Technical Papers
Dec 27, 2019

Evaluating the Effect of Carbon Nanotube on Low Temperature Property of Asphalt Binder through Dissipated Energy–Based Approach

Publication: Journal of Materials in Civil Engineering
Volume 32, Issue 3

Abstract

Although many research works are available on evaluating the effect of carbon nanotube (CNT) on intermediate and high temperature performance of asphalt binder, limited studies have been reported for its effect on low temperature properties. Moreover, reported research work showed inconsistent conclusive remarks about its influence on the low temperature properties of asphalt binder. Therefore, along with the conventionally adopted technique, this study aimed at investigating the effect of CNT on low temperature properties of asphalt binder using the dissipated energy-based approach to make an appropriate conclusive remark. CNT content was varied as 0%, 0.75%, 1.5%, and 2.25% by the weight of asphalt binder. Initially, creep stiffness and creep rate corresponding to 60 s creep period were evaluated. Although CNT addition changed the creep stiffness and creep rate, the impact was not statistically significant at 0.75% CNT. However, a subsequently higher dose of 1.5% CNT significantly increased the creep stiffness and decreased the creep rate. A master curve for creep stiffness, relaxation modulus, creep stiffness rate, and creep relaxation rate was drawn to understand the effect of prolonged creep period on low temperature properties. The detrimental effect of CNT on low temperature properties of asphalt binder was found to be apparent, especially in a higher creep period zone. Subsequently, viscoelastic modeling of creep compliance data obtained from a bending beam rheometer (BBR) test was carried out using the Burgers model. Different energy components (stored and dissipative) were subsequently evaluated based on model parameters. Stored, as well as dissipated energy components, were found to be decreasing with an increase in CNT content to 1.5%. However, the degree of decrease in the dissipated energy component was found to be relatively higher compared to the corresponding decrease in the stored energy component. As a result, the dissipated energy ratio (DER), which is expected to be higher for better low temperature performance, was found to be decreasing with the incremental dosages of CNT. Although CNT addition decreased the DER value, the impact was not statistically significant at 0.75% CNT. However, a subsequently higher dose of 1.5% CNT showed a significant decrease in DER value. Such a response further reinforced that CNT addition may have a negative impact on low temperature properties of asphalt binder.

Get full access to this article

View all available purchase options and get full access to this article.

References

Aflaki, S., P. Hajikarimi, E. H. Fini, and B. Zada. 2014. “Comparing effects of biobinder with other asphalt modifiers on low-temperature characteristics of asphalt.” J. Mater. Civ. Eng. 26 (3): 429–439. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000835.
Al-Qadi, I. L., S. H. Yang, M. Elseifi, S. Dessouky, A. Loulizi, J. F. Masson, and K. K. McGhee. 2008. Characterization of low temperature creep properties of crack sealants using bending beam rehometry. Champaign, IL: Illinois Center for Transportation, Univ. of Illinois at Urbana Champaign.
Ameri, M., S. Nowbakht, M. Molayem, and M. R. M. Aliha. 2016. “Investigation of fatigue and fracture properties of asphalt mixtures modified with carbon nanotubes.” Fatigue Fract. Eng. Mater. Struct. 39 (7): 896–906. https://doi.org/10.1111/ffe.12408.
Ameri, M., M. Vamegh, H. Rooholamini, and F. Haddadi. 2018. “Investigating effects of nano/SBR polymer on rutting performance of binder and asphalt mixture.” Adv. Mater. Sci. Eng. 2018: 7. https://doi.org/10.1155/2018/5891963.
Amin, I., S. M. El-Badawy, T. Breakah, and M. H. Ibrahim. 2016. “Laboratory evaluation of asphalt binder modified with carbon nanotubes for Egyptian climate.” Constr. Build. Mater. 121 (Sep): 361–372. https://doi.org/10.1016/j.conbuildmat.2016.05.168.
Amirkhanian, A. N., F. Xiao, and S. N. Amirkhanian. 2011a. “Characterization of unaged asphalt binder modified with carbon nano particles.” Int. J. Pavement Res. Technol. 4 (5): 281–286.
Amirkhanian, A. N., F. Xiao, and S. N. Amirkhanian. 2011b. “Evaluation of high temperature rheological characteristics of asphalt binder with carbon nano particles.” J. Test. Eval. 39 (4): 1–9. https://doi.org/10.1520/JTE103133.
Arabani, M., and M. Faramarzi. 2015. “Characterization of CNTs-modified HMA’s mechanical properties.” Constr. Build. Mater. 83 (May): 207–215. https://doi.org/10.1016/j.conbuildmat.2015.03.035.
Ashish, P. K., and D. Singh. 2018a. “High- and intermediate-temperature performance of asphalt binder containing carbon nanotube using different rheological approaches.” J. Mater. Civ. Eng. 30 (1): 04017254. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002106.
Ashish, P. K., and D. Singh. 2018b. “Development of empirical model for predicting G*/Sinδ and viscosity value for nanoclay and Carbon Nano Tube modified asphalt binder.” Constr. Build. Mater. 165 (Mar): 363–371. https://doi.org/10.1016/j.conbuildmat.2018.01.021.
Ashish, P. K., and D. Singh. 2018c. “Study on understanding functional characteristics of multi-wall CNT modified asphalt binder.” Int. J. Pavement Eng. 1–14. https://doi.org/10.1080/10298436.2018.1519190.
Ashish, P. K., and D. Singh. 2019a. “Use of nanomaterials for asphalt binder and mixtures: A comprehensive review on development, prospect, and challenges.” Road Mater. Pavement Des. 1–47. https://doi.org/10.1080/14680629.2019.1634634.
Ashish, P. K., and D. Singh. 2019b. “Effect of Carbon Nano Tube on performance of asphalt binder under creep-recovery and sustained loading conditions.” Constr. Build. Mater. 215 (Aug): 523–543. https://doi.org/10.1016/j.conbuildmat.2019.04.199.
Ashish, P. K., D. Singh, and S. Bohm. 2016a. “A study on the rheological performance of a nanoclay-modified asphalt binder using the Brookfield viscometer and dynamic shear rheometer.” In Vol. 268 of Proc., 4th Geo-China Int. Conf., 9–15. Reston, VA: ASCE.
Ashish, P. K., D. Singh, and S. Bohm. 2016b. “Evaluation of rutting, fatigue and moisture damage performance of nanoclay modified asphalt binder.” Constr. Build. Mater. 113 (Jun): 341–350. https://doi.org/10.1016/j.conbuildmat.2016.03.057.
ASTM. 2007. Standard test method for ductility of bituminous materials. ASTM D113. West Conshohocken, PA: ASTM.
ASTM. 2010. Standard test method for kinematic viscosity of asphalts (bitumens). ASTM D2170. West Conshohocken, PA: ASTM.
ASTM. 2013a. Standard practice for accelerated aging of asphalt binder using a pressurized aging vessel (PAV). ASTM D6521. West Conshohocken, PA: ASTM.
ASTM. 2013b. Standard test method for penetration of bituminous materials. ASTM D5. West Conshohocken, PA: ASTM.
ASTM. 2014a. Standard test method for effects of heat and air on asphaltic materials (thin-film oven test). ASTM D1754. West Conshohocken, PA: ASTM.
ASTM. 2014b. Standard test method for softening point of bitumen (ring-and-ball apparatus). ASTM D36. West Conshohocken, PA: ASTM.
ASTM. 2015. Standard test method for determining the rheological properties of asphalt binder using a dynamic shear rheometer. ASTM D7175. West Conshohocken, PA: ASTM.
ASTM. 2016a. Standard practice for determining low-temperature performance grade (PG) of asphalt binders. ASTM D6816. West Conshohocken, PA: ASTM.
ASTM. 2016b. Standard test method for determining the flexural creep stiffness of asphalt binder using the bending beam rheometer (BBR). ASTM D6648. West Conshohocken, PA: ASTM.
Bayekolaei, M. D., K. Naderi, and F. M. Nejad. 2016. “A statistical analysis on the mechanical properties of nanocomposite modified asphalt mixtures.” Pet. Sci. Technol. 34 (16): 1439–1446. https://doi.org/10.1080/10916466.2016.1202969.
Brinson, H. F., and L. C. Brinson. 2008. Vol. 66 of Polymer engineering science and viscoelasticity, 79. New York: Springer.
Das, A. K., and D. Singh. 2018. “Effects of regular and nano sized hydrated lime fillers on fatigue and bond strength behavior of asphalt mastic.” Transp. Res. Rec. 2672 (28): 31–41. https://doi.org/10.1177/0361198118759064.
De Melo, J. V. S., and G. Trichês. 2018. “Evaluation of properties and fatigue life estimation of asphalt mixture modified by organophilic nanoclay.” Constr. Build. Mater. 140 (Jun): 364–373. https://doi.org/10.1016/j.conbuildmat.2017.02.143.
Ebrahimi, M. G., M. Saleh, and M. A. M. Gonzalez. 2014. “Interconversion between viscoelastic functions using the Tikhonov regularisation method and its comparison with approximate techniques.” Road Mater. Pavement Des. 15 (4): 820–840. https://doi.org/10.1080/14680629.2014.924428.
Faramarzi, M., M. Arabani, A. K. Haghi, and V. Mottaghitalab. 2015. “Carbon nanotubes-modified asphalt binder: Preparation and characterization.” Int. J. Pavement Res. Technol. 8 (1): 29–37.
Gong, M., J. Yang, H. Yao, M. Wang, X. Niu, and J. E. Haddock. 2017. “Investigating the performance, chemical, and microstructural properties of carbon nanotube-modified asphalt binder.” Road Mater. Pavement Des. 19 (7): 1499–1522. https://doi.org/10.1080/14680629.2017.1323661.
Habal, A., and D. Singh. 2019. “Effects of warm mix asphalt additives on bonding potential and failure pattern of asphalt-aggregate systems using strength and energy parameters.” Int. J. Pavement Eng. 1–13. https://doi.org/10.1080/10298436.2019.1623399.
Hanz, A. J., A. Faheem, E. Mahmoud, and H. U. Bahia. 2010. “Measuring effects of warm-mix additives: Use of newly developed asphalt binder lubricity test for the dynamic shear rheometer.” Transp. Res. Rec. 2180 (1): 85–92. https://doi.org/10.3141/2180-10.
Hasan, M. R. M., and Z. You. 2016. “Ethanol based foamed asphalt as potential alternative for low emission asphalt technology.” J. Traffic Transp. Eng. 3 (2): 116–126. https://doi.org/10.1016/j.jtte.2016.03.001.
Hassan, M. M., H. Dylla, S. Asadi, L. N. Mohammad, and S. Cooper. 2012. “Laboratory evaluation of environmental performance of photocatalytic titanium dioxide warm-mix asphalt pavements.” J. Mater. Civ. Eng. 24 (5): 599–605. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000408.
Johansson, L. S., and U. Isacsson. 1998. “Effect of filler on low temperature physical hardening of bitumen.” Constr. Build. Mater. 12 (8): 463–470. https://doi.org/10.1016/S0950-0618(98)00028-2.
Li, Y. L., M. Y. Shen, H. S. Su, C. L. Chiang, and M. C. Yip. 2012. “A study on mechanical properties of CNT-reinforced carbon/carbon composites.” J. Nanomater. 2012: 6. https://doi.org/10.1155/2012/262694.
Liu, S., W. Cao, S. Shang, H. Qi, and J. Fang. 2010a. “Analysis and application of relationships between low-temperature rheological performance parameters of asphalt binders.” Constr. Build. Mater. 24 (4): 471–478. https://doi.org/10.1016/j.conbuildmat.2009.10.015.
Liu, S., C. Ma, W. Cao, and J. Fang. 2010b. “Influence of aluminate coupling agent on low-temperature rheological performance of asphalt mastic.” Constr. Build. Mater. 24 (5): 650–659. https://doi.org/10.1016/j.conbuildmat.2009.11.004.
Ma, P. C., J. K. Kim, and B. Z. Tang. 2007. “Effects of silane functionalization on the properties of carbon nanotube/epoxy nanocomposites.” Compos. Sci. Technol. 67 (14): 2965–2972. https://doi.org/10.1016/j.compscitech.2007.05.006.
Ma, P. C., B. Z. Tang, and J. K. Kim. 2008. “Effect of CNT decoration with silver nanoparticles on electrical conductivity of CNT-polymer composites.” Carbon 46 (11): 1497–1505. https://doi.org/10.1016/j.carbon.2008.06.048.
Manchado, M. L., L. Valentini, J. Biagiotti, and J. M. Kenny. 2005. “Thermal and mechanical properties of single-walled carbon nanotubes–polypropylene composites prepared by melt processing.” Carbon 43 (7): 1499–1505. https://doi.org/10.1016/j.carbon.2005.01.031.
Marasteanu, M. 2004. “Role of bending beam rheometer parameters in thermal stress calculations.” Transp. Res. Rec. 1875 (1): 9–13. https://doi.org/10.3141/1875-02.
Marasteanu, M. O., and A. Basu. 2004. “Stiffness m-value and the low temperature relaxation properties of asphalt binders.” Road Mater. Pavement Des. 5 (1): 121–131. https://doi.org/10.1080/14680629.2004.9689966.
McNally, T., P. Pötschke, P. Halley, M. Murphy, D. Martin, S. E. Bell, G. P. Brennan, D. Bein, P. Lomoine, and J. P. Quinn. 2005. “Polyethylene multiwalled carbon nanotube composites.” Polymer 46 (19): 8222–8232. https://doi.org/10.1016/j.polymer.2005.06.094.
Park, S. W., and Y. R. Kim. 1999. “Interconversion between relaxation modulus and creep compliance for viscoelastic solids.” J. Mater. Civ. Eng. 11 (1): 76–82. https://doi.org/10.1061/(ASCE)0899-1561(1999)11:1(76).
Pszczola, M., M. Jaczewski, D. Rys, P. Jaskula, and C. Szydlowski. 2018. “Evaluation of asphalt mixture low-temperature performance in bending beam creep test.” Materials 11 (1): 100–121. https://doi.org/10.3390/ma11010100.
Qiu, Y., H. Ding, A. Rahman, and E. Yang. 2018. “Using combined Avrami-Ozawa method to evaluate low-temperature reversible aging in asphalt binders.” Road Mater. Pavement Des. 1–16. https://doi.org/10.1080/14680629.2018.1479291.
Santagata, E., O. Baglieri, L. Tsantilis, and G. Chiappinelli. 2015a. “Fatigue and healing properties of nano-reinforced bituminous binders.” Int. J. Fatigue 80 (Nov): 30–39. https://doi.org/10.1016/j.ijfatigue.2015.05.008.
Santagata, E., O. Baglieri, L. Tsantilis, and G. Chiappinelli. 2015b. “Fatigue properties of bituminous binders reinforced with carbon nanotubes.” Int. J. Pavement Eng. 16 (1): 80–90. https://doi.org/10.1080/10298436.2014.923099.
Schapery, R. A., and S. W. Park. 1999. “Methods of interconversion between linear viscoelastic material functions. Part II—An approximate analytical method.” Int. J. Solids Struct. 36 (11): 1677–1699. https://doi.org/10.1016/S0020-7683(98)00060-2.
Seo, M. K., and S. J. Park. 2004. “Electrical resistivity and rheological behaviors of carbon nanotubes-filled polypropylene composites.” Chem. Phys. Lett. 395 (1): 44–48. https://doi.org/10.1016/j.cplett.2004.07.047.
Sheikhmotevali, A. H., and M. Ameri. 2014. “Application of bitumen rheological parameters to predict thermal cracking behavior of polymer modified asphalt mixture.” Constr. Build. Mater. 66 (Sep): 259–267. https://doi.org/10.1016/j.conbuildmat.2014.05.070.
Tsantilis, L., O. Baglieri, and E. Santagata. 2018. “Low-temperature properties of bituminous nanocomposites for road applications.” Constr. Build. Mater. 171 (May): 397–403. https://doi.org/10.1016/j.conbuildmat.2018.03.154.
Wang, P., Z. J. Dong, Y. Q. Tan, and Z. Y. Liu. 2016. “Anti-ageing properties of styrene–butadiene–styrene copolymer-modified asphalt combined with multi-walled carbon nanotubes.” Road Mater. Pavement Des. 18 (3): 1–17. https://doi.org/10.1080/14680629.2016.1181561.
Wang, P., Z. J. Dong, Y. Q. Tan, and Z. Y. Liu. 2017. “Effect of multi-walled carbon nanotubes on the performance of styrene–butadiene–styrene copolymer modified asphalt.” Mater. Struct. 50 (17): 1–11. https://doi.org/10.1617/s11527-016-0890-9.
Xiao, F., A. N. Amirkhanian, and S. N. Amirkhanian. 2011a. “Influence of carbon nanoparticles on the rheological characteristics of short-term aged asphalt binders.” J. Mater. Civ. Eng. 23 (4): 423–431. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000184.
Xiao, F., A. N. Amirkhanian, and S. N. Amirkhanian. 2011b. “Long-term ageing influence on rheological characteristics of asphalt binders containing carbon nanoparticles.” Int. J. Pavement Eng. 12 (6): 533–541. https://doi.org/10.1080/10298436.2011.560267.
Yang, Q., Q. Liu, J. Zhong, B. Hong, D. Wang, and M. Oeser. 2019. “Rheological and micro-structural characterization of bitumen modified with carbon nanomaterials.” Constr. Build. Mater. 201 (Mar): 580–589. https://doi.org/10.1016/j.conbuildmat.2018.12.173.
Yu, J. Y., P. C. Feng, H. L. Zhang, and S. P. Wu. 2009. “Effect of organo-montmorillonite on aging properties of asphalt.” Constr. Build. Mater. 23 (7): 2636–2640. https://doi.org/10.1016/j.conbuildmat.2009.01.007.
Yusoff, N. I. M., F. M. Jakarni, V. H. Nguyen, M. R. Hainin, and G. D. Airey. 2013. “Modelling the rheological properties of bituminous binders using mathematical equations.” Constr. Build. Mater. 40 (Mar): 174–188. https://doi.org/10.1016/j.conbuildmat.2012.09.105.
Zhang, H., D. Zhang, and C. Zhu. 2015a. “Properties of bitumen containing various amounts of organic montmorillonite.” J. Mater. Civ. Eng. 27 (11): 04015010. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001261.
Zhang, H., C. Zhu, J. Yu, C. Shi, and D. Zhang. 2015b. “Influence of surface modification on physical and ultraviolet aging resistance of bitumen containing inorganic nanoparticles.” Constr. Build. Mater. 98 (Nov): 735–740. https://doi.org/10.1016/j.conbuildmat.2015.08.138.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 32Issue 3March 2020

History

Received: Dec 11, 2018
Accepted: Aug 5, 2019
Published online: Dec 27, 2019
Published in print: Mar 1, 2020
Discussion open until: May 27, 2020

Permissions

Request permissions for this article.

Authors

Affiliations

Ph.D. Research Scholar, Dept. of Civil Engineering, Indian Institute of Technology Bombay, Mumbai, Maharashtra 400076, India (corresponding author). ORCID: https://orcid.org/0000-0002-9433-3652. Email: [email protected]
Dharamveer Singh [email protected]
Associate Professor, Dept. of Civil Engineering, Indian Institute of Technology Bombay, Mumbai, Maharashtra 400076, India. Email: [email protected]
Undergraduate Student, Dept. of Civil and Environmental Engineering, Indian Institute of Technology Patna, Bihta, Bihar 801103, India. Email: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share