Distribution, Sources, and Hazards of Ambient Carbonaceous Particulates in Central India
Publication: Journal of Hazardous, Toxic, and Radioactive Waste
Volume 23, Issue 4
Abstract
Complex environmental and health issues are on the rise in India because of the country’s huge emissions of carbonaceous particulates. The aim of this study was to describe concentration variation, segregation, composition, and sources of carbonaceous particulates—elemental carbon (EC) [also known as black carbon (BC)], organic carbon (OC), and carbonate carbon (CC) associated with coarse () and fine particulate matter ()—from 2005 to 2013 in India’s most polluted city, Raipur. Raipur, located in central India, is surrounded by coal-based heavy industry. Annual ambient air concentrations () of , , and varied 0.5–64.7, 0.1–52.1, and , respectively, during the study period. , , and concentrations were higher than concentrations and ranged 0.9–74.9, 2.2–56, and , respectively. The composition and segregation of particulate matter are discussed here. The potential source contribution function (PSCF) analysis model was used for apportioning distant carbon sources.
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Acknowledgments
The Department of Science and Technology, Government of India, is greatly acknowledged for financial support (Grant No. ES/48/ICRP/008/2002). The Alexander von Humboldt Foundation, Bonn, Germany, is thanked for its financial support of the analysis of aerosol carbons at the Karlsruhe Institute of Technology.
References
Anenberg, S. C., et al. 2012. “Global air quality and health co-benefits of mitigating near-term climate change through methane and black carbon emission controls.” Environ. Health Perspect. 120 (6): 831–839. https://doi.org/10.1289/ehp.1104301.
Babu, S. S., and K. K. Moorthy. 2002. “Aerosol black carbon over a tropical station in India.” Geophys. Res. Lett. 29 (23): 13-1–13-4. https://doi.org/10.1029/2002GL015662.
Begum, B. A., A. Hossain, N. Nahar, A. Markwitz, and P. K. Hopke. 2012. “Organic and black carbon in at an urban site at Dhaka, Bangladesh.” Aerosol Air Qual. Res. 12 (6): 1062–1072. https://doi.org/10.4209/aaqr.2012.05.0138.
Begum, B. A., E. Kim, S. K. Biswas, and P. K. Hopke. 2004. “Investigation of sources of atmospheric aerosol at urban and semi-urban areas in Bangladesh.” Atmos. Environ. 38 (19): 3025–3038. https://doi.org/10.1016/j.atmosenv.2004.02.042.
Bisht, D. S., U. C. Dumka, D. G. Kaskaoutis, A. S. Pipal, A. K. Srivastava, V. K. Soni, S. D. Attri, M. Sateesh, and S. Tiwari. 2015. “Carbonaceous aerosols and pollutants over Delhi urban environment: Temporal evolution, source apportionment and radiative forcing.” Sci. Total Environ. 521–522: 431–445. https://doi.org/10.1016/j.scitotenv.2015.03.083.
Bond, T. C., et al. 2013. “Bounding the role of black carbon in the climate system: A scientific assessment.” J. Geophys. Res. Atmos. 118 (11): 5380–5552. https://doi.org/10.1002/jgrd.50171.
Briggs, N. L., and C. M. Long. 2016. “Critical review of black carbon and elemental carbon source apportionment in Europe and the United States.” Atmos. Environ. 144: 409–427. https://doi.org/10.1016/j.atmosenv.2016.09.002.
Brunekreef, B., and S. T. Holgate. 2002. “Air pollution and health.” Lancet 360 (9341): 1233–1242. https://doi.org/10.1016/S0140-6736(02)11274-8.
Cao, J. J., S. C. Lee, K. F. Ho, X. Y. Zhang, S. C. Zouc, K. Fung, J. C. Chow, and J. G. Watson. 2003. “Characteristics of carbonaceous aerosol in Pearl River Delta region, China during 2001 winter period.” Atmos. Environ. 37 (11): 1451–1460. https://doi.org/10.1016/S1352-2310(02)01002-6.
Cheng, Y. H., C. C. Lin, J. J. Liu, and C. J. Hsieh. 2014. “Temporal characteristics of black carbon concentrations and its potential emission sources in a southern Taiwan industrial urban area.” Environ. Sci. Pollut. Res. Int. 21 (5): 3744–3755. https://doi.org/10.1007/s11356-013-2373-7.
Cheng, Y. H., B. T. Shiu, M. H. Lin, and J. W. Yan. 2013. “Levels of black carbon and their relationship with particle number levels—Observation at an urban roadside in Taipei City.” Environ. Sci. Pollut. Res. Int. 20 (3): 1537–1545. https://doi.org/10.1007/s11356-012-1081-z.
Dan, M., G. Zhuang, X. Li, H. Tao, and Y. Zhuang. 2004. “The characteristics of carbonaceous species and their sources in in Beijing.” Atmos. Environ. 38 (21): 3443–3452. https://doi.org/10.1016/j.atmosenv.2004.02.052.
Deepshikha, S., S. K. Satheesh, and J. Srinivasan. 2005. “Regional distribution of absorbing efficiency of dust aerosols over India and adjacent continents inferred using satellite remote sensing.” Geophys. Res. Lett. 32 (3): L03811. https://doi.org/10.1029/2004GL022091.
Duan, F., K. He, Y. Ma, Y. Jia, F. Yang, Y. Lei, S. Tanaka, and T. Okuta. 2005. “Characteristics of carbonaceous aerosols in Beijing, China.” Chemosphere 60 (3): 355–364. https://doi.org/10.1016/j.chemosphere.2004.12.035.
EPA. 1996. Air quality criteria for particulate matter. Cincinnati: EPA.
Giri, B., K. S. Patel, N. K. Jaiswal, S. Sharma, B. Ambade, W. Wang, S. L. M. Simonich, and B. R. T. Simoneit. 2013. “Composition and sources of organic tracers in aerosol particles of industrial central India.” Atmos. Res. 120–121: 312–324. https://doi.org/10.1016/j.atmosres.2012.09.016.
Gong, X., C. Zhang, H. Chen, S. A. Nizkorodov, J. Chen, and X. Yang. 2016. “Size distribution and mixing state of black carbon particles during a heavy air pollution episode in Shanghai.” Atmos. Chem. Phys. 16 (8): 5399–5411. https://doi.org/10.5194/acp-16-5399-2016.
Gramsch, E., E. Reyes, P. Oyola, R. Ma, G. López, P. Pérez, and R. Martínez. 2014. “Particle size distribution and its relationship to black carbon in two urban and one rural site in Santiago de Chile.” J. Air Waste Manage. Assoc. 64 (7): 785–796. https://doi.org/10.1080/10962247.2014.890141.
Guha, A., B. K. De, P. Dhar, T. Banik, M. Chakraborty, R. Roy, A. Choudhury, M. M. Gogoi, S. S. Babu, and K. K. Moorthy. 2015. “Seasonal characteristics of aerosol black carbon in relation to long range transport over Tripura in northeast India.” Aerosol Air Qual. Res. 15 (3): 786–798. https://doi.org/10.4209/aaqr.2014.02.0029.
Helin, A., et al. 2018. “Characteristics and source apportionment of black carbon in the Helsinki metropolitan area, Finland.” Atmos. Environ. 190: 87–98. https://doi.org/10.1016/j.atmosenv.2018.07.022.
Heo, J. B., P. K. Hopke, and S. M. Yi. 2009. “Source apportionment of in Seoul, Korea.” Atmos. Chem. Phys. 9 (14): 4957–4971. https://doi.org/10.5194/acp-9-4957-2009.
Hernández-Mena, L., H. Saldarriaga-Noreña, M. A. Murillo-Tovar, O. Amador-Muñoz, A. López-López, and S. M. Waliszewski. 2011. “Determination of black carbon in fine particles using a semi-continuous method at two sites in the city of Guadalajara, Mexico, during 2007.” Bull. Environ. Contam. Toxicol. 87 (3): 336–342. https://doi.org/10.1007/s00128-011-0330-z.
Ho, K. F., R. J. Zhang, S. C. Lee, S. S. H. Ho, S. X. Liu, K. Fung, J. J. Cao, Z. X. Shen, and H. M. Xu. 2011. “Characteristics of carbonate carbon in in a typical semi-arid area of northeastern China.” Atmos. Environ. 45 (6): 1268–1274. https://doi.org/10.1016/j.atmosenv.2010.12.007.
Huang, X.-F., J. Z. Yu, L.-Y. He, and M. Hu. 2006. “Size distribution characteristics of elemental carbon emitted from Chinese vehicles: Results of a tunnel study and atmospheric implications.” Environ. Sci. Technol. 40 (17): 5355–5360. https://doi.org/10.1021/es0607281.
Jacobson, M. Z. 2001. “Strong irradiative heating due to the mixing state of black carbon in atmospheric aerosols.” Nature 409 (6821): 695–697. https://doi.org/10.1038/35055518.
Kim, Y. J., M. J. Kim, K. H. Lee, and S. S. Park. 2006. “Investigation of carbon pollution episodes using semi-continuous instrument in Incheon, Korea.” Atmos. Environ. 40 (22): 4064–4075. https://doi.org/10.1016/j.atmosenv.2006.03.028.
Kim, Y. P., K. C. Moon, J. H. Lee, and N. J. Baik. 1999. “Concentration of carbonaceous species in particles at Seoul and Cheju in Korea.” Atmos. Environ. 33 (17): 2751–2758. https://doi.org/10.1016/S1352-2310(98)00313-6.
Klompmaker, J. O., D. R. Montagne, K. Meliefste, G. Hoek, and B. Brunekreef. 2015. “Spatial variation of ultrafine particles and black carbon in two cities: Results from a short-term measurement campaign.” Sci. Total Environ. 508: 266–275. https://doi.org/10.1016/j.scitotenv.2014.11.088.
Latha, K. M., and K. V. S. Badarinath. 2003. “Black carbon aerosols over tropical urban environment: A case study.” Atmos. Res. 69 (1–2): 125–133. https://doi.org/10.1016/j.atmosres.2003.09.001.
Latha, K. M., and K. V. S. Badarinath. 2005. “Seasonal variations of black carbon aerosols and total aerosol mass concentrations over urban environment in India.” Atmos. Environ. 39 (22): 4129–4141. https://doi.org/10.1016/j.atmosenv.2005.04.004.
Lau, K. M., and K. M. Kim. 2006. “Observational relationships between aerosol and Asian monsoon rainfall, and circulation.” Geophys. Res. Lett. 33 (21): 1–5. https://doi.org/10.1029/2006GL027546.
Li, S. M., J. Tang, H. Xue, and D. T. Sauntry. 2000. “Size distribution and estimated optical properties of carbonate, water soluble organic carbon, and sulfate in aerosols at a remote high altitude site in western China.” Geophys. Res. Lett. 27 (8): 1107–1110. https://doi.org/10.1029/1999GL010929.
Li, X., Z. Shen, J. Cao, S. Liu, C. Zhu, and T. Zhang. 2006. “Distribution of carbonaceous aerosol during spring 2005 over the Horqin Sand land in north eastern China.” China Particuology 4 (6): 316–322. https://doi.org/10.1016/S1672-2515(07)60282-6.
Lin, J. J., and H. S. Tai. 2001. “Concentrations and distributions of carbonaceous species in ambient particles in Kaohsiung City, Taiwan.” Atmos. Environ. 35 (15): 2627–2636. https://doi.org/10.1016/S1352-2310(00)00444-1.
Liu, Y., C. Yan, and M. Zheng. 2018. “Source apportionment of black carbon during winter in Beijing.” Sci. Total Environ. 618: 531–541. https://doi.org/10.1016/j.scitotenv.2017.11.053.
Matsui, H., D. S. Hamilton, and N. M. Mahowald. 2018. “Black carbon radiative effects highly sensitive to emitted particle size when resolving mixing-state diversity.” Nat. Commun. 9 (1): 3446. https://doi.org/10.1038/s41467-018-05635-1.
Menon, S., J. Hansen, L. Nazarenko, and Y. F. Luo. 2002. “Climate effects of black carbon aerosols in China and India.” Science 297 (5590): 2250–2253. https://doi.org/10.1126/science.1075159.
Moloi, K., S. Chimidza, E. S. Lindgren, A. Viksna, and P. Standzenieks. 2002. “Black carbon, mass and elemental measurements of airborne particles in the village of Serowe, Botswana.” Atmos. Environ. 36 (14): 2447–2457. https://doi.org/10.1016/S1352-2310(02)00085-7.
Nair, V. S., S. S. Babu, K. K. Moorthy, A. K. Sharma, and A. Marinoni. 2013. “Black carbon aerosols over the Himalayas: Direct and surface albedo forcing.” Tellus B 65 (1): 19738. https://doi.org/10.3402/tellusb.v65i0.19738.
Oanh, N. T. K., et al. 2006. “Particulate air pollution in six Asian cities: Spatial and temporal distributions, and associated sources.” Atmos. Environ. 40 (18): 3367–3380. https://doi.org/10.1016/j.atmosenv.2006.01.050.
Ozdemir, H., L. Pozzoli, T. Kindap, G. Demir, B. Mertoglu, N. Mihalopoulos, C. Theodosi, M. Kanakidou, U. Im, and A. Unal. 2014. “Spatial and temporal analysis of black carbon aerosols in Istanbul megacity.” Sci. Total Environ. 473–474: 451–458. https://doi.org/10.1016/j.scitotenv.2013.11.102.
Pandis, S. N., R. A. Harley, G. R. Cass, and J. H. Seinfeld. 1992. “Secondary organic aerosol formation and transport.” Atmos. Environ. 26 (13): 2269–2282. https://doi.org/10.1016/0960-1686(92)90358-R.
Pang, Y., B. J. Turpin, and L. A. Gundel. 2006. “On the importance of organic oxygen for understanding organic aerosol particles.” Aerosol Sci. Technol. 40 (2): 128–133. https://doi.org/10.1080/02786820500423790.
Parashar, D. C., R. Gadi, T. K. Mandal, and A. P. Mitra. 2005. “Carbonaceous aerosol emissions from India.” Atmos. Environ. 39 (40): 7861–7871. https://doi.org/10.1016/j.atmosenv.2005.08.034.
Park, S. S., Y. J. Kim, and K. Fung. 2002. “ carbon measurements in two urban areas: Seoul and Kwangju, Korea.” Atmos. Environ. 36 (8): 1287–1297.
Pauraitė, J., G. Mordas, S. Byčenkienė, and V. Ulevicius. 2015. “Spatial and temporal analysis of organic and black carbon mass concentrations in Lithuania.” Atmosphere 6 (8): 1229–1242. https://doi.org/10.3390/atmos6081229.
Polissar, A. V., P. K. Hopke, and R. L. Poirot. 2001. “Atmospheric aerosol over Vermont: Chemical composition and sources.” Environ. Sci. Technol. 35 (23): 4604–4621. https://doi.org/10.1021/es0105865.
Rajesh, T. A., and S. Ramachandran. 2017. “Characteristics and source apportionment of black carbon aerosols over an urban site.” Environ. Sci. Pollut. Res. Int. 24 (9): 8411–8424. https://doi.org/10.1007/s11356-017-8453-3.
Raman, R. S., and P. K. Hopke. 2007. “Source apportionment of fine particles utilizing partially speciated carbonaceous aerosol data at two rural locations in New York State.” Atmos. Environ. 41 (36): 7923–7939. https://doi.org/10.1016/j.atmosenv.2007.06.066.
Ramanathan, V., and G. Carmichael. 2008. “Global and regional climate changes due to black carbon.” Nat. Geosci. 1 (4): 221–227. https://doi.org/10.1038/ngeo156.
Rao, P. S., A. Kumar, M. F. Ansari, P. Pipalatkar, and T. Chakrabarti. 2009. “Air quality impact of sponge iron industries in central India.” Bull. Environ. Contam. Toxicol. 82 (2): 255–259. https://doi.org/10.1007/s00128-008-9519-1.
Reddington, C. L., G. McMeeking, G. W. Mann, H. Coe, M. G. Frontoso, D. Liu, M. Flynn, D. V. Spracklen, and K. S. Carslaw. 2013. “The mass and number size distributions of black carbon aerosol over Europe.” Atmos. Chem. Phys. 13 (9): 4917–4939. https://doi.org/10.5194/acp-13-4917-2013.
Ruchirawat, M., P. Navasumrit, D. Settachan, and H. Autrup. 2006. “Environmental Impacts on children’s health in Southeast Asia: Genotoxic compounds in urban air.” Ann. N.Y. Acad. Sci 1076 (1): 678–690. https://doi.org/10.1196/annals.1371.037.
Safai, P. D., S. Kewat, P. S. Praveen, P. S. P. Rao, G. A. Momin, K. Ali, and P. C. S. Devara. 2007. “Seasonal variation of black carbon aerosols over a tropical urban city of Pune, India.” Atmos. Environ. 41 (13): 2699–2709. https://doi.org/10.1016/j.atmosenv.2006.11.044.
Salma, I., X. Chi, and W. Maenhaut. 2004. “Elemental and organic carbon in urban canyon and background environments in Budapest, Hungary.” Atmos. Environ. 38 (1): 27–36. https://doi.org/10.1016/j.atmosenv.2003.09.047.
Sandeep, P., I. V. Saradhi, and G. G. Pandit. 2013. “Seasonal variation of black carbon in fine particulate matter () at the tropical coastal city of Mumbai, India.” Bull. Environ. Contam. Toxicol. 91 (5): 605–610. https://doi.org/10.1007/s00128-013-1108-2.
Santoso, M., D. D. Lestiani, and P. K. Hopke. 2013. “Atmospheric black carbon in in Indonesian cities.” J. Air Waste Manage. Assoc. 63 (9): 1022–1025. https://doi.org/10.1080/10962247.2013.804465.
Singla, V., S. Mukherjee, A. S. Kashikar, P. D. Safai, and G. Pandithurai. 2019. “Black carbon: Source apportionment and its implications on CCN activity over a rural region in Western Ghats, India.” Environ. Sci. Pollut. Res. Int. 26 (7): 7071–7081. https://doi.org/10.1007/s11356-019-04162-w.
Streets, D. G., S. Gupta, S. T. Waldhoff, M. Q. Wang, T. C. Bond, and B. Yiyun. 2001. “Black carbon emissions in China.” Atmos. Environ. 35 (25): 4281–4296. https://doi.org/10.1016/S1352-2310(01)00179-0.
Tiwari, S., A. S. Pipal, A. K. Srivastava, D. S. Bisht, and G. Pandithurai. 2015. “Determination of wood burning and fossil fuel contribution of black carbon at Delhi, India using aerosol light absorption technique.” Environ. Sci. Pollut. Res. Int. 22 (4): 2846–2855. https://doi.org/10.1007/s11356-014-3531-2.
Tunno, B. J., D. R. Michanowicz, J. L. Shmool, E. Kinnee, L. Cambal, S. Tripathy, S. Gillooly, C. Roper, L. Chubb, and J. E. Clougherty. 2016. “Spatial variation in inversion-focused vs 24-h integrated samples of and black carbon across Pittsburgh, PA.” J. Exposure Sci. Environ. Epidemiol. 26 (4): 365–376. https://doi.org/10.1038/jes.2015.14.
Turpin, B. J., and J. J. Huntzicker. 1995. “Identification of secondary organic aerosol episodes and quantitation of primary and secondary organic aerosol concentrations during SCAQS.” Atmos. Environ. 29 (23): 3527–3544. https://doi.org/10.1016/1352-2310(94)00276-Q.
VDI (Verein Deutscher Ingenieure). 1997. Measurement of soot (emission)—Thermographic analysis of elemental carbon by thermal desorption of organic carbon. Dusseldorf, Germany: VDI.
Verma, S., S. K. Pani, and S. N. Bhanja. 2013. “Sources and radiative effects of wintertime black carbon aerosols in an urban atmosphere in east India.” Chemosphere. 90 (2): 260–269. https://doi.org/10.1016/j.chemosphere.2012.06.063.
Viidanoja, J., M. Sillanpaa, J. Laakia, V. M. Kerminen, R. Hillamo, P. Aarnio, and T. Koskentalo. 2002. “Organic and black carbon in and : 1 year of data from an urban site in Helsinki, Finland.” Atmos. Environ. 36 (19): 3183–3193. https://doi.org/10.1016/S1352-2310(02)00205-4.
Vilcassim, M. J., G. D. Thurston, R. E. Peltier, and T. Gordon. 2014. “Black carbon and particulate matter () concentrations in New York City’s subway stations.” Environ. Sci. Technol. 48 (24): 14738–14745. https://doi.org/10.1021/es504295h.
Vineis, P., et al. 2006. “Air pollution and risk of lung cancer in a prospective study in Europe.” Int. J. Cancer 119 (1): 169–174. https://doi.org/10.1002/ijc.21801.
Wang, G., J. Bai, Q. Kong, and A. Emilenko. 2005. “Black carbon particles in the urban atmosphere in Beijing.” Adv. Atmos. Sci. 22 (5): 640–646. https://doi.org/10.1007/BF02918707.
Winiger, P., et al. 2019. “Source apportionment of circum-Arctic atmospheric black carbon from isotopes and modeling.” Sci. Adv. 5 (2): eaau8052. https://doi.org/10.1126/sciadv.aau8052.
Yu, H., C. Wu, D. Wu, and J. Z. Yu. 2010. “Size distributions of elemental carbon and its contribution to light extinction in urban and rural locations in the Pearl River Delta region, China.” Atmos. Chem. Phys. 10 (11): 5107–5119. https://doi.org/10.5194/acp-10-5107-2010.
Yu, J. Z., J. W. T. Tung, A. W. M. Wu, A. K. H. Lau, P. K. K. Louie, and J. C. H. Fung. 2004. “Abundance and seasonal characteristics of elemental and organic carbon in Hong Kong PM10.” Atmos. Environ. 38 (10): 1511–1521. https://doi.org/10.1016/j.atmosenv.2003.11.035.
Zhang, M. G., Y. F. Xu, R. J. Zhang, and Z. W. Han. 2005. “Emission and concentration distribution of black carbon aerosol in East Asia during springtime.” Chin. J. Geophys. Chem. 48 (1): 55–61. https://doi.org/10.1002/cjg2.625.
Zhang, Q., et al. 2018. “Characteristics and source apportionment of winter black carbon aerosols in two Chinese megacities of Xi’an and Hong Kong.” Environ. Sci. Pollut. Res. 25 (33): 33783–33793. https://doi.org/10.1007/s11356-018-3309-z.
Zhang, R. J., J. J. Cao, S. C. Lee, Z. X. Shen, and K. F. Ho. 2007. “Carbonaceous aerosols in PM10 and pollution gases in winter in Beijing.” J. Environ. Sci. 19 (5): 564–571. https://doi.org/10.1016/S1001-0742(07)60094-1.
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Received: Oct 5, 2018
Accepted: Apr 2, 2019
Published online: Jul 12, 2019
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