Abstract

This work evaluated the use of Pinus sp. wastes treated with a chromium, copper and boron compound (CCB), a wood preservative, to fabricate particleboards based on castor oil–polyurethane resin. The effects of wood particle content, resin mass fraction, pressing time, and their interactions on the physical (thickness swelling, moisture content, water absorption, and density) and mechanical properties (internal bond, and edge and face screw-holding capacity) were evaluated via full factorial design and ANOVA. Two experimental conditions resulted in mechanical properties which meet or surpass the standard requirements and were therefore selected for porosimetric and microscopic analyses. Retention of CCB active ingredients was determined (for particles and particleboards) in order to evaluate possible volatilization during manufacture. The results showed that after a 7.7% increase in wood particle content, the thickness swelling after 2 h decreased by 16.5% and water absorption after 2 h (24 h) decreased by 17.4% (25.3%). In contrast, the moisture content increased by 5.9%. On the other hand, the 25% increase in resin mass fraction resulted in 22.1% and 19% reductions in thickness swelling after 2 and 24 h, respectively. Water absorption after 24 h also decreased by 20.7%. In contrast, internal bond increased by 13.8% with a 25% increase in resin mass fraction. The interaction of factors was not significant for the studied properties. In particular, the factors considered did not significantly affect the screw-holding capacity response. The decrease in active ingredients of the preservative was linked to mass balance by taking into consideration the amount of resin in the composition of the panels.

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Data Availability Statement

All data, models, and code generated or used during the study appear in the paper.

Acknowledgments

The authors are grateful to the National Council for Scientific and Technological Development (CNPq) for financial support and to Montana Chemical and Plural Chemical Industry for the scientific support.

References

ABNT (Brazilian Technical Standards Association). 1973. Penetration and retention of preservative in wood poles. NBR 6232. Rio de Janeiro, Brazil: ABNT.
ABNT (Brazilian Technical Standards Association). 1997. Design of structure of timber. NBR 7190, Rio de Janeiro, Brazil: ABNT.
ABNT (Brazilian Technical Standards Association). 2006. Wood particleboard. NBR 14810. Rio de Janeiro, Brazil: ABNT.
Almeida, A. S., G. Criscuolo, T. H. Almeida, A. L. Christoforo, E. Chahud, L. A. M. N. Branco, R. V. Pinheiro, and F. A. R. Lahr. 2019. “Influence of CCA-A preservative on physical-mechanical properties of Brazilian tropical woods.” BioResources 14 (2): 3030–3041.
ANSI (American National Standards Institute). 1999. Particleboard. ANSI A 208.1. Gaithersburg, MD: ANSI.
Bertolini, M. S., F. A. Rocco Lahr, M. F. Nascimento, and J. A. M. Agnelli. 2013. “Accelerated artificial aging of particleboards from residues of CCB treated Pinus sp. and castor oil resin.” Mater. Res. 16 (2): 293–303. https://doi.org/10.1590/S1516-14392013005000003.
Bovea, M. D., and R. Vidal. 2004. “Materials selection for sustainable product design: A case study of wood based furniture eco-design.” Mater. Des. 25 (2): 111–116. https://doi.org/10.1016/j.matdes.2003.09.018.
Buyuksari, U., N. Ayrilmis, E. Avci, and E. Koc. 2010. “Evaluation of the physical, mechanical properties and formaldehyde emission of particleboard manufactured from waste stone pine (Pinus pinea L.) cones.” Bioresour. Technol. 101 (1): 255–259. https://doi.org/10.1016/j.biortech.2009.08.038.
Campos, C. I. 2005. “Propriedades físico-mecânicas de MDF produzido com fibras de madeira de reflorestamento e adesivos alternativos em diferentes teores.” [In Portuguese.] Ph.D. thesis, Instituto de Química de São Carlos, Univ. of São Paulo.
CEN (European Committee for Standardization). 2003. Particleboards: Specifications. EN 312. Brussels, Belgium: CEN.
Ciannamea, E. M., P. M. Stefani, and R. A. Ruseckaite. 2010. “Medium-density particleboards from modified rice husks and soybean protein concentrate-based adhesives.” Bioresour. Technol. 101 (2): 818–825. https://doi.org/10.1016/j.biortech.2009.08.084.
Clausen, C. A., S. N. Kartal, and J. Muehl. 2001. “Particleboard made from remediated CCA-treated wood: Evaluation of panel properties.” Forest Prod. J. 51 (7/8): 1–4.
Collin, J. F., C. G. Jung, J. M. Romnée, and J. Delcarte. 2005. “Pyrolytic treatment of CCB treated wood. International Research Group on Wood Protection.” In Proc., 6th Int. Symp. “Environment and Wood Preservation,” 5. Stockholm, Sweden: International Research Group on Wood Protection.
CS (Commercial Standard). 1968. Mat formed wood particleboard. CS 236-66, Geneva: CS.
Dias, F. M. 2008. “Use of castor-oil polyurethane resin in the particleboards manufacturing.” In Wood products: Summary of studies developed at the wood and timber structures laboratory, SET-EESC-USP. Edited by F. A. Rocco Lahr, 73–92. São Carlos, Brazil: Engineering School of São Carlos, Univ. of São Paulo.
EPA. 2011. “The United States of America: United States environmental protection agency.” Accessed January 16, 2015. https://www.epa.gov/ingredients-used-pesticide-products/chromated-arsenicals-cca.
FAO (Food and Agriculture Organization). 2017. “FAOSTAT: Forestry production and trade.” Accessed October 30, 2018. http://faostat.fao.org/site/626/DesktopDefault.aspx?PageID=626#ancor.
Ferreira, B. S., J. V. F. Silva, and C. I. Campos. 2017. “Static bending strength of heat-treated and chromated copper arsenate-treated plywood.” BioResources 12 (3): 6276–6282. https://doi.org/10.15376/biores.12.3.6276-6282.
Ferro, F. S., T. H. Almeida, D. H. Almeida, A. L. Christoforo, and F. A. Rocco Lahr. 2016. “Physical properties of OSB panels manufactured with CCA and CCB treated Schizolobium amazonicum and bonded with castor oil based polyurethane resin.” Int. J. Mater. Eng. 6 (5): 151–154. https://doi.org/10.5923/j.ijme.20160605.02.
Fiorelli, J., D. D. Curtolo, N. G. Barrero, H. Savastano Junior, E. M. J. A. Pallone, and R. Johnson. 2012. “Particulate composite based on coconut fiber and castor oil polyurethane adhesive: An eco-efficient product.” Ind. Crops Prod. 40: 69–75. https://doi.org/10.1016/j.indcrop.2012.02.033.
Gamage, N., S. Setunge, M. Jollands, and J. Hague. 2009. “Properties of hardwood saw mill residue-based particleboards as affected by processing parameters.” Ind. Crops Prod. 29 (1): 248–254. https://doi.org/10.1016/j.indcrop.2008.05.012.
García, D., J. López, R. Balart, R. A. Ruseckaite, and P. M. Stefani. 2007. “Composites based on sintering rice husk–waste tire rubber mixtures.” Mater. Des. 28 (7): 2234–2238. https://doi.org/10.1016/j.matdes.2006.06.001.
Gürü, M., S. Tekeli, and I. Bilici. 2006. “Manufacturing of urea–formaldehyde-based composite particleboard from almond shell.” Mater. Des. 27 (10): 1148–1151. https://doi.org/10.1016/j.matdes.2005.03.003.
Helsen, L., and E. Den Bulck. 2003. “Metal retention in the solid waste after low-temperature pyrolysis of chromated cooper arsenate (CCA): Treated wood.” Environ. Eng. Sci. 20 (6): 569–580. https://doi.org/10.1089/109287503770736087.
IBA (Indústria Brasileira de Árvores). 2016. “Indústria Brasileira de Árvores 2016.” Accessed November 26, 2018. https://iba.org/images/shared/Biblioteca/IBA_RelatorioAnual2016_.pdf.
Iwakiri, S., A. B. M. Stinghen, E. L. Silveira, E. H. C. Zamarian, J. G. Prata, and M. Bronoski. 2008. “Effects of the density on the mechanical properties of particleboard.” Floresta 38 (3): 487–493. https://doi.org/10.5380/rf.v38i3.12414.
Juliana, A. H., M. T. Paridah, and U. M. K. Anwar. 2012. “Properties of three-layer particleboards made from kenaf (Hibiscus cannabinus L.) and rubberwood (Hevea brasiliensis).” Mater. Des. 40: 59–63. https://doi.org/10.1016/j.matdes.2012.03.030.
Kamdem, D. P., H. Jiang, H. Cui, J. Freed, and L. M. Matuana. 2004. “Properties of wood plastic composites made of recycled HDPE and wood flour from CCA-treated wood removed from service.” Composites Part A 35 (3): 347–355. https://doi.org/10.1016/j.compositesa.2003.09.013.
Maloney, T. M. 1977. Modern particleboard & dry-process fiberboard manufacturing. San Francisco, CA: Miller Freeman.
Moura, L. F., J. O. Brito, and G. Bortoletto Júnior. 2012. “Efeitos da termorretificação na perda de massa e propriedades mecânicas de Eucalyptus grandis e Pinus caribaea var. Hondurensis.” Floresta 42 (2): 305–314. https://doi.org/10.5380/rf.v42i2.17635.
Murphy, R. J., P. Mc Quillan, J. Jermer, and R. D. Peek. 2004. “Preservative-treated wood as a component in the recovered wood stream in Europe: A quantitative and qualitative review.” In Proc., 35 Annual Meeting—Int. Research Group on Wood Protection, 21. Stockholm, Sweden: International Research Group on Wood Protection.
Nascimento, M. F. 2003. “CPH—Chapas de partículas homogêneas: Madeiras do nordeste do Brasil.” [In Portuguese.] Ph.D. thesis, Chemistry and Physics Institutes, Univ. of São Paulo.
Piao, C., and C. J. Monlezun. 2010. “Laminated crossarms made from decommissioned chromated copper arsenate-treated utility pole wood. Part I: Mechanical and acoustic properties.” For. Prod. J. 60 (2): 157–165. https://doi.org/10.13073/0015-7473-60.2.157.
Rocco Lahr, F. A., R. Fernandes, and M. S. Bertolini. 2010. “Influence of CCB-preservation in the hardness of Pinus sp.” In Proc., 19th Brazilian Congress of Engineering and Science of Materials. Campos do Jordão, Brazil: UFSCAR.
SINDUSCONSP (Sindicato da Indústria da Construção Civil do Estado de São Paulo). 2010. “Setor vê perigo na madeira tratada.” [In Portuguese.] Notícias da Construção. Accessed July 20, 2017. https://www.cbcs.org.br/userfiles/noticias/cbcsnaimprensa/240610_Noticias-da-construcao_setor-ve-perigo-em-madeira-tratada.pdf.
Trianoski, R., S. Iwakiri, J. L. M. Matos, and J. G. Prata. 2011. “Avaliação de espécies alternativas de rápido crescimento para produção de painéis de madeira aglomerada de três camadas.” Sci. Forest Piracicaba 39 (89): 97–104.
Varanda, L. D. 2012. “Produção e avaliação do desempenho de painéis de partículas de Eucalyptus grandis confeccionados com adição de casca de aveia.” [In Portuguese.] Ph.D. thesis, Escola de Engenharia de São Carlos, Univ. of São Paulo.
Varanda, L. D., A. M. Souza, D. H. Almeida, F. H. Icimoto, F. S. Ferro, A. L. Christoforo, and F. A. L. Rocco. 2014. “Physical and mechanical properties of Paricá wood species treated with CCB preservative.” Int. J. Compt. Mater. 4: 150–156.
Wang, S. Y., T. H. Yang, L. T. Lin, C. J. Lin, and M. J. Tsai. 2007. “Properties of low-formaldehyde-emission particleboard made from recycled wood-waste chips sprayed with PMDI/PF resin.” Build. Environ. 42 (7): 2472–2479. https://doi.org/10.1016/j.buildenv.2006.06.009.
Wang, S. Y., T. H. Yang, L. T. Lin, C. J. Lin, and M. J. Tsai. 2008. “Fire-retardant-treated low-formaldehyde-emission particleboard made from recycled wood-waste.” Bioresour. Technol. 99 (6): 2072–2077. https://doi.org/10.1016/j.biortech.2007.03.047.
Wechsler, A., M. Zaharia, A. Crosky, H. Jones, M. Ramírez, A. Ballerini, M. Nuñez, and V. Sahajwallaa. 2013. “Macadamia (Macadamia integrifolia) shell and castor (Rícinos communis) oil based sustainable particleboard: A comparison of its properties with conventional wood based particleboard.” Mater. Des. 50: 117–123. https://doi.org/10.1016/j.matdes.2013.03.008.
Xu, J., R. Sugawara, R. Widyorini, G. Han, and S. Kawai. 2004. “Manufacture and properties of low -density binderless particleboard from kenaf core.” J. Wood Sci. 50 (1): 62–67. https://doi.org/10.1007/s10086-003-0522-1.
Yang, T. H., C. J. Lin, S. Y. Wang, and M. J. Tsai. 2007. “Characteristics of particleboard made from recycled wood-waste chips impregnated with phenol formaldehyde resin.” Build. Environ. 42 (1): 189–195. https://doi.org/10.1016/j.buildenv.2005.08.028.
Zhao, J., X. M. Wang, J. M. Chang, Y. Yao, and Q. Cui. 2010. “Sound insulation property of wood–waste tire rubber composite.” Compos. Sci. Technol. 70 (14): 2033–2038. https://doi.org/10.1016/j.compscitech.2010.03.015.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 31Issue 11November 2019

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Received: Jun 6, 2018
Accepted: Jun 4, 2019
Published online: Aug 28, 2019
Published in print: Nov 1, 2019
Discussion open until: Jan 28, 2020

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Marilia da Silva Bertolini [email protected]
Assistant Professor, Dept. of Production Engineering, São Paulo State Univ. (Unesp), Campus of Itapeva, Itapeva, São Paulo 18409-010, Brazil. Email: [email protected]
César Augusto Galvão de Morais [email protected]
Assistant Professor, Dept. of Production Engineering, São Paulo State Univ. (Unesp), Campus of Itapeva, Itapeva, São Paulo 18409-010, Brazil. Email: [email protected]
Francisco Antônio Rocco Lahr [email protected]
Professor, Wood and Timber Structures Laboratory, Dept. of Structural Engineering, São Carlos School of Engineering, Univ. of São Paulo, São Carlos, São Paulo 13566-590, Brazil. Email: [email protected]
Rodrigo Teixeira Santos Freire [email protected]
Associate Professor, Centre for Innovation and Technology in Composite Materials, Dept. of Natural Sciences, Federal Univ. of São João del Rei, São João del Rei 36301-160, Brazil. Email: [email protected]
Associate Professor, Centre for Innovation and Technology in Composite Materials, Dept. of Mechanical Engineering, Federal Univ. of São João del Rei, São João del Rei 26307-352, Brazil (corresponding author). ORCID: https://orcid.org/0000-0001-7091-456X. Email: [email protected]
André Luis Christoforo [email protected]
Adjunct Professor, Dept. of Civil Engineering, Federal Univ. of São Carlos (UFSCar), São Carlos 13565-905, Brazil. Email: [email protected]

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