Technical Papers
Dec 16, 2012

Cesium Immobilization in Soil by Ball-Milling Treatment with Nanometallic Ca/CaO Additive

Publication: Journal of Hazardous, Toxic, and Radioactive Waste
Volume 17, Issue 1

Abstract

This work assessed ball-milling treatment for remediation of cesium (Cs)-contaminated soil. The immobilization efficiency increases from 56.4% in the absence of treatment to 89.9, 91.5, 97.7, and 96.4% when the soil is ball milled for 30, 60, and 120 min, respectively. However, the addition of nanometallic Ca/CaO and NaH2PO4 increased the immobilization efficiency to approximately 96.4% compared with ball milling alone, even when the milling time was decreased to 60 min. Actually, with the addition of Ca/CaO and NaH2PO4, the leachable fraction of Cs was reduced in the soil after a short milling time. These promising results suggest that ball milling can be regarded as applicable for the remediation of cesium-contaminated soil in dry and water-free conditions. This treatment method requires no expensive reagent and does not generate exhaust gases. It requires only electricity with cheap and commercially available reagents. This treatment process is an environmentally friendly depollution technique.

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Acknowledgments

The authors are thankful to the New Energy and Industrial Technology Development Organization (NEDO) Program, Japan (Project ID: 09B35003a), for providing financial support to conduct this study.

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Go to Journal of Hazardous, Toxic, and Radioactive Waste
Journal of Hazardous, Toxic, and Radioactive Waste
Volume 17Issue 1January 2013
Pages: 2 - 8

History

Received: Feb 27, 2012
Accepted: Jul 16, 2012
Published online: Dec 16, 2012
Published in print: Jan 1, 2013

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Srinivasa Reddy Mallampati [email protected]
Dept. of Environmental Sciences, Faculty of Life and Environmental Sciences, Prefectural Univ. of Hiroshima, 562 Nanatsuka-Cho, Shobara City, Hiroshima 727-0023, Japan. E-mail: [email protected]
Yoshiharu Mitoma [email protected]
Dept. of Environmental Sciences, Faculty of Life and Environmental Sciences, Prefectural Univ. of Hiroshima, 562 Nanatsuka-Cho, Shobara City, Hiroshima 727-0023, Japan (corresponding author). E-mail: [email protected]
Tetsuji Okuda
Environmental Research and Management Center, Hiroshima Univ., 1-5-3 Kagamiyama, Higashi-Hiroshima, Hiroshima 739-8513, Japan.
Shogo Sakita
Dept. of Environmental Sciences, Faculty of Life and Environmental Sciences, Prefectural Univ. of Hiroshima, 562 Nanatsuka-Cho, Shobara City, Hiroshima 727-0023, Japan.
Mitsunori Kakeda
Dept. of Environmental Sciences, Faculty of Life and Environmental Sciences, Prefectural Univ. of Hiroshima, 562 Nanatsuka-Cho, Shobara City, Hiroshima 727-0023, Japan.

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