Technical Papers
Aug 25, 2012

Influence of the Type of Binder and Crumb Rubber on the Creep and Recovery of Crumb Rubber Modified Bitumen

Publication: Journal of Materials in Civil Engineering
Volume 25, Issue 4

Abstract

This investigation reports the influence of the type of binder and crumb rubber gradation and dosage rate on the creep and recovery properties of crumb rubber modified bitumen (CRMB). Two types of binders, air blown and blended, were used with two gradations of crumb rubber, fine and coarse, at three dosage rates, 8, 10, and 12%. The morphology of these 12 binders were characterized by using environmental scanning electron microscopy (ESEM). Furthermore, energy dispersive X-ray spectroscopy was carried out on the samples to identify the chemical composition of the network structure as seen from ESEM. All the samples were subjected to creep and recovery tests by using a dynamic shear rheometer at five different temperatures of 46, 52, 58, 64, and 70°C. A generalized Voigt-Kelvin model was used to model the creep and recovery response of the material for all the temperatures tested. It was found that the nature of the binder plays a critical role on the development of morphology of CRMB. This morphology influences the creep and recovery characteristics of the final blend. The fibril diameter and the number of network junctions as determined through the image processing of ESEM images and the Voigt-Kelvin model parameters were found to be related.

Get full access to this article

View all available purchase options and get full access to this article.

Acknowledgments

The authors would like to acknowledge Ms. Sonal Maheswarai, Senior Scientist, R&D, M/s Bharat Petroleum Corporation Limited for manufacturing these binders and sharing the same with us. They thank Ms. Shanthi, Material Testing Facility at the Department of Metallurgy, IIT Madras for help with the use of ESEM. The authors would like to acknowledge here the permission given by Dr. Abhijit P. Deshpande, Department of the Chemical Engineering, IIT Madras for the use of dynamic shear rheometer.

References

Abdelrahman, M. A., and Carpenter, S. H. (1999). “Mechanism of interaction of asphalt cement with crumb rubber modifier.” Transportation Research Record 1661, Transportation Research Board, Washington, DC, 106–113.
Airey, G. D., Singleton, T. M., and Collop, A. C. (2002). “Properties of polymer modified bitumen after rubber-bitumen interaction.” J. Mater. Civ. Eng., 14(4), 344–354.
ASTM. (2010). “Standard test method for multiple stress creep and recovery (MSCR) of asphalt binder using a dynamic shear rheometer.”, West Conshohocken, PA.
Bahia, H. U., and Davis, R. (1994). “Effect of crumb rubber modifiers (CRM) on performance-related properties of asphalt binders.” J. Assoc. Asphalt Paving Technol., 63, 414–449.
Bahia, H. U., Hanson, D. I., Zeng, M., Zhai, H., Khatri, M. A., and Anderson, R. M. (2001). “Characterization of modified asphalt binders in superpave mix design.”, Transportation Research Board, National Research Council, Washington, DC.
Barth, E. J. (1962). Asphalt: Science and technology, Gordon and Breach, New York.
Blumenthal, M. (1994). “Producing ground scrap tire rubber: A comparison between ambient and cryogenic technologies.” Proc., 17th Biennial Waste Processing Conf., ASME, New York.
Buckly, D., and Berger, M. (1962). “The swelling of polymer system in solvents.” J. Polym. Sci., 56(163), 163–174.
Bureau of Indian Standards (BIS). (2006). “Specification for paving bitumen, third revision.”, New Delhi, India.
Chen, J.-S., Liao, M.-C., and Shiah, M.-S. (2002). “Asphalt modified by styrene-butadiene-styrene triblock copolymer: Morphology and model.” J. Mater. Civ. Eng., 14(3), 224–229.
Corbett, W. L. (1984). “Refinery processing of asphalt cement.” Transportation Research Record 999, Transportation Research Board, Washington, DC, 1–6.
Dragnevski, K. I., Donalda, A. M., Clarkeb, S. M., and Maltby, A. (2009). “Novel applications of ESEM and EDX for the study of molecularly thin amide monolayers on polymer films.” Colloids Surf. A, 337(1–3), 47–51.
Frantzis, P. (2004). “Crumb rubber—Bitumen interactions: Diffusion of bitumen into rubber.” J. Mater. Civ. Eng., 16(4), 387–390.
Glozman, E. P., and Akhmetova, R. S. (1970). “Chemical composition of bitumen components.” Chem. Technol. Fuels Oils, 6(5), 364–367.
Green, E., and Tolonen, W. (1977). “The chemical and physical properties of asphalt-rubber mixtures, part I-Basic material behavior.”, Arizona Dept. of Transportation, Phoenix.
Heitzman, M. (1992). “State of the practice design and construction of asphalt paving materials with crumb rubber modifier.”, Federal Highway Administration, Washington, DC.
Kerner, E. H. (1956). “The elastic and thermo-elastic properties of composite media.” Proc., Phys. Soc., Sect. B., 69(8), 808–813.
Kraus, G. (1982). “Modification of asphalt by block polymers of butadiene and styrene.” J. Rubber Chem. Technol., 55(5), 1389–1402.
Loeber, L., Sutton, O., Morel, J., Valleton, J.-M., and Muller, G. (1996). “New direct observations of asphalts and asphalt binders by scanning electron microscopy and atomic force microscopy.” J. Microsc., 182(1), 32–39.
Masson, J. F., Leblond, V., and Margeson, J. (2006). “Bitumen morphologies by phase detection atomic force microscopy.” J. Microsc., 221(1), 17–29.
Mattis, P., and Kimball, S. (2003). “GIMP-GNU image manipulation program.” 〈http://www.gimp.org/〉 (Sep. 6, 2010).
Mohammad, L., Huang, B., Roberts, F., and Rasoulian, M. (2000). “Accelerated loading performance and laboratory characterization of crumb rubber asphalt pavements.” Road Mater. Pavement Des., 1(4), 467–493.
Morales, G. M., et al. (2004). “Viscous properties and microstructure of recycled eva modified bitumen.” Fuel, 83(1), 31–38.
Navarro, F. J., Partal, P., Martinez-Boza, F., and Gallegos, C. (2005). “Influence of crumb rubber concentration on the rheological behavior of a crumb rubber modified bitumen.” Energy Fuels, 19(5), 1984–1990.
Oliver, J. (1981). “Modification of paving asphalts by digestion with scrape rubber.” Transportation Research Record 821, Transportation Research Board, Washington, DC, 37–44.
Patwardhan, S. R., and Khade, S. B. (1982). “Kinetics of air-blowing of petroleum bitumen.” Ind. Eng. Chem. Process. Des. Dev., 21(1), 154–157.
Polacco, G., Stastna, J., and Zanzotto, L. (2008). “Accumulated strain in polymer-modified asphalts.” Rheol. Acta, 47(5–6), 491–498.
Putman, P. J., and Amirkhanian, S. (2006). “Crumb rubber modification of binders: Interaction and particle effects.” Proc., Asphalt Rubber, Palm Springs, CA (Oct. 25–27, 2006).
Reyes, M., Kazatchkov, I. B., Stastna, J., and Zanzotto, L. (2009). “Modeling of repeated creep and recovery experiments in asphalt binders.” Transportation Research Record 2126, Transportation Research Board, Washington, DC, 63–72.
Roberts, F., Kandhal, P., Brown, E., and Dunning, R. (1989). “Investigation and evaluation of ground tire rubber in hot mix asphalt.”, National Center for Asphalt Technology, Auburn, AL.
Rozeveld, S. J., Shin, E. E., Bhurke, A., France, L., and Drzal, L. T. (1997). “Network morphology of straight and polymer modified asphalt cements.” Microsc. Res. Tech., 38(5), 529–543.
Shen, J., Amirkhanian, S., Xiao, F., and Tang, B. (2009). “Influence of surface area and size of crumb rubber on high temperature properties of crumb rubber modified binders.” Constr. Build. Mater., 23(1), 304–310.
Shindo, D. and Oikawa, T. (2002). Analytical electron microscopy for materials science, Springer, Tokyo.
Siddique, R., and Naik, T. R. (2004). “Properties of concrete containing scrap-tire rubber—An overview.” Waste Manage., 24(6), 563–569.
Stangl, K., Jager, A., and Lackner, R. (2006). “Microstructure-based identification of bitumen performance.” Road Mater. Pavement Des., 7, 111–142.
Superpave Committee. (2005). “Superpave performance by design.”, National Academy of Sciences, Washington, DC.
Visser, A., and Verhaegle, B. (2000). “Bitumen rubber: Lessons learned in South Africa.” Proc., Asphalt Rubber, Faro, Portugal (Nov. 14–17, 2000).
Wineman, A. S., and Rajagopal, K. (2000). Mechanical response of polymers—An introduction, Cambridge University Press, Cambridge, UK.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 25Issue 4April 2013
Pages: 438 - 449

History

Received: Jun 22, 2011
Accepted: Jun 7, 2012
Published online: Aug 25, 2012
Published in print: Apr 1, 2013

Permissions

Request permissions for this article.

Authors

Affiliations

P. S. Divya
Assistant Pavement Engineer, V R TECHNICHE Consultants Pvt. Ltd., Noida 201305, India; formerly, Dept. of Civil Engineering, Indian Institute of Technology Madras, Chennai 600036, India.
C. S. Gideon
M.Tech. Student, Dept. of Civil Engineering, Indian Institute of Technology Madras, Chennai 600036, India.
J. Murali Krishnan [email protected]
M.ASCE
Associate Professor, Dept. of Civil Engineering, Indian Institute of Technology Madras, Chennai 600036, India (corresponding author). E-mail: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share