Technical Papers
Sep 27, 2020

Impact of Organic Compounds Extracted from Hemp-Origin Aggregates on the Hardening Process and Compressive Strength of Different Types of Mineral Binders

Publication: Journal of Materials in Civil Engineering
Volume 32, Issue 12

Abstract

Biocomposite building materials with mineral binders are becoming more topical recently because they can address growing environmental concerns regarding carbon footprints and resource depletion better than traditional building materials. However, these new materials also pose new challenges. There have been issues with the compatibility of plant-origin aggregates (such as hemp-origin aggregates) with commonly used mineral binders due to organic compounds released by these aggregates, and these issues have not yet been extensively studied. Magnesium-based binders are a group of alternative binders that are being used in the production of biocomposites, and although they do not appear to have the same compatibility issues, they too have not yet been widely researched. In this study, the impact of organic compounds released by hemp-origin aggregates on the physical and mechanical properties of binders were tested. The hydration processes of commonly used binders such as cement and lime alongside alternative binders-magnesium cements influenced by released organic compounds were investigated. Organic-compound extracts from hemp-origin aggregates were prepared in a water medium with different pH values. The resulting extracted organic compounds were shown to retard the setting time of hydraulic binders (cement and hydraulic lime) and decrease their compressive strength by more than 50%. Magnesium-cement binders, however, show only slight retardation in setting time and no compressive strength loss. Thus, magnesium-cement binders have demonstrated their superior compatibility with plant-origin aggregates.

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Data Availability Statement

All data, models, and code generated or used during the study appear in the published article.

Acknowledgments

This work was carried out within the framework of a European Regional Development Fund Project Nr.1.1.1.1/16/A/007, “A New Concept for Sustainable and Nearly Zero-Energy Buildings.”

References

Alengaram, U. J., B. A. Al Muhit, and M. Z. Bin Jumaat. 2013. “Utilization of oil palm kernel shell as lightweight aggregate in concrete—A review.” Constr. Build. Mater. 38 (Jan): 161–172. https://doi.org/10.1016/J.CONBUILDMAT.2012.08.026.
Amiandamhen, S. O., M. Meincken, and L. Tyhoda. 2016. “Magnesium based phosphate cement binder for composite panels: A response surface methodology for optimisation of processing variables in boards produced from agricultural and wood processing industrial residues.” Ind. Crops Prod. 94 (Dec): 746–754. https://doi.org/10.1016/j.indcrop.2016.09.051.
Andzs, M., J. Gravitis, and A. Veveris. 2013. “Extraction of lignin from hemp shives.” Vide. Tehnol. Resour. Environ. Technol. Resour. 1 (Oct): 103–105. https://doi.org/10.17770/etr2013vol1.798.
Ballieu, P. 2013. “Concrete setting retarder mechanism.” Accessed May 3, 2019. https://www.academia.edu/9689617/Concrete_setting_retarder_mechanism.
Bernard, E., and B. Lothenbach. 2014. “Magnesium silicate hydrates (M-S-H): Formation kinetics and range of composition magnesium silicate hydrates (M-S-H): Formation kinetics and range of composition.” In Proc., 34th Cement and Concrete Science Conf. Sheffield, UK: Univ. of Sheffield.
Bourdot, A., C. Magniont, M. Lagouin, C. Niyigena, P. Evon, and S. Amziane. 2019. “Impact of bio-aggregates properties on the chemical interactions with mineral binder, application to vegetal concrete.” J. Adv. Concr. Technol. 17 (9): 542–558. https://doi.org/10.3151/jact.17.542.
CEN (European Committee for Standardization). 1999. Methods of test for mortar for masonry. Determination of flexural and compressive strength of hardened mortar. EN 1015-11:2019. Brussels, Belgium: CEN.
Cizer, O., C. Rodriguez-Navarro, E. Ruiz-Agudo, J. Elsen, D. Van Gemert, and K. Van Balen. 2012. “Phase and morphology evolution of calcium carbonate precipitated by carbonation of hydrated lime.” J. Mater. Sci. 47 (16): 6151–6165. https://doi.org/10.1007/s10853-012-6535-7.
Delhomme, F., A. Hajimohammadi, A. Almeida, C. Jiang, D. Moreau, Y. Gan, X. Wang, and A. Castel. 2020. “Physical properties of Australian hurd used as aggregate for hemp concrete.” Mater. Today Commun. 24 (Oct): 100986. https://doi.org/10.1016/j.mtcomm.2020.100986.
del Valle-Zermeno, R., J. E. Aubert, A. Laborel-Preneron, J. Formosa, and J. M. Chimenos. 2016. “Preliminary study of the mechanical and hygrothermal properties of hemp-magnesium phosphate cements.” Constr. Build. Mater. 105 (Feb): 62–68. https://doi.org/10.1016/j.conbuildmat.2015.12.081.
Diquelou, Y., E. Gourlay, L. Arnaud, and B. Kurek. 2015. “Impact of hemp shiv on cement setting and hardening: Influence of the extracted components from the aggregates and study of the interfaces with the inorganic matrix.” Cem. Concr. Compos. 55 (Jan): 112–121. https://doi.org/10.1016/j.cemconcomp.2014.09.004.
Donahue, P. K., and M. D. Aro. 2010. “Durable phosphate-bonded natural fiber composite products.” Constr. Build. Mater. 24 (2): 215–219. https://doi.org/10.1016/j.conbuildmat.2007.05.015.
Estrela, C., L. L. Bammann, C. R. Estrela, R. S. Silva, and J. D. Pecora. 2000. “Antimicrobial and chemical study of MTA, portland cement, calcium hydroxide paste, Sealapex and Dycal.” Braz. Dent. J. 11 (1): 3–9.
Ghose, T. K. 1987. “Measurement of cellulase activities.” Pure Appl. Chem. 59 (2): 257–268. https://doi.org/10.1351/pac198759020257.
Hamzaoui, R., S. Guessasma, K. Abahri, and O. Bouchenafa. 2020. “Formulation of modified cement mortars using optimal combination of fly ashes, shiv, and hemp fibers.” J. Mater. Civ. Eng. 32 (2): 04019354. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002918.
Horgnies, M., J. J. Chen, and C. Bouillon. 2013. “Overview about the use of Fourier transform infrared spectroscopy to study cementitious materials.” WIT Trans. Eng. Sci. 77: 251–262. https://doi.org/10.2495/MC130221.
Hussain, A., J. Calabria-Holley, M. Lawrence, M. P. Ansell, Y. Jiang, D. Schorr, and P. Blanchet. 2019. “Development of novel building composites based on hemp and multi-functional silica matrix.” Composites, Part B 156 (Jan): 266–273. https://doi.org/10.1016/j.compositesb.2018.08.093.
Iyengar, S. R., and A. Al-Tabbaa. 2007. “Developmental study of a low-PH magnesium phosphate cement for environmental applications.” Environ. Technol. 28 (12): 1387–1401. https://doi.org/10.1080/09593332808618899.
Jia, J., H. Zhou, J. Wei, X. Jiang, H. Hua, F. Chen, and S. Wei. 2010. “Development of magnesium calcium phosphate biocement for bone regeneration.” J. R. Soc. Interface 7 (49): 1171–1180. https://doi.org/10.1098/rsif.2009.0559.
Klijn-Chevalerias, M., and S. Javed. 2017. “The Dutch approach for assessing and reducing environmental impacts of building materials.” Build. Environ. 111 (Jan): 147–159. https://doi.org/10.1016/j.buildenv.2016.11.003.
Kochova, K., K. Schollbach, F. Gauvin, and H. J. H. Brouwers. 2017. “Effect of saccharides on the hydration of ordinary Portland cement.” Constr. Build. Mater. 150 (Sep): 268–275. https://doi.org/10.1016/j.conbuildmat.2017.05.149.
Kwon, H. J., J. Sunthornvarabhas, J. W. Park, J. H. Lee, H. J. Kim, K. Piyachomkwan, K. Sriroth, and D. Cho. 2014. “Tensile properties of kenaf fiber and corn husk flour reinforced poly (lactic acid) hybrid bio-composites: Role of aspect ratio of natural fibers.” Composites Part B 56 (Jan): 232–237. https://doi.org/10.1016/j.compositesb.2013.08.003.
Laborel-Preneron, A., C. Magniont, and J. E. Aubert. 2018. “Characterization of barley straw, hemp shiv and corn cob as resources for bioaggregate based building materials.” Waste Biomass Valorization 9 (7): 1095–1112. https://doi.org/10.1007/s12649-017-9895-z.
Lahalle, H., C. Cau Dit Coumes, A. Mesbah, D. Lambertin, C. Cannes, S. Delpech, and S. Gauffinet. 2016. “Investigation of magnesium phosphate cement hydration in diluted suspension and its retardation by boric acid.” Cem. Concr. Res. 87 (Sep): 77–86. https://doi.org/10.1016/j.cemconres.2016.04.010.
Li, Z., T. Zhang, J. Hu, Y. Tang, Y. Niu, J. Wei, and Q. Yu. 2014. “Characterization of reaction products and reaction process of MgO-SiO2-H2O system at room temperature.” Constr. Build. Mater. 61 (Jun): 252–259. https://doi.org/10.1016/j.conbuildmat.2014.03.004.
Madurwar, M. V., R. V. Ralegaonkar, and S. A. Mandavgane. 2013. “Application of agro-waste for sustainable construction materials: A review.” Constr. Build. Mater. 38 (Jan): 872–878. https://doi.org/10.1016/j.conbuildmat.2012.09.011.
Magniont, C., and G. Escadeillas. 2017. “Chemical composition of bio-aggregates and their interactions with mineral binders.” In Bio-aggregates based building materials, 1–37. Dordrecht, Netherlands: Springer.
Ning, L., and C. Bing. 2016. “Experimental investigation concrete using magnesium phosphate cement, fly ash, and rape stalk.” J. Mater. Civ. Eng. 28 (4): 04015163. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001459.
Nisini, E., C. Santulli, and A. Liverani. 2017. “Mechanical and impact characterization of hybrid composite laminates with carbon, basalt and flax fibres.” Composites, Part B Eng. 127 (Oct): 92–99. https://doi.org/10.1016/j.compositesb.2016.06.071.
Nozahic, V., S. Amziane, G. Torrent, K. Saidi, and H. De Baynast. 2012. “Design of green concrete made of plant-derived aggregates and a pumice–lime binder.” Cem. Concr. Compos. 34 (2): 231–241. https://doi.org/10.1016/j.cemconcomp.2011.09.002.
Pacheco-Torgal, F., and S. Jalali. 2011. “Cementitious building materials reinforced with vegetable fibres: A review.” Constr. Build. Mater. 25 (2): 575–581. https://doi.org/10.1016/j.conbuildmat.2010.07.024.
Pantawee, S., T. Sinsiri, C. Jaturapitakkul, and P. Chindaprasirt. 2017. “Utilization of hemp concrete using hemp shiv as coarse aggregate with aluminium sulfate [Al2(SO4)3] and hydrated lime [Ca(OH)2] treatment.” Constr. Build. Mater. 156 (Dec): 435–442. https://doi.org/10.1016/j.conbuildmat.2017.08.181.
Plekhanova, T. A., J. Keriene, A. Gailius, and G. I. Yakovlev. 2007. “Structural, physical and mechanical properties of modified wood-magnesia composite.” Constr. Build. Mater. 21 (9): 1833–1838. https://doi.org/10.1016/j.conbuildmat.2006.06.029.
PubChem Compound Database. n.d. “National center for biotechnology information.” Accessed June 20, 2019. https://pubchem.ncbi.nlm.nih.gov/compound/Magnesium-oxide.
Qiao, H., Q. Cheng, J. Wang, and Y. Shi. 2014. “The application review of magnesium oxychloride cement.” J. Chem. Pharm. Res. 6 (5): 180–185.
Ramakrishna, G., and T. Sundararajan. 2005. “Studies on the durability of natural fibres and the effect of corroded fibres on the strength of mortar.” Cem. Concr. Compos. 27 (5): 575–582. https://doi.org/10.1016/j.cemconcomp.2004.09.008.
Saez Del Bosque, I. F., S. Martinez-Ramirez, and M. T. Blanco-Varela. 2014. “FTIR study of the effect of temperature and nanosilica on the nano structure of C–S–H gel formed by hydrating tricalcium silicate.” Constr. Build. Mater. 52: 314–323. https://doi.org/10.1016/j.conbuildmat.2013.10.056.
Saez-Péerez, M. P., M. Brummer, and J. A. Duran-Suarez. 2020. “A review of the factors affecting the properties and performance of hemp aggregate concretes.” J. Build. Eng. 31 (Oct): 101323. https://doi.org/10.1016/j.jobe.2020.101323.
Sepe, R., F. Bollino, L. Boccarusso, and F. Caputo. 2018. “Influence of chemical treatments on mechanical properties of hemp fiber reinforced composites.” Composites, Part B Eng. 133 (Jan): 210–217. https://doi.org/10.1016/j.compositesb.2017.09.030.
Sinka, M., L. Radina, G. Sahmenko, A. Korjakins, and D. Bajare. 2015. “Enhancement of lime-hemp concrete properties using different manufacturing technologies.” In Proc., 1st Int. Conf. Bio-Based Building Material. Clermont-Ferrand, France: International Union of Laboratories and Experts in Construction Materials, Systems and Structures.
Sinka, M., P. Van Den Heede, N. De Belie, D. Bajare, G. Sahmenko, and A. Korjakins. 2018. “Comparative life cycle assessment of magnesium binders as an alternative for hemp concrete.” Resour. Conserv. Recycl. 133 (Jun): 288–299. https://doi.org/10.1016/j.resconrec.2018.02.024.
Stevulova, N., J. Cigasova, A. Estokova, E. Terpakova, A. Geffert, F. Kacik, E. Singovszka, and M. Holub. 2014. “Properties characterization of chemically modified hemp hurds.” Materials (Basel). 7 (12): 8131–8150. https://doi.org/10.3390/ma7128131.
Thomas, N. L., and J. D. Birchall. 1983. “The retarding action of sugars on cement hydration.” Cem. Concr. Res. 13 (6): 830–842. https://doi.org/10.1016/0008-8846(83)90084-4.
Trezza, M. A. 2007. “Hydration study of ordinary Portland cement in the presence of zinc ions.” Mater. Res. 10 (4): 331–334. https://doi.org/10.1590/S1516-14392007000400002.
Walker, R., and S. Pavia. 2014. “Effect of hemp’s soluble components on the physical properties of hemp concrete.” J. Mater. Sci. Res. 3 (3): 12. https://doi.org/10.5539/jmsr.v3n3p12.
Wei, J., and B. Gencturk. 2018. “Degradation of natural fiber in cement composites containing diatomaceous earth.” J. Mater. Civ. Eng. 30 (11): 1–17. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002486.
Wei, J., and C. Meyer. 2015. “Degradation mechanisms of natural fiber in the matrix of cement composites.” Cem. Concr. Res. 73 (Jul): 1–16. https://doi.org/10.1016/j.cemconres.2015.02.019.
Xu, B., B. Lothenbach, A. Leemann, and F. Winnefeld. 2018. “Reaction mechanism of magnesium potassium phosphate cement with high magnesium-to-phosphate ratio.” Cem. Concr. Res. 108 (Mar): 140–151. https://doi.org/10.1016/j.cemconres.2018.03.013.
Xu, B., H. Ma, C. Hu, S. Yang, and Z. Li. 2016. “Influence of curing regimes on mechanical properties of magnesium oxychloride cement-based composites.” Constr. Build. Mater. 102 (Part 1): 613–619. https://doi.org/10.1016/j.conbuildmat.2015.10.205.
Yan, L., B. Kasal, and L. Huang. 2016. “A review of recent research on the use of cellulosic fibres, their fibre fabric reinforced cementitious, geo-polymer and polymer composites in civil engineering.” Composites, Part B Eng. 92 (May): 94–132. https://doi.org/10.1016/j.compositesb.2016.02.002.
Zhang, T., C. R. Cheeseman, and L. J. Vandeperre. 2011. “Development of low PH cement systems forming magnesium silicate hydrate (M-S-H).” Cem. Concr. Res. 41 (4): 439–442. https://doi.org/10.1016/j.cemconres.2011.01.016.
Zhang, T., J. Zou, B. Wang, Z. Wu, Y. Jia, and C. R. Cheeseman. 2018. “Characterization of magnesium silicate hydrate (MSH) gel formed by reacting MgO and silica fume.” Materials (Basel). 11 (6): 1–15. https://doi.org/10.3390/ma11060909.
Zhou, X., and Z. Li. 2012. “Light-weight wood-magnesium oxychloride cement composite building products made by extrusion.” Constr. Build. Mater. 27 (1): 382–389. https://doi.org/10.1016/j.conbuildmat.2011.07.033.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 32Issue 12December 2020

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Received: Jan 3, 2020
Accepted: Jun 2, 2020
Published online: Sep 27, 2020
Published in print: Dec 1, 2020
Discussion open until: Feb 27, 2021

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Dept. of Building Materials and Products, Institute of Materials and Constructions, Riga Technical Univ., Kalku 1, Riga, LV 1658 (corresponding author). Email: [email protected]
Professor, Dept. of Building Materials and Products, Institute of Materials and Constructions, Riga Technical Univ., Kalku 1, Riga, LV 1658. ORCID: https://orcid.org/0000-0002-2332-1347
A. Korjakins, Ph.D.
Professor, Dept. of Building Materials and Products, Institute of Materials and Constructions, Riga Technical Univ., Kalku 1, Riga, LV 1658.
D. Bajare, Ph.D.
Professor, Dept. of Building Materials and Products, Institute of Materials and Constructions, Riga Technical Univ., Kalku 1, Riga, LV 1658.

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