Technical Papers
Apr 25, 2019

Thermal and Mechanical Properties of SiO2 Aerogel–Incorporated Geopolymer Insulation Materials

Publication: Journal of Materials in Civil Engineering
Volume 31, Issue 7

Abstract

Geopolymer-blended aerogel materials (GAMs) prepared by adding different proportions of water and SiO2 aerogel (AG) were studied with respect to stability, viscosity, segregation degree, density, thermal conductivity, compressive strength, and interfacial characteristics. These properties were tested by contact angle tester, rheometer, thermal conductivity tester, universal testing machine, and scanning electron microscope, among others. Results indicated that AG can stably exist within GAMs regardless of its high alkaline activator. With increasing AG content, the apparent viscosity of GAM slurry rose obviously and segregation degree increased slightly, then remained at around 2.6%. Due to its high porosity, an increased volume of AG generally contributed to a lowered density and thermal conductivity. The relationship between thermal conductivity and AG content conforms to a modified Maxwell-Euchen model, and the value of parameter t is determined as 1.1–1.2. However, AG generally can lead to reduced compressive strength of GAMs. Considering this disadvantage, the AG surface was further modified with epoxy resin AB adhesive and silence coupling KH550. The compressive strength of GAMs with modified AG reached 46 MPa, a 30% increase, due to enhancement of the intertransition zone between aerogel and geopolymeric matrix as witnessed via scanning electron imaging.

Get full access to this article

View all available purchase options and get full access to this article.

Data Availability Statement

Data analyzed during this study are available at https://doi.org/10.17632/62kyt6cfp7.1.

Acknowledgments

The authors would like to acknowledge the National Natural Science Foundation of China (No. 51572293) and Key Science and Technology Program of Shanxi Province, China (MC2014-04).

References

Al Bakri, M. M., H. Mohammed, H. Kamarudin, I. K. Niza, and Y. Zarina. 2011. “Review on fly ash-based geopolymer concrete without portland cement.” J. Eng. Technol. Res. 3 (1): 1–4. https://doi.org/10.1016/0045-7949(88)90278-7.
Babu, K. G., and D. S. Babu. 2004. “Performance of fly ash concretes containing lightweight EPS aggregates.” Cem. Concr. Compos. 26 (6): 605–611. https://doi.org/10.1016/S0958-9465(03)00034-9.
Bi, S., M. Liu, J. Shen, X. M. Hu, and L. Zhang. 2017. “Ultrahigh self-sensing performance of geopolymer nanocomposites via unique interface engineering.” ACS Appl. Mater. Interfaces 9 (14): 12851–12858. https://doi.org/10.1021/acsami.7b00419.
Chen, H., J. Zheng, L. Qiao, Y. Ying, L. Jiang, and S. Che. 2015. “Surface modification of NdFe12x, magnetic powder using silane coupling agent KH550.” Adv. Powder Technol. 26 (2): 618–621. https://doi.org/10.1016/j.apt.2015.01.011.
Chinese Standard. 2008a. Test methods for inorganic rigid insulation products. GB/T 5486. Beijing: Chinese Standard.
Chinese Standard. 2008b. Thermal insulation—Determination of steady-state thermal resistance and related properties—Guarded hot plate apparatus. GB/T 10294. Beijing: Chinese Standard.
Cuce, E., P. M. Cuce, C. J. Wood, and S. B. Riffat. 2014. “Toward aerogel based thermal superinsulation in buildings: A comprehensive review.” Renewable Sustainable Energy Rev. 34 (3): 273–299. https://doi.org/10.1016/j.rser.2014.03.017.
Duxson, P., A. Fernández-Jiménez, J. L. Provis, G. C. Lukey, A. Palomo, and J. S. van Deventer. 2007. “Geopolymer technology: The current state of the art.” J. Mater. Sci. 42 (9): 2917–2933. https://doi.org/10.1007/s10853-006-0637-z.
Gao, T., B. P. Jelle, A. Gustavsen, and S. Jacobsen. 2014. “Aerogel-incorporated concrete: An experimental study.” Constr. Build. Mater. 52 (2): 130–136. https://doi.org/10.1016/j.conbuildmat.2013.10.100.
Gao, Y., and C. Zou. 2015. “Experimental study on segregation resistance of nano SiO2, fly ash lightweight aggregate concrete.” Constr. Build. Mater. 93: 64–69. https://doi.org/10.1016/j.conbuildmat.2015.05.102.
Gupta, N., and W. Ricci. 2008. “Processing and compressive properties of aerogel/epoxy composites.” J. Mater. Process. Technol. 198 (1): 178–182. https://doi.org/10.1016/j.jmatprotec.2007.06.084.
He, J., J. Zhang, Y. Yu, and G. Zhang. 2012. “The strength and microstructure of two geopolymers derived from metakaolin and red mud-fly ash admixture: A comparative study.” Constr. Build. Mater. 30 (5): 80–91. https://doi.org/10.1016/j.conbuildmat.2011.12.011.
Huang, Y., L. Gong, Y. Pan, C. Li, T. Zhou, and X. Cheng. 2018. “Facile construction of the aerogel/geopolymer composite with ultra-low thermal conductivity and high mechanical performance.” RSC Adv. 8 (5): 2350–2356. https://doi.org/10.1039/C7RA12041A.
Ibrahim, M., P. H. Biwole, E. Wurtz, and P. Achard. 2014. “A study on the thermal performance of exterior walls covered with a recently patented silica-aerogel-based insulating coating.” Build. Environ. 81 (7): 112–122. https://doi.org/10.1016/j.buildenv.2014.06.017.
Jelle, B. P. 2011. “Traditional, state-of-the-art and future thermal building insulation materials and solutions: Properties, requirements and possibilities.” Energy Build. 43 (10): 2549–2563. https://doi.org/10.1016/j.enbuild.2011.05.015.
Jelle, B. P., A. Gustavsen, and R. Baetens. 2010. “The high performance thermal building insulation materials and solutions of tomorrow.” J. Build. Phys. 34 (2): 99–123. https://doi.org/10.1177/1744259110372782.
Kamseu, E., Z. N. Ngouloure, B. N. Ali, S. Zekeng, U. C. Melo, S. Rossignol, and C. Leonelli. 2015. “Cumulative pore volume, pore size distribution and phases percolation in porous inorganic polymer composites: Relation microstructure and effective thermal conductivity.” Energy Build. 88: 45–56. https://doi.org/10.1016/j.enbuild.2014.11.066.
Kasemsiri, P., A. Neramittagapong, and P. Chindaprasirt. 2015. “Curing kinetic, thermal and adhesive properties of epoxy resin cured with cashew nut shell liquid.” Thermochimica Acta 600 (4): 20–27. https://doi.org/10.1016/j.tca.2014.11.031.
Kim, S., J. Seo, J. Cha, and S. Kim. 2013. “Chemical retreating for gel-typed aerogel and insulation performance of cement containing aerogel.” Constr. Build. Mater. 40 (3): 501–505. https://doi.org/10.1016/j.conbuildmat.2012.11.046.
Koebel, M. M., A. Rigacci, and P. Achard. 2011. “Aerogels for superinsulation: A synoptic view.” In Aerogels handbook. Advances in sol-gel derived materials and technologies, edited by M. Aegerter, N. Leventis, and M. Koebel. New York: Springer.
Koebel, M. M., A. Rigacci, and P. Achard. 2012. “Aerogel-based thermal superinsulation: An overview.” J. Sol.-Gel Sci. Technol. 63 (3): 315–339. https://doi.org/10.1007/s10971-012-2792-9.
Krieger, I. M., and T. J. Dougherty. 1959. “A mechanism for non-Newtonian flow in suspensions of rigid spheres.” Trans. Soc. Rheol. 3 (1): 137–152. https://doi.org/10.1122/1.548848.
Lanzón, M., and P. García-Ruiz. 2008. “Lightweight cement mortars: Advantages and inconveniences of expanded perlite and its influence on fresh and hardened state and durability.” Constr. Build. Mater. 22 (8): 1798–1806. https://doi.org/10.1016/j.conbuildmat.2007.05.006.
Liu, Z. H., Y. D. Ding, X. Shu, and N. Liu. 2016a. “Preparation, characterization and properties of SiO2 aerogel composite thermal insulation coating.” Chem. Eng. Trans. 55: 259–264. https://doi.org/10.3303/CET1655044.
Liu, Z. H., Y. D. Ding, F. Wang, and Z. P. Deng. 2016b. “Thermal insulation material based on SiO2 aerogel.” Constr. Build. Mater. 122: 548–555. https://doi.org/10.1016/j.conbuildmat.2016.06.096.
Ng, S., B. P. Jelle, L. I. C. Sandberg, T. Gao, and Ó. H. Wallevik. 2015. “Experimental investigations of aerogel-incorporated ultra-high performance concrete.” Constr. Build. Mater. 77: 307–316. https://doi.org/10.1016/j.conbuildmat.2014.12.064.
Ng, S., B. P. Jelle, and T. Stæhli. 2016a. “Calcined clays as binder for thermal insulating and structural aerogel incorporated mortar.” Cem. Concr. Compos. 72: 213–221. https://doi.org/10.1016/j.cemconcomp.2016.06.007.
Ng, S., B. P. Jelle, Y. Zhen, and Ó. H. Wallevik. 2016b. “Effect of storage and curing conditions at elevated temperatures on aerogel-incorporated mortar samples based on UHPC recipe.” Constr. Build. Mater. 106: 640–649. https://doi.org/10.1016/j.conbuildmat.2015.12.162.
Panesar, D. K., and B. Shindman. 2012. “The mechanical, transport and thermal properties of mortar and concrete containing waste cork.” Cem. Concr. Compos. 34 (9): 982–992. https://doi.org/10.1016/j.cemconcomp.2012.06.003.
Pierre, A. C., and G. M. Pajonk. 2002. “Chemistry of aerogels and their applications.” Chem. Rev. 102 (11): 4243–4266. https://doi.org/10.1021/cr0101306.
Provis, J. L., and J. S. J. V. Deventer. 2007. “Geopolymerisation kinetics. Part I: In situ energy-dispersive X-ray diffractometry.” Chem. Eng. Sci. 62 (9): 2309–2317. https://doi.org/10.1016/j.ces.2007.01.027.
Qu, X., and X. Zhao. 2017. “Previous and present investigations on the components, microstructure and main properties of autoclaved aerated concrete: A review.” Constr. Build. Mater. 135: 505–516. https://doi.org/10.1016/j.conbuildmat.2016.12.208.
Ratke, L. 2008. “Herstellung und Eigenschaften eines neuen Leichtbetons: Aerogelbeton.” [In German.] Beton- und Stahlbetonbau 103 (4): 236–243. https://doi.org/10.1002/best.200700608.
Sanjayan, J. G., and R. Zhao. 2011. “Geopolymer and portland cement concretes in simulated fire.” Mag. Concr. Res. 63 (3): 163–173. https://doi.org/10.1680/macr.9.00110.
Svingala, F. R. 2009. “Alkali activated aerogels.” M.Sc. thesis, Dept. of Mechanical Engineering, Rochester Institute of Technology.
Thapliyal, P. C., and K. Singh. 2014. “Aerogels as promising thermal insulating materials: An overview.” J. Mater. 2014: 1–10. https://doi.org/10.1155/2014/127049.
Vickers, L., A. V. Riessen, and W. D. A. Rickard. 2015. “Thermal properties of geopolymers.” In Fire-resistant geopolymers, 77–98. Singapore: Springer.
Wang, F. Z. 2003. Research and application of high performance lightweight aggregate concrete. [In Chinese.] Wuhan, China: Wuhan Univ. of Technology.
Wei, B., Q. Chang, C. Bao, L. Dai, G. Zhang, and F. Wu. 2013. “Surface modification of filter medium particles with silane coupling agent KH550.” Colloid Surf. A 434 (19): 276–280. https://doi.org/10.1016/j.colsurfa.2013.05.069.
Zhang, Z., J. L. Provis, A. Reid, and H. Wang. 2014. “Geopolymer foam concrete: An emerging material for sustainable construction.” Constr. Build. Mater. 56 (3): 113–127. https://doi.org/10.1016/j.conbuildmat.2014.01.081.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 31Issue 7July 2019

History

Received: Jul 5, 2018
Accepted: Dec 10, 2018
Published online: Apr 25, 2019
Published in print: Jul 1, 2019
Discussion open until: Sep 25, 2019

Permissions

Request permissions for this article.

Authors

Affiliations

Ph.D. Candidate, School of Chemical and Environmental Engineering, China Univ. of Mining and Technology, Beijing 100083, PR China. Email: [email protected]
Dongmin Wang, Ph.D. [email protected]
Professor, School of Chemical and Environmental Engineering, China Univ. of Mining and Technology, Beijing 100083, PR China (corresponding author). Email: [email protected]
Jihui Zhao, Ph.D. [email protected]
Associate Professor, School of Civil Engineering, Sun Yat-sen Univ., Guangzhou 510006, PR China. Email: [email protected]
Duanle Li, Ph.D. [email protected]
Postdoctoral, School of Chemical and Environmental Engineering, China Univ. of Mining and Technology, Beijing 100083, PR China. Email: [email protected]
Ze Liu, Ph.D. [email protected]
Associate Professor, School of Chemical and Environmental Engineering, China Univ. of Mining and Technology, Beijing 100083, PR China. Email: [email protected]
Serina Ng, Ph.D. [email protected]
Professor, Building and Infrastructure, SINTEF, Trondheim 7034, Norway. Email: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share