Technical Papers
May 24, 2019

Effect of pH and Subgrade Type on Trace-Metal Leaching from Steel-Slag Embankments into Groundwater

Publication: Journal of Materials in Civil Engineering
Volume 31, Issue 8

Abstract

An experimental research program was carried out to evaluate the environmental impacts of embankments constructed with steel slag on groundwater. A series of sequential water leach tests and sequential column leach tests were performed to study the leaching of aluminum, copper, and zinc into groundwater due to the flow of percolating rainwater through treated steel slag. The results indicated that treating steel slag prior to use by mixing with an alum-based water treatment residual resulted in lower effluent pH and metal concentrations. Metal leaching was greatly affected by the effluent pH and total metal content, as well as the natural pH and buffering capacity of the subgrade. The results of the employed numerical model showed that the field metal concentrations were expected to be considerably lower than those measured in laboratory column leach tests due to dispersion within the vadose zone.

Get full access to this article

View all available purchase options and get full access to this article.

Acknowledgments

This study was financially supported by Maryland Department of Transportation (MDOT) and Maryland Water Resources Research Center (MWRRC). Endorsement by the MDOT and MWRRC or the steel slag suppliers is not implied and should not be assumed.

References

Akinmusuru, J. O. 1991. “Potential beneficial uses of steel slag wastes for civil engineering purposes.” Resour. Conserv. Recycl. 5 (1): 73–80. https://doi.org/10.1016/0921-3449(91)90041-L.
Apul, D. S., K. H. Gardner, T. T. Eighmy, A.-M. Fallman, and R. N. J. Comans. 2005. “Simultaneous application of dissolution/precipitation and surface complexation/surface precipitation modeling to contaminant leaching.” Environ. Sci. Technol. 39 (15): 5736–5741. https://doi.org/10.1021/es0486521.
Astrup, T., J. J. Dijkstra, R. N. J. Comans, H. A. van der Sloot, and T. H. Christensen. 2006. “Geochemical modeling of leaching from MSWI air-pollution-control residues.” Environ. Sci. Technol. 40 (11): 3551–3557. https://doi.org/10.1021/es052250r.
ASTM. 2012a. Standard practice for shake extraction of solid waste with water. ASTM D3987. West Conshohocken, PA: ASTM.
ASTM. 2012b. Standard test methods for laboratory compaction characteristics of soil using standard effort. ASTM D698. West Conshohocken, PA: ASTM.
ASTM. 2014. Standard test method for leaching solid material in a column apparatus. ASTM D4874. West Conshohocken, PA: ASTM.
Aydilek, A. H., and A. Y. Dayioglu. 2016. Geotechnical and environmental impacts of steel slag use in highway construction. Baltimore, MD: Maryland Dept. of Transportation, State Highway Administration.
Barca, C., D. Meyer, Y. Andres, F. Chazarenc, M. Liira, P. Drissen, and Y. Comeau. 2014. “Steel slag filters to upgrade phosphorus removal in small wastewater treatment plants: Removal mechanisms and performance.” Ecol. Eng. 68 (1): 214–222. https://doi.org/10.1016/j.ecoleng.2014.03.065.
Bear, J. 1979. Hydraulics of groundwater. London: McGraw-Hill.
Bin-Shafique, S., C. Benson, T. Edil, and K. Hwang. 2006. “Leachate concentrations from water leach and column leach tests on fly-ash stabilized soil.” Environ. Eng. Sci. 23 (1): 51–65.
Bundy, M. M., and D. H. Kang. 2016. Evaluation of waste concrete road materials for use in oyster aquaculture—Phase 3. Baltimore, MD: Maryland Department of Transportation, State Highway Administration.
Camacho, L. M., and S. H. Munson-McGee. 2006. “Anomalous transient leaching behavior of metals solidified/stabilized by pozzolanic fly ash.” J. Hazard. Mater. 137 (1): 144–151. https://doi.org/10.1016/j.jhazmat.2005.12.055.
Cetin, B., A. H. Aydilek, and Y. Guney. 2012. “Leaching of four trace metals from high carbon fly ash stabilized highway base layers.” Resour. Conserv. Recycl. 58: 8–17. https://doi.org/10.1016/j.resconrec.2011.10.004.
Cetin, B., A. H. Aydilek, and L. Li. 2012. “Experimental and numerical study of metal leaching from fly ash amended highway bases.” Waste Manage. 32 (5): 965–978. https://doi.org/10.1016/j.wasman.2011.12.012.
Cetin, B., A. H. Aydilek, and L. Li. 2014. “Trace metal leaching from embankment soils amended with high carbon fly ash.” J. Geotech. Geoenviron. Eng. 140 (1): 1–13. https://doi.org/10.1061/(ASCE)GT.1943-5606.0000996.
Cheng, W. P., C. H. Fu, P. H. Chen, and R. F. Yu. 2012. “Dynamics of aluminum leaching from water purification sludge.” J. Hazard. Mater. 217–218: 149–155. https://doi.org/10.1016/j.jhazmat.2012.03.007.
Chi-Duran, I., J. Enriquez, C. Manquian, K. Wrighton-Araneda, W. Canon-Mancisidor, D. Venegas-Yazigi, F. Herrera, and D. P. Singh. 2018. “pH-controlled assembly of 3D and 2D zinc-based metal-organic frameworks with tetrazole ligands.” ACS Omega 3 (1): 801–807. https://doi.org/10.1021/acsomega.7b01792.
Collins, R. J., and S. K. Ciesielski. 1992. “Highway construction use of wastes and by-products.” In Utilization of waste materials in civil engineering construction, 140–152. New York: ASCE.
Comans, R. N. J., H. A. van der Sloot, D. Hoede, and P. A. Bonouvrie. 1991. “Chemical processes at a redox/pH interface arising from the use of steel slag in the aquatic environment.” In Proc., Int. Conf. on Environmental Implications of Construction with Waste Materials, edited by J. J. J. M. Goumans, H. A. van der Sloot, and T. G. Aalbers, 243–254. Amsterdam, Netherlands: Elsevier.
Cornelis, G., C. H. Johnson, T. Van Gerven, and C. Vandecasteele. 2008. “Leaching mechanisms of oxyanionic metalloid and metal species in alkaline solid wastes.” Appl. Geochem. 23 (5): 955–976. https://doi.org/10.1016/j.apgeochem.2008.02.001.
Dayioglu, A. Y., and A. H. Aydilek. 2016. “Trace metal leaching from steel slag embankments into surface waters.” In Proc., Transportation Research Board Annual Meeting. Washington, DC: Transportation Research Board.
Dayioglu, A. Y., A. H. Aydilek, and B. Cetin. 2014. “Preventing swelling and decreasing alkalinity of steel slags used in highway infrastructures.” Transp. Res. Rec. 2401 (1): 52–57. https://doi.org/10.3141/2401-06.
Delhaize, E., and P. R. Ryan. 1995. “Aluminum toxicity and tolerance in plants.” Plant Physiol. 107 (2): 315–321. https://doi.org/10.1104/pp.107.2.315.
Deniz, D., E. Tutumluer, and J. Popovics. 2010. “Evaluation of expansive characteristics of reclaimed asphalt pavement and virgin aggregate used as base materials.” Transp. Res. Rec. 2167 (1): 10–17. https://doi.org/10.3141/2167-02.
Eighmy, T. T., J. D. Eusden Jr., J. E. Krzanowski, D. S. Domingo, D. Stampfli, and J. R. Martin. 1995. “Comprehensive approach toward understanding element speciation and leaching behavior in municipal solid waste incineration electrostatic precipitator ash.” Environ. Sci. Technol. 29 (3): 629–646. https://doi.org/10.1021/es00003a010.
Elsayed-Ali, O. H., T. Abdel-Fattah, and H. E. Elsayed-Ali. 2011. “Copper cation removal in an electrokinetic cell containing zeolite.” J. Hazard. Mater. 185 (2–3): 1550–1557. https://doi.org/10.1016/j.jhazmat.2010.10.086.
Fedje, K. K. 2010. “Metals in MSWI fly ash—Problems or opportunities?” Ph.D. thesis, Dept. of Chemical and Biological Engineering, Division of Environmental Inorganic Chemistry, Chalmers Univ. of Technology.
Fernandez-Olmo, I., C. Lasa, and A. Irabien. 2007. “Modeling of zinc solubility in stabilized/solidified electric arc furnace dust.” J. Hazard. Mater. 144 (3): 720–724. https://doi.org/10.1016/j.jhazmat.2007.01.102.
Garrabrants, A. C., F. Sanchez, and D. S. Kosson. 2004. “Changes in constituent equilibrium leaching and pore water characteristics of a portland cement mortar as a result of carbonation.” Waste Manage. 24 (1): 19–36. https://doi.org/10.1016/S0956-053X(03)00135-1.
Ghionna, V., S. Pedroni, P. Tenani, and S. Veggi. 1996. “Geotechnical investigation on steel slags mixtures for landfills embankments construction.” In Proc., Second Int. Conf. on Environmental Geotechnics, 709–714. Rotterdam, Netherlands: A.A.Balkema.
Gitari, W. M., O. O. Fatoba, L. F. Petrik, and W. R. K. Vadapalli. 2009. “Leaching characteristics of selected South African fly ashes: Effect of pH on the release of major and trace species.” J. Environ. Sci. Health Part A 44 (2): 206–220. https://doi.org/10.1080/10934520802539897.
Gomes, J. F. P., and C. G. Pinto. 2006. “Leaching of heavy metals from steelmaking slags.” Rev. Metal. 42 (6): 409–416. https://doi.org/10.3989/revmetalm.2006.v42.i6.39.
Grubb, D. G., M. Wazne, S. C. Jagupilla, and N. E. Malasavage. 2011. “The beneficial use of steel slag fines to immobilize arsenite and arsenate: Slag characterization and metal thresholding studies.” J. Hazard. Toxic Radioactive Waste 15 (3): 130–150. https://doi.org/10.1061/(ASCE)HZ.1944-8376.0000077.
Grubb, D. G., M. Wazne, S. C. Jagupilla, N. E. Malasavage, and W. B. Bradfield. 2013. “Aging effects in field-compacted dredged material: Steel slag fines blends.” J. Hazard. Toxic Radioactive Waste 17 (2): 107–119. https://doi.org/10.1061/(ASCE)HZ.2153-5515.0000154.
Havanagi, V. G., A. K. Sinha, V. K. Arora, and S. Mathur. 2012. “Waste materials for construction of road embankment and pavement layers.” Int. J. Environ. Eng. Res. 1 (2): 51–59.
Jankowski, J., R. W. Colin, D. French, and S. Groves. 2006. “Mobility of trace elements from selected Australian fly ashes and its potential impact on aquatic ecosystems.” Fuel 85 (2): 243–256. https://doi.org/10.1016/j.fuel.2005.05.028.
Jegadeesan, G., S. R. Al-Abed, and P. Pinto. 2008. “Influence of trace metal distribution on its leachability from coal fly ash.” Fuel 87 (10–11): 1887–1893. https://doi.org/10.1016/j.fuel.2007.12.007.
Johnson, C. A., M. Kaeppeli, S. Brandenberger, A. Ulrich, and W. Baumann. 1999. “Hydrological and geochemical factors affecting leachate composition in municipal solid waste incinerator bottom ash. Part II: The geochemistry of leachate from landfill Lostorf, Switzerland.” J. Contam. Hydrol. 40 (3): 239–259. https://doi.org/10.1016/S0169-7722(99)00052-2.
Johnson, G. V., and H. Zhang. 2004. Cause and effects of soil acidity, Oklahoma cooperative extension fact sheet. Stillwater, OK: Oklahoma State Univ.
Komonweeraket, K., B. Cetin, A. H. Aydilek, C. H. Benson, and T. B. Edil. 2015. “Effects of pH on the leaching mechanisms of elements from fly ash mixed soils.” Fuel 140: 788–802. https://doi.org/10.1016/j.fuel.2014.09.068.
Li, L., C. H. Benson, T. B. Edil, and B. Hatipoglu. 2006. “Groundwater impacts from coal ash in highways.” Waste Resour. Manage. 159 (4): 151–163. https://doi.org/10.1680/warm.2006.159.4.151.
Li, L., C. H. Benson, T. B. Edil, and B. Hatipoglu. 2007. “Groundwater impacts from coal ash in highways.” Waste Resour. Manage. 159 (4): 151–163.
Li, L., B. Peng, F. Santos, Y. Li, and F. Amini. 2011. “Groundwater impacts from leaching of coal combustion products in roadways embankment constructions.” J. ASTM Int. 8 (8): 103659. https://doi.org/10.1520/JAI103659.
Lim, T. T., J. H. Tay, L. C. Tan, and V. Choa. 2004. “The changes in mobility and speciation of heavy metals in clay-amended incinerator fly ash.” Environ. Geol. 47 (1): 1–10. https://doi.org/10.1007/s00254-004-1117-x.
Liu, Y., Y. Li, X. Li, and Y. Jiang. 2008. “Leaching behavior of heavy metals and PAHs from MSWI bottom ash in long-term static immersing experiment.” Waste Manage. 28 (7): 1126–1136. https://doi.org/10.1016/j.wasman.2007.05.014.
Loncnar, M., H. A. van der Sloot, A. Mladenovič, M. Zupančič, L. Kobal, and P. Bukovec. 2016. “Study of the leaching behaviour of ladle slags by means of leaching tests combined with geochemical modelling and mineralogical investigations.” J. Hazard. Mater. 317: 147–157. https://doi.org/10.1016/j.jhazmat.2016.05.046.
Malviya, R., and R. Chaudhary. 2006. “Leaching behavior and immobilization of heavy metals in solidified/stabilized products.” J. Hazard. Mater. 137 (1): 207–217. https://doi.org/10.1016/j.jhazmat.2006.01.056.
Maryland Department of State Planning. 1973. Natural soil groups of Maryland. Annapolis, MD: Maryland Department of State Planning.
MD-SHA (Maryland State Highway Administration). 2016. Access manual, Chapter 5: Technical Design Standards. Baltimore, MD: MD-SHA.
Meima, J. A., and R. N. J. Comans. 1998. “Application of surface complexation/precipitation modeling to contaminant leaching from weathered municipal solid waste incinerator bottom ash.” Environ. Sci. Technol. 32 (5): 688–693. https://doi.org/10.1021/es9701624.
Meima, J. A., and R. N. J. Comans. 1999. “Leaching of trace elements from municipal solid waste incinerator bottom ash at different stages of weathering.” Appl. Geochem. 14 (2): 159–171. https://doi.org/10.1016/S0883-2927(98)00047-X.
Motz, H., and J. Geiseler. 2001. “Products of steel slags: An opportunity to save natural resources.” Waste Manage. 21 (3): 285–293. https://doi.org/10.1016/S0956-053X(00)00102-1.
O’Donohue, J., M. A. Reid, A. Varghese, B. Portmann, and R. Williams. 1993. “Micronodular cirrhosis and acute liver failure due to chronic copper self-intoxication.” Eur. J. Gastroenterol. Hepatol. 5: 561–562.
Ogata, A., and R. B. Banks. 1961. A solution of the differential equation of longitudinal dispersion in porous media; fluid movement in earth materials. Washington, DC: U.S. Government Printing Office.
Ozkok, E., A. P. Davis, and A. H. Aydilek. 2016. “Treatment methods for mitigation of high alkalinity in leachates of aged steel slag.” J. Environ. Eng. 142 (2): 04015063. https://doi.org/10.1061/(ASCE)EE.1943-7870.0001024.
Plum, L. M., L. Rink, and H. Haase. 2010. “The essential toxin: Impact of zinc on human health.” Int. J. Environ. Res. Pub. Health 7 (4): 1342–1365. https://doi.org/10.3390/ijerph7041342.
Pourakbar, S., A. Asadi, B. B. K. Huat, N. Cristelo, and M. H. Fasihnikoutalab. 2017. “Application of alkali-activated agro-waste reinforced with wollastonite fibers in soil stabilization.” J. Mater. Civ. Eng. 29 (2): 04016206. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001735.
Sabbas, T., et al. 2003. “Management of municipal solid waste incineration residues.” Waste Manage 23 (1): 61–88. https://doi.org/10.1016/S0956-053X(02)00161-7.
Shaw, C. A., and Tomljenovic L. 2013. “Aluminum in the central nervous system (CNS): Toxicity in humans and animals, vaccine adjuvants, and autoimmunity.” Immunol. Res. 56 (2013): 304–316.
Sheldon, A. R., and N. W. Menzies. 2005. “The effect of copper toxicity on the growth and root morphology of Rhodes grass (Chloris gayana Knuth.) in resin buffered solution culture.” Plant Soil: Int. J. Plant-Soil Relat. 278 (1–2): 341–349. https://doi.org/10.1007/s11104-005-8815-3.
Sinha, A. K., V. G. Havanagi, A. Ranjan, S. Mathur, and B. K. Singh. 2013. “Geotechnical characterization of Jarosite waste material for road construction.” In Proc., Indian Geotechnical Conf., 22–24. New Delhi, India: Indian Roads Congress.
Sparks, D. L. 2003. Environmental soil chemistry. 2nd ed. San Diego: Academic Press.
Svilovic, S., D. Rusic, and R. Stipisic. 2009. “Modeling batch kinetics of copper ions sorption using synthetic zeolite NaX.” J. Hazard. Mater. 170 (2–3): 941–947. https://doi.org/10.1016/j.jhazmat.2009.05.063.
Van Der Sloot, H. A., D. Hoede, and P. Bonouvrie. 1991. Comparison of different regulatory leaching test procedure for waste materials and construction materials. Petten, Netherlands: Netherlands Energy Research Foundation.
van Genuchten, M. T. 1981. “Analytical solutions for chemical transport with simultaneous adsorption, zero-order production and first order decay.” J. Hydrol. 49 (3–4): 213–233.
Wan Zuhairi, W. Y., A. R. Samsudin, and N. Ridwan. 2008. “The retention characteristics of heavy metals in natural soils using soil column experiment.” In Proc., 12th Int. Conf. of Int. Association for Computer Methods and Advances in Geomechanics (IACMAG). Red Hook, NY: Curran Associates.
World Steel Association. 2016a. “FACT SHEET: Steel industry by-products.” Accessed March 12, 2018. https://www.worldsteel.org/en/dam/jcr:1b916a6d-06fd-4e84-b35d-c1d911d18df4/Fact_By-products_2016.pdf.
World Steel Association. 2016b. World steel in figures. Brussels, Belgium: World Steel Association.
Yildirim, I. Z., and M. Prezzi. 2009. Use of steel slag in subgrade applications. Indianapolis, IN: Indiana Dept. of Transportation.
Zhang, Y., B. Cetin, W. J. Likos, and T. B. Edil. 2016. “Impacts of pH on leaching potential of elements from MSW incineration fly ash.” Fuel 184: 815–825. https://doi.org/10.1016/j.fuel.2016.07.089.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 31Issue 8August 2019

History

Received: Mar 13, 2018
Accepted: Jan 30, 2019
Published online: May 24, 2019
Published in print: Aug 1, 2019
Discussion open until: Oct 24, 2019

Permissions

Request permissions for this article.

Authors

Affiliations

Asli Y. Dayioglu, A.M.ASCE [email protected]
Assistant Professor, Dept. of Civil Engineering, Istanbul Technical Univ., Istanbul 34467, Turkey. Email: [email protected]
Ahmet H. Aydilek, A.M.ASCE [email protected]
Professor, Dept. of Civil and Environmental Engineering, Univ. of Maryland, College Park, MD 20742 (corresponding author). Email: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share