Abstract

In drinking water treatment, it is difficult to predict the remaining service life of a partially spent granular activated carbon bed when contaminants are intermittent, such as taste and odor-causing compounds. A laboratory-scale minicolumn test using a grab granular activated carbon (GAC) sample from a full-scale bed was assessed using pore and surface diffusion model (PSDM) simulations. The impact of bed depth and flow velocity on the performance of preloaded GAC was negligible provided that the minicolumn test matched the same empty bed contact time as at full scale. The impact of minicolumn diameter was insignificant when the minicolumn to GAC particle diameter ratio was larger than 13. Minicolumns using a single representative grain size fraction were predicted to simulate full-scale beds with reasonable accuracy. The impact of temperature may be significant. A potential limitation of the test is that the media may be harvested at different GAC bed depths: accuracy requires that the adsorption capacity and kinetics of the adsorbate be relatively constant across those depths.

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Data Availability Statement

Some or all data, models, or code generated or used during the study are available from the corresponding author by request (Figs. 19).

Acknowledgments

The authors are grateful for financial support from the Natural Sciences and Engineering Research Council (NSERC) of Canada, Project No. IRCPJ 428979-16.

References

Carter, M. C., and W. J. Weber. 1994. “Modeling adsorption of TCE by activated carbon preloaded by background organic matter.” Environ. Sci. Technol. 28 (4): 614–623. https://doi.org/10.1021/es00053a013.
Corwin, C. J., and R. S. Summers. 2011. “Adsorption and desorption of trace organic contaminants from granular activated carbon adsorbers after intermittent loading and throughout backwash cycles.” Water Res. 45 (2): 417–426. https://doi.org/10.1016/j.watres.2010.08.039.
Crittenden, J. C., J. K. Berrigan, and D. W. Hand. 1986a. “Design of rapid small-scale adsorption tests for a constant diffusivity.” J. Water Pollut. Control Fed. 58 (4): 312–319. https://doi.org/10.2307/25042907.
Crittenden, J. C., J. K. Berrigan, D. W. Hand, and B. Lykins. 1987. “Design of rapid fixed-bed adsorption tests for nonconstant diffusivities.” J. Environ. Eng. 113 (2): 243–259. https://doi.org/10.1061/(ASCE)0733-9372(1987)113:2(243).
Crittenden, J. C., N. J. Hutzler, D. G. Geyer, J. L. Oravitz, and G. Friedman. 1986b. “Transport of organic compounds with saturated groundwater flow: Model development and parameter sensitivity.” Water Resour. Res. 22 (3): 271–284. https://doi.org/10.1029/WR022i003p00271.
Crittenden, J. C., P. S. Reddy, H. Arora, J. Trynoski, D. W. Hand, D. L. Perram, and R. S. Summers. 1991. “Predicting GAC performance with rapid small-scale column tests.” J. Am. Water Works Assoc. 83 (1): 77–87. https://doi.org/10.1002/j.1551-8833.1991.tb07088.x.
DeVault, D. 1943. “The theory of chromatography.” J. Am. Chem. Soc. 65 (4): 532–540. https://doi.org/10.1021/ja01244a011.
Dougherty, T. M. 2015. “The effect of groundwater temperature and DOM on adsorption of VOCs by GAC adsorption.” Master’s dissertation, Dept. of Civil, Environmental, and Architectural Engineering, Univ. of Colorado Boulder.
Friedman, G. 1984. “Mathematical modeling of multicomponent adsorption in batch and fixed-BED REACTORS.” Master’s dissertation, Dept. of Chemical Engineering, Michigan Technological Univ.
Gillogly, T. E. T. 1999. “MIB adsorption in drinking water treatment.” Ph.D. dissertation, Univ. of Illinois at Urbana-Champaign.
Gillogly, T. E. T., V. L. Snoeyink, J. C. Vogel, C. M. Wilson, and E. P. Royal. 1999. “Determining GAC bed life.” J. Am. Water Works Assoc. 91 (8): 98–110. https://doi.org/10.1002/j.1551-8833.1999.tb08687.x.
Gnielinski, V. 1978. “Gleichungen Zur Berechnung Des Wärmeübergangs in Querdurchströmten Einzelnen Rohrreihen Und Rohrbündeln.” [In German.] Forschung im Ingenieurwesen A 44 (1): 15–25. https://doi.org/10.1007/BF02560750.
Graham, M. R., R. S. Summers, M. R. Simpson, and B. W. Macleod. 2000. “Modeling equilibrium adsorption of 2-methylisoborneol and geosmin in natural waters.” Water Res. 34 (8): 2291–2300. https://doi.org/10.1016/S0043-1354(99)00390-5.
Hayduk, W., and H. Laudie. 1974. “Prediction of diffusion coefficients for nonelectrolytes in dilute aqueous solutions.” AlChE J. 20 (3): 611–615. https://doi.org/10.1002/aic.690200329.
Huang, Y., Z. Nie, J. Yuan, A. Murray, Y. Li, G. Woods-Chabane, and R. Hofmann. 2019. “Experimental validation of a test to estimate the remaining adsorption capacity of granular activated carbon for taste and odour compounds.” Environ. Sci. Water Res. Technol. 5 (3): 609–617. https://doi.org/10.1039/C8EW00600H.
Hutzler, N. J., J. C. Crittenden, and J. S. Gierke. 1986. “Transport of organic compounds with saturated groundwater flow: Experimental results.” Water Resour. Res. 22 (3): 285–295. https://doi.org/10.1029/WR022i003p00285.
Jarvie, M. E., D. W. Hand, S. Bhuvendralingam, J. C. Crittenden, and D. R. Hokanson. 2005. “Simulating the performance of fixed-bed granular activated carbon adsorbers: Removal of synthetic organic chemicals in the presence of background organic matter.” Water Res. 39 (11): 2407–2421. https://doi.org/10.1016/j.watres.2005.04.023.
Knappe, D. R. U., V. L. Snoeyink, P. Roche, M. J. Prados, and M. M. Bourbigot. 1999. “Atrazine removal by preloaded GAG.” J. Am. Water Works Assoc. 91 (10): 97–109. https://doi.org/10.1002/j.1551-8833.1999.tb08719.x.
Li, C., L. Wang, and Y. Shen. 2014. “The removal of atrazine, simazine, and prometryn by granular activated carbon in aqueous solution.” Desalin. Water Treat. 52 (19–21): 3510–3516. https://doi.org/10.1080/19443994.2013.803650.
Nam, S.-W., D.-J. Choi, S.-K. Kim, N. Her, and K.-D. Zoh. 2014. “Adsorption characteristics of selected hydrophilic and hydrophobic micropollutants in water using activated carbon.” J. Hazard. Mater. 270 (Apr): 144–152. https://doi.org/10.1016/j.jhazmat.2014.01.037.
Pikaar, I., A. A. Koelmans, and P. C. M. van Noort. 2006. “Sorption of organic compounds to activated carbons: Evaluation of isotherm models.” Chemosphere 65 (11): 2343–2351. https://doi.org/10.1016/j.chemosphere.2006.05.005.
Pirbazari, M., H. S. Borow, S. Craig, V. Ravindran, and M. J. McGuire. 1992. “Physical chemical characterization of five earthy musty-smelling compounds.” Water Sci. Technol. 25 (2): 81–88. https://doi.org/10.2166/wst.1992.0038.
Pota, A. A., and A. P. Mathews. 1999. “Effects of particle stratification on fixed bed absorber performance.” J. Environ. Eng. 125 (8): 705–711. https://doi.org/10.1061/(ASCE)0733-9372(1999)125:8(705).
Schideman, L. C., B. J. Mariñas, V. L. Snoeyink, and C. Campos. 2006. “Three-component competitive adsorption model for fixed-bed and moving-bed granular activated carbon adsorbers. Part I. Model development.” Environ. Sci. Technol. 40 (21): 6805–6811. https://doi.org/10.1021/es060590m.
Schreiber, B., T. Brinkmann, V. Schmalz, and E. Worch. 2005. “Adsorption of dissolved organic matter onto activated carbon—The influence of temperature, absorption wavelength, and molecular size.” Water Res. 39 (15): 3449–3456. https://doi.org/10.1016/j.watres.2005.05.050.
Schreiber, B., V. Schmalz, T. Brinkmann, and E. Worch. 2007. “The effect of water temperature on the adsorption equilibrium of dissolved organic matter and atrazine on granular activated carbon.” Environ. Sci. Technol. 41 (18): 6448–6453. https://doi.org/10.1021/es070704+.
Sontheimer, H., J. C. Crittenden, and R. S. Summers. 1988. Activated carbon for water treatment. Karlsruhe, Germany: DVGW-Forschungsstelle.
Srinivasan, R., and G. A. Sorial. 2011. “Treatment of taste and odor causing compounds 2-methyl isoborneol and geosmin in drinking water: A critical review.” J. Environ. Sci. 23 (1): 1–13. https://doi.org/10.1016/S1001-0742(10)60367-1.
Summers, R. S., B. Haist, J. Koehler, J. Ritz, G. Zimmer, and H. Sontheimer. 1989. “The influence of background organic matter on GAC adsorption.” J. Am. Water Works Assoc. 81 (5): 66–74. https://doi.org/10.1002/j.1551-8833.1989.tb03207.x.
Summers, R. S., and P. V. Roberts. 1988. “Activated carbon adsorption of humic substances II: Size exclusion and electrostatic interactions.” J. Colloid Interface Sci. 122 (2): 382–397. https://doi.org/10.1016/0021-9797(88)90373-6.
White, S. M., and C. L. Tien. 1987. “Analysis of flow channeling near the wall in packed beds.” Wärme–Stoffübertragung 21 (5): 291–296. https://doi.org/10.1007/BF01009290.
Yu, Z., S. Peldszus, and P. M. Huck. 2009a. “Adsorption of selected pharmaceuticals and an endocrine disrupting compound by granular activated carbon. 1: Adsorption capacity and kinetics.” Environ. Sci. Technol. 43 (5): 1467–1473. https://doi.org/10.1021/es801961y.
Yu, Z., S. Peldszus, and P. M. Huck. 2009b. “Adsorption of selected pharmaceuticals and an endocrine disrupting compound by granular activated carbon. 2: Model prediction.” Environ. Sci. Technol. 43 (5): 1474–1479. https://doi.org/10.1021/es7032185.

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Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 146Issue 1January 2020

History

Received: Jul 3, 2018
Accepted: May 30, 2019
Published online: Oct 30, 2019
Published in print: Jan 1, 2020
Discussion open until: Mar 30, 2020

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Postgraduate, Drinking Water Research Group, Dept. of Civil and Mineral Engineering, Univ. of Toronto, 35 St. George St., Toronto, ON, Canada M5S 1A4. Email: [email protected]
Postdoctoral Fellow, Drinking Water Research Group, Dept. of Civil and Mineral Engineering, Univ. of Toronto, 35 St. George St., Toronto, ON, Canada M5S 1A4 (corresponding author). ORCID: https://orcid.org/0000-0002-0412-5279. Email: [email protected]
Ph.D. Candidate, Drinking Water Research Group, Dept. of Civil and Mineral Engineering, Univ. of Toronto, 35 St. George St., Toronto, ON, Canada M5S 1A4. Email: [email protected]
Audrey Murray, Ph.D. [email protected]
Postdoctoral Fellow, Drinking Water Research Group, Dept. of Civil and Mineral Engineering, Univ. of Toronto, 35 St. George St., Toronto, ON, Canada M5S 1A4. Email: [email protected]
Postgraduate, Drinking Water Research Group, Dept. of Civil and Mineral Engineering, Univ. of Toronto, 35 St. George St., Toronto, ON, Canada M5S 1A4. Email: [email protected]
Gwen Woods-Chabane, Ph.D. [email protected]
Postdoctoral Fellow, Drinking Water Research Group, Dept. of Civil and Mineral Engineering, Univ. of Toronto, 35 St. George St., Toronto, ON, Canada M5S 1A4. Email: [email protected]
Ron Hofmann, Ph.D. [email protected]
P.Eng.
Professor, Drinking Water Research Group, Dept. of Civil and Mineral Engineering, Univ. of Toronto, 35 St. George St., Toronto, ON, Canada M5S 1A4. Email: [email protected]

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