastructures.” Nano Today 43 (Apr): 101438. https://doi.org/10.1016/j.nantod.2022.101438.
Dong, W., W. Li, Z. Tao, and K. Wang. 2019. “Piezoresistive properties of cement-based sensors: Review and perspective.” Constr. Build. Mater. 203 (Apr): 146–163. https://doi.org/10.1016/j.conbuildmat.2019.01.081.
Du, H., and S. Dai Pang. 2018. “Dispersion and stability of graphene nanoplatelet in water and its influence on cement composites.” Constr. Build. Mater. 167 (Apr): 403–413.
Han, B., S. Ding, J. Wang, and J. Ou. 2019. “Basic principles of nano-engineered cementitious composites.” In Nano-engineered cementitious composites, 1–96. Singapore: Springer.
Han, B., L. Zhang, S. Zeng, S. Dong, X. Yu, R. Yang, and J. Ou. 2017a. “Nano-core effect in nano-engineered cementitious composites.” Composites, Part A 95 (Apr): 100–109. https://doi.org/10.1016/j.compositesa.2017.01.008.
Han, B., Q. Zheng, S. Sun, S. Dong, L. Zhang, X. Yu, and J. Ou. 2017b. “Enhancing mechanisms of multi-layer graphenes to cementitious composites.” Composites, Part A 101 (Oct): 143–150. https://doi.org/10.1016/j.compositesa.2017.06.016.
Jensen, O., and P. Hansen. 2001. “Autogenous deformation and RH-change in perspective.” Cem. Concr. Res. 31 (12): 1859–1865. https://doi.org/10.1016/S0008-8846(01)00501-4.
Jensen, O. M. 2013. “Use of superabsorbent polymers in concrete.” Concr. Int. 35 (1): 48–52.
Kevern, J. T., and C. Farney. 2012. “Reducing curing requirements for pervious concrete with a superabsorbent polymer for internal curing.” Transp. Res. Rec. 2290 (1): 115–121. https://doi.org/10.3141/2290-15.
Le, J., H. Du, and S. Pang. 2014. “Use of 2D Graphene Nanoplatelets (GNP) in cement composites for structural health evaluation.” Composites, Part B 67 (Dec): 555–563. https://doi.org/10.1016/j.compositesb.2014.08.005.
Lee, S., K. Ha, Y. Jung, S. Jang, and I. Yeo. 2014. “Characteristics of mortar containing sodium polyacrylate absorbent synthesized by inverse emulsion polymerization.” KSCE J. Civ. Eng. 18 (5): 1397–1402. https://doi.org/10.1007/s12205-014-0167-1.
Lo, T. 2005. Carbonation & chloride penetration of concrete structures.” In Annual Concrete Seminar. Hong Kong: City Univ. of Hong Kong.
Long, W., T. Ye, L. Li, and G. Feng. 2019. “Electrochemical characterization and inhibiting mechanism on calcium leaching of graphene oxide reinforced cement composites.” Nanomaterials (Basel) 9 (2): 2–19. https://doi.org/10.3390/nano9020288.
Long, W.-J., J.-J. Wei, F. Xing, and K. H. Khayat. 2018. “Enhanced dynamic mechanical properties of cement paste modified with graphene oxide nanosheets and its reinforcing mechanism.” Cem. Concr. Compos. 93 (Oct): 127–139. https://doi.org/10.1016/j.cemconcomp.2018.07.001.
Manzur, T., S. Iffat, and M. A. Noor. 2015. “Efficiency of sodium polyacrylate to improve durability of concrete under adverse curing condition.” Adv. Mater. Sci. Eng. 2015 (Jan): 1–8. https://doi.org/10.1155/2015/685785.
Mohammed, A., J. Sanjayan, W. Duan, and A. Nazari. 2016. “Graphene oxide impact on hardened cement expressed in enhanced freeze-thaw resistance.” J. Mater. Civ. Eng. 28 (9): 04016072. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001586.
NT BUILD (NORDTEST). 1995. Concrete, hardened: Accelerated chloride penetration. NT BUILD 443. Finland: Esbo.
Olafusi, O. S., E. R. Sadiku, J. Snyman, J. M. Ndambuki, and W. K. Kupolati. 2019. “Application of nanotechnology in concrete and supplementary cementitious materials: A review for sustainable construction.” SN Appl. Sci. 1 (6): 1–8. https://doi.org/10.1007/s42452-019-0600-7.
Qureshi, T., and A. Al-Tabbaa. 2020. “Self-healing concrete and cementitious materials.” In Advanced functional materials. London: IntechOpen.
Qureshi, T. S., A. Kanellopoulos, and A. Al-Tabbaa. 2016. “Encapsulation of expansive powder minerals within a concentric glass capsule system for self-healing concrete.” Constr. Build. Mater. 121 (Sep): 629–643. https://doi.org/10.1016/j.conbuildmat.2016.06.030.
Qureshi, T. S., and D. K. Panesar. 2017. “A review: The effect of graphene oxide on the properties of cement-based composites.” In Vol. 31 of Proc., CSCE Annual Conf., 1–10. Vancouver, BC, Canada: Canadian Society for Civil Engineering.
Qureshi, T. S., and D. K. Panesar. 2019a. “A comparison of graphene oxide, reduced graphene oxide and pure graphene: Early age properties of cement composites.” In Proc., 2nd RILEM Spring Convention & Int. Conf. on Sustainable Materials, Systems and Structures. Paris: RILEM.
Qureshi, T. S., and D. K. Panesar. 2019b. “Impact of graphene oxide and highly reduced graphene oxide on cement-based composites.” Constr. Build. Mater. 206 (May): 71–83. https://doi.org/10.1016/j.conbuildmat.2019.01.176.
Qureshi, T. S., and D. K. Panesar. 2020. “Nano reinforced cement paste composite with functionalized graphene and pristine graphene nanoplatelets.” Composites, Part B 197 (Sep): 108063. https://doi.org/10.1016/j.compositesb.2020.108063.
Qureshi, T. S., D. K. Panesar, and K. Peterson. 2019c. “Thin section microscopy and DVS study to determine the influence of graphene materials on the microstructure of cement-based composite.” In Proc., 17th Euroseminar on Microscopy Applied to Building Materials, 134–140. Toronto: Univ. of Toronto.
Qureshi, T. S., D. K. Panesar, B. Sidhureddy, A. Chen, and P. C. Wood. 2019d. “Nano-cement composite with graphene oxide produced from epigenetic graphite deposit.” Composites, Part B 159 (Feb): 248–258. https://doi.org/10.1016/j.compositesb.2018.09.095.
Rajput, K. 2020. “Concrete mix ratio | What is concrete mix ratio | Types of concrete mix ratio.” Accessed October 15, 2020. https://civiljungle.com/concrete-mix-ratio/.
Siahkouhi, M., G. Razaqpur, N. Hoult, M. Hajmohammadian Baghban, and G. Jing. 2021. “Utilization of carbon nanotubes (CNTs) in concrete for structural health monitoring (SHM) purposes: A review.” Constr. Build. Mater. 309 (Nov): 125–137. https://doi.org/10.1016/j.conbuildmat.2021.125137.
Snoeck, D., K. Van Tittelboom, N. De Belie, S. Steuperaert, and P. Peter Delruel. 2012. “The use of superabsorbent polymers as a crack sealing and crack healing mechanism in cementitious materials.” In Proc., 3rd Int. Conf. on Concrete Repair, Rehabilitation and Retrofitting, 152–157. Paris: RILEM.
Sun, S., B. Han, S. Jiang, X. Yu, Y. Wang, H. Li, and J. Ou. 2017. “Nano graphite platelets-enabled piezoresistive cementitious composites for structural health monitoring.” Constr. Build. Mater. 136 (Apr): 314–328. https://doi.org/10.1016/j.conbuildmat.2017.01.006.
Tao, J., X. Wang, Z. Wang, and Q. Zeng. 2019. “Graphene nanoplatelets as an effective additive to tune the microstructures and piezoresistive properties of cement-based composites.” Constr. Build. Mater. 209 (Jun): 665–678. https://doi.org/10.1016/j.conbuildmat.2019.03.173.
Wang, B., R. Jiang, and Z. Wu. 2016. “Investigation of the mechanical properties and microstructure of graphene nanoplatelet-cement composite.” Nanomaterials (Basel) 6 (11): 200. https://doi.org/10.3390/nano6110200.
Wang, J., S. Dong, C. Zhou, A. Ashour, and B. Han. 2021. “Investigating pore structure of nano-engineered concrete with low-field nuclear magnetic resonance.” J. Mater. Sci. 56 (1): 243–259. https://doi.org/10.1007/s10853-020-05268-0.
Wang, J., B. Han, Z. Li, X. Yu, and X. Dong. 2019. “Effect investigation of nanofillers on CSH gel structure with Si NMR.” J. Mater. Civ. Eng. 31 (1): 04018352. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002559.
Wu, S., T. Qureshi, and G. Wang. 2021. “Application of graphene in fiber-reinforced cementitious composites: A review.” Energies 14 (15): 4614. https://doi.org/10.3390/en14154614.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 35Issue 4April 2023

History

Received: Mar 10, 2022
Accepted: Aug 3, 2022
Published online: Jan 31, 2023
Published in print: Apr 1, 2023
Discussion open until: Jun 30, 2023

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Senior Lecturer, Dept. of Geography and Environmental Management, Univ. of the West of England, Coldharbour Lane, Frenchay, Bristol BS16 1QY, UK (corresponding author). ORCID: https://orcid.org/0000-0002-8959-9181. Email: [email protected]
M.Sc. Civil Engineering Student, Dept. of Geography and Environmental Management, Univ. of the West of England, Coldharbour Lane, Frenchay, Bristol BS16 1QY, UK. ORCID: https://orcid.org/0000-0003-1942-3014. Email: [email protected]

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  • Nanoengineered Geopolymer Composites with Biomass-Based 2D Graphitic Carbon Nanoplatelets, Journal of Materials in Civil Engineering, 10.1061/JMCEE7.MTENG-18126, 36, 8, (2024).

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