Technical Papers
Apr 20, 2020

Controlling Surface Chemical States of Halloysite Aerogel for Concrete Composites with Improved Thermal Insulation

Publication: Journal of Materials in Civil Engineering
Volume 32, Issue 7

Abstract

The stability and dispersion of aerogel in concrete is the key to evaluation of the thermal insulation performance of the aerogel/concrete system. This study focuses on the structural stability of aerogel under the effect of factors such as hydrophilic concrete system, mechanical mixing, and interaction between aerogel and the concrete matrix. Stable aerogel/concrete materials were prepared by regulating and controlling kinetic parameters of the surface of halloysite (HNT) aerogels. Characterizations of the samples were investigated using techniques such as Fourier-transform infrared spectrometer, thermogravimetric analysis, N2 adsorption-desorption isotherms, scanning electron microscope, and thermal constant analyzer. The results indicated that the surfactant successfully attaches to the surface of the HNT aerogels. Aerogel particles are stable in concrete and kept their original shape. The thermal conductivity of concrete becomes lower as the content of HNT aerogels increases.

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Data Availability Statement

All data, models, and code generated or used during the study appear in the published article.

Acknowledgments

This work was financially supported by the Natural Science Foundation of Tianjin City (Grant No. 18JCQNJC03000), the National Natural Science Foundation of China (Grant No. 51772202), and the China Postdoctoral Science Foundation (Grant No. 2019M651052).

References

Arel, H. S. 2016. “Recyclability of waste marble in concrete production.” J. Cleaner Prod. 131 (Sep): 17–188. https://doi.org/10.1016/j.jclepro.2016.05.052.
ASTM 2011. Standard test method for splitting tensile strength of cylindrical concrete specimens. ASTM C496/C496M-2004e1. West Conshohocken, PA: ASTM International.
Baetens, R., B. P. Jelle, and A. Gustavsen. 2011. “Aerogel insulation for building applications: A state-of-the-art review.” Energy Build. 43 (4): 761–769. https://doi.org/10.1016/j.enbuild.2010.12.012.
Chauhan, V., K. Holmberg, and R. Bordes. 2018. “A reverse degradation vs. temperature relationship for a carbonate-containing gemini surfactant.” J. Colloid Interface Sci. 531 (Dec): 189–193. https://doi.org/10.1016/j.jcis.2018.07.048.
Cho, J., G. R. Waetzig, M. Udayakantha, C. Y. Hong, and S. Banerjee. 2018. “Incorporation of hydroxyethylcellulose-functionalized halloysite as a means of decreasing the thermal conductivity of oilwell cement.” Sci. Rep. 8 (1): 16149. https://doi.org/10.1038/s41598-018-34283-0.
Elchalakani, M., M. Dong, A. Karrech, G. Li, M. S. M. Ali, T. Xie, and B. Yang. 2018. “Development of fly ash- and slag-based geopolymer concrete with calcium carbonate or microsilica.” J. Mater. Civ. Eng. 30 (12): 04018325. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002527.
Fang, L. Y., J. L. Tan, Y. Zheng, H. N. Li, C. W. Li, and S. Y. Feng. 2016. “Effect of organic salts on the aggregation behavior of tri-(trimethylsiloxy)silylpropylpyridinium chloride in aqueous solution.” Colloids Surf. A 509 (Nov): 48–55. https://doi.org/10.1016/j.colsurfa.2016.08.086.
Fang, L. Y., J. L. Tan, Y. Zheng, G. Yang, J. T. Yu, and S. Y. Feng. 2017. “Synthesis, aggregation behavior of novel cationic silicone surfactants in aqueous solution and their application in metal extraction.” J. Mol. Liq. 231 (Apr): 134–141. https://doi.org/10.1016/j.molliq.2017.02.017.
Garbalinska, H., and J. Strzalkowski. 2018. “Thermal and strength properties of lightweight concretes with variable porosity structures.” J. Mater. Civ. Eng. 30 (12): 04018326. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002549.
Guo, W. W., J. J. Liu, P. Zhang, L. Song, X. Wang, and Y. Hu. 2018. “Multi-functional hydroxyapatite/polyvinyl alcohol composite aerogels with self-cleaning, superior fire resistance and low thermal conductivity.” Compos. Sci. Technol. 158 (Apr): 128–136. https://doi.org/10.1016/j.compscitech.2018.01.020.
Jelle, B. P. 2011. “Traditional, state-of-the-art and future thermal building insulation materials and solutions-Properties, requirements and possibilities.” Energy Build. 43 (10): 2549–2563. https://doi.org/10.1016/j.enbuild.2011.05.015.
Jelle, B. P., A. Gustavsen, and R. Baetens. 2010. “The path to the high performance thermal building insulation materials and solutions of tomorrow.” J. Build. Phys. 34 (2): 99–123. https://doi.org/10.1177/1744259110372782.
Kim, J., B. Kim, C. Anand, A. Mano, J. S. M. Zaidi, K. Ariga, J. You, A. Vinu, and E. Kim. 2015. “A single-step synthesis of electroactive mesoporous prodot-silica structures.” Angew. Chem. Int. Ed. 54 (29): 8407–8410. https://doi.org/10.1002/anie.201502498.
Kim, S., J. Seo, J. Cha, and S. Kim. 2013. “Chemical retreating for gel-typed aerogel and insulation performance of cement containing aerogel.” Constr. Build. Mater. 40 (Mar): 501–505. https://doi.org/10.1016/j.conbuildmat.2012.11.046.
Liao, X. M., Z. O. Gao, Y. Xia, F. Niu, and W. Z. Zhai. 2017. “Rational design and synthesis of carboxylate gemini surfactants with an excellent aggregate behavior for nano-La2O3 morphology-controllable preparation.” Langmuir 33 (13): 3304–3310. https://doi.org/10.1021/acs.langmuir.7b00096.
Liu, G. Y., X. L. Yang, and H. Zhong. 2017. “Molecular design of flotation collectors: A recent progress.” Adv. Colloid Interfaces Sci. 246 (Aug): 181–195. https://doi.org/10.1016/j.cis.2017.05.008.
Luo, Z. L., Y. Li, C. Duan, and B. B. Wang. 2018. “Fabrication of a superhydrophobic mesh based on PDMS/SiO2 nanoparticles/PVDF microparticles/KH-550 by one-step dip-coating method.” RSC Adv. 8 (29): 16251–16259. https://doi.org/10.1039/C8RA03262A.
Nocentini, K., P. Achard, and P. Biwole. 2018. “Hygro-thermal properties of silica aerogel blankets dried using microwave heating for building thermal insulation.” Energy Build. 158 (Jan): 14–22. https://doi.org/10.1016/j.enbuild.2017.10.024.
Obrey, K. A. D., K. V. Wilson, and D. A. Loy. 2011. “Enhancing mechanical properties of silica aerogels.” J. Non-Cryst. Solids 357 (19–20): 3435–3441. https://doi.org/10.1016/j.jnoncrysol.2011.06.014.
Parmenter, K. E., and F. Milstein. 1998. “Mechanical properties of silica aerogels.” J. Non-Cryst. Solids 223 (3): 179–189. https://doi.org/10.1016/S0022-3093(97)00430-4.
Schneider, P., P. Hudec, and O. Solcova. 2008. “Pore-volume and surface area in microporous-mesoporous solids.” Microporous Mesoporous Mater. 115 (3): 491–496. https://doi.org/10.1016/j.micromeso.2008.02.024.
She, W., Y. Du, C. W. Miao, J. P. Liu, G. T. Zhao, J. Y. Jiang, and Y. S. Zhang. 2018. “Application of organic- and nanoparticle-modified foams in foamed concrete: Reinforcement and stabilization mechanisms.” Cem. Concr. Compos. 106 (Apr): 12–22. https://doi.org/10.1016/j.cemconres.2018.01.020.
Sun, P. P., S. S. Zhang, J. Y. Pang, Y. B. Tan, D. Sun, C. X. Xia, X. H. Cheng, and X. Xin. 2018. “Self-assembly of ionic-liquid-type imidazolium gemini surfactant with polyoxometalates into supramolecular architectures for photocatalytic degradation of dye.” J. Mol. Liq. 272 (Dec): 180–187. https://doi.org/10.1016/j.molliq.2018.08.016.
Tan, J. L., and S. Y. Feng. 2014. “Effect of counterions on micellization of pyrrolidinium based silicone ionic liquids in aqueous solutions.” J. Chem. Eng. Data 59 (6): 1830–1834. https://doi.org/10.1021/je401118k.
Tan, J. L., D. P. Ma, S. Y. Feng, and C. Q. Zhang. 2013a. “Effect of headgroups on the aggregation behavior of cationic silicone surfactants in aqueous solution.” Colloid Surf. A 417 (Jan): 146–153. https://doi.org/10.1016/j.colsurfa.2012.10.041.
Tan, J. L., P. J. Zhao, D. P. Ma, S. Y. Feng, and C. Q. Zhang. 2013b. “Effect of hydrophobic chains on the aggregation behavior of cationic silicone surfactants in aqueous solution.” Colloid. Polym. Sci. 291 (6): 1487–1494. https://doi.org/10.1007/s00396-012-2885-6.
Wang, J., S. L. Wang, W. Lin, Z. H. Kang, and Q. You. 2017. “Formula optimization and rheology study of clean fracturing fluid.” J. Mol. Liq. 241 (Sep): 563–569. https://doi.org/10.1016/j.molliq.2017.06.050.
Xia, Y., Z. N. Gao, X. M. Liao, C. C. Pan, Y. F. Zhang, and X. S. Feng. 2017. “Rapid synthesis of hierarchical, flower-like ag microstructures with a gemini surfactant as a directing agent for SERS applications.” Cryst. Eng. Comm. 19 (43): 6547–6555. https://doi.org/10.1039/C7CE01573A.
Xie, T. Y., A. Gholampour, and T. Ozbakkaloglu. 2018. “Toward the development of sustainable concretes with recycled concrete aggregates: Comprehensive review of studies on mechanical properties.” J. Mater. Civ. Eng. 30 (9): 04018211. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002304.
Ximenes, S., A. Silva, A. Soares, I. Flores-Colen, and J. de Brito. 2016. “Parametric analysis to study the influence of aerogel-based renders’ components on thermal and mechanical performance.” Materials 9 (5): 336. https://doi.org/10.3390/ma9050336.
Yan, S. S., W. Y. Wei, Z. N. Gao, Y. Xia, and J. Han. 2018. “Gemini surfactant with pyrrolidinium head groups and a hydroxyl-substituted spacer: Surface properties and assisted one-pot synthesis of dendritic Au nanocrystals.” New J. Chem. 42 (14): 11573–11582. https://doi.org/10.1039/C8NJ01357H.
Zeng, H., M. L. Gao, T. Shen, and F. Ding. 2018. “Organo silica nanosheets with gemini surfactants for rapid adsorption of ibuprofen from aqueous solutions.” J. Taiwan Inst. Chem. Eng. 93 (Dec): 329–335. https://doi.org/10.1016/j.jtice.2018.07.038.
Zhang, Y., Q. Yue, L. Yu, X. Y. Yang, X. F. Hou, D. Y. Zhao, X. W. Cheng, and Y. H. Deng. 2018. “Amphiphilic block copolymers directed interface coassembly to construct multifunctional microspheres with magnetic core and monolayer mesoporous aluminosilicate shell.” Adv. Mater. 30 (26): 1800345. https://doi.org/10.1002/adma.201800345.
Zhao, S., G. Huang, C. J. An, J. Wei, and Y. Yao. 2015. “Enhancement of soil retention for phenanthrene in binary cationic gemini and nonionic surfactant mixtures: Characterizing two-step adsorption and partition processes through experimental and modeling approaches.” J. Hazard. Mater. 286 (Apr): 144–151. https://doi.org/10.1016/j.jhazmat.2014.12.044.

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Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 32Issue 7July 2020

History

Received: Aug 22, 2019
Accepted: Oct 18, 2019
Published online: Apr 20, 2020
Published in print: Jul 1, 2020
Discussion open until: Sep 20, 2020

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Authors

Affiliations

Hongyan Li, Ph.D.
Associate Professor, School of Materials Science and Engineering, Tianjin Chengjian Univ., Tianjin 300384, PR China.
Cong Sun
Graduate Student, School of Materials Science and Engineering, Tianjin Chengjian Univ., Tianjin 300384, PR China.
Magdalena Sztukowska
Graduate Student, School of Materials Science and Engineering, Tianjin Chengjian Univ., Tianjin 300384, PR China; Graduate Student, School of International Education, Tianjin Chengjian Univ., Tianjin 300384, PR China; Graduate Student, Faculty of Civil and Environmental Engineering, Bialystok Univ. of Technology, Wiejska 45E, 15-351 Bialystok, Poland.
Professor, School of Materials Science and Engineering, Tianjin Chengjian Univ., Tianjin 300384, PR China (corresponding author). ORCID: https://orcid.org/0000-0002-6372-6031. Email: [email protected]
Jiangang Wang
Lecturer, School of Materials Science and Engineering, Tianjin Chengjian Univ., Tianjin 300384, PR China.
Huan Li
Lecturer, School of Materials Science and Engineering, Tianjin Chengjian Univ., Tianjin 300384, PR China.
Baolian Zhang, Ph.D.
Professor, School of Materials Science and Engineering, Tianjin Chengjian Univ., Tianjin 300384, PR China.
Xiaolan Liao
Associate Professor, School of Materials Science and Engineering, Tianjin Chengjian Univ., Tianjin 300384, PR China.

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