TECHNICAL PAPERS
Sep 15, 2011

Metal Mobility and Fraction Distribution in a Multimetal Contaminated Soil Chemically Stabilized with Different Agents

Publication: Journal of Hazardous, Toxic, and Radioactive Waste
Volume 15, Issue 4

Abstract

To investigate the efficiency of chemical stabilization on soil residuals after soil washing, laboratory batch experiments were performed on a clayish soil contaminated with Cu, Cr, Ni, Pb, Zn with lime, Na2HPO4, or a mixture containing FeSO4 under various concentrations. The instant and overall mobility and the fraction distribution of these metals after 7-day stabilization were determined by acid extraction and the modified Tessier’s sequential extraction procedures. Results show that the potential mobility of metals is orders of magnitude much more than instant mobility, and specific attention therefore should be paid to the potential mobility when evaluating the performance of chemical stabilization. Metal fraction analyses suggested that the metal stabilization involved various mechanisms dependent on the metal’s properties, species, and the interference between metals. Among the stabilization combinations, the mixture of FeSO4 and lime most effectively reduced the sum of the metal instant mobility, and 15mgg-1 Na2HPO4 achieved the highest efficiency in lessening the corresponding overall mobility. However, a more substantial decrement of instant mobility was observed.

Get full access to this article

View all available purchase options and get full access to this article.

Acknowledgments

The authors wish to thank the National Natural Science Foundation of China (Project No. NNSFC40802088) for financially supporting this study.

References

Alvarez, M. B., Malla, M. E., and Batistoni, D. A. (2001). “Comparative assessment of two sequential chemical extraction schemes for the fractionation of cadmium, chromium, lead and zinc in surface coastal sediments.” Fresenius J. Anal. Chem., 369, 81–90.
Asikainen, J. M., and Nikalaidis, N. P. (1994). “Sequential extraction of chromium from contaminated aquifer sediments.” Ground Water Monit. Rem., 14, 185–191.
Basta, N. T., and McGowen, S. L. (2004). “Evaluation of chemical immobilization treatments for reducing heavy metal transport in a smelter-contaminated soil.” Environ. Pollut., 127(1), 73–82.
Brown, S., Chaney, R., Hallfrisch, J., Ryan, J. A., and Berti, W. R. (2004). “In situ soil treatments to reduce the phyto- and bioavailability of lead, zinc and cadmium.” J. Environ. Qual., 33(2), 522–531.
Chinese Ministry of Environment Protection (CMEP). (1993). Quality standard for groundwater (GB/T14848-93), China Environmental Science Press, Beijing, 1–4.
Chinese Ministry of Environment Protection (CMEP). (2007). Solid waste-extraction procedure for leaching toxicity: Sulfuric acid and nitric acid methods (HJ/T299-2007), China Environmental Science Press, Beijing, 1–9.
Crannell, B. S., Eighmy, T. T., Krzanowski, J. E., Eusden, J. D., Shaw, E. L., and Francis, C. A. (2000). “Heavy metal stabilization in municipal solid waste combustion bottom ash using soluble phosphate.” Waste Manage., 20(2–3), 135–148.
Eary, L. E., and Rai, D. (1989). “Kinetics of chromate reduction by ferrous ions derived from hematite and biotite at 25°C.” Am. J. Sci., 289(2), 180–213.
Elliott, H. A., Liberati, M. R., and Huang, C. P. (1986). “Competitive adsorption of heavy metals by soils.” J. Environ. Qual., 15(3), 214–219.
Ford, R. G., Scheinost, A. C., and Sparks, D. L. (2001). “Frontiers in metal sorption/precipitation mechanisms on soil mineral surfaces.” Adv. Agronomy, 74, 41–62.
Garcia, M. A., Chimenos, J. M., Fernandez, A. I., Miralles, L., Segarra, M., and Espiell, F. (2004). “Low-grade MgO used to stabilize heavy metals in highly contaminated soils.” Chemosphere, 56(5), 481–491.
Gomes, P. C., Fontes, M. P. F., da Silva, A. G., Mendonca, E. S., and Netto, A. R. (2001). “Selectivity sequence and competitive adsorption of heavy metals by Brazilian soils.” Soil Sci. Soc. Am. J., 65(4), 1115–1121.
Grafe, M., Nachtegaal, M., and Sparks, D. L. (2004). “Formation of metal arsenate precipitates at the goethite–water interface.” Environ. Sci. Technol., 38(24), 6561–6570.
Han, F. X., Su, Y., Sridhar, B. B. M., and Monts, D. L. (2004). “Distribution, transformation and bioavailability of trivalent and hexavalent chromium in contaminated soil.” Plant Soil, 265, 243–252.
Hartley, W., Edwards, R., and Lepp, N. W. (2004). “Arsenic and heavy metal mobility in iron oxide-amended contaminated soils as evaluated by short- and long-term leaching tests.” Environ. Pollut., 131(3), 495–504.
Impellitteri, C. A. (2005). “Effects of pH and phosphate on metal distribution with emphasis on As speciation and mobilization in soils from a lead smelting site.” Sci. Total Environ., 345(1–3), 175–190.
Isoyama, M., and Mada, S. I. (2007). “Remediation of Pb-contaminated soils by washing with hydrochloric acid and subsequent immobilization with calcite and allophanic soil.” J. Hazard. Mater., 143, 636–642.
Kabala, C., and Singh, B. R. (2001). “Fractionation and mobility of copper, lead and zinc in soil profiles in the vicinity of a copper smelter.” J. Environ. Qual., 30(2), 485–492.
Kalembkiewicz, J., and Soèo, E. (2005). “Investigations of chemical fraction of Cr in soil.” Pol. J. Environ. Stud., 14(5), 593–598.
Khodadoust, A. P., Reddy, K. R., and Maturi, K. (2004). “Removal of nickel and phenanthrene from kaoline soil using different extractants.” Environ. Eng. Sci., 21(6), 691–704.
Kumpiene, J., Lagerkvist, A., and Maurice, C. (2008). “Stabilization of As, Cr, Cu, Pb and Zn in soil using amendments: A review.” Waste Manage., 28(1), 215–225.
Laor, Y., Farmer, W. J., Aochi, Y., and Strom, P. F. (1998). “Phenanthrene binding and adsorption to dissolved and to mineral-associated humic acid.” Water Res., 32(6), 1923–1931.
Manceau, A., et al. (2000). “Crystal chemistry of trace elements in natural and synthetic goethite.” Geochim. Cosmochim. Acta, 64(21), 3643–3661.
Melamed, R., Cao, X., Chen, M., and Ma, L. Q. (2003). “Field assessment of lead immobilization in a contaminated soil after phosphate application.” Sci. Total Environ., 305, 117–127.
Ownby, D. R., Galvan, K. A., and Lydy, M. J. (2005). “Lead and zinc bioavailability to Eisenia fetida after phosphorus amendment to repository soils.” Environ. Pollut., 136, 315–321.
Pantsar-Kallio, M., Reinikainen, S. P., and Oksanen, M. (2001). “Interactions of soil components and their effects on speciation of chromium in soils.” Anal. Chim. Acta, 439(1), 9–17.
Papini, M. P., Saurini, T., Bianchi, A., Majone, M., and Beccari, M. (2004). “Modeling the competitive adsorption of Pb, Cu, Cd, and Ni onto a natural heterogeneous sorbent material (Italian ‘red soil’).” Ind. Eng. Chem. Res., 43(17), 5032–5041.
Sedlak, D. L., and Chan, P. G. (1997). “Reduction of hexavalent chromium by ferrous iron.” Geochim. Cosmochim. Acta, 61(11), 2185–2192.
Takematsu, N. (1979). “Sorption of transition metals on manganese and iron oxides and silicate minerals.” J. Oceanogr. Soc. Jpn., 35(1), 36–42.
Tokunaga, S., Park, S. W., and Ulmanu, M. (2005). “Extraction behavior of metallic contaminants and soil constituents from contaminated soils.” Environ. Technol., 26(6), 673–682.
U.S. EPA. (2007). “Inductively coupled plasma-atomic emission spectrometry.” Method 6010C, SW-846, Washington, DC
Wang, G. M., Zhou, L. X., and Wong, J. W. C. (2006). “Adsorption of dissolved organic matter in soil and dissolved organic matter effect on the copper precipitation in high pH range.” Environ. Sci., 27(4), 754–759 (in Chinese).
Warren, L. A., and Zimmerman, A. P. (1994). “Suspended particulate oxides and organic matter interactions in trace metal sorption reactions in a small urban river.” Biogeochemistry, 24(1), 21–34.
Zhang, W. H., et al. (2010a). “Influence of soil washing with a chelator on subsequent chemical immobilization of heavy metals in a contaminated soil.” J. Hazard. Mater., 178(1–3), 578–587.
Zhang, W. H., Cao, J., Huang, H., and Zhang, R. D. (2010b). “Effect of coexisting lead and phenanthrene on their individual sorption on a clayish soil.” Soil Sediment Contam., 19(3), 332–337.
Zhang, W. H., Huang, H., Tan, F. F., Wang, H., and Qiu, R. L. (2010c). “Influence of EDTA-washing on the species and mobility of heavy metals residual in soils.” J. Hazard. Mater., 173(1–3), 369–376.

Information & Authors

Information

Published In

Go to Journal of Hazardous, Toxic, and Radioactive Waste
Journal of Hazardous, Toxic, and Radioactive Waste
Volume 15Issue 4October 2011
Pages: 266 - 274

History

Received: Apr 7, 2010
Accepted: Jul 23, 2010
Published online: Sep 15, 2011
Published in print: Oct 1, 2011

Permissions

Request permissions for this article.

Authors

Affiliations

Weihua Zhang, Ph.D. [email protected]
Associate Professor, School of Environmental Science and Engineering, Sun Yat-sen Univ., Guangzhou 510275, China (corresponding author). E-mail: [email protected]
Lizhi Tong
Graduate Student, School of Environmental Science and Engineering, Sun Yat-sen Univ., Guangzhou 510275, China.
Yuan Yuan
Graduate Student, School of Environmental Science and Engineering, Sun Yat-sen Univ., Guangzhou 510275, China.
Luwen Zhuang
Graduate Student, School of Environmental Science and Engineering, Sun Yat-sen Univ., Guangzhou 510275, China.
Hao Huang
Graduate Student, School of Environmental Science and Engineering, Sun Yat-sen Univ., Guangzhou 510275, China.
Rongliang Qiu, Ph.D.
Professor, School of Environmental Science and Engineering, Sun Yat-sen Univ., Guangzhou, 510275, China.

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share