Laboratory Investigation of the Effect of Mixed Nitrogen Dioxide and Nitrogen Oxide Gases on Titanium Dioxide Photocatalytic Efficiency in Concrete Pavements
Publication: Journal of Materials in Civil Engineering
Volume 23, Issue 7
Abstract
Nitrogen oxides () emitted from vehicle exhausts are associated with adverse health effects on the public. Self-cleaning, air-purifying concrete pavement is a rapidly emerging technology that can be constructed by using a photocatalyst such as titanium dioxide (). The main objective of this study was to evaluate the environmental effectiveness of coating in photodegrading mixed and NO gases from the atmosphere. Results of the experimental program determined that increasing the flow rate and ratio negatively affect the effectiveness of the photocatalytic process. However, within the evaluated range, the titanium content and aggregate gradation had little effect on removal efficiency. The highest photodegradation rate was observed at 25% relative humidity, which balances the availability of hydroxyl radicals at the surface with contact with the photocatalytic surface.
Get full access to this article
View all available purchase options and get full access to this article.
Acknowledgments
The authors would like to acknowledge the assistance of Cristal Millennium for providing this research with PC 105 ultrafine titanium dioxide used for testing and the Louisiana Transportation Research Center (LTRC) for granting access to their laboratory. The authors would also like to acknowledge the assistance of the Louisiana Department of Environmental Quality.
References
Beeldens, A. (2008). “Air purification by pavement blocks: Final results of the research at the BRRC.” Proc., Transport Research Arena Europe, Ljubljana, Slovenia.
Carslaw, D. C. (2005). Evidence of an increasing NO2/NOX emissions ratio from road traffic emissions, Atmos. Environ., 39(26), 4793–4802.
Cassar, L., Pepe, C., Tognon, G., Guerrini, G. L., and Amadelli, R. (2003). “White cement for architectural concrete possessing photocatalytic properties.” Proc., 11th Int. Congress on the Chemistry of Cement, Durban, South Africa.
Dylla, H., Hassan, M. M., Mohammad, L., and Rupnow, T. (2010). “Evaluation of the environmental effectiveness of titanium dioxide photocatalyst coating for concrete pavements.” Transp. Res. Rec., 2164(1), 46–51.
Environmental Protection Agency (EPA). (2010). “Final revisions to the primary national ambient air quality standard for nitrogen dioxide (NO2).” 〈http://www.epa.gov/airquality/nitrogenoxides/pdfs/20100124presentation.pdf〉 (Jun. 21, 2010).
Fujishima, A., Rao, T. N., and Tryk, D. A. (2000). “Titanium dioxide photocatalysis.” J. Photochem. Photobiol. C, 1(1), 1–21.
Hassan, M. M., Dylla, H., Mohammad, L., and Rupnow, T. (2010). “Evaluation of the durability of titanium dioxide photocatalyst coating for concrete pavement.” Constr. Build. Mater., 24(8), 1456–1461.
Japanese Industrial Standard (JIS) (2004). “Fine ceramics (advanced ceramics, advanced technical ceramics)—Test method for air purification performance of photocatalytic materials–Part 1: Removal of nitric oxide.” JIS R 1701-1, 1–9.
Jimenez, J. L., Koplow, M. D., Nelson, D. D., Zahniser, M. S., and Schmidt, S. E. (1999). “Characterization of on-road vehicle NO emissions by a TILDAS remote sensor.” J. Air Waste Manage. Assoc., 49(4), 463–470.
Kim, J. J., Smorodinsky, S., Lipsett, M., Singer, B. C., Hodgson, A. T., and Ostro, B. (2004). “Traffic-related air pollution near busy roads: The East Bay Children’s Respiratory Health Study.” Am. J. Respir. Crit. Care Med., 170(5), 520–536.
McConnell, R., et al. (2010). “Childhood incident asthma and traffic-related air pollution at home and school.” Environ. Health Perspect., 118(7), 1021–1026.
Minoura, H., and Ito, A. (2010). “Observation of the primary NO2 and NO oxidation near the trunk road in Tokyo.” Atmos. Environ., 44(1), 23–29.
Poon, C. S., and Cheung, E. (2007). “NO removal efficiency of photocatalytic paving blocks prepared with recycled materials.” Constr. Build. Mater., 21(8), 1746–1753.
Ramazan, K. A., Syomin, D., and Finlayson-Pitts, B. J. (2004). “The photochemical production of HONO during the heterogeneous hydrolysis of NO2.” Phys. Chem. Chem. Phys., 6(14), 3836–3843.
Tao, Z., Hewings, G., and Kieran, D. (2010). “An economic analysis of Midwestern US criteria pollutant emissions trends from 1970 to 2000.” Ecol. Econ., 69(8), 1666–1674.
Thermo Scientific. (2008). Model 146i Instruction Manual, Thermo Fisher Scientific Inc., Franklin, MA.
Zhao, J., and Yang, X. (2003). “Photocatalytic oxidation of indoor air purification: A literature review.” Build. Environ., 38(5), 645–654.
Information & Authors
Information
Published In
Copyright
© 2011 American Society of Civil Engineers.
History
Received: Aug 16, 2010
Accepted: Dec 14, 2010
Published online: Dec 16, 2010
Published in print: Jul 1, 2011
Authors
Metrics & Citations
Metrics
Citations
Download citation
If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.