BTEX Migration through Various Geomembranes and Vapor Barriers
Publication: Journal of Geotechnical and Geoenvironmental Engineering
Volume 142, Issue 10
Abstract
Four polyethylene based vapor barriers and six different geomembranes were examined for their diffusive properties with respect to benzene, toluene, ethylbenzene, and xylenes (BTEX). All four vapor barriers performed comparably. Of the geomembranes tested, high-density polyethylene (HDPE) showed the greatest diffusive resistance to BTEX, while polyvinyl chloride (PVC) showed the least, LLDPE (linear low-density polyethylene), CSPE (chlorosulphonated polyethylene) and two KEE/EIA (ketone ethylene ester/ethylene interpolymer alloy) geomembranes all performed similarly, bounded by HDPE and PVC. Based on data collected at 22, 30, and 40°C, Arrhenius relationships are presented for the six geomembranes. Each geomembrane was evaluated for performance as a diffusive barrier in a landfill cover scenario. Each vapor barrier and two geomembranes were evaluated, through contaminant transport modeling, for performance as a diffusive barrier to vapor intrusion into a warehouse and substantial potential differences in performance are reported.
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Acknowledgments
The writers would like to thank Kuraray America and Geosyntec Consultants for funding this project. The value of discussion with R. Armstrong and E. Chow (Kuraray America) and G. Corcoran (Geosyntec Consultants) as well as assistance provided by the Analytical Services Unit at Queen’s University, specifically Dr. A. Rutter, M. Thompson, and P. Whitley, are all very gratefully acknowledged.
References
Aminabhavi, T. M., and Naik, H. G. (1998a). “Chemical compatibility study of geomembranes—Sorption/desorption, diffusion and swelling phenomena.” J. Hazard. Mater., 60(2), 175–203.
Aminabhavi, T. M., and Naik, H. G. (1998b). “Chemical compatibility testing of geomembranes sorption/desorption, diffusion, permeation and swelling phenomena.” Geotext. Geomembr., 16(6), 333–354.
Aminabhavi, T. M., and Naik, H. G. (1998c). “Chemical resistivity of very low density polyethylene geomembranes: sorption/desorption, diffusion and swelling.” Polym. Polym. Compos., 6(4), 205–213.
Aminabhavi, T. M., and Naik, H. G. (1999a). “Chemical compatibility of geomembranes—Sorption, diffusion and swelling phenomena.” J. Plastic Film Sheet., 15(1), 47–56.
Aminabhavi, T. M., and Naik, H. G. (1999b). “Chemical compatibility testing of linear low density polyethylene geomembrane sorption/desorption, diffusion and swelling studies in the presence of organic liquids.” J. Polym. Eng., 19(5), 315–332.
Aminabhavi, T. M., and Naik, H. G. (1999c). “Molecular migration of low sorbing organic liquids into polymeric geomembranes.” Polym. Int., 48(5), 373–381.
Aminabhavi, T. M., and Naik, H. G. (1999f). “Sorption/desorption studies on polypropylene geomembrane in the presence of hazardous organic liquids.” J. Appl. Polym. Sci., 72(10), 1291–1298.
Aminabhavi, T. M., and Naik, H. G. (1999e). “Sorption/desorption, diffusion, and swelling characteristics of geomembranes in the presence of halo-organic liquids.” J. Appl. Polym. Sci., 72(3), 349–359.
Aminabhavi, T. M., and Naik, H. G. (1999d). “Sorption/desorption, diffusion, permeation and swelling of high density polyethylene geomembrane in the presence of hazardous organic liquids.” J. Hazard. Mater., 64(3), 251–262.
Bathurst, R. J., Rowe, R. K., Zeeb, B., and Reimer, K. (2006). “A geocomposite barrier for hydrocarbon containment in the arctic.” Int. J. Geoeng. Case Hist., 1(1), 18–34.
Canadian Council of Ministers of the Environment. (2004a). “Canadian soil quality guidelines for the protection of environmental and human health: Benzene (2004).” Winnipeg, Canada.
Canadian Council of Ministers of the Environment. (2004b). “Canadian soil quality guidelines for the protection of environmental and human health: Ethylbenzene.” Winnipeg, Canada.
Canadian Council of Ministers of the Environment. (2004c). “Canadian soil quality guidelines for the protection of environmental and human health: Toluene.” Winnipeg, Canada.
Canadian Council of Ministers of the Environment. (2004d). “Canadian soil quality guidelines for the protection of environmental and human health: Xylenes (2004).” Winnipeg, Canada.
Centers for Disease Control and Prevention. (2015a). “NIOSH pocket guide to chemical hazards: Benzene.” 〈http://www.cdc.gov/niosh/npg/npgd0049.html〉 (Jul. 29, 2015).
Centers for Disease Control and Prevention. (2015b). “NIOSH pocket guide to chemical hazards: Ethylbenzene.” 〈http://www.cdc.gov/niosh/npg/npgd0264.html〉 (Jul. 29, 2015).
Centers for Disease Control and Prevention. (2015c). “NIOSH pocket guide to chemical hazards: Toluene.” 〈http://www.cdc.gov/niosh/npg/npgd0619.html〉 (Jul. 29, 2015).
Centers for Disease Control and Prevention. (2015d). “NIOSH pocket guide to chemical hazards: m-Xylene.” 〈http://www.cdc.gov/niosh/npg/npgd0671.html〉 (Jul. 29, 2015).
Centers for Disease Control and Prevention. (2015e). “NIOSH pocket guide to chemical hazards: p-Xylene.” 〈http://www.cdc.gov/niosh/npg/npgd0670.html〉 (Jul. 29 2015).
Centers for Disease Control and Prevention. (2015f). “NIOSH pocket guide to chemical hazards: o-Xylene.” 〈http://www.cdc.gov/niosh/npg/npgd0668.html〉 (Jul. 29, 2015).
Chainey, M. (1990). “Transport phenomena in polymer films.” Handbook of polymer science and technology, composites and specialty applications, Vol. 4, Marcel Dekker, New York, 499–540.
Crank, J., and Park, J. (1968). Diffusion of polymers, Academic Press, London.
Edil, T. (2003). “A review of aqueous-phase VOC transport in modern landfill liners.” Waste Manage., 23(7), 561–571.
EUGRIS (European Groundwater and Contaminated Land Remediation Information System). (2015). “Further description, benzene, toluene, ethylbenzene, and xylenes.” 〈http://www.eugris.info/FurtherDescription.asp?Ca=2&Cy=0&T=Benzene,%20toluene,%20ethylbenzene,%20and%20xylene&e=6〉 (Nov. 21, 2015).
Eun, J., Tinjum, J., Benson, C., and Edil, T. (2014). “Volatile organic compound (VOC) transport through a composite liner with co-extruded geomembrane containing ethylene vinyl-alcohol (EVOH).” Geo-Congress 2014, 1960–1969.
Ewais, A. M. R., and Rowe, R. K. (2014). “Effects of blown film process on initial properties of HDPE geomembranes of different thicknesses.” Geosynthetics Int., 21(1), 62–82.
Geosynthetic Institute. (2014). “GRI test method 13.” Folsom, PA.
Geosynthetic Institute. (2015). “GRI test method 17.” Folsom, PA.
Islam, M. Z., and Rowe, R. K. (2009). “Permeation of BTEX through unaged and aged HDPE geomembranes.” J. Geotech. Geoenviron. Eng., 1130–1140.
Johnson, P. C. (2002). “Identification of critical parameters for the Johnson and Ettinger (1991) vapor intrusion model.” American Petroleum Institute, 39.
Johnson, P. C., Ettinger, R. A., Kurtz, J., Bryan, R., and Kester, J. E. (2002). “Migration of soil gas vapors to indoor air: Determining vapor attenuation factors using a screening-level and field data from the CDOT-MTL Denver, Colorado site.” American Petroleum Institute.
Jones, D. D., et al. (2013). “Evaluation of geosynthetics used in barrier systems to contain hydrocarbon-contaminated soils in Antarctica.” Proc. GeoMontreal 2013, Montréal.
Jones, D. D. (2016). “Containment of PCBs and VOCs using geosynthetics.” Ph.D. thesis, Queen’s Univ., Kingston, ON, Canada.
Joo, J. C., Kim, J. Y., and Nam, K. (2004). “Mass transfer of organic compounds in dilute aqueous solutions into high density polyethylene geomembrane.” J. Environ. Eng., 175–183.
Joo, J. C., Nam, K., and Kim, J. Y. (2005). “Estimation of mass transport parameters of organic compounds through high density polyethylene geomembranes using a modified double-compartment apparatus.” J. Environ. Eng., 790–799.
McWatters, R., and Rowe, R. K. (2007). “Diffusive migration of volatile organic compounds through PVC geomembranes.” Proc., Environmental Conf., Washington, DC, 106–120.
McWatters, R., and Rowe, R. K. (2009). “Transport of volatile organic compounds through PVC and LLDPE geomembranes from both aqueous and vapour phases.” Geosynth. Int., 16(6), 468–481.
McWatters, R., and Rowe, R. K. (2010). “Diffusive transport of VOCs through LLDPE and two co-extruded geomembranes.” J. Geotech. Geoenviron. Eng., 1167–1177.
McWatters, R. S., et al. (2014a). “Geosynthetics in Antarctica—An overview of geosynthetics employed in barrier systems used in remediation activities at Casey Station, Antarctica.” Proc., 10th Int. Conf. on Geosynthetics, Berlin.
McWatters, R. S., et al. (2014b). “Geosynthetics used in the barrier systems for remediation of hydrocarbon contaminated soil in Antarctica.” Proc., 7th Int. Congress on Environmental Geotechnics, International Society of Soil Mechanics and Geotechnical Engineering.
McWatters, R. S., andRowe, R. K. (2014). “An investigation of toluene and TCE diffusion through EVOH in aqueous solutions.” 10th Int. Conf. on Geosynthetics, International Geosynthetics Society.
McWatters, R. S., and Rowe, R. K. (2015). “Permeation of volatile organic compounds through EVOH thin film membranes and coextruded LLDPE/EVOH/LLDPE geomembranes.” J. Geotech. Geoenviron. Eng., 04014091.
McWatters, R. S., Rowe, R. K., and Jones, D. D. (2015a). “Coextruded geomembranes in barrier systems in extreme environments—From high temperature laboratory tests to Antarctic field sites.” Proc., Geosynthetics 2015, Industrial Fabrics Association International.
McWatters, R. S., Rutter, A., and Rowe, R. K. (2016). “Geomembrane applications for controlling diffusive migration of petroleum hydrocarbons in cold region environments.” J. Environ. Manage., in press.
MOECC (Ministry of Environment and Climate Change). (1998). “Ontario regulations 232/98: Landfilling sites.” 〈〉 (Sep. 10, 2015).
Müller, W., Jacob, I., Tatzky-Gerth, R., and August, H. (1998). “Solubilities, diffusion and partitioning coefficients of organic pollutants in HDPE geomembranes: Experimental results and calculations.” Proc., 6th Int. Conf. on Geosynthetics, Industrial Fabrics Association International, 239–248.
Naylor, T. D. (1989). “Permeation properties.” Comprehensive polymer science, Pergamon Press, Oxford, U.K., 643–668.
Njobuenwu, D. O., Amadi, S. A., and Ukpaka, P. C. (2005). “Dissolution rate of BTEX contaminants in water.” Can. Geotech. J., 83(6), 985–989.
NYSDOH (New York State Department of Health). (2006). “Guidance for evaluating soil vapour intrusion in the state of New York.” 〈https://www.health.ny.gov/environmental/investigations/soil_gas/svi_guidance/docs/svi_main.pdf〉.
Park, J. K., and Nibras, M. (1993). “Mass flux of organic chemicals through polyethylene geomembranes.” Water Environ. Res., 65(3), 227–237.
Park, M.-G., Benson, C. H., and Edil, T. B. (2012). “Comparison of batch and double compartment tests for measuring VOC transport parameters in geomembranes.” Geotext. Geomembr., 31, 15–30.
POLLUTE 7 [Computer software]. GAEA Technologies, Napanee, ON, Canada.
Rowe, R. K. (1995). “Leachate characteristics of MSW landfills.”, Dept. of Civil Engineering, Geotechnical Research Center, Univ. of Western Ontario, London, ON, Canada.
Rowe, R. K. (1998). “Geosynthetics and the minimization of contaminant migration through barrier systems beneath solid waste.” Proc., 6th Int. Conf. on Geosynthetics, International Geosynthetics Society, Jupiter, FL, 27–103.
Rowe, R. K. (2012). “Systems engineering the design and operations of municipal solid waste landfills to minimize leakage of contaminants to groundwater.” Geosynth. Int., 16(6), 391–404.
Rowe, R. K., Quigley, R. M., Brachman, R. W. I., and Booker, J. R. (2004). Barrier systems for waste disposal facilities, E & FN Spon, London, 587.
Sangam, H. P., and Rowe, R. K. (2001). “Migration of dilute aqueous organic pollutants through HDPE geomembranes.” Geotext. Geomembr., 19(6), 329–357.
Sangam, H. P., and Rowe, R. K. (2005). “Effect of surface fluorination on diffusion through an HDPE geomembrane.” J. Geotech. Geoenviron. Eng., 694–704.
Touze-Foltz, N., Mendes, M. J. A., Méry, J., and Mazeas, L. (2013). “Transfer of phenolic compounds through landfill bottom liners.” Ind. Geotech. J., 43(4), 367–381.
USEPA (U.S. Environmental Protection Agency). (1996). “Volatile organic compounds by gas chromatography mass spectrometry (GCMS).” Method 8260B, 〈〉.
USEPA (U.S. Environmental Protection Agency). (2001). “Building radon out.” 〈http://www.epa.gov/radon/pdfs/buildradonout.pdf〉 (Jul. 23, 2015).
USEPA (U.S. Environmental Protection Agency). (2008). “Indoor air vapor intrusion mitigation approaches.” 〈http://nepis.epa.gov/Adobe/PDF/P100AE72.pdf〉 (Jul. 10, 2015).
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© 2016 American Society of Civil Engineers.
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Received: Sep 13, 2015
Accepted: Jan 21, 2016
Published online: May 23, 2016
Published in print: Oct 1, 2016
Discussion open until: Oct 23, 2016
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