Effect of Pore Physical and Chemical Microstructure Properties on Durability and Rebar Corrosion of Self-Compacting Concretes Containing Silica Fume and Metakaolin
Publication: Journal of Materials in Civil Engineering
Volume 34, Issue 12
Abstract
This study aims to investigate the effect of pore physical and chemical microstructure factors on the durability properties of self-compacting concrete containing metakaolin and silica fume. This study identified the pore physical microstructure characteristics including pore size distribution, total porosity, pore connectivity factor, and the volume of large and small capillary pores. The pore chemical microstructure factors, including the concentration of potassium and sodium ions, were analyzed. The durability of self-compacting concretes including electrical resistance, chloride ion migration, and resistance to rebar corrosion (using rebar corrosion rate) was evaluated. The self-compacting concrete mixtures were considered based on the water-to-cementitious materials () ratios of 0.35, 0.45, and 0.55 and using silica fume substituting 0% and 8% of cement by weight, Also, for of 0.45, metakaolin and silica fume and cement were considered as the binder. Results indicate that in self-consolidating concretes (SCCs) without pozzolans, the volume of the large capillary pores affects the rate of rebar corrosion. No significant relationship was observed between the pore physical microstructure characteristics and rebar corrosion rate of pozzolanic SCCs.
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Data Availability Statement
Some or all data, models, or code that support the findings of this study are available from the corresponding author upon reasonable request.
References
Aguirre, A. M., and R. Mejía de Gutiérrez. 2013. “Durability of reinforced concrete exposed to aggressive conditions.” Mater. Constr. 63 (23): 309. https://doi.org/10.3989/mc.2013.00313.
Aguirre-Guerrero, A. M., R. Mejía-de-Gutiérrez, and M. João Ribeiro Montês-Correia. 2016. “Corrosion performance of blended concretes exposed to different aggressive environments.” Constr. Build. Mater. 121 (Sep): 704–716. https://doi.org/10.1016/j.conbuildmat.2016.06.038.
Al-alaily, H. S., and A. A. A. Hassan. 2016. “Time-dependence of chloride diffusion for concrete containing metakaolin.” J. Build. Eng. 7 (Jun): 159–169. https://doi.org/10.1016/j.jobe.2016.06.003.
Ambroise, J., S. Maximilien, and J. Pera. 1994. “Properties of metakaolin blended cements.” Adv. Cem. Based Mater. 1 (4): 161–168. https://doi.org/10.1016/1065-7355(94)90007-8.
Andrade, C., and C. Alonso. 1996. “Corrosion rate monitoring in the laboratory and on-site.” Constr. Build. Mater. 10 (5): 315–328. https://doi.org/10.1016/0950-0618(95)00044-5.
ASTM. 1999. Standard test method for half-cell potentials of uncoated reinforcing steel in concrete. ASTM C876. West Conshohocken, PA: ASTM.
ASTM. 2011. Standard specification for portland cement. ASTM C150-04. West Conshohocken, PA: ASTM.
Atahan, H. N., O. Nuri Oktar, and M. Ali Tas. 2009. “Effects of water—Cement ratio and curing time on the critical pore width of hardened cement paste.” Constr. Build. Mater. 23 (3): 1196–1200. https://doi.org/10.1016/j.conbuildmat.2008.08.011.
Belin, P., G. Habert, M. Thiery, and N. Roussel. 2014. “Cement paste content and water absorption of recycled concrete coarse aggregates.” Mater. Struct. 47 (9): 1451–1465. https://doi.org/10.1617/s11527-013-0128-z.
Bentz, D. P. 2007. “A virtual rapid chloride permeability test.” Cem. Concr. Compos. 29 (Nov): 723–731. https://doi.org/10.1016/j.cemconcomp.2007.06.006.
Broomfield, J. P. 2006. Corrosion of steel in concrete: Understanding, investigation and repair. London: CRC Press.
Cabera, J., and P. Ghoddousi. 1994. “The influence of fly ash on the resistivity and rate of corrosion of reinforced concrete.” In Proc., Int. Conf. on Durability of Concrete. Farmington Hills, MI: American Concrete Institute.
Cam, H. T., and N. Neithalath. 2010. “Moisture and ionic transport in concretes containing coarse limestone powder.” Cem. Concr. Compos. 32 (7): 486–496. https://doi.org/10.1016/j.cemconcomp.2010.04.002.
Chen, X., and S. Wu. 2013. Influence of water-to-cement ratio and curing period on pore structure of cement mortar, 804–812. New York: Elsevier.
Cwirzen, A., and V. Penttala. 2005. “Aggregate–cement paste transition zone properties affecting the salt–frost damage of high-performance concretes.” Cem. Concr. Res. 35 (4): 671–679. https://doi.org/10.1016/j.cemconres.2004.06.009.
Dadsetan, S., and J. Bai. 2017. “Mechanical and microstructural properties of self-compacting concrete blended with metakaolin, ground granulated blast-furnace slag and fly ash.” Constr. Build. Mater. 146 (Aug): 658–667. https://doi.org/10.1016/j.conbuildmat.2017.04.158.
Das, B. B., and B. Kondraivendhan. 2012. “Implication of pore size distribution parameters on compressive strength, permeability and hydraulic diffusivity of concrete.” Constr. Build. Mater. 28 (1): 382–386. https://doi.org/10.1016/j.conbuildmat.2011.08.055.
Dotto, J. M. R., A. G. de Abreu, D. C. C. Dal Molin, and I. L. Müller. 2004. “Influence of silica fume addition on concretes physical properties and on corrosion behaviour of reinforcement bars.” Cem. Concr. Compos. 26 (1): 31–39. https://doi.org/10.1016/S0958-9465(02)00120-8.
Duan, P., Z. Shui, W. Chen, and C. Shen. 2013. “Enhancing microstructure and durability of concrete from ground granulated blast furnace slag and metakaolin.” J. Mater. Res. Technol. 2 (1): 52–59. https://doi.org/10.1016/j.jmrt.2013.03.010.
European Federation for Specialist Construction Chemicals and Concrete Systems. 2002. Guidelines for self-compacting concrete. Brussels, Belgium: European Federation of National Associations.
Filho, J. H., M. H. F. Medeiros, E. Pereira, P. Helene, and G. C. Isaia. 2013. “High-volume fly ash concrete with and without hydrated lime: Chloride diffusion coefficient from accelerated test.” J. Mater. Civ. Eng. 25 (3): 411–418. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000596.
Frías, M., M. I. Sánchez de Rojas, and J. Cabrera. 2000. “The effect that the pozzolanic reaction of metakaolin has on the heat evolution in metakaolin-cement mortars.” Cem. Concr. Res. 30 (2): 209–216. https://doi.org/10.1016/S0008-8846(99)00231-8.
Ghoddousi, P., and L. Adelzade Saadabadi. 2017. “Study on hydration products by electrical resistivity for self-compacting concrete with silica fume and metakaolin.” Constr. Build. Mater. 154 (Nov): 219–228. https://doi.org/10.1016/j.conbuildmat.2017.07.178.
Ghoddousi, P., and L. Adelzade Saadabadi. 2018. “Pore structure indicators of chloride transport in metakaolin and silica fume self-compacting concrete.” Int. J. Civ. Eng. 16 (5): 583–592. https://doi.org/10.1007/s40999-017-0164-0.
Ghoddousi, P., and T. Parhizkar. 2007. “The effect of concrete quality on performance of surface treatment materials.” In Proc., Sustainable Construction Materials and Technologies, 78–84. Coventry, UK: UW Milwaukee CBU.
Ghoddousi, P., T. Parhizkar, A. Akbar Ramezanianpour, and N. Mozaffari. 2004. Concrete technology in the environmental conditions of Persion Gulf. Tehran, Iran: Building and Housing Research Center.
Güneyisi, E., M. Gesoǧlu, F. Karaboǧa, and K. Mermerdaş. 2013. “Corrosion behavior of reinforcing steel embedded in chloride contaminated concretes with and without metakaolin.” Composites, Part B 45 (1): 1288–1295. https://doi.org/10.1016/j.compositesb.2012.09.085.
Hassan, A. A. A., M. Lachemi, M. Khandaker, and M. A. Hossain. 2012. “Effect of metakaolin and silica fume on the durability of self-consolidating concrete.” Cem. Concr. Compos. 34 (6): 801–807. https://doi.org/10.1016/j.cemconcomp.2012.02.013.
Hooton, M. R., Æ. Nokken, R. D. Conductivity, Á. Permeability, and Á. Katz Thompson. 2008. “Using pore parameters to estimate permeability or conductivity of concrete.” Mater. Struct. 41 (1): 1–16. https://doi.org/10.1617/s11527-006-9212-y.
Hossain, M. M., M. R. Karim, M. Hasan, M. K. Hossain, and M. F. M. Zain. 2016. “Durability of mortar and concrete made up of pozzolans as a partial replacement of cement: A review.” Constr. Build. Mater. 116 (Mar): 128–140. https://doi.org/10.1016/j.conbuildmat.2016.04.147.
Iqbal, M., and R. Siddique. 2011. “Resources, conservation and recycling utilization of silica fume in concrete: Review of durability properties.” Resour. Conserv. Recycl. 57 (Apr): 30–35. https://doi.org/10.1016/j.resconrec.2011.09.016.
Karahan, O., K. M. A. Hossain, E. Ozbay, M. Lachemi, and E. Sancak. 2012. “Effect of metakaolin content on the properties self-consolidating lightweight concrete.” Constr. Build. Mater. 31 (Jun): 320–325. https://doi.org/10.1016/j.conbuildmat.2011.12.112.
Keleştemur, O., and B. Demirel. 2010. “Corrosion behavior of reinforcing steel embedded in concrete produced with finely ground pumice and silica fume.” Constr. Build. Mater. 24 (10): 1898–1905. https://doi.org/10.1016/j.conbuildmat.2010.04.013.
Khatib, J. M., and S. Wild. 1996. “Pore size distribution of metakaolin paste.” Cem. Concr. Res. 26 (10): 1545–1553. https://doi.org/10.1016/0008-8846(96)00147-0.
Kocak, Y. 2020. “Effects of metakaolin on the hydration development of portland–composite cement.” J. Build. Eng. 31 (Jan): 101419. https://doi.org/10.1016/j.jobe.2020.101419.
Kumar, R., and B. Bhattacharjee. 2004. “Assessment of permeation quality of concrete through mercury intrusion porosimetry.” Cem. Concr. Res. 34 (2): 321–328. https://doi.org/10.1016/j.cemconres.2003.08.013.
Kuzielová, E., M. Žemlička, E. Bartoničková, and M. T. Palou. 2017. “The correlation between porosity and mechanical properties of multicomponent systems consisting of portland cement–slag–silica fume–metakaolin.” Constr. Build. Mater. 135 (Dec): 306–314. https://doi.org/10.1016/j.conbuildmat.2016.12.105.
Lee, C. L., R. Huang, W. T. Lin, and T. L. Weng. 2012. “Establishment of the durability indices for cement-based composite containing supplementary cementitious materials.” Mater. Des. 37 (Dec): 28–39. https://doi.org/10.1016/j.matdes.2011.12.030.
Li, Y. X., Y. M. Chen, J. X. Wei, X. Y. He, H. T. Zhang, and W. S. Zhang. 2006. “A study on the relationship between porosity of the cement paste with mineral additives and compressive strength of mortar based on this paste.” Cem. Concr. Res. 36 (9): 1740–1743. https://doi.org/10.1016/j.cemconres.2004.07.007.
Liu, J., Q. Q. Guangfeng Ou, X. Chen, J. Hong, and F. Xing. 2017. “Chloride transport and microstructure of concrete with/without fly ash under atmospheric chloride condition.” Constr. Build. Mater. 146 (Jan): 493–501. https://doi.org/10.1016/j.conbuildmat.2017.04.018.
Liu, Z., Y. Zhang, and Q. Jiang. 2014. “Continuous tracking of the relationship between resistivity and pore structure of cement pastes.” Constr. Build. Mater. 53 (Nov): 26–31. https://doi.org/10.1016/j.conbuildmat.2013.11.067.
Madandoust, R., and S. Yasin Mousavi. 2012. “Fresh and hardened properties of self-compacting concrete containing metakaolin.” Constr. Build. Mater. 35 (3): 752–760. https://doi.org/10.1016/j.conbuildmat.2012.04.109.
Marcotte, T. D., and C. M. Hansson. 2003. “The influence of silica fume on the corrosion resistance of steel in high performance concrete exposed to simulated sea water.” J. Mater. Sci. 38 (23): 4765–4776. https://doi.org/10.1023/A:1027431203746.
Mlinárik, L., and K. Kopecskó. 2013. “Cement hydration in the presence of metakaolin.” In Proc., 2nd Conf. of Junior Researchers in Civil Engineering, 120–124. Budapest, Hungary: Budapest Univ. of Technology and Economics.
Neithalath, N., and J. Jain. 2010. “Relating rapid chloride transport parameters of concretes to microstructural features extracted from electrical impedance.” Cem. Concr. Res. 40 (7): 1041–1051. https://doi.org/10.1016/j.cemconres.2010.02.016.
NT Build 492. 1999. Concrete, mortar and cement-based repair materials: Chloride migration coefficient from non-steady-state migration experiments. Copenhagen, Denmark: Nordic Council of Ministers.
Page, C. L., and Ø. Vennesland. 1983. “Pore solution composition and chloride binding capacity of silica-fume cement pastes.” J. Matériaux et Constr. 16 (1): 19–25. https://doi.org/10.1007/BF02474863.
Parande, A. K., B. Ramesh Babu, M. Aswin Karthik, K. K. Deepak Kumaar, and N. Palaniswamy. 2008. “Study on strength and corrosion performance for steel embedded in metakaolin blended concrete/mortar.” Constr. Build. Mater. 22 (3): 127–134. https://doi.org/10.1016/j.conbuildmat.2006.10.003.
Pilvar, A., A. Akbar, and H. Rajaie. 2015. “New method development for evaluation concrete chloride ion permeability.” Constr. Build. Mater. 93 (18): 790–797. https://doi.org/10.1016/j.conbuildmat.2015.05.092.
Poon, C. S., L. Lam, S. C. Kou, Y.-L. Wong, and R. Wong. 2001. “Rate of pozzolanic reaction of metakaolin in high-performance cement pastes.” Cem. Concr. Res. 31 (9): 1301–1306. https://doi.org/10.1016/S0008-8846(01)00581-6.
Qin, Z., Z. Z. Cong Ma, G. Long, and B. Chen. 2020. “Effects of metakaolin on properties and microstructure of magnesium phosphate cement.” Constr. Build. Mater. 234 (13): 117353. https://doi.org/10.1016/j.conbuildmat.2019.117353.
Rajabipour, F., and J. Weiss. 2007. “Electrical conductivity of drying cement paste.” Mater. Struct. 40 (10): 1143–1160. https://doi.org/10.1617/s11527-006-9211-z.
Ramezanianpour, A. A., and H. Bahrami Jovein. 2012. “Influence of metakaolin as supplementary cementing material on strength and durability of concretes.” Constr. Build. Mater. 30 (23): 470–479. https://doi.org/10.1016/j.conbuildmat.2011.12.050.
Ramezanianpour, A. A., H. R. Rezaei, and H. R. Savoj. 2015. “Influence of silica fume on chloride diffusion and corrosion resistance of concrete—A review.” Asian J. Civ. Eng. 16 (3): 301–321.
RILEM Technical Committee. 2007. “Final report of RILEM TC 205-DSC: Durability of self-compacting concrete.” Mater. Struct. 41 (2): 225–233. https://doi.org/10.1617/s11527-007-9319-9.
Scott, A., and M. G. Alexander. 2016. “Cement and concrete research effect of supplementary cementitious materials (binder type) on the pore solution chemistry and the corrosion of steel in alkaline environments.” Cem. Concr. Res. 89 (Sep): 45–55. https://doi.org/10.1016/j.cemconres.2016.08.007.
Shi, X., N. Xie, K. Fortune, and J. Gong. 2012. “Durability of steel reinforced concrete in chloride environments: An overview.” Constr. Build. Mater. 30 (Sep): 125–138. https://doi.org/10.1016/j.conbuildmat.2011.12.038.
Shi, Z., Z. Shui, Q. Li, and H. Geng. 2015. “Combined effect of metakaolin and sea water on performance and microstructures of concrete.” Constr. Build. Mater. 74 (Jan): 57–64. https://doi.org/10.1016/j.conbuildmat.2014.10.023.
Snyder, K. A., X. Feng, B. D. Keen, T. Mason, K. A. Snydera, X. Fenga, B. D. Keenc, and T. O. Masonb. 2003. “Estimating the electrical conductivity of cement paste pore solutions from , and concentrations.” Cem. Concr. Res. 33 (6): 793–798. https://doi.org/10.1016/S0008-8846(02)01068-2.
Song, H. W., J. C. Jang, V. Saraswathy, and K. J. Byun. 2007. “An estimation of the diffusivity of silica fume concrete.” Build. Environ. 42 (3): 1358–1367. https://doi.org/10.1016/j.buildenv.2005.11.019.
Stern, M., and A. L. Geaby. 1957. “Electrochemical polarization.” J. Electrochem. Soc. 104 (1): 56. https://doi.org/10.1149/1.2428496.
Talero, R. 2012. “Synergic effect of Friedel’s salt from pozzolan and from OPC co-precipitating in a chloride solution.” Constr. Build. Mater. 33 (Dec): 164–180. https://doi.org/10.1016/j.conbuildmat.2011.12.040.
Türkmen, İ., M. Gavgalı, and R. Gül. 2003. “Influence of mineral admixtures on the mechanical properties and corrosion of steel embedded in high strength concrete.” Mater. Lett. 57 (13): 2037–2043. https://doi.org/10.1016/S0167-577X(02)01136-9.
Vollpracht, A., B. Lothenbach, R. Snellings, and J. Haufe. 2015. “The pore solution of blended cements: A review.” Mater. Struct. 49 (Dec): 3341–3367. https://doi.org/10.1617/s11527-015-0724-1.
Weiss, W., T. Barrett, C. Qiao, and H. Todak. 2016. “Toward a specification for transport properties of concrete based on the formation factor of a sealed specimen.” Journals 5 (1): 179–194. https://doi.org/10.1520/ACEM20160004.
Weiss, W., R. Spragg, O. Isgor, M. Ley, and T. Van Dam. 2017. “Toward performance specifications for concrete: Linking resistivity, RCPT and diffusion predictions using the formation factor for use in specifications.” In Proc., 2017 fib Symp. Lausanne, Switzerland: International Federation for Structural Concrete.
Xie, J., L. D. Heng Zhang, J. Y. Yongzhu Yang, and X. L. Doudou Shan. 2020. “Effect of nano metakaolin on compressive strength of recycled concrete.” Constr. Build. Mater. 256 (20): 119393. https://doi.org/10.1016/j.conbuildmat.2020.119393.
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Received: Apr 24, 2021
Accepted: Mar 21, 2022
Published online: Sep 27, 2022
Published in print: Dec 1, 2022
Discussion open until: Feb 27, 2023
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