Technical Papers
Dec 10, 2019

Investigating the Working Mechanisms of Viscosity-Modifying Admixtures through Rheological and Water Transport Properties

Publication: Journal of Materials in Civil Engineering
Volume 32, Issue 2

Abstract

Viscosity modifying admixtures (VMAs) show great potential in achieving the desired rheological properties for 3D concrete printing. In addition to rheology, water transport properties are critically important; due to the absence of formwork, freshly printed components with high exposed surface areas are susceptible to excessive water loss. In this study, the effect of VMAs (i.e., attapulgite/palygorskite nanoclay and diutan gum) on the water transport properties of cement pastes were investigated. Bleeding, water retention under suction pressure, and evaporation under airflow were measured. The nanoclay was found to reduce bleeding but had no effect on water retention or evaporation. The diutan gum was found to reduce bleeding, improve water retention, and decrease evaporation loss. The potential working mechanisms of nanoclay and diutan gum are discussed and tied to observations of the rheological and water transport properties of the modified pastes.

Get full access to this article

View all available purchase options and get full access to this article.

Acknowledgments

The authors would like to acknowledge the Thornton Tomasetti Student Innovation Fellowship and National Science Foundation (NSF 1653419) for financial support and technical support by the staff of Columbia University’s Carleton Laboratory.

References

ACTI-GEL® 208. n.d. “How it works.” Accessed November 11, 2019. https://acti-gel.com/acti-gel/.
Brumaud, C., R. Baumann, M. Schmitz, M. Radler, and N. Roussel. 2014. “Cellulose ethers and yield stress of cement pastes.” Cem. Concr. Res. 55 (Jan): 14–21. https://doi.org/10.1016/j.cemconres.2013.06.013.
Brumaud, C., H. Bessaies-Bey, C. Mohler, R. Baumann, M. Schmitz, M. Radler, and N. Roussel. 2013. “Cellulose ethers and water retention.” Cem. Concr. Res. 53 (Nov): 176–184. https://doi.org/10.1016/j.cemconres.2013.06.010.
Bülichen, D., J. Kainz, and J. Plank. 2012. “Working mechanism of methyl hydroxyethyl cellulose (MHEC) as water retention agent.” Cem. Concr. Res. 42 (7): 953–959. https://doi.org/10.1016/j.cemconres.2012.03.016.
Cao, E., R. Bryant, and D. J. A. Williams. 1996. “Electrochemical properties of Na–Attapulgite.” J. Colloid Interface Sci. 179 (1): 143–150. https://doi.org/10.1006/jcis.1996.0196.
Chang, S. H., M. H. Ryan, and R. K. Gupta. 1993. “The effect of pH, ionic strength, and temperature on the rheology and stability of aqueous clay suspensions.” Rheol. Acta. 32 (3): 263–269. https://doi.org/10.1007/BF00434190.
Desbrieres, J. 1993a. “Cement cake properties in static filtration. Influence of polymeric additives on cement filter cake permeability.” Cem. Concr. Res. 23 (2): 347–358. https://doi.org/10.1016/0008-8846(93)90100-N.
Desbrieres, J. 1993b. “Cement cake properties in static filtration. On the role of fluid loss control additives on the cake porosity.” Cem. Concr. Res. 23 (6): 1431–1442. https://doi.org/10.1016/0008-8846(93)90080-S.
DIN (Deutsches Institut für Normung). 2000. Testing of mortars containing mineral binders: Determination of water retentivity of freshly mixed mortar by the filter plate method. Berlin: DIN.
Fan, Y., S. Zhang, S. Kawashima, and S. P. Shah. 2014. “Influence of kaolinite clay on the chloride diffusion property of cement-based materials.” Cem. Concr. Compos. 45 (Jan): 117–124. https://doi.org/10.1016/j.cemconcomp.2013.09.021.
Ferron, R. D., S. Shah, E. Fuente, and C. Negro. 2013. “Aggregation and breakage kinetics of fresh cement paste.” Cem. Concr. Res. 50 (Aug): 1–10. https://doi.org/10.1016/j.cemconres.2013.03.002.
Galan, E. 1996. “Properties and applications of palygorskite-sepiolite clays.” Clay Miner. 31 (4): 443–453. https://doi.org/10.1180/claymin.1996.031.4.01.
Ghourchian, S., M. Wyrzykowski, L. Baquerizo, and P. Lura. 2018. “Susceptibility of portland cement and blended cement concretes to plastic shrinkage cracking.” Cem. Concr. Compos. 85 (Jan): 44–55. https://doi.org/10.1016/j.cemconcomp.2017.10.002.
Ginez, A. 1999. “Attapulgite as a suspension control agent and rheology modifier in flowables.” In Vol. 19 of Pesticide formulations and application systems: Global pest control formulations for the next millennium, 108–110. West Conshohocken, PA: ASTM.
Govin, A., M. C. Bartholin, B. Biasotti, M. Giudici, V. Langella, and P. Grosseau. 2016. “Modification of water retention and rheological properties of fresh state cement-based mortars by guar gum derivatives.” Constr. Build. Mater. 122 (Sep): 772–780. https://doi.org/10.1016/j.conbuildmat.2016.06.125.
Hu, J., Z. Ge, and K. Wang. 2014. “Influence of cement fineness and water-to-cement ratio on mortar early-age heat of hydration and set times.” Constr. Build. Mater. 50 (Jan): 657–663. https://doi.org/10.1016/j.conbuildmat.2013.10.011.
Kawashima, S., J. H. Kim, D. J. Corr, and S. P. Shah. 2012. “Study of the mechanisms underlying the fresh-state response of cementitious materials modified with nanoclays.” Constr. Build. Mater. 36 (Nov): 749–757. https://doi.org/10.1016/j.conbuildmat.2012.06.057.
Kazemian, A., X. Yuan, E. Cochran, and B. Khoshnevis. 2017. “Cementitious materials for construction-scale 3D printing: Laboratory testing of fresh printing mixture.” Constr. Build. Mater. 145 (Aug): 639–647. https://doi.org/10.1016/j.conbuildmat.2017.04.015.
Khayat, K. H. 1998. “Viscosity-enhancing admixtures for cement-based materials—An overview.” Cem. Concr. Compos. 20 (2–3): 171–188. https://doi.org/10.1016/S0958-9465(98)80006-1.
Liddel, P. V., and D. V. Boger. 1996. “Yield stress measurements with the vane.” J. Non-Newtonian Fluid Mech. 63 (2–3): 235–261. https://doi.org/10.1016/0377-0257(95)01421-7.
Lloret, E., A. R. Shahab, M. Linus, R. J. Flatt, F. Gramazio, M. Kohler, and S. Langenberg. 2015. “Complex concrete structures: Merging existing casting techniques with digital fabrication.” Comput. Aided Des. 60 (Mar): 40–49. https://doi.org/10.1016/j.cad.2014.02.011.
Loh, C.-K., T.-S. Tan, T.-S. Yong, and T.-H. Wee. 1998. “An experimental study on bleeding and channelling of cement paste and mortar.” Adv. Cem. Res. 10 (1): 1–16. https://doi.org/10.1680/adcr.1998.10.1.1.
Lowke, D., and C. Gehlen. 2015. “Effect of pore solution composition on zeta potential and superplasticizer adsorption.” In Proc., 11th International Conference on Superplasticizers and Other Chemical Admixtures in Concrete, 253. Farmington Hills, MI: American Concrete Institute.
Lura, P., B. Pease, G. B. Mazzotta, F. Rajabipour, and J. Weiss. 2007. “Influence of shrinkage-reducing admixtures on development of plastic shrinkage cracks.” ACI Mater. J. 104 (2): 187–194. https://doi.org/10.14359/18582.
Ma, S., and S. Kawashima. 2019. Rheological and water transport properties of cement pastes modified with diutan gum and attapulgite/palygorskite nanoclays for 3D concrete printing, 61–69. Berlin: Springer.
Ma, S., Y. Qian, and S. Kawashima. 2018a. “Performance-based study on the rheological and hardened properties of blended cement mortars incorporating palygorskite clays and carbon nanotubes.” Constr. Build. Mater. 171 (May): 663–671. https://doi.org/10.1016/j.conbuildmat.2018.03.121.
Ma, S., Y. Qian, and S. Kawashima. 2018b. “Experimental and modeling study on the non-linear structural build-up of fresh cement pastes incorporating viscosity modifying admixtures.” Cem. Concr. Res. 108 (Jun): 1–9. https://doi.org/10.1016/j.cemconres.2018.02.022.
Macklin, M. B., M. A. Franciosi, L. A. Jardine, and B.-W. Chun. 2008. Cement additive for stucco applications. Washington, DC: US Patent and Trademark Office.
Marliere, C., E. Mabrouk, M. Lamblet, and P. Coussot. 2012. “How water retention in porous media with cellulose ethers works.” Cem. Concr. Res. 42 (11): 1501–1512. https://doi.org/10.1016/j.cemconres.2012.08.010.
Massoussi, N., E. Keita, and N. Roussel. 2017. “The heterogeneous nature of bleeding in cement pastes.” Cem. Concr. Res. 95 (May): 108–116. https://doi.org/10.1016/j.cemconres.2017.02.012.
Mehta, P., and P. J. M. Monteiro. 2006. Concrete: Microstructure, properties, and materials. New York: McGraw-Hill Education.
Murray, H. H. 1991. “Overview—Clay mineral applications.” Appl. Clay Sci. 5 (5–6): 379–395. https://doi.org/10.1016/0169-1317(91)90014-Z.
Neaman, A., and A. Singer. 2000. “Rheological properties of aqueous suspensions of palygorskite.” Soil Sci. Soc. Am. J. 64 (1): 427. https://doi.org/10.2136/sssaj2000.641427x.
Ohama, Y. 1998. “Polymer-based admixtures.” Cem. Concr. Compos. 20 (2–3): 189–212. https://doi.org/10.1016/S0958-9465(97)00065-6.
Palacios, M., and R. J. Flatt. 2016. “20–Working mechanism of viscosity-modifying admixtures.” Sci. Technol. Concr. Admixtures 415–432. https://doi.org/10.1016/B978-0-08-100693-1.00020-5.
Palacios, M., R. J. Flatt, F. Puertas, and A. Sanchez-Herencia. 2012. “Compatibility between polycarboxylate and viscosity-modifying admixtures in cement pastes.” In Proc., 10th Int. Conf. on Superplasticizers and Other Chemical Admixtures in Concrete, 29–42. Farmington Hills, MI: American Concrete Institute.
Panda, B., S. Ruan, C. Unluer, and M. J. Tan. 2019. “Improving the 3D printability of high volume fly ash mixtures via the use of nano attapulgite clay.” Composites Part B 165 (May): 75–83. https://doi.org/10.1016/j.compositesb.2018.11.109.
Patural, L., P. Marchal, A. Govin, P. Grosseau, B. Ruot, and O. Devès. 2010a. “Cellulose ethers influence on water retention and consistency in cement-based mortars.” Cem. Concr. Res. 41 (1): 46–55. https://doi.org/10.1016/j.cemconres.2010.09.004.
Patural, L., P. Porion, H. Van Damme, A. Govin, P. Grosseau, B. Ruot, and O. Devès. 2010b. “A pulsed field gradient and NMR imaging investigations of the water retention mechanism by cellulose ethers in mortars.” Cem. Concr. Res. 40 (9): 1378–1385. https://doi.org/10.1016/j.cemconres.2010.04.001.
Phyfferoen, A., H. Monty, B. Skaggs, N. Sakata, S. Yanai, and M. Yoshizaki. 2002. “Evaluation of the biopolymer, diutan gum, for use in self-compacting concrete.” In Proc., 1st North American Conf. on the Design and Use of Self-Consolidating Concrete, 147–152. Chicago: ACBM.
Pierre, A., A. Perrot, V. Picandet, and Y. Guevel. 2015. “Cellulose ethers and cement paste permeability.” Cem. Concr. Res. 72 (Jun): 117–127. https://doi.org/10.1016/j.cemconres.2015.02.013.
Plank, J. 2004. “Applications of biopolymers and other biotechnological products in building materials.” Appl. Microbiol. Biotechnol. 66 (1): 1–9. https://doi.org/10.1007/s00253-004-1714-3.
Plank, J., and C. Hirsch. 2007. “Impact of zeta potential of early cement hydration phases on superplasticizer adsorption.” Cem. Concr. Res. 37 (4): 537–542. https://doi.org/10.1016/j.cemconres.2007.01.007.
Poinot, T., A. Govin, and P. Grosseau. 2014. “Importance of coil-overlapping for the effectiveness of hydroxypropylguars as water retention agent in cement-based mortars.” Cem. Concr. Res. 56 (Feb): 61–68. https://doi.org/10.1016/j.cemconres.2013.11.005.
Qian, Y., and G. De Schutter. 2018. “Enhancing thixotropy of fresh cement pastes with nanoclay in presence of polycarboxylate ether superplasticizer (PCE).” Cem. Concr. Res. 111 (Sep): 15–22. https://doi.org/10.1016/j.cemconres.2018.06.013.
Qian, Y., and S. Kawashima. 2016. “Use of creep recovery protocol to measure static yield stress and structural rebuilding of fresh cement pastes.” Cem. Concr. Res. 90 (Dec): 73–79. https://doi.org/10.1016/j.cemconres.2016.09.005.
Quanji, Z., G. R. Lomboy, and K. Wang. 2014. “Influence of nano-sized highly purified magnesium alumino silicate clay on Thixotropic behavior of fresh cement pastes.” Constr. Build. Mater. 69 (Oct): 295–300. https://doi.org/10.1016/j.conbuildmat.2014.07.050.
Roussel, N., A. Lemaître, R. J. Flatt, and P. Coussot. 2010. “Steady state flow of cement suspensions: A micromechanical state of the art.” Cem. Concr. Res. 40 (1): 77–84. https://doi.org/10.1016/j.cemconres.2009.08.026.
Roussel, N., G. Ovarlez, S. Garrault, and C. Brumaud. 2012. “The origins of thixotropy of fresh cement pastes.” Cem. Concr. Res. 42 (1): 148–157. https://doi.org/10.1016/j.cemconres.2011.09.004.
Sanjayan, J. G., B. Nematollahi, M. Xia, and T. Marchment. 2018. “Effect of surface moisture on inter-layer strength of 3D printed concrete.” Constr. Build. Mater. 172 (May): 468–475. https://doi.org/10.1016/j.conbuildmat.2018.03.232.
Scherer, G. W. 1990. “Theory of drying.” J. Am. Ceram. Soc. 73 (1): 3–14. https://doi.org/10.1111/j.1151-2916.1990.tb05082.x.
Schmidt, W. 2014. Design concepts for the robustness improvement of self-compacting concrete: Effects of admixtures and mixture components on the rheology and early hydration at varying temperatures. Eindhoven, Netherlands: Technische Universiteit Eindhoven.
Schmidt, W., H. J. H. Brouwers, H.-C. Kühne, and B. Meng. 2013. “The working mechanism of starch and diutan gum in cementitious and limestone dispersions in presence of polycarboxylate ether superplasticizers.” Appl. Rheol. 23 (5): 1–12. https://doi.org/10.3933/applrheol-23-52903.
Schmidt, W., H. J. H. Brouwers, H.-C. Kühne, and B. Meng. 2017. “Interactions of polysaccharide stabilising agents with early cement hydration without and in the presence of superplasticizers.” Constr. Build. Mater. 139 (May): 584–593. https://doi.org/10.1016/j.conbuildmat.2016.11.022.
Schmidt, W., C. Weimann, and L. C. Weba. 2016. “Influences of hydration effects on the flow phenomena of concrete with admixtures.” In Advances in cement and concrete technology in Africa, 79–88. Berlin: BAM Federal Institute for Materials Research and Testing.
Sonebi, M. 2006. “Rheological properties of grouts with viscosity modifying agents as diutan gum and welan gum incorporating pulverised fly ash.” Cem. Concr. Res. 36 (9): 1609–1618. https://doi.org/10.1016/j.cemconres.2006.05.016.
Stroh, J., M.-C. Schlegel, W. Schmidt, Y. N. Thi, B. Meng, and F. Emmerling. 2016. “Time-resolved in situ investigation of portland cement hydration influenced by chemical admixtures.” Constr. Build. Mater. 106 (Mar): 18–26. https://doi.org/10.1016/j.conbuildmat.2015.12.097.
Tan, T. S., T. H. Wee, S. A. Tan, C. T. Tam, and S. L. Lee. 1987. “A consolidation model for bleeding of cement paste.” Adv. Cem. Res. 1 (1): 18–26. https://doi.org/10.1680/adcr.1987.1.1.18.
Tregger, N. A., M. E. Pakula, and S. P. Shah. 2010. “Influence of clays on the rheology of cement pastes.” Cem. Concr. Res. 40 (3): 384–391. https://doi.org/10.1016/j.cemconres.2009.11.001.
Üzer, E., and J. Plank. 2016. “Impact of welan gum stabilizer on the dispersing performance of polycarboxylate superplasticizers.” Cem. Concr. Res. 82 (Apr): 100–106. https://doi.org/10.1016/j.cemconres.2009.11.001.
Xu, L., H. Gong, M. Dong, and Y. Li. 2015. “Rheological properties and thickening mechanism of aqueous diutan gum solution: Effects of temperature and salts.” Carbohydr. Polym. 132 (Nov): 620–629. https://doi.org/10.1016/j.carbpol.2015.06.083.
Zhang, Y., Y. Zhang, G. Liu, Y. Yang, M. Wu, and B. Pang. 2018. “Fresh properties of a novel 3D printing concrete ink.” Constr. Build. Mater. 174 (Jun): 263–271. https://doi.org/10.1016/j.conbuildmat.2018.04.115.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 32Issue 2February 2020

History

Received: Sep 5, 2018
Accepted: Jul 11, 2019
Published online: Dec 10, 2019
Published in print: Feb 1, 2020
Discussion open until: May 10, 2020

Permissions

Request permissions for this article.

Authors

Affiliations

Siwei Ma, Ph.D. [email protected]
Postdoctoral Research Assistant, Lyles School of Civil Engineering, Purdue Univ., West Lafayette, IN 47907; Dept. of Civil Engineering and Engineering Mechanics, Columbia Univ., 500 West 120th St., New York 10027 (corresponding author). Email: [email protected]
Shiho Kawashima, Ph.D. [email protected]
Associate Professor, Dept. of Civil Engineering and Engineering Mechanics, Columbia Univ., 500 West 120th St., New York 10027. Email: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share