Preparation and Performance of Polyphosphoric Acid/Bio-Oil Composite–Modified Asphalt Containing a High Content Bio-Oil
Publication: Journal of Materials in Civil Engineering
Volume 34, Issue 3
Abstract
As an important ecofriendly material in pavement engineering, bioasphalt has received more and more attention recently. However, the negative high-temperature behavior of bioasphalt limits its extensive application. With the purpose of enhancing the bioasphalt high-temperature behavior, polyphosphoric acid (PPA) was used to modify bioasphalt. The PPA/bio-oil composite–modified asphalt’s high-temperature behavior was investigated by the dynamic shear rheometer (DSR) test. The low-temperature behavior was evaluated by using the bending beam rheometer (BBR) test. Finally, the modification mechanism of modified asphalt was analyzed by carrying out a Fourier-transform infrared reflection (FTIR) test. The results indicated that compared with the neat asphalt, the rutting index of PPA/bio-oil composite–modified asphalt was significantly improved. Also, it had excellent low-temperature crack resistance. As the bio-oil and PPA contents in respect to the weight of neat asphalt were 15% and 5%, respectively, PPA/bio-oil composite–modified asphalt performance was optimal. Shear time and shear rate did not have a remarkable effect on PPA/bio-oil composite–modified asphalt performance. Moreover, bio-oil did not affect the chemical structure of the neat asphalt. But, PPA generated new chemical functional groups with neat asphalt and produced chemical modification. This research makes pavement engineering greener, more economical, and environmentally friendly.
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Data Availability Statement
Some or all data, models, or code that support the findings of this study are available from the corresponding author upon reasonable request.
Acknowledgments
This work was supported by the National Natural Science Foundation of China (52078063), the Postgraduate Scientific Research Innovation Project of Hunan Province (CX20200822), the science and technology innovation project of Shanghai Chengtou (group) Co., Ltd (CTKY-PTRC-2018-003), and the Project of Shenzhen Municipal Engineering Corporation(2020zkhx387).
References
AASHTO. 2005. Standard method of test for determining the flexural creep stiffness of asphalt binder using the bending beam rheometer (BBR). AASHTO T 313-05. Washington, DC: AASHTO.
Cao, X., P. Liu, and B. Tang. 2015. “Review of research progress in bio-asphalt.” Mater. Rep. 29 (17): 95–100.
Cao, Z., M. Chen, J. Yu, and X. Han. 2020. “Preparation and characterization of active rejuvenated SBS modified bitumen for the sustainable development of high-grade asphalt pavement.” J. Cleaner Prod. 273 (Nov): 123012. https://doi.org/10.1016/j.jclepro.2020.123012.
Dong, Z., C. Yang, H. Luan, T. Zhou, and P. Wang. 2019. “Chemical characteristics of bio-asphalt and its rheological properties after CR/SBS composite modification.” Constr. Build. Mater. 200 (Mar): 46–54. https://doi.org/10.1016/j.conbuildmat.2018.12.092.
Fini, E. H., E. W. Kalberer, A. Shahbazi, M. Basti, Z. You, H. Ozer, and Q. Aurangzeb. 2011. “Chemical characterization of biobinder from swine manure: Sustainable modifier for asphalt binder.” J. Mater. Civ. Eng. 23 (11): 1506–1513. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000237.
Gama, D. A., Y. Yan, J. K. G. Rodrigues, and R. Roque. 2018. “Optimizing the use of reactive terpolymer, polyphosphoric acid and high-density polyethylene to achieve asphalt binders with superior performance.” Constr. Build. Mater. 169 (Apr): 522–529. https://doi.org/10.1016/j.conbuildmat.2018.02.206.
Gao, J., W. Hainian, Y. Zhanping, C. Xi, and J. Xin. 2017. “High-temperature performance evaluation of bio-asphalt on the basis of MSCR test.” J. South China Univ. Technol. 45 (11): 24–30. https://doi.org/10.3969/j.issn.1000-565X.2017.11.004.
Gao, J., H. Wang, C. Liu, D. Ge, Z. You, and M. Yu. 2020. “High-temperature rheological behavior and fatigue performance of lignin modified asphalt binder.” Constr. Build. Mater. 230 (11): 117063. https://doi.org/10.1016/j.conbuildmat.2019.117063.
Gao, J., H. Wang, Z. You, and M. R. Mohd Hasan. 2018. “Research on properties of bio-asphalt binders based on time and frequency sweep test.” Constr. Build. Mater. 160 (Jan): 786–793. https://doi.org/10.1016/j.conbuildmat.2018.01.048.
Ge, D., K. Yan, L. You, and Z. Wang. 2017. “Modification mechanism of asphalt modified with Sasobit and Polyphosphoric acid (PPA).” Constr. Build. Mater. 143 (Jan): 419–428. https://doi.org/10.1016/j.conbuildmat.2017.03.043.
Gong, M., J. Yang, J. Zhang, H. Zhu, and T. Tong. 2016. “Physical–chemical properties of aged asphalt rejuvenated by bio-oil derived from biodiesel residue.” Constr. Build. Mater. 105 (Feb): 35–45. https://doi.org/10.1016/j.conbuildmat.2015.12.025.
He, J., R. Zhu, and B. Lin. 2019. “Prospects, obstacles and solutions of biomass power industry in China.” J. Cleaner Prod. 237 (Nov): 117783. https://doi.org/10.1016/j.jclepro.2019.117783.
Highway Research Institute of the Transportation Department. 2011. Standard test methods of bitumen and bituminous mixtures for highway engineering. JTG E20-2011. Beijing: China Communications Press.
Hossain, Z., M. S. Alam, and G. Baumgardner. 2020. “Evaluation of rheological performance and moisture susceptibility of polyphosphoric acid modified asphalt binders.” Road Mater. Pavement Des. 21 (1): 237–252. https://doi.org/10.1080/14680629.2018.1483261.
Jiang, X. 2018. “Study on property of polymer composite bio-asphalt.” Accessed June 6, 2018. https://kns.cnki.net/KCMS/detail/detail.aspx?dbname=CMFD201901&filename=1018791197.nh.
Jiang, X., P. Li, Z. Ding, L. Yang, and J. Zhao. 2019. “Investigations on viscosity and flow behavior of polyphosphoric acid (PPA) modified asphalt at high temperatures.” Constr. Build. Mater. 228 (Dec): 116610. https://doi.org/10.1016/j.conbuildmat.2019.07.336.
Li, N. 2016. “Experimental study and economic analysis of biomass pyrolysis liquefaction device.” Accessed June 16, 2016. https://kns.cnki.net/kcms/detail/detail.aspx?FileName=1016230988.nh&DbName=CMFD2017.
Liang, M., S. Ren, W. Fan, H. Wang, W. Cui, and P. Zhao. 2017. “Characterization of fume composition and rheological properties of asphalt with crumb rubber activated by microwave and TOR.” Constr. Build. Mater. 154 (Nov): 310–322. https://doi.org/10.1016/j.matdes.2017.04.060.
Liao, X., M. Lei, Z. Chen, Y. Zhu, and J. Zhu. 2014. “Experimental research on the pavement performance of bio-binder mixing asphalt.” Mater. Rep. 28 (2): 144–149.
Liu, Z., and Q. Ye. 2012. “Research on rheological properties of polyphosphoric acid modified asphalt.” Highway 2012 (11): 198–200. https://doi.org/10.3969/j.issn.0451-0712.2012.11.044.
Lu, Q. 2016. “Study of using waste oil modified asphalt to enhance the low temperature of asphalt.” Highway Eng. 41 (3): 74–77. https://doi.org/10.3969/j.issn.1674-0610.2016.03.016.
Lv, S., X. Peng, C. Liu, F. Qu, X. Zhu, W. Tian, and J. Zheng. 2020a. “Aging resistance evaluation of asphalt modified by Buton-rock asphalt and bio-oil based on the rheological and microscopic characteristics.” J. Cleaner Prod. 257 (Jun): 120589. https://doi.org/10.1016/j.jclepro.2020.120589.
Lv, S., J. Yuan, X. Peng, M. Borges Cabrera, S. Guo, X. Luo, and J. Gao. 2020b. “Performance and optimization of bio-oil/Buton rock asphalt composite modified asphalt.” Constr. Build. Mater. 264 (Dec): 120235. https://doi.org/10.1016/j.conbuildmat.2020.120235.
Lv, S., J. Yuan, X. Peng, B. C. Milkos, H. Liu, X. Luo, and L. You. 2020c. “Standardization to evaluate the lasting capacity of rubberized asphalt mixtures with different testing approaches.” Constr. Build. Mater. 269 (Feb): 121341. https://doi.org/10.1016/j.conbuildmat.2020.121341.
Ma, Q., X. Xin, W. Fan, M. Liang, and X. Wang. 2015. “Rheological properties and modification mechanism of PPA modified asphalt.” J. China Univ. Pet. 39 (6): 165–170. https://doi.org/10.3969/j.issn.1673-5005.2015.06.022.
Ma, Y., W. Hu, P. A. Polaczyk, B. Han, R. Xiao, M. Zhang, and B. Huang. 2020. “Rheological and aging characteristics of the recycled asphalt binders with different rejuvenator incorporation methods.” J. Cleaner Prod. 262 (Jul): 121249. https://doi.org/10.1016/j.jclepro.2020.121249.
Ma, Y., S. Wang, H. Zhou, W. Hu, P. Polaczyk, M. Zhang, and B. Huang. 2021. “Compatibility and rheological characterization of asphalt modified with recycled rubber-plastic blends.” Constr. Build. Mater. 270 (Feb): 121416. https://doi.org/10.1016/j.conbuildmat.2020.121416.
Qian, C., W. Fan, F. Ren, X. Lv, and B. Xing. 2019. “Influence of polyphosphoric acid (PPA) on properties of crumb rubber (CR) modified asphalt.” Constr. Build. Mater. 227 (Dec): 117094. https://doi.org/10.1016/j.conbuildmat.2019.117094.
Raouf, M. A., and R. C. Williams. 2010. “Temperature and shear susceptibility of a nonpetroleum binder as a pavement material.” Transp. Res. Rec. 2180 (1): 9–18. https://doi.org/10.3141/2180-02.
Samieadel, A., and E. H. Fini. 2020. “Interplay between wax and polyphosphoric acid and its effect on bitumen thermomechanical properties.” Constr. Build. Mater. 243 (May): 118194. https://doi.org/10.1016/j.conbuildmat.2020.118194.
Su, N., F. Xiao, J. Wang, L. Cong, and S. Amirkhanian. 2018. “Productions and applications of bio-asphalts—A review.” Constr. Build. Mater. 183 (Sep): 578–591. https://doi.org/10.1016/j.conbuildmat.2018.06.118.
Sun, D., T. Lu, F. Xiao, X. Zhu, and G. Sun. 2017. “Formulation and aging resistance of modified bio-asphalt containing high percentage of waste cooking oil residues.” J. Cleaner Prod. 161 (Sep): 1203–1214. https://doi.org/10.1016/j.jclepro.2017.06.155.
Tan, Y., X. Shao, and X. Zhang. 2002. “Research on evaluations approach to low-temperature performance of asphalt based on rheology characteristic of low temperature.” [In Chinese.] China J. Highway Transp. 3: 3–7. https://doi.org/10.19721/j.cnki.1001-7372.2002.03.001.
Wang, L., M. Ren, and C. Li. 2017. “Morphological and rheological property analysis of polyphosphoric acid modified asphalt.” Acta Materiae Compositae Sin. 34 (10): 2330–2336. https://doi.org/10.13801/j.cnki.fhclxb.20170112.009.
Wang, P., X. Tian, R. Zhang, and S. Zhen. 2021. “Effect of waterborne epoxy resin on properties of modified emulsified asphalt and its microstructure.” J. Mater. Civ. Eng. 33 (8): 04021177. https://doi.org/10.1061/(ASCE)MT.1943-5533.0003793.
Wang, Z. 2017. “Study on the effect of aging on the performance of poly phosphoric acid moified asphalt.” Accessed June 13, 2017. https://kns.cnki.net/KCMS/detail/detail.aspx?dbname=CMFD201801&filename=1017858811.nh.
Wei, J., S. Shi, Y. Zhou, P. Li, Z. Chen, and Y. Guan. 2019. “Rheological property of polyphosphoric acid modified asphalt.” J. Traffic Transp. Eng. 19 (6): 14–26. https://doi.org/10.19818/j.cnki.1671-1637.2019.06.002.
Wen, H., S. Bhusal, and B. Wen. 2013. “Laboratory evaluation of waste cooking oil-based bioasphalt as an alternative binder for hot mix asphalt.” J. Mater. Civ. Eng. 25 (10): 1432–1437. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000713.
Wu, S. P., G. J. Zhu, G. Liu, and L. Pang. 2009. “Laboratory research on thermal behavior and characterization of the ultraviolet aged asphalt binder.” J. Therm. Anal. Calorim. 95 (2): 595–599. https://doi.org/10.1007/s10973-008-9252-3.
Yang, J. 2019. “Study on anti-aging ability of polyphosphoric acid/SBR composited and modified asphalt at high and low temperature performance.” J. China Foreign Highway 39 (6): 249–254. https://doi.org/10.14048/j.issn.1671-2579.2019.06.053.
You, Z., J. Mills-Beale, E. Fini, S. W. Goh, and B. Colbert. 2011. “Evaluation of low-temperature binder properties of warm-mix asphalt, extracted and recovered RAP and RAS, and bioasphalt.” J. Mater. Civ. Eng. 23 (11): 1569–1574. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000295.
Yousefi, A. A., A. Ait-Kadi, and C. Roy. 2000. “Effect of used-tire-derived pyrolytic oil residue on the properties of polymer-modified asphalts.” Fuel 79 (8): 975–986. https://doi.org/10.1016/S0016-2361(99)00216-1.
Zhang, C. 2019. “Supply and demand status quo of domestic asphalt and suggestions.” Refining Chem. Ind. 30 (4): 1–3. https://doi.org/10.3969/j.issn.1671-4962.2019.04.001.
Zhang, Z., and M. Oeser. 2020. “Residual strength model and cumulative damage characterization of asphalt mixture subjected to repeated loading.” Int. J. Fatigue 135 (Jun): 105534. https://doi.org/10.1016/j.ijfatigue.2020.105534.
Zheng, J., H. Li, W. He, and Q. Fang. n.d. “Multi-index evaluation of low temperature performance of SBS modified asphalt based on force extension test.” [In Chinese.] J. Wuhan Univ. Technol. Mater. 1–6.
Zhou, C. 2017. Study on road performance of poly phosphoric acid modified asphalt. Hongqiao District, China: Hebei Univ. of Technology.
Zhou, S., H. Wu, and Y. Liu. 2019. “Study on properties of polyphosphoric acid modified bio-asphalt and mixture.” Contemp. Chem. Ind. 48 (6): 1205–1208. https://doi.org/10.13840/j.cnki.cn21-1457/tq.2019.06.024.
Zhu, D. 2018. “Research on application of plant asphalt in road engineering.” [In Chinese.] Shandong Transp. Technol. 1: 46–49.
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Received: Jan 29, 2021
Accepted: Jul 22, 2021
Published online: Dec 28, 2021
Published in print: Mar 1, 2022
Discussion open until: May 28, 2022
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