TECHNICAL PAPERS
May 11, 2010

Chromium (III) Immobilization and Its Influence on C3S Hydration

Publication: Practice Periodical of Hazardous, Toxic, and Radioactive Waste Management
Volume 14, Issue 4

Abstract

The hydration characteristics of C3S were studied in the presence of chromium (III) for up to 7 days. Chromium was introduced by either direct incorporation (as Cr2O3 ) during C3S preparation or during the subsequent hydration with a chromium (CrCl3) solution. Levels of Cr(III) used were 1 and 3% by wt. of C3S . The chemically combined water content and free lime content were determined after 3 and 6 h and 1, 3, and 7 days of hydration. The results showed a retardation effect for the hydration of C3S in the presence of Cr, especially during the first hours of hydration. This retardation effect was more evident in C3SCr incorporated mixes than in C3S mixes hydrated in Cr-containing solutions. X-ray diffraction examination was performed on selected samples. The immobilization percentage of Cr(III) by C3S during hydration was determination by atomic absorption spectroscopy. A high degree of Cr immobilization (93.27–99.39%) was found after 7 days of hydration.

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Go to Practice Periodical of Hazardous, Toxic, and Radioactive Waste Management
Practice Periodical of Hazardous, Toxic, and Radioactive Waste Management
Volume 14Issue 4October 2010
Pages: 246 - 249

History

Received: Sep 9, 2009
Accepted: May 3, 2010
Published online: May 11, 2010
Published in print: Oct 2010

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Authors

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Eisa E. Hekal
Dept. of Chemistry, Faculty of Science, Ain Shams Univ., Cairo, Egypt.
F. S. Hashem [email protected]
Dept. of Chemistry, Faculty of Science, Ain Shams Univ., Cairo, Egypt (corresponding author). E-mail: [email protected]
M. S. Amin
Dept. of Chemistry, Faculty of Science, Ain Shams Univ., Cairo, Egypt.

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