Fabrication of Piezoresistive CNT/CNF Cementitious Composites with Superplasticizer as Dispersant
Publication: Journal of Materials in Civil Engineering
Volume 24, Issue 6
Abstract
Dispersion of carbon nanotubes (CNTs)/carbon nanofibers (CNFs) in cement matrixes is one of the key problems for fabricating piezoresistive CNT/CNF cementitious composites. The use of existing dispersants such as sodium dodecyl sulfate (SDS), sodium dodecylbenzene sulfonate (NaDDBS), and methylcellulose to disperse CNTs/CNFs has negative effects on the hydration of cement and will cause decreases in the mechanical properties of cementitious composites. In this study, a superplasticizer, a commonly used component in cementitious composites, is found to be capable of effectively dispersing CNTs and CNFs in a cement matrix. This eliminates the need for additional dispersants for fabricating piezoresistive CNT/CNF cementitious composites and avoids the impairment of composite properties by additional dispersants. The dispersion of CNTs/CNFs in cement matrix is evaluated by observing the dispersion of CNTs/CNFs in the superplasticizer aqueous solution, examining the morphology of composites, and analyzing the discreteness of resistance of composites. The piezoresistive responses of the composites with different types and concentrations of CNTs and CNFs are also investigated. Experimental results show that the fabricated CNT/CNF cementitious composites have strong piezoresistive responses, and the piezoresistive response sensitivity depends heavily on the types and concentrations of CNTs and CNFs. These findings indicate that piezoresistive CNT/CNF cementitious composites can be developed only by using a typical component of cementitious materials (i.e., superplasticizer) as dispersant and without adding any additional dispersants for CNTs/CNFs.
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Acknowledgments
The authors acknowledge the financial support of the U.S. National Science Foundation (CMMI-0856477), Federal Highway Administration (FHWA) of the U.S. Department of Transportation (DTFH61-10-C-00011), the Northland Advanced Transportation Systems Research Laboratory (NATSRL) of the University of Minnesota Duluth, and ITS of the University of Minnesota. This work was also partially supported by the National Science Foundation of China (Grant Nos. 51178148 and 50808055) and the Natural Scientific Research Innovation Foundation in the Harbin Institute of Technology (Grant No. HIT. NSRIF. 2009096).
References
Azhari, F. (2008). “Cement-based sensors for structural health monitoring.” M.S. thesis, Univ. of British Columbia, Vancouver, Canada.
De Ibarra, Y. S., Gaitero, J. J., and Campillo, I. (2006). “Atomic force microscopy and nonoindentation of cement pastes with nanotube dispersions.” Phys. Status Solidi APSSABA, 203(6), 1076–1081.
Gao, D., Sturm, M., and Mo, Y. L. (2009). “Electrical resistance of carbon-nanofiber concrete.” Smart Mater. Struct.SMSTER, 18(9), 095039.
Han, B. G., Yu, X., and Kwon, E. (2009). “A self-sensing carbon nanotube/cement composite for traffic monitoring.” NanotechnologyNNOTER, 20(44), 445–501.
Han, B. G., Yu, X., and Ou, J. P. (2010). “Effect of water content on the piezoresistivity of MWNT/cement composites.” J. Mater. Sci.JMTSAS, 45(14), 3714–3719.
Heikal, M., Morsy, M. S., and Aiad, I. (2006). “Effect of polycarboxylate superplasticizer on hydration characteristics of cement pastes containing silica fume.” CeramicsCERSEP, 50(1), 5–14.
Hu, C. Y., Xu, Y. J., Duo, S. W., Zhang, R. F., and Li, M. S. (2009). “Non-covalent functionalization of carbon nanotubes with surfactants and polymers.” J. Chin. Chem. Soc. (Taipei)JCCTAC, 56, 234–239.
Jiang, J. B., and Grace, W. R. (2008). “Advanced admixture applications in high performance concrete infrastructure construction.” Proc., 3rd ACF International Conference-ACF/VCA, Vietnam Institute for Building Materials, Hanoi, Vietnam, 130–136.
Li, C., and Chou, T. W. (2008). “Modeling of damage sensing in fiber composites using carbon nanotube networks.” Compos. Sci. Technol.CSTCEH, 68(15-16), 3373–3379.
Li, G. Y., Wang, P. M., and Zhao, X. H. (2007). “Pressure-sensitive properties and microstructure of carbon nanotube reinforced cement composites.” Cem. Concr. Compos.CCOCEG, 29(5), 377–382.
Lu, J. R., Chen, X. F., Lu, W., and Chen, G. H. (2006). “The piezoresistive behaviors of polyethylene/foliated graphite nanocomposites.” Eur. Polym. J.EUPJAG, 42(5), 1015–1021.
Makar, J. M., and Beaudoin, J. J. (2003). “Carbon nanotubes and their application in the construction industry.” Proc., 1st Int. Symposium on Nanotechnology in Construction, National Research Council Canada, Ottawa, Ontario, 331–341.
Makhotra, V. M. (1981). “Superplasticizer: Their effect on fresh and hardened concrete.” Concr. Int.CNCIEH, 3(5), 66–81.
Mehta, P. K. (1999). “Advancements in concrete technology.” Concr. Int.CNCIEH, 96(4), 69–76.
Pang, J. Y., Xu, G. Y., Yuan, S. L., Tan, Y. B., and He, F. (2009). “Dispersing carbon nanotubes in aqueous solutions by a silicon surfactant: experimental and molecular dynamics simulation study.” Colloid Surf. A, Physicochem. Eng. Aspect.CPEAEH, 350(1-3), 101–108.
Raki, L., Beaudoin, J., Alizadeh, R., Makar, J., and Sato, T. (2010). “Cement and concrete nanoscience and nanotechnology.” Materials, 3(2), 918–942.
Ramachandran, V. S. (1995). Concrete Admixtures Handbook: Properties, Science and Technology, Noyes Publications, NJ, 428–434.
Strano, M. S. (2006). “Nanocomposites: Polymer-wrapped nanotubes.” Nat. Mater.NMAACR, 5(6), 433–434.
Vaisman, L., Wagner, H. D., and Marom, G. (2006). “The role of surfactants in dispersion of carbon nanotubes.” Adv. Colloid Interface Sci.ACISB9, 128–130, 37–46.
Veedu, V. P. (2010). “Multifunctional cementitious nanocomposite material and methods of making the same.” Patent: US 7666327 B1.
Wang, L., Ding, T., and Wang, P. (2009). “Influence of carbon black concentration on piezoresistivity for carbon-black-filled silicone rubber composite.” CarbonCRBNAH, 47(14), 3151–3157.
Wu, H., Guo, H., Lei, J., Zhang, R., and Liu, Y. (2007). “Research on synthesis and action mechanism of polycarboxylate superplasticizer.” Front. Chem. ChinaCRCUED, 2(3), 322–325.
Yu, X., and Kwon, E. (2009). “Carbon-nanotube/cement composite with piezoresistive property.” Smart Mater. Struct.SMSTER, 18(5), 055010.
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© 2012. American Society of Civil Engineers.
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Received: Feb 17, 2011
Accepted: Nov 23, 2011
Published online: Nov 25, 2011
Published in print: Jun 1, 2012
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