Abstract

Dispersive clays are one of the common problematic soils owing to their unstable structure, which causes numerous geotechnical problems in construction projects. One of the main strategies to ameliorate these weak soils is to modify their mechanical properties with additives. Because little research about the influence of nanomaterials on the problematic soils’ characteristics is available, this study aims to evaluate the effect of nanosilica on the mechanical, mineralogical, and microstructural behavior of dispersive clay. A series of experimental tests, including the pinhole, double-hydrometer, and crumb tests, is conducted to determine the dispersivity potential of the soil treated with nanosilica. The Atterberg limits, standard compaction, unconfined compression (UCS), and direct shear tests are also carried out. Additionally, mineralogy and the microstructure of the base soil and treated specimens were analyzed through X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy-dispersive X-ray spectroscopy (EDS). The results indicate that adding the optimum amount of 1% nanosilica to the dispersive clay altered the soil characteristic into nondispersive. The liquid limit (LL), plastic limit (PL), and optimum moisture content (OMC) of the treated soil specimens increased; nevertheless, the plasticity index (PI) and maximum dry density (MDD) decreased with the application of nanosilica. Remarkable improvement in UCS, absorbed energy, secant elastic modulus (E50), and the direct shear strength was achieved in the specimens treated with 1% nanosilica content after 7 and 28 days curing. The formation of calcium–silicate–hydrate (C─ S─ H) gel and substantial reduction of the porous structure were observed through the XRD results and SEM micrograph after 28 days of curing.

Get full access to this article

View all available purchase options and get full access to this article.

Data Availability Statement

All data, models, and codes generated or used during the study appear in the published article.

References

Abbasi, N., A. Farjad, and S. Sepehri. 2018. “The use of nanoclay particles for stabilization of dispersive clayey soils.” Geotech. Geol. Eng. 36 (1): 327–335. https://doi.org/10.1007/s10706-017-0330-9.
Al-Mukhtar, M., S. Khattab, and J.-F. Alcover. 2012. “Microstructure and geotechnical properties of lime-treated expansive clayey soil.” Eng. Geol. 139 (Jun): 17–27. https://doi.org/10.1016/j.enggeo.2012.04.004.
Al-Swaidani, A., I. Hammoud, and A. Meziab. 2016. “Effect of adding natural pozzolana on geotechnical properties of lime-stabilized clayey soil.” J. Rock Mech. Geotech. Eng. 8 (5): 714–725. https://doi.org/10.1016/j.jrmge.2016.04.002.
ASTM. 2005. Standard test method for dispersive characteristics of clay soil by double hydrometer. ASTM D4221-99. West Conshohocken, PA: ASTM.
ASTM. 2006. Standard test method for identification and classification of dispersive clay soils by the pinhole test. West Conshohocken, PA: ASTM.
ASTM. 2007. Standard test method for particle-size analysis of soils. ASTM D422-63. West Conshohocken, PA: ASTM.
ASTM. 2010. Standard test methods for liquid limit, plastic limit, and plasticity index of soils. West Conshohocken, PA: ASTM.
ASTM. 2011. Standard test method for direct shear test of soils under consolidated drained conditions. West Conshohocken, PA: ASTM.
ASTM. 2012. Standard test methods for laboratory compaction characteristics of soil using standard effort. West Conshohocken, PA: ASTM.
ASTM. 2013a. Standard test method for unconfined compressive strength of cohesive soil 1. ASTM D2166-13. West Conshohocken, PA: ASTM.
ASTM. 2013b. Standard test methods for determining dispersive characteristics of clayey soils by the crumb test. West Conshohocken, PA: ASTM.
ASTM. 2015. Standard test methods for pore water extraction and determination of the soluble salt content of soils by refractometer. West Conshohocken, PA: ASTM.
Athukorala, R., B. Indraratna, and J. S. Vinod. 2013. “Modeling the internal erosion behavior of lignosulfonate treated soil.” In Proc., Geo-Congress 2013: Stability and Performance of Slopes and Embankments III, 1865–1874. San Diego: Geo-Institute of ASCE.
Bahmani, S. H., B. B. K. Huat, A. Asadi, and N. Farzadnia. 2014. “Stabilization of residual soil using SiO2 nanoparticles and cement.” Constr. Build. Mater. 64 (Aug):350–359. https://doi.org/10.1016/j.conbuildmat.2014.04.086.
Bell, F. G. 2003. Geological hazards: Their assessment, avoidance and mitigation. London: CRC Press.
Carlos, H., S. Filho, R. B. Saldanha, C. Gravina, and N. C. Consoli. 2021. “Sustainable binders stabilizing dispersive clay.” J. Mater. Civ. Eng. 33 (3): 1–11. https://doi.org/10.1061/(ASCE)MT.1943-5533.0003595.
Changizi, F., and A. Haddad. 2015. “Strength properties of soft clay treated with mixture of nano-SiO2 and recycled polyester fiber.” J. Rock Mech. Geotech. Eng. 7 (4): 367–378. https://doi.org/10.1016/j.jrmge.2015.03.013.
Consoli, N. C., S. Carretta, H. B. Leon, H. Carlos, S. Filho, and L. F. Tomasi. 2019a. “Strength and stiffness of ground waste glass—Carbide lime blends.” J. Mater. Civ. Eng. 31 (10): 2–7. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002862.
Consoli, N. C., E. José, B. Marin, R. Alejandro, H. Carlos, S. Filho, T. Miranda, and N. Cristelo. 2019b. “Effect of mellowing and coal fly ash addition on behavior of sulfate-rich dispersive clay after lime stabilization.” J. Mater. Civ. Eng. 31 (6): 1–10. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002699.
Consoli, N. C., R. A. Q. Samaniego, and N. M. K. Villalba. 2016. “Durability, strength, and stiffness of dispersive clay–lime blends.” J. Mater. Civ. Eng. 28 (11): 4016124. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001632.
Craft, C. D., and R. G. Acciardi. 1984. “Failure of pore-water analyses for dispersion.” J. Geotech. Eng. 110 (4): 459–472. https://doi.org/10.1061/(ASCE)0733-9410(1984)110:4(459).
Cui, H., Z. Jin, X. Bao, W. Tang, and B. Dong. 2018. “Effect of carbon fiber and nanosilica on shear properties of silty soil and the mechanisms.” Constr. Build. Mater. 189 (Nov): 286–295. https://doi.org/10.1016/j.conbuildmat.2018.08.181.
Falamaki, A., N. Shariatmadari, and A. Noorzad. 2008. “Strength properties of hexametaphosphate treated soils.” J. Geotech. Geoenviron. Eng. 134 (8): 1215–1218. https://doi.org/10.1061/(ASCE)1090-0241(2008)134:8(1215).
Fernando, J. 2010. “Effect of water quality on the dispersive characteristics of soils found in the Morwell Area, Victoria, Australia.” In Geotechnical and geological engineering, 835–850. Berlin: Springer.
Floody, M. C., B. K. G. Theng, P. Reyes, and M. L. Mora. 2009. “Natural nanoclays: Applications and future trends—A Chilean perspective.” Clay Miner. 44 (2): 161–176. https://doi.org/10.1180/claymin.2009.044.2.161.
Francisca, F. M. 2007. “Evaluating the constrained modulus and collapsibility of loess from standard penetration test.” Int. J. Geomech. 7 (4): 307–310. https://doi.org/10.1061/(ASCE)1532-3641(2007)7:4(307).
Ghafoori, N., I. Batilov, and M. Najimi. 2017. “Influence of dispersion methods on sulfate resistance of nanosilica-contained mortars.” J. Mater. Civ. Eng. 29 (7): 04017038. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001882.
Ghasabkolaei, N., A. J. Choobbasti, N. Roshan, and S. E. Ghasemi. 2017. “Geotechnical properties of the soils modified with nanomaterials: A comprehensive review.” Arch. Civ. Mech. Eng. 17 (3): 639–650. https://doi.org/10.1016/j.acme.2017.01.010.
Ghavami, S., B. Farahani, H. Jahanbakhsh, and F. M. Nejad. 2018. “Effects of silica fume and nano-silica on the engineering properties of kaolinite.” AUT J. Civ. Eng. 2 (2): 135–142. https://doi.org/10.22060/AJCE.2018.14203.5462.
Goodarzi, A. R., and M. Salimi. 2015. “Stabilization treatment of a dispersive clayey soil using granulated blast furnace slag and basic oxygen furnace slag.” Appl. Clay Sci. 108 (May): 61–69. https://doi.org/10.1016/j.clay.2015.02.024.
Jamsawang, P., H. Poorahong, N. Yoobanpot, S. Songpiriyakij, and P. Jongpradist. 2017. “Improvement of soft clay with cement and bagasse ash waste.” Constr. Build. Mater. 154 (Nov): 61–71. https://doi.org/10.1016/j.conbuildmat.2017.07.188.
Jansen, R. B. 2012. Advanced dam engineering for design, construction, and rehabilitation. Berlin: Springer.
Jo, B., C. Kim, G. Tae, and J. Park. 2007. “Characteristics of cement mortar with nano-SiO2 particles.” 21 (6): 1351–1355. https://doi.org/10.1016/j.conbuildmat.2005.12.020.
Kalhor, A., M. Ghazavi, M. Roustaei, and S. M. Mirhosseini. 2019. “Influence of nano-SiO2 on geotechnical properties of fine soils subjected to freeze-thaw cycles.” Cold Reg. Sci. Technol. 161 (3): 129–136. https://doi.org/10.1016/j.coldregions.2019.03.011.
Kalkan, E. 2009. “Effects of silica fume on the geotechnical properties of fine-grained soils exposed to freeze and thaw.” Cold Reg. Sci. Technol. 58 (3): 130–135. https://doi.org/10.1016/j.coldregions.2009.03.011.
Kalkan, E., and S. Akbulut. 2004. “The positive effects of silica fume on the permeability, swelling pressure and compressive strength of natural clay liners.” Eng. Geol. 73 (1–2): 145–156. https://doi.org/10.1016/j.enggeo.2004.01.001.
Kunther, W., S. Ferreiro, and J. Skibsted. 2017. “Influence of the Ca/Si ratio on the compressive strength of cementitious calcium–silicate–hydrate binders.” J. Mater. Chem. A 5 (33): 17401–17412. https://doi.org/10.1039/C7TA06104H.
Lee, F. H., Y. Lee, S. H. Chew, and K. Y. Yong. 2005. “Strength and modulus of marine clay-cement mixes.” J. Geotech. Geoenviron. Eng. 131 (2): 178–186. https://doi.org/10.1061/(ASCE)1090-0241(2005)131:2(178).
Li, G. 2004. “Properties of high-volume fly ash concrete incorporating nano-SiO2.” 34 (6): 1043–1049. https://doi.org/10.1016/j.cemconres.2003.11.013.
Mallela, J., H. Quintus, and K. L. Smith. 2004. Consideration of lime-stabilized layers in mechanistic-empirical pavement design. Arlington, VA: The National Lime Association.
Mohanty, S., N. Roy, S. P. Singh, and P. Sihag. 2019. “Effect of industrial by-products on the strength of stabilized dispersive soil.” Int. J. Geotech. Eng. 15 (4): 1–13. https://doi.org/10.1080/19386362.2019.1654281.
Molaabasi, H., S. N. Semsani, M. Saberian, A. Khajeh, J. Li, and M. Harandi. 2020. “Evaluation of the long-term performance of stabilized sandy soil using binary mixtures: A micro- and macro-level approach.” J. Cleaner Prod. 267 (Sep): 122209. https://doi.org/10.1016/j.jclepro.2020.122209.
Nel, A., T. Xia, L. Mädler, and N. Li. 2006. “Toxic potential of materials at the nanolevel.” Science 311 (5761): 622–627. https://doi.org/10.1126/science.1114397.
Nonat, A. 2004. “The structure and stoichiometry of CSH.” Cem. Concr. Res. 34 (9): 1521–1528. https://doi.org/10.1016/j.cemconres.2004.04.035.
Okagbue, C. O. 2007. “Stabilization of clay using woodash.” J. Mater. Civ. Eng. 19 (1): 14–18. https://doi.org/10.1061/(ASCE)0899-1561(2007)19:1(14).
Ouhadi, V. R., and A. R. Goodarzi. 2006. “Assessment of the stability of a dispersive soil treated by alum.” 85 (1–2): 91–101. https://doi.org/10.1016/j.enggeo.2005.09.042.
Parameswaran, T. G., and P. V. Sivapullaiah. 2017. “Influence of sodium and lithium monovalent cations on dispersivity of clay soil.” J. Mater. Civ. Eng. 29 (7): 4017042. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001877.
Pham, H., and Q. P. Nguyen. 2014. “Effect of silica nanoparticles on clay swelling and aqueous stability of nanoparticle dispersions.” J. Nanopart. Res. 16 (1): 2137. https://doi.org/10.1007/s11051-013-2137-9.
Premkumar, S., J. Piratheepan, P. Rajeev, and A. Arulrajah. 2016. “Stabilizing dispersive soil using brown coal fly ash and hydrated lime.” Geo-Chicago 2016 (1): 874–884. https://doi.org/10.1061/9780784480144.087.
Prusinski, J. R., and S. Bhattacharja. 1999. “Effectiveness of Portland cement and lime in stabilizing clay soils.” Transp. Res. Rec. 1652 (1): 215–227. https://doi.org/10.3141/1652-28.
Qing, Y., Z. Zenan, K. Deyu, and C. Rongshen. 2007. “Influence of nano-SiO2 addition on properties of hardened cement paste as compared with silica fume.” Constr. Build. Mater. 21 (3): 539–545. https://doi.org/10.1016/j.conbuildmat.2005.09.001.
Rajabi, A. M., and S. B. Ardakani. 2020. “Effects of natural-zeolite additive on mechanical and physicochemical properties of clayey soils.” J. Mater. Civ. Eng. 32 (10): 4020306. https://doi.org/10.1061/(ASCE)MT.1943-5533.0003336.
Sobolev, K., I. Flores, R. Hermosillo, and L. M. Torres-Martínez. 2006. “Nanomaterials and nanotechnology for high-performance cement composites.” In Proc., ACI Session on Nanotechnology of Concrete: Recent Developments and Future Perspectives, 91–118. Farmington Hills, MI: American Concrete Institute.
Stoltz, G., O. Cuisinier, and F. Masrouri. 2012. “Multi-scale analysis of the swelling and shrinkage of a lime-treated expansive clayey soil.” Appl. Clay Sci. 61 (Jun): 44–51. https://doi.org/10.1016/j.clay.2012.04.001.
Turkoz, M., H. Savas, A. Acaz, and H. Tosun. 2014. “Applied clay science the effect of magnesium chloride solution on the engineering properties of clay soil with expansive and dispersive characteristics.” Appl. Clay Sci. 101 (Nov): 1–9. https://doi.org/10.1016/j.clay.2014.08.007.
Umesh, T. S., S. V. Dinesh, and P. V. Sivapullaiah. 2011. “Characterization of dispersive soils.” Mater. Sci. Appl. 2 (6): 629–633.
Umesha, T. S., S. V. Dinesh, and P. V. Sivapullaiah. 2009. “Control of dispersivity of soil using lime and cement.” Int. J. Geol. 3 (1): 8–16.
Vakili, A. H., M. Kaedi, M. Mokhberi, M. R. bin Selamat, and M. Salimi. 2018. “Treatment of highly dispersive clay by lignosulfonate addition and electroosmosis application.” Appl. Clay Sci. 152 (11): 1–8. https://doi.org/10.1016/j.clay.2017.11.039.
Vakili, A. H., M. R. Selamat, and H. Moayedi. 2013. “Effects of using pozzolan and portland cement in the treatment of dispersive clay.” Sci. World J. 2013 (Jan).
Vinod, J. S., B. Indraratna, and M. A. A. Mahamud. 2010. “Internal erosional behaviour of lignosulfonate treated dispersive clay.” In Ground improvement technologies and case histories, 549–554. Wollongong, Australia: Univ. of Wollongong.
Wang, Y., Y. Liu, W. Zhan, K. Zheng, M. Lian, C. Zhang, X. Ruan, and T. Li. 2020. “Long-term stabilization of Cd in agricultural soil using mercapto-functionalized nano-silica (MPTS/nano-silica): A three-year field study.” Ecotoxicol. Environ. Saf. 197 (Jul): 110600. https://doi.org/10.1016/j.ecoenv.2020.110600.
Zhang, G. 2007. “Soil nanoparticles and their influence on engineering properties of soils.” In Advances in measurement and modeling of soil behavior, 1–13. Denver: Geo-Institute of ASCE.
Zorluer, I., Y. Icaga, S. Yurtcu, and H. Tosun. 2010. “Application of a fuzzy rule-based method for the determination of clay dispersibility.” Geoderma 160 (2): 189–196.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 33Issue 12December 2021

History

Received: Nov 6, 2020
Accepted: Apr 13, 2021
Published online: Sep 25, 2021
Published in print: Dec 1, 2021
Discussion open until: Feb 25, 2022

Permissions

Request permissions for this article.

Authors

Affiliations

Farimah Fattahi Masrour [email protected]
Master’s Graduate, Dept. of Civil Engineering, Arak Univ., Arak 1677745144, Iran (corresponding author). Email: [email protected]
Majid Naghdipour Mirsadeghi [email protected]
Master’s Graduate, Dept. of Environmental Engineering, College of Environment, Karaj 4418748416, Iran. Email: [email protected]
Hossein MolaAbasi [email protected]
Assistant Professor, Dept. of Civil Engineering, Gonbad Univ., Gonbad, Golestan 4971799151, Iran. Email: [email protected]
Associate Professor, Dept. of Civil Engineering, Univ. of Guilan, Rasht, Guilan 4199613776, Iran. ORCID: https://orcid.org/0000-0002-7950-322X. Email: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

  • Effect of Nano-calcium carbonate on the Geotechnical and Microstructural Characteristics of Highly Plastic Paddy Clay, Arabian Journal for Science and Engineering, 10.1007/s13369-023-07679-y, (2023).
  • Evaluating the Effect of Nano-SiO2 on Different Types of Soils: A Multi-Scale Study, International Journal of Environmental Research and Public Health, 10.3390/ijerph192416805, 19, 24, (16805), (2022).
  • Praseodymium-oxide decorated montmorillonite nanocomposite as a novel admixture for dredged soil stabilisation, Geomechanics and Geoengineering, 10.1080/17486025.2022.2099019, (1-12), (2022).
  • Investigation on performance of expansive soil stabilized with fly ash and nano-SiO2, Materials Today: Proceedings, 10.1016/j.matpr.2022.08.524, 67, (1268-1275), (2022).

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share