TECHNICAL PAPERS
Nov 5, 2010

Comparison of Aniline Oxidation by Electro-Fenton and Fluidized-Bed Fenton Processes

Publication: Journal of Environmental Engineering
Volume 137, Issue 5

Abstract

This study investigated the aniline oxidation at various conditions, namely, pH, H2O2 dose, Fe2+ dose, and aniline concentration, as well as the effects of inorganic ion concentrations on the electro-Fenton and fluidized-bed Fenton processes. Aniline degradation depended on the H2O2 and Fe2+ dose for both processes. The results showed that both processes had the best aniline oxidation efficiency at pH 2.8–3.2. In the electro-Fenton process, approximately 95% of the aniline was removed after 60 min. While the SiO2 carrier contents of fluidized-bed Fenton process was adjusted to 74g/L, the aniline was gradually removed, and the degradation rate finally reached 83%. The inhibition effect of phosphate ions on aniline oxidation on both processes was more significant than that of chloride ions. Chloride ions have higher inhibition ability on aniline oxidation in the fluidized-bed Fenton process than in the electro-Fenton process. However, the inhibition of phosphate ions on aniline oxidation in the electro-Fenton process was more obvious than in the fluidized-bed Fenton process.

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Acknowledgments

The writers would like to thank the National Science Council of Taiwan for financially supporting this research under Contract No. NSCTNSC 96-2628-E-041-001-MY3.

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Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 137Issue 5May 2011
Pages: 363 - 370

History

Received: Feb 1, 2010
Accepted: Oct 7, 2010
Published online: Nov 5, 2010
Published in print: May 1, 2011

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Authors

Affiliations

Jin Anotai
Professor, Dept. of Environmental Engineering, Faculty of Engineering, King Mongkut’s Univ. of Technology Thonburi, Bangkok 10140, Thailand; and National Center of Excellence for Environmental and Hazardous Waste Management (NCE-EHWM), Chulalongkorn Univ., Bangkok, Thailand.
Chia-Chi Su
Postdoctoral Fellow, Dept. of Environmental Resources Management, Chia Nan Univ. of Pharmacy and Science, No. 60, Erh-Jen Rd., Sec. 1, Jen-Te, Tainan 717, Taiwan.
Yi-Chun Tsai
M.S. Student, Dept. of Environmental Resources Management, Chia Nan Univ. of Pharmacy and Science, No. 60, Erh-Jen Rd., Sec. 1, Jen-Te, Tainan 717, Taiwan.
Ming-Chun Lu [email protected]
Professor, Dept. of Environmental Resources Management, Chia Nan Univ. of Pharmacy and Science, No. 60, Erh-Jen Rd., Sec. 1, Jen-Te, Tainan 717, Taiwan (corresponding author). E-mail: [email protected]

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