Technical Papers
Jun 28, 2018

Micromechanical and Chemical Characterization of Foamed Warm-Mix Asphalt Aging

Publication: Journal of Materials in Civil Engineering
Volume 30, Issue 9

Abstract

This study evaluates the effects of aging on the micromechanical and chemical properties of foamed warm-mix asphalt (WMA) and hot-mix asphalt (HMA) materials. Two asphalt binders were considered. Atomic force microscopy (AFM) was used to examine the micromechanical and adhesion properties of the asphalt binders considered at different aging conditions. In addition, Fourier-transform infrared spectroscopy (FTIR) and gel permeation chromatography (GPC) techniques were used to identify and quantify the changes in the chemical composition of different asphalt binders due to aging. The results of the AFM tests indicated that the reduced modulus values of the asphalt binders increased with the aging of these binders, while the bonding energy decreased. In addition, the results of the AFM, FTIR, and GPC tests suggested that the WMA binders will experience equal or less aging over the service life of a pavement structure as compared to HMA binders. Good correlations were obtained between the micromechanical and adhesion properties of the considered asphalt binders measured using the AFM and their chemical properties obtained using the GPC and FTIR tests.

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Acknowledgments

This study was sponsored by the Ohio Department of Transportation (ODOT) and the Federal Highway Administration (FHWA). Their support throughout this study is greatly appreciated.

References

AASHTO. 2000. Standard Specification for Recovery of Asphalt from Solution by Abson Method. AASHTO T170, Washington, DC: AASHTO.
AASHTO. 2002. Standard Practice for Mixture Conditioning of Hot Mix Asphalt. AASHTO R30, Washington, DC: AASHTO.
AASHTO. 2012. Standard Practice for Accelerated Aging of Asphalt Binder Using a Pressurized Aging Vessel (PAV). AASHTO R28, Washington, DC: AASHTO.
AASHTO. 2013. Standard Method of Test for Effect of Heat and Air on a Moving Film of Asphalt Binder (Rolling Thin-Film Oven Test). AASHTO T240, Washington, DC: AASHTO.
AASHTO. 2014. Standard Method of Test for Quantitative Extraction of Asphalt Binder from Hot Mix Asphalt (HMA). AASHTO T164, Washington, DC: AASHTO.
Abbas, A. R., M. Nazzal, S. Kaya, S. Akinbowale, B. Subedi, and L. Abu Qtaish. 2015. “Effect of warm mix asphalt on aging of asphalt binders.” In Proc., TMS Middle East—Mediterranean Materials Congress on Energy and Infrastructure Systems (MEMA), 55–64. Cham, Switzerland: Springer.
Abbas, A. R., M. Nazzal, S. Kaya, S. Akinbowale, B. Subedi, M. S. Arefin, and L. Abu Qtaish. 2016. “Effect of aging on foamed warm mix asphalt produced by water injection.” J. Mater. Civ. Eng. 28 (11): 04016128. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001617.
Agilent Technologies, Inc. 2008. Agilent 5500 LS AFM/SPM user manual. Palo Alto, CA: Agilent Technologies, Inc.
Ali, A., A. Abbas, M. Nazzal, A. Alhasan, A. Roy, and D. Powers. 2013. “Effect of temperature reduction, foaming water content, and aggregate moisture content on performance of foamed warm mix asphalt.” Constr. Build. Mater. 48: 1058–1066. https://doi.org/10.1016/j.conbuildmat.2013.07.081.
Allen, R. G., D. N. Little, and A. Bhasin. 2012. “Structural characterization of micromechanical properties in asphalt using atomic force microscopy.” J. Mater. Civ. Eng. 24 (10): 1317–1327. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000510.
Arega, Z., A. Bhasin, A. Motamed, and F. Turner. 2011. “Influence of warm-mix additives and reduced aging on the rheology of asphalt binders with different natural wax contents.” J. Mater. Civ. Eng. 23 (10): 1453–1459. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000315.
Bell, C. A. 1989. Summary report on aging of asphalt-aggregate systems. Washington, DC: Strategic Highway Research Program, National Research Council.
Bowers, B. F. 2013. “Investigation of asphalt pavement mixture blending utilizing analytical chemistry techniques.” Ph.D. dissertation, Univ. of Tennessee.
Bowers, B. F., B. Huang, X. Shu, and B. C. Miller. 2014. “Investigation of reclaimed asphalt pavement blending efficiency through GPC and FTIR.” Constr. Build. Mater. 50: 517–523. https://doi.org/10.1016/j.conbuildmat.2013.10.003.
Butt, H. J., B. Cappella, and M. Kappl. 2005. “Force measurements with the atomic force microscope: Technique, interpretation and applications.” Surf. Sci. Rep. 59 (1): 1–152. https://doi.org/10.1016/j.surfrep.2005.08.003.
Fischer-Cripps, A. C. 2000. “A review of analysis methods for sub-micron indentation testing.” Vacuum 58 (4): 569–585. https://doi.org/10.1016/S0042-207X(00)00377-8.
Gandhi, T., and S. Amirkhanian. 2008. “Laboratory simulation of warm mix asphalt (WMA) binder aging characteristics.” In Proc., Airfield and highway pavements: Efficient pavements supporting transportation’s future, 195–204. Washington, DC: ASCE.
Goh, S. W., and Z. You. 2011. “Moisture damage and fatigue cracking of foamed warm mix asphalt using a simple laboratory setup.” In Proc., Transportation and Development Institute Congress 2011: Integrated Transportation and Development for a Better Tomorrow, 762–771. Reston, VA: ASCE.
Kim, H., S. J. Lee, S. N. Amirkhanian, and K. D. Jeong. 2013. “Quantification of oxidative aging of polymer-modified asphalt mixes made with warm mix technologies.” J. Mater. Civ. Eng. 25 (1): 1–8. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000479.
Kim, K. W., J. L. Burati Jr., and J. S. Park. 1995. “Methodology for defining LMS portion in asphalt chromatogram.” J. Mater. Civ. Eng. 7 (1): 31–40. https://doi.org/10.1061/(ASCE)0899-1561(1995)7:1(31).
Kim, K. W., K. Kim, Y. S. Doh, and S. N. Amirkhanian. 2006. “Estimation of RAP’s binder viscosity using GPC without binder recovery.” J. Mater. Civ. Eng. 18 (4): 561–567. https://doi.org/10.1061/(ASCE)0899-1561(2006)18:4(561).
Lamontagne, J., P. Dumas, V. Mouillet, and J. Kister. 2001. “Comparison by Fourier transform infrared (FTIR) spectroscopy of different ageing techniques: Application to road bitumens.” Fuel 80 (4): 483–488. https://doi.org/10.1016/S0016-2361(00)00121-6.
Lee, S. J., S. N. Amirkhanian, K. Shatanawi, and K. W. Kim. 2008. “Short-term aging characterization of asphalt binders using gel permeation chromatography and selected Superpave binder tests.” Constr. Build. Mater. 22 (11): 2220–2227. https://doi.org/10.1016/j.conbuildmat.2007.08.005.
Marsac, P., et al. 2014. “Potential and limits of FTIR methods for reclaimed asphalt characterization.” Mater. Struct. 47 (8): 1273–1286. https://doi.org/10.1617/s11527-014-0248-0.
Masson, J. F., V. Leblond, and J. Margeson. 2006. “Bitumen morphologies by phase-detection atomic force microscopy.” J. Microsc. 221 (1): 17–29. https://doi.org/10.1111/j.1365-2818.2006.01540.
Mill, T., D. Tse, B. Loo, C. Yao, and E. Canaves. 1992. “Oxidation pathways for asphalt.” ACS Div. Fuel Chem. 37 (3): 1367–1375.
Mills-Beale, J., Z. You, E. Fini, B. Zada, C. H. Lee, and Y. K. Yap. 2014. “Aging influence on rheology properties of petroleum-based asphalt modified with biobinder.” J. Mater. Civ. Eng. 26 (2): 358–366. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000712.
National Asphalt Association. 2015. “Asphalt pavement industry survey on recycled materials and warm-mix asphalt usage.” Accessed May 19, 2016. https://www.asphaltpavement.org/PDFs/IS138/IS138-2014_RAP-RAS-WMA_Survey_Final.pdf.
Nazzal, M. D., and L. Abu-Qtaish. 2013. The use of atomic force microscopy to evaluate warm mix asphalt. Columbus, OH: Ohio Dept. of Transportation, Research and Development.
Nazzal, M. D., L. Abu-Qtaish, S. Kaya, and D. Powers. 2015. “Using atomic force microscopy to evaluate the nanostructure and nanomechanics of warm mix asphalt.” J. Mater. Civ. Eng. 27 (10): 04015005. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001254.
Nazzal, M. D., S. Kaya, and L. Abu-Qtaish. 2012. “Evaluation of WMA healing properties using atomic force microscopy.” In Proc., 7th RILEM Int. Conf. on Cracking in Pavements, 1125–1134. Dordrecht, Netherlands: Springer.
Nazzal, M. D., S. Kaya, T. Gunay, and P. Ahmedzade. 2013. “Fundamental characterization of asphalt clay nanocomposites.” J. Nanomech. Micromech. 3 (1): 1–8. https://doi.org/10.1061/(ASCE)NM.2153-5477.0000050.
Nazzal, M. D., W. Mogawer, S. Kaya, and T. Bennert. 2014. “Multiscale evaluation of the composite asphalt binder in high-reclaimed asphalt pavement mixtures.” J. Mater. Civ. Eng. 26 (7): 04014019. https://doi.org/10.1061/(ASCE)MT.1943-5533.0000825.
Nguyen, T., X. Gu, M. Fasolka, K. Briggman, J. Hwang, A. Karim, and J. Martin. 2005. “Mapping chemical heterogeneity of polymeric materials with chemical force microscopy.” Polym. Mater. Sci. Eng. 90: 141–143.
Oliver, W. C., and G. M. Pharr. 2004. “Measurement of hardness and elastic modulus by instrumented indentation: Advances in understanding and refinements to methodology.” J. Mater. Res. 19 (01): 3–20. https://doi.org/10.1557/jmr.2004.19.1.3.
Pauli, T., W. Grimes, A. Cookman, and S. C. Huang. 2014. “Adherence energy of asphalt thin films measured by force-displacement atomic force microscopy.” J. Mater. Civ. Eng. 26 (12): 04014089. https://doi.org/10.1061/(ASCE)MT.1943-5533.0001003.
Petersen, J. C., J. F. Branthaver, R. E. Robertson, P. M. Harnsberger, J. J. Duvall, and E. K. Ensley. 1993. “Effects of physicochemical factors on asphalt oxidation kinetics.” Transp. Res. Rec. 1391: 1–10.
Radmacher, M. 2007. “Studying the mechanics of cellular processes by atomic force microscopy.” Methods Cell Biol. 83: 347–372.
Rebelo, L. M., J. S. de Sousa, A. S. Abreu, M. P. M. A. Baroni, A. E. V. Alencar, S. A. Soares, J. Mendes Filho, and J. B. Soares. 2014. “Aging of asphaltic binders investigated with atomic force microscopy.” Fuel 117: 15–25. https://doi.org/10.1016/j.fuel.2013.09.018.
Rubio, M. C., G. Martínez, L. Baena, and F. Moreno. 2012. “Warm mix asphalt: An overview.” J. Cleaner Prod. 24: 76–84. https://doi.org/10.1016/j.jclepro.2011.11.053.
Safaei, F., J. S. Lee, L. A. H. D. Nascimento, C. Hintz, and Y. R. Kim. 2014. “Implications of warm-mix asphalt on long-term oxidative ageing and fatigue performance of asphalt binders and mixtures.” Supplement, Road Mater. Pavement Des. 15 (S1): 45–61. https://doi.org/10.1080/14680629.2014.927050.
Tranchida, D., S. Piccarolo, J. Loos, and A. Alexeev. 2006. “Accurately evaluating Young’s modulus of polymers through nanoindentations: A phenomenological correction factor to the Oliver and Pharr procedure.” Appl. Phys. Lett. 89 (17): 171905. https://doi.org/10.1063/1.2364863.
Xiao, F., D. Newton, B. Putman, V. S. Punith, and S. N. Amirkhanian. 2013. “A long-term ultraviolet aging procedure on foamed WMA mixtures.” Mater. Struct. 46 (12): 1987–2001. https://doi.org/10.1617/s11527-013-0031-7.
Yao, H., Z. You, L. Li, S. W. Goh, C. H. Lee, Y. K. Yap, and X. Shi. 2013. “Rheological properties and chemical analysis of nanoclay and carbon microfiber modified asphalt with Fourier transform infrared spectroscopy.” Constr. Build. Mater. 38: 327–337. https://doi.org/10.1016/j.conbuildmat.2012.08.004.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 30Issue 9September 2018

History

Received: Dec 15, 2017
Accepted: Mar 19, 2018
Published online: Jun 28, 2018
Published in print: Sep 1, 2018
Discussion open until: Nov 28, 2018

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Authors

Affiliations

Lana Abu Qtaish
Graduate Research Assistant, Dept. of Civil Engineering, Ohio Univ., Athens, OH 45701.
Munir D. Nazzal, M.ASCE [email protected]
Associate Professor, Dept. of Civil Engineering, Ohio Univ., Athens, OH 45701 (corresponding author). Email: [email protected]
Ala Abbas
Professor, Dept. of Civil Engineering, Univ. of Akron, Akron, OH 44325.
Savas Kaya
Professor, School of Electrical Engineering and Computer Science, Ohio Univ., Athens, OH 45701.
Sunday Akinbowale
Graduate Assistant, Dept. of Civil Engineering, Univ. of Akron, Akron, OH 44304.
Mir Shahnewaz Arefin
Graduate Assistant, Dept. of Civil Engineering, Univ. of Akron, Akron, OH 44304.
Sang-Soo Kim
Associate Professor, Dept. of Civil Engineering, Ohio Univ., Athens, OH 45701.

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