TECHNICAL PAPERS
Dec 16, 2010

Laboratory Investigation of the Effect of Mixed Nitrogen Dioxide and Nitrogen Oxide Gases on Titanium Dioxide Photocatalytic Efficiency in Concrete Pavements

Publication: Journal of Materials in Civil Engineering
Volume 23, Issue 7

Abstract

Nitrogen oxides (NOx) emitted from vehicle exhausts are associated with adverse health effects on the public. Self-cleaning, air-purifying concrete pavement is a rapidly emerging technology that can be constructed by using a photocatalyst such as titanium dioxide (TiO2). The main objective of this study was to evaluate the environmental effectiveness of TiO2 coating in photodegrading mixed NO2 and NO gases from the atmosphere. Results of the experimental program determined that increasing the flow rate and NO2/NOx ratio negatively affect the effectiveness of the photocatalytic process. However, within the evaluated range, the titanium content and aggregate gradation had little effect on NOx removal efficiency. The highest photodegradation rate was observed at 25% relative humidity, which balances the availability of hydroxyl radicals at the surface with NOx contact with the photocatalytic surface.

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Acknowledgments

The authors would like to acknowledge the assistance of Cristal Millennium for providing this research with PC 105 ultrafine titanium dioxide used for testing and the Louisiana Transportation Research Center (LTRC) for granting access to their laboratory. The authors would also like to acknowledge the assistance of the Louisiana Department of Environmental Quality.

References

Beeldens, A. (2008). “Air purification by pavement blocks: Final results of the research at the BRRC.” Proc., Transport Research Arena Europe, Ljubljana, Slovenia.
Carslaw, D. C. (2005). Evidence of an increasing NO2/NOX emissions ratio from road traffic emissions, Atmos. Environ., 39(26), 4793–4802.
Cassar, L., Pepe, C., Tognon, G., Guerrini, G. L., and Amadelli, R. (2003). “White cement for architectural concrete possessing photocatalytic properties.” Proc., 11th Int. Congress on the Chemistry of Cement, Durban, South Africa.
Dylla, H., Hassan, M. M., Mohammad, L., and Rupnow, T. (2010). “Evaluation of the environmental effectiveness of titanium dioxide photocatalyst coating for concrete pavements.” Transp. Res. Rec., 2164(1), 46–51.
Environmental Protection Agency (EPA). (2010). “Final revisions to the primary national ambient air quality standard for nitrogen dioxide (NO2).” 〈http://www.epa.gov/airquality/nitrogenoxides/pdfs/20100124presentation.pdf〉 (Jun. 21, 2010).
Fujishima, A., Rao, T. N., and Tryk, D. A. (2000). “Titanium dioxide photocatalysis.” J. Photochem. Photobiol. C, 1(1), 1–21.
Hassan, M. M., Dylla, H., Mohammad, L., and Rupnow, T. (2010). “Evaluation of the durability of titanium dioxide photocatalyst coating for concrete pavement.” Constr. Build. Mater., 24(8), 1456–1461.
Japanese Industrial Standard (JIS) (2004). “Fine ceramics (advanced ceramics, advanced technical ceramics)—Test method for air purification performance of photocatalytic materials–Part 1: Removal of nitric oxide.” JIS R 1701-1, 1–9.
Jimenez, J. L., Koplow, M. D., Nelson, D. D., Zahniser, M. S., and Schmidt, S. E. (1999). “Characterization of on-road vehicle NO emissions by a TILDAS remote sensor.” J. Air Waste Manage. Assoc., 49(4), 463–470.
Kim, J. J., Smorodinsky, S., Lipsett, M., Singer, B. C., Hodgson, A. T., and Ostro, B. (2004). “Traffic-related air pollution near busy roads: The East Bay Children’s Respiratory Health Study.” Am. J. Respir. Crit. Care Med., 170(5), 520–536.
McConnell, R., et al. (2010). “Childhood incident asthma and traffic-related air pollution at home and school.” Environ. Health Perspect., 118(7), 1021–1026.
Minoura, H., and Ito, A. (2010). “Observation of the primary NO2 and NO oxidation near the trunk road in Tokyo.” Atmos. Environ., 44(1), 23–29.
Poon, C. S., and Cheung, E. (2007). “NO removal efficiency of photocatalytic paving blocks prepared with recycled materials.” Constr. Build. Mater., 21(8), 1746–1753.
Ramazan, K. A., Syomin, D., and Finlayson-Pitts, B. J. (2004). “The photochemical production of HONO during the heterogeneous hydrolysis of NO2.” Phys. Chem. Chem. Phys., 6(14), 3836–3843.
Tao, Z., Hewings, G., and Kieran, D. (2010). “An economic analysis of Midwestern US criteria pollutant emissions trends from 1970 to 2000.” Ecol. Econ., 69(8), 1666–1674.
Thermo Scientific. (2008). Model 146i Instruction Manual, Thermo Fisher Scientific Inc., Franklin, MA.
Zhao, J., and Yang, X. (2003). “Photocatalytic oxidation of indoor air purification: A literature review.” Build. Environ., 38(5), 645–654.

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Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 23Issue 7July 2011
Pages: 1087 - 1093

History

Received: Aug 16, 2010
Accepted: Dec 14, 2010
Published online: Dec 16, 2010
Published in print: Jul 1, 2011

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Authors

Affiliations

Heather Dylla
Graduate Research Assistant, Dept. of Construction Management and Industrial Engineering, Louisiana State Univ.
Marwa M. Hassan [email protected]
Assistant Professor, Dept. of Construction Management and Industrial Engineering, Louisiana State Univ., 3218 Patrick F. Taylor, Baton Rouge, LA 70803 (corresponding author). E-mail: [email protected]
Marion Schmitt
Research Assistant, Dept. of Construction Management and Industrial Engineering, Louisiana State Univ.
Tyson Rupnow, M.ASCE
Concrete Research Engineer, Louisiana Transportation Research Center.
Louay N. Mohammad, M.ASCE
Irma Louise Rush Stewart Distinguished Professor, Dept. of Civil and Environmental Engineering, Director Engineering Materials Characterization Research Facility, Louisiana Transportation Research Center.

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