Effect of Curing Time on the Performance of Fly Ash Geopolymer-Stabilized RAP Bases
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VIEW THE REPLYPublication: Journal of Materials in Civil Engineering
Volume 33, Issue 3
Abstract
The long-term integrity of fly ash (FA) geopolymer-stabilized high-percentage reclaimed asphalt pavement (RAP) in the pavement base layer was investigated in this research. The FA geopolymer-stabilized RAP and virgin aggregate (VA) mixes were studied as an economical and durable alternative to 100% VA bases, with an emphasis on the influence of curing time. The maturity age of FA is usually set as 28 days, similar to traditional portland cement. However, due to partial pozzolanic reactions, though geopolymerized, the dilution of partial FA particles does not fully play its role at 28 days of curing time. Hence, this is not a realistic reference time for predicting the service life of FA geopolymer-stabilized aggregate blends. Therefore, a detailed experimental investigation was undertaken to evaluate the ultimate strength, durability, and microstructural characteristics of four distinct FA geopolymer-stabilized RAP:VA blends for a long-term ambient curing time up to 270 days. In this study, the long-term cured specimens showed significant improvement in mechanical strength and stiffness, yielding lower permanent deformations. It was noticed that only about 12% and 40% average unconfined compressive strength (UCS) could be achieved in 7- and 28-day cured specimens, respectively, with reference to their ultimate strength at 270 days. Hence, to examine the microstructural characteristics of powdered FA geopolymer blends, X-ray diffraction (XRD), scanning electron microscopy (SEM) equipped with energy dispersive X-ray spectroscopy (EDS), and Fourier transform-infrared spectroscopy (FT-IR) studies were performed. The test results revealed that the consumption of reactive metal ions was continued for an extended period under a controlled curing regime, which resulted in improved mechanical strength and durability of the solidified product.
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Data Availability Statement
All data, models, and code generated or used during the study appear in the published article.
Acknowledgments
This research was supported by the Department of Science and Technology (DST/TSG/STS/2013/40), Government of India. This research was also supported by the Australian Research Council Industrial Transformation Training Centre (IC170100006) and funded by the Government of Australia.
References
AASHTO. 2003. Standard method of test for determining the resilient modulus of soils and aggregate materials. AASHTO T307-99. Washington, DC: AASHTO.
Abed, M., and R. Nemes. 2019. “Long-term durability of self-compacting high-performance concrete produced with waste materials.” Constr. Build. Mater. 212 (Jul): 350–361. https://doi.org/10.1016/j.conbuildmat.2019.04.004.
Alvarez-Ayuso, E., et al. 2008. “Environmental, physical and structural characterization of geopolymer matrixes synthesized from coal combustion fly ashes.” J. Hazard. Mater. 154 (1–3): 175–183. https://doi.org/10.1016/j.jhazmat.2007.10.008.
ASTM. 1996. Standard test methods for wetting and drying compacted soil-cement mixtures. ASTM D559. West Conshohocken, PA: ASTM.
ASTM. 2012a. Standard specification for coal fly ash and raw or calcined natural pozzolan for use in concrete. ASTM C618. West Conshohocken, PA: ASTM.
ASTM. 2012b. Standard test methods for laboratory compaction characteristics of soil using modified effort. ASTM D1557. West Conshohocken, PA: ASTM.
ASTM. 2015. Standard test method for relative density (specific gravity) and absorption of coarse aggregate. ASTM C127. West Conshohocken, PA: ASTM.
ASTM. 2017a. Standard test methods for compressive strength of molded soil-cement cylinders. ASTM D1633. West Conshohocken, PA: ASTM.
ASTM. 2017b. Standard practice for classification of soils for engineering purposes (unified soil classification system). ASTM D2487. West Conshohocken, PA: ASTM.
ASTM. 2019a. Standard test method for particle-size analysis of soils. ASTM D422. West Conshohocken, PA: ASTM.
ASTM. 2019b. Standard test methods for pH of soils. ASTM D4972. West Conshohocken, PA: ASTM.
Austroads. 2006. Guide to pavement technology. Part 4D: Stabilised materials. AGPT04D-06. Sydney, Australia: Austroads.
Avirneni, D., P. R. Peddinti, and S. Saride. 2016. “Durability and long-term performance of geopolymer stabilized reclaimed asphalt pavement base courses.” Constr. Build. Mater. 121 (Sep): 198–209. https://doi.org/10.1016/j.conbuildmat.2016.05.162.
CCANZ (Cement and Concrete Association of New Zealand). 2008. Road recycling and construction using cement stabilization, 1–12. Wellington, New Zealand: CCANZ.
Chindaprasirt, P., T. Chareerat, S. Hatanaka, and T. Cao. 2011. “High-strength geopolymer using fine high-calcium fly ash.” J. Mater. Civ. Eng. 23 (3): 264–270. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000161.
Chindaprasirt, P., C. Jaturapitakkul, W. Chalee, and U. Rattanasak. 2009. “Comparative study on the characteristics of fly ash and bottom ash geopolymers.” Waste Manage. 29 (2): 539–543. https://doi.org/10.1016/j.wasman.2008.06.023.
Davidovits, J. 1991. “Geopolymers: Inorganic polymeric new materials.” J. Therm. Anal. Calorim. 37 (8): 1633–1656. https://doi.org/10.1007/BF01912193.
Hoy, M., S. Horpibulsuk, and A. Arulrajah. 2016. “Strength development of recycled asphalt pavement-fly ash geopolymer as a road construction material.” Constr. Build. Mater. 117 (Aug): 209–219. https://doi.org/10.1016/j.conbuildmat.2016.04.136.
Hoy, M., R. Rachan, S. Horpibulsuk, A. Arulrajah, and M. Mirzababaei. 2017. “Effect of wetting–drying cycles on compressive strength and microstructure of recycled asphalt pavement—Fly ash geopolymer.” Constr. Build. Mater. 144 (Jul): 624–634. https://doi.org/10.1016/j.conbuildmat.2017.03.243.
Hoyos, L. R., A. J. Puppala, and C. A. Ordonez. 2011. “Characterization of cement-fiber-treated reclaimed asphalt pavement aggregates: Preliminary investigation.” J. Mater. Civ. Eng. 23 (7): 977–989. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000267.
IRC (Indian Roads Congress). 2018. Guidelines for the design of flexible pavements. Indian code of practice. IRC 37-2018. New Delhi, India: IRC.
Jaarsveld, J. V., J. V. Deventer, and L. Lorenzen. 1998. “Factors affecting the immobilization of metals in geopolymerized fly ash.” Metall. Mater. Trans. B 29 (1): 283–291. https://doi.org/10.1007/s11663-998-0032-z.
Mohammadinia, A., A. Arulrajah, A. D’Amico, and S. Horpibulsuk. 2018. “Alkali-activation of fly ash and cement kiln dust mixtures for stabilization of demolition aggregates.” Constr. Build. Mater. 186 (Oct): 71–78. https://doi.org/10.1016/j.conbuildmat.2018.07.103.
Puppala, A. J., A. Pedarla, B. Chittoori, V. K. Ganne, and S. Nazarian. 2017. “Long-term durability studies on chemically treated reclaimed asphalt pavement material as a base layer for pavements.” Transp. Res. Rec. 2657 (1): 1–9. https://doi.org/10.3141/2657-01.
Rees, C. A., J. L. Provis, G. C. Lukey, and J. S. Van Deventer. 2007. “In situ ATR-FTIR study of the early stages of fly ash geopolymer gel formation.” Langmuir 23 (17): 9076–9082. https://doi.org/10.1021/la701185g.
Rickard, W. D., G. J. Gluth, and K. Pistol. 2016. “In-situ thermo-mechanical testing of fly ash geopolymer concretes made with quartz and expanded clay aggregates.” Cem. Concr. Res. 80 (Feb): 33–43. https://doi.org/10.1016/j.cemconres.2015.11.006.
Sakai, E., S. Miyahara, S. Ohsawa, S. H. Lee, and M. Daimon. 2005. “Hydration of fly ash cement.” Cem. Concr. Res. 35 (6): 1135–1140. https://doi.org/10.1016/j.cemconres.2004.09.008.
SAPEM (South African Pavement Engineering Manual). 2014. South African pavement engineering manual. Pretoria, South Africa: South African National Roads Agency Society Limited.
Saride, S., D. Avirneni, and S. Challapalli. 2016. “Micro-mechanical interaction of activated fly ash mortar and reclaimed asphalt pavement materials.” Constr. Build. Mater. 123 (Oct): 424–435. https://doi.org/10.1016/j.conbuildmat.2016.07.016.
Soutsos, M., A. P. Boyle, R. Vinai, A. Hadjierakleous, and S. J. Barnett. 2016. “Factors influencing the compressive strength of fly ash based geopolymers.” Constr. Build. Mater. 110 (May): 355–368. https://doi.org/10.1016/j.conbuildmat.2015.11.045.
Taha, R., A. Al-Harthy, K. Al-Shamsi, and M. Al-Zubeidi. 2002. “Cement stabilization of reclaimed asphalt pavement aggregate for road bases and subbases.” J. Mater. Civ. Eng. 14 (3): 239–245. https://doi.org/10.1061/(ASCE)0899-1561(2002)14:3(239).
Texas DOT (Texas Department of Transportation). 2014. Standard specifications for construction and maintenance of highways, streets, and bridges (item 276). Austin, TX: Texas DOT.
Vuong, B. T., and R. Brimble. 2000. Austroads repeated load triaxial test method: Determination of permanent deformation and resilient modulus characteristics of unbound granular materials under drained conditions. Melbourne, Australia: Austroads.
Xu, H., and J. S. J. Van Deventer. 2002. “Factors affecting the geopolymerization of alkali-feldspars.” Min. Metall. Explor. 19 (4): 209–214. https://doi.org/10.1007/BF03403271.
Yuan, D., S. Nazarian, L. R. Hoyos, and A. J. Puppala. 2010. Cement treated RAP mixes for roadway bases. Austin, TX: Texas DOT.
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© 2021 American Society of Civil Engineers.
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Received: Mar 31, 2020
Accepted: Jul 23, 2020
Published online: Jan 4, 2021
Published in print: Mar 1, 2021
Discussion open until: Jun 4, 2021
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