Tensile Piezoresistive Behavior of Polyethylene Terephthalate/Carbon Black Composite
Publication: Journal of Materials in Civil Engineering
Volume 30, Issue 6
Abstract
The polyethylene terephthalate/carbon black (PET/CB) composite was fabricated by twin-screw extrusion and injection molding method. The morphology, electrical conductive percolation threshold, tensile piezoresistivity, and stress-strain behavior of the composite were investigated. A scanning electron microscope showed that the carbon black was dispersed in the PET matrix homogeneously, but some little visible carbon black agglomerates can also be detected in the composite. The electrical conductive percolation threshold of composite was 15% by weight of carbon black. When the carbon black content changed from 15 to 20% by weight, the PET/CB composite had the tensile piezoresistivity. At the axial tensile strain from 0 to 0.001, the composite with 20% by weight carbon black had the highest value of fractional change in resistivity, which had a linear relationship to tensile strain. After five times cyclic tensile loading and 100,000 cycles fatigue tensile loading, the composite showed good repeatability in tensile piezoresistivity. The yield strength and tensile strength of composite were 18 and 23.8 MPa, respectively. The results showed the potential way of using PET/CB composite as strain sensors for civil engineering.
Get full access to this article
View all available purchase options and get full access to this article.
Acknowledgments
Sincere acknowledgements are given to Zhi Ge and Ning Zhang for their great help in the lab. This work was supported by the China Ministry of Transport Enterprise Technical Innovation Project (Grant No. 2015 315 Q15 070).
References
Azhari, F., and Banthia, N. (2012). “Cement-based sensors with carbon fibers and carbon nanotubes for piezoresistive sensing.” J. Cement Concr. Compos., 34(7), 866–873.
Bautista-Quijano, J., Aviles, F., Aguilar, J., and Tapia, A. (2010). “Strain sensing capabilities of a piezoresistive MWCNT-polysulfone film.” J. Sens. Actuators A, 159(2), 135–140.
Bautista-Quijanoa, J. R., Avilésa, F., Cauich-Rodrigueza, J. V., and Schönfelderb, R. (2013). “Tensile piezoresistivity and disruption of percolation in singlewall and multiwall carbon nanotube/polyurethane composites.” J. Synthetic Metals, 185(2), 96–102.
Fernandes, C. P., Glantz, P. O. J., Svensson, S. A., and Bergmark, A. (2003). “A novel sensor for biteforce determinations.” J. Dental Mater., 19(2), 118–126.
Gau, C., Ko, H., and Chen, H. (2009). “Piezoresistive characteristics of MWNT nanocomposites and fabrication as a polymer pressure sensor.” J. Nanotechnol., 20(18), 185–503.
Ge, Z., Sun, R. J., Zhang, K., and Li, P. C. (2013). “Physical and mechanical properties of mortar using waste polyethylene terephthalate bottles.” J. Constr. Build. Mater., 44(3), 81–86.
Hu, N., Karube, Y., Arai, M., Watanabe, T., Yan, C., and Li, Y. (2010). “Investigation on sensitivity of a polymer/carbon nanotube composite strain sensor.” J. Carbon, 48(3), 680–687.
Hu, N., Karube, Y., Yan, C., Masuda, Z., and Fukunaga, H. (2008). “Tunneling effect in a polymer/carbon nanotube nanocomposite strain sensor.” J. Acta Mater., 56(13), 2929–2936.
Klimiec, E., Zaraska, W., Piekarski, J., and Jasiewicz, B. (2013). “PVDF sensors-research on foot pressure distribution in dynamic conditions.” J. Adv. Sci. Technol., 79(1), 94–99.
Knite, M., Teteris, V., Kiploka, A., and Kaupuzs, J. (2004). “Polyisoprene-carbon black nanocomposites as tensile strain and pressure sensor materials.” J. Sens. Actuators A, 110(1–3), 142–149.
Liao, B., Zhou, G. Q., and Wu, L. (2012). “The development and application analysis of the new pressure sensor.” J. China Coal Soc., 37(17), 1576–1580.
McNally, T., et al. (2005). “Polyethylene multiwalled carbon nanotube composites.” J. Polym., 46(19), 8222–8232.
Mariaenrica, F. (2010). “Recycling of PET bottles as fine aggregate in concrete.” J. Waste Manage., 30(6), 1101–1106.
Mietta, J. L., Jorge, G., and Martin, N. R. (2014). “A flexible strain gauge exhibiting reversible piezoresistivity based on an anisotropic magnetorheological polymer.” J. Smart Mater. Struct., 23(8), 085026.
Obitayo, W., and Liu, T. (2012). “A review: Carbon nanotube-based piezoresistive strain sensors.” J. Sens., 2012(1), 1–15.
Ozerol, E. A., Senkal, B. F., and Okutan, M. (2015). “Preparation and characterization of graphite composites of polyaniline.” J. Microelectron. Eng., 146(10), 76–80.
Sebaaly, P. E., Tabatabaee, N., and Kulakowski, B. (1995). “Evaluation of the hall effect sensor for pavement instrumentation.” J. Test. Eval., 23(3), 189–195.
She, Y., Chen, G., and Wu, D. (2007). “Fabrication of polyethylene/graphite nanocomposite from modified expanded graphite.” J. Polym. Int., 56(5), 679–685.
Simmons, J. G. (1963). “Generalized formula for the electric tunnel effect between similar electrodes separated by a thin insulating film.” J. Appl. Phys., 34(6), 1793–1803.
Taherian, R. (2016). “Experimental and analytical model for the electrical conductivity of polymer-based nanocomposites.” J. Compos. Sci. Technol., 123(2), 17–31.
Tee, B. C. K., Wang, C., Allen, R., and Bao, Z. (2012). “An electrically and mechanically self-healing composite with pressure- and flexion-sensitive properties for electronic skin applications.” J. Nat. Nanotechnol., 7(12), 825–832.
Ventura, I. A., Zhou, J., and Lubineau, G. (2015). “Drastic modification of the piezoresistive behavior of polymer nanocomposites by using conductive polymer coatings.” J. Compos. Sci. Technol., 117(9), 342–350.
Wang, L., Ding, T., and Wang, P. (2008). “Effects of instantaneous compression pressure on electrical resistance of carbon black filled silicone rubber composite during compressive stress relaxation.” J. Compos. Sci. Technol., 68(15–16), 3448–3450.
Wang, L., Ma, F., Shi, Q., Liu, H., and Wang, X. (2011). “Study on compressive resistance creep and recovery of flexible pressure sensitive material based on carbon black filled silicone rubber composite.” J. Sens. Actuators A, 165(2), 207–215.
Wichmann, M. H. G., Buschhorn, S. T., Gehrmann, J., and Schulte, K. (2009). “Piezoresistive response of epoxy composites with carbon nanoparticles under tensile load.” J. Phys. Rev. B, 80(24), 245–437.
Yao, Z. Y., Zhang, X. M., and Ge, Z. (2015). “Mix proportion design and mechanical properties of recycled PET concrete.” J. Test. Eval., 43(2), 344–352.
Zhang, R., Baxendale, M., and Peijs, T. (2007). “Universal resistivity-strain dependence of carbon nanotube/polymer composites.” J. Phys. Rev. B, 76(19), 195–433.
Zhang, X. M., Yao, Z. Y., and Ge, Z. (2017). “Piezoresistive characterization of polyethylene terephthalate-graphite composite.” J. Test. Eval., 45(1), 303–312.
Zheng, X., and Han, C. Y. (2012). “A micro pressure sensor based on SU-8 polymer.” J. Appl. Mech. Mater., 220(11), 1902–1905.
Information & Authors
Information
Published In
Copyright
©2018 American Society of Civil Engineers.
History
Received: Aug 10, 2017
Accepted: Nov 14, 2017
Published online: Apr 9, 2018
Published in print: Jun 1, 2018
Discussion open until: Sep 9, 2018
Authors
Metrics & Citations
Metrics
Citations
Download citation
If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.