TECHNICAL PAPERS
Jul 1, 2008

Metals Precipitation from Effluents: Review

Publication: Practice Periodical of Hazardous, Toxic, and Radioactive Waste Management
Volume 12, Issue 3

Abstract

At the onset of 21st century, the pollution of surface and groundwater by toxic metals continues to represent a challenge for the authorities responsible for environmental protection. The uncontrolled rejection of metals in aquatic ecosystems such as Ag, As, Be, Cd, Cr, Cu, Hg, Ni, Pb, Sb, Tl and Zn, constitute a serious threat to human and animal health. Several methods of treatment of waters polluted by metals have been proposed during the last several decades. However, the technique of precipitation of metals remains the most favorable option on an industrial scale due to reasons of cost-effectiveness, performance, and simplicity. The present review presents current knowledge on various technical alternatives for precipitation of metals. The discussion relates to the individual characteristics of the metal contaminants, as well as their behavior compared to various techniques of precipitation.

Get full access to this article

View all available purchase options and get full access to this article.

Acknowledgments

The writers are sincerely thankful to the Natural Sciences and Engineering Research Council of Canada, Agence Universitaire de la Francophonie, the Canada Research Chair Program, and FQRNT for their financial support.

References

Accornero, M., Marini, L., Ottonello, G., and Zuccolini, M. V. (2005). “The fate of major constituents and chromium and other trace elements when acid waters from the derelict Libiola mine (Italy) are mixed with stream waters.” Appl. Geochem., 20(7), 1368–1390.
Al-Asheh, S., and Duvnjak, Z. (1999). “Sorption of heavy metals from synthetic metal solutions and industrial wastewater using plant materials.” Water Qual. Res. J. Canada, 34(3), 481–503.
Alderighi, L., Gans, P., Ienco, A., Peters, D., Sabatini, A., and Vacca, A. (1999). “Hyperquad simulation and speciation (HySS): A utility program for the investigation of equilibria involving soluble and partially soluble species.” Coord. Chem. Rev., 184(1), 311–318.
Aldrich, C., and Feng, D. (2000). “Removal of heavy metals from wastewater effluents by biosorptive flotation.” Min. Eng., 13(10-11), 1129–1138.
Allen, H. E. (2002). Bioavailability of metals in terrestrial ecosystems: Importance of partitioning for bioavailability to invertebrates, microbes, and plants, Society of Environmental Toxicology and Chemistry, Pensacola, Fla.
Allison, J. D., Brown, D. S., and Novo-Gradac, K. J. (1991). “MINTEQA2/PRODEFA2. A geochemical assessment model for environmental systems: Version 3.0. user’s manual.” Rep. EPA/600/3-91/021, U.S. Environmental Protection Agency, Office of Research and Development, Environmental Research Laboratory, Athens, Ga.
Al-Tarazi, M., Heesink, A. B. M., and Versteeg, G. F. (2004). “Precipitation of metal sulphides using gaseous hydrogen sulphide: Mathematical modeling.” Chem. Eng. Sci., 59(3), 567–579.
Alves, L. C., Henrique, H. M., Xavier, A. M. F., and Cammarota, M. C. (2005). “Potential treatment alternative for laboratory effluents.” Bioresour. Technol., 96(15), 1650–1657.
Apul, D. S., Gardner, K. H., Eighmy, T. T., Fallman, A. M., and Comans, R. N. J. (2005). “Simultaneous application of dissolution/precipitation and surface complexation/surface precipitation modeling to contaminant leaching.” Environ. Sci. Technol., 39(15), 5736–5741.
Arienzo, M., Chiarenzelli, J., and Scrudato, R. (2001). “Remediation of metal-contaminated aqueous systems by electrochemical peroxidation: An experimental investigation.” J. Hazard. Mater., 87(1-3), 187–198.
Atwood, D. A., and Zaman, M. K. (2006). “Mercury removal from water.” Struct. Bonding (Berlin), 120, 163–182.
Avudainayagam, S., Meghraj, M., Owens, G., Kookana, R. S., Chittleborough, D., and Naidu, R. (2003). “Chemistry of chromium in soils with emphasis on tannery waste sites.” Rev. Environ. Contam Toxicol., 178, 53–91.
Baath, E. (1989). “Effects of heavy metals in soil on microbial processes and populations (a review).” Water, Air, Soil Pollut., 47(3–4), 335–379.
Babel, S., and Kurniawan, T. A. (2003). “Low-cost adsorbents for heavy metals uptake from contaminated water: Review.” J. Hazard. Mater., 97(1-3), 219–243.
Bailey, S. E., Olin, T. J., Bricka, R. M., and Arian, D. (1999). “A review of potentially low-cost sorbents for heavy metals.” Water Res., 33(11), 2469–2479.
Ball, J. (2002). “User’s manual for WATEQ4F, with revised thermodynamic data base and test cases for calculating speciation of major, trace, and redox elements in natural waters (program version 2.46).” Rep. 91-183, U.S. Geological Survey, Reston, Va.
Ball, J., Nordstrom, D. K., and Zachmann, D. W. (1987). “WATEQ4F—A personal computer Fortran translation of the geochemical model WATEQ2 with revised data base.” Rep. 87-50, U.S. Geological Survey, Menlo Park, Calif.
Baltpurvins, K. A., Burns, R. C., and Lawrance, G. A. (1996a) “Heavy metals in wastewater: Modelling the hydroxide precipitation of copper(II) from wastewater using lime as the precipitation.” Waste Manage., 16(8), 717–725.
Baltpurvins, K. A., Burns, R. C., and Lawrance, G. A. (1996b) “Use of the solubility domain approach for the modeling of the hydroxide precipitation of heavy metals from wastewater.” Environ. Sci. Technol., 30(5), 1493–1499.
Baltpurvins, K. A., Burns, R. C., Lawrance, G. A., and Stuart, A. D. (1997). “Effect of electrolyte composition on zinc hydroxide precipitation by lime.” Water Res., 31, 973–980.
Barak, P. (1990). “SPECIES: A spreadsheet program for modeling speciation of soil solution.” J. Agron. Educ., 19, 44–46.
Barnes, L. J., Scheeren, P. J. M., and Buisman, C. J. N. (1994). Emerging technology for bioremediation of metals, J. L. Means, and R. E. Hinchee, eds., Lewis, Boca Raton, Fla., 38–49.
Belkhouche, N. E., Didi, M. A., and Villemin, D. (2005). “Separation of nickel and copper by solvent extraction using Di-2 ethylhexylphosphoric acid-based synergistic mixture.” Solvent Extr. Ion Exch., 23(5), 677–693.
Ben Frarès, N., Taha, S., and Dorange, G. (2005). “Influence of the operating conditions on the elimination of zinc ions by nanofiltration.” Desalination, 185(1–3), 245–253.
Bhavsar, S. P., Diamond, M. L., Gandhi, N., and Nilsen, J. (2004). “Dynamic coupled metal transport-speciation model: Application to assess a zinc-contaminated lake.” Envir. Toxicol. Chem., 23(10), 2410–2420.
Blais, J. F., Dufresne, S., and Mercier, G. (1999). “State of the art of the technological development from metal removal from industrial effluents.” J. Water Sci., 12(4), 689–713 (in French).
Bolan, N. S., Adriano, D. C., Duraisamy, P., Mani, A., and Arulmozhiselvan, K. (2003). “Immobilization and phytoavailability of cadmium in variable charge soils. I. Effect of phosphate addition.” Plant Soil, 250(1), 83–94.
Boszke, L., Glosinska, G., and Siepak, J. (2002). “Some aspects of speciation of mercury in a water environment.” Polish J. Environ. Studies, 11(4), 285–298.
Brenneisen, P., Steinbrenner, H., and Sies, H. (2005). “Selenium, oxidative stress, and health aspects.” Mol. Aspects Med., 26, 256–267.
Brooks, C. S. (1986). “Metal recovery from industrial wastes.” J. Met., 38, 50–57.
Brooks, C. S. (1991). Metal recovery from industrial wastes, Lewis, Chelsea, Mich.
Cancès, B., Ponthieu, M., Castrec-Rouelle, M., Aubry, E., and Benedetti, M. F. (2003). “Metal ions speciation in a soil land its solution: Experimental data and model results.” Geoderma, 113(3–4), 341–355.
Caussy, D., Gochfeld, M., Gurzau, E., Neagu, C., and Ruedel, H. (2003). “Lessons from case studies of metals: Investigating exposure, bioavailability, and risk.” Ecotoxicol. Environ. Saf., 56(1), 45–51.
Chang, L. Y. (1995). “A waste minimization study of chelated copper complex in wastewater—Treatability and process analysis.” Waste Manage., 15(3), 209–220.
Chang, Y. K., Chang, J. E., Lin, T. T., and Hsu, Y. M. (2002). “Integrated copper-containing wastewater treatment using xanthate process.” J. Hazard. Mater., 94(1), 89–99.
Chapman, P. M., Wang, F., Janssen, C. R., Goulet, R. R., and Kamunde, C. N. (2003). “Conducting ecological risk assessments of inorganic metals and metalloids: Current status.” Hum. Ecol. Risk Asses., 9, 641–697.
Charerntanyarak, L. (1999). “Heavy metals removal by chemical coagulation and precipitation.” Water Sci. Technol., 39(10-11), 135–138.
Chaston, S., Grassia, G. S., and Sheehy, A. J. (1996). “The next iteration factor (NIF) method for calculating equilibrium conditions in subsurface wasters, for the isolation of microorganisms from petroleum reservoirs.” Aust. J. Chem., 49, 943–949.
Chirwa, E. M. N., and Wang, Y. T. (1997). “Hexavalent chromium reduction by Bacillus sp. in a packed-bed bioreactor.” Environ. Sci. Technol., 31(5), 1446–1451.
Chu, W. (1999). “Lead metal removal by recycled alum sludge.” Water Res., 33(13), 3019–3025.
Clarkson, T. W. (1998). “Human toxicology of mercury.” J. Trace Elem. Exp. Med., 11(2–3), 303–317.
Couillard, D., and Mercier, G. (1992). “Précipitations sélectives des métaux solubilisés biologiquement de boues aérobies d’épuration.” Can. J. Chem. Eng., 70, 1021–1029 (in French).
Dabrowski, A., Hubicki, Z., Podkoscielny, P., and Robens, E. (2004). “Selective removal of the heavy metal ions from waters and industrial wastewaters by ion-exchange method.” Chemosphere, 56(2), 91–106.
Davydova, S. (2005). “Heavy metals as toxicants in big cities.” Microchem. J., 79(1–2), 133–136.
Del Piero, S., Melchior, A., Polese, P., Portanova, R., and Tolazzi, M. (2006). “A novel multipurpose Excel tool for equilibrium speciation based on Newton–Raphson method and on a hybrid genetic algorithm.” Ann. Chim. (Rome), 96(1–2), 29–49.
Denkhaus, E., and Salnikow, K. (2002). “Nickel essentiality, toxicity and carcinogenicity.” Crit. Rev. Oncol. Hematol., 42(1), 35–56.
DiPalma, L., Ferrantelli, P., Merli, C., and Petrucci, E. (2003). “Treatment of the solution extracted from metal contaminated soils by reverse osmosis and chemical precipitation.” Ann. Chim. (Rome), 93(12), 1005–1011.
Djedidi, Z., Drogui, P., Ben Cheikh, R., Mercier, G., and Blais, J. F. (2005). “Laboratory study of successive soil saline leaching and electrochemical lead recovery.” J. Environ. Eng., 131(2), 305–314.
Doyle, F. M. (2003). “Ion flotation—Its potential for hydrometallurgical operations.” Int. J. Min. Process., 72(1-4), 387–399.
Drake, P. L., and Hazelwood, K. J. (2005). “Exposure-related health effects of silver and silver compounds: A review.” Ann. Occup. Hyg., 49(7), 575–585.
Duan, J., and Gregory, J. (2003). “Coagulation by hydrolysing metal salts.” Adv. Colloid Interface Sci., 100–102, 475–502.
Dyer, J. A., Scrivner, N. C., and Dentel, S. K. (1998). “A practical guide for determining the solubility of metal hydroxides and oxides in water.” Environ. Prog., 17(1), 1–8.
Ettler, V., Matura, M., Mihaljevic, M., and Bezdicka, P. (2006). “Metal speciation and attenuation in stream waters and sediments contaminated by landfill leachate.” Environ. Geol., 49(4), 610–619.
Evenko, C. R., and Dzomback, D. A. (1997). “Remediation of metals-contaminated soils and groundwater.” Technology Evaluation Rep. TE-97-01, Ground-Water Remediation Technologies Analysis Center, Pittsburgh.
Felmy, A. R., Girvin, D. C., and Jenne, E. A. (1984). “MINTEQ: A computer program for calculating aqueous geochemical equilibria.” Rep. EPA/600/3-84/032, U.S. Environmental Protection Agency, Office of Research and Development, Environmental Research Laboratory, Athens, Ga.
Filella, M., Belzile, N., and Chen, Y. W. (2002). “Antimony in the environment: A review focused on natural waters II. Relevant solution chemistry.” Earth-Sci. Rev., 59(1–4), 265–285.
Florea, A. M., and Büsselberg, D. (2006). “Occurence, use, and potential toxic effects of metals and metal compounds.” BioMetals, 19(4), 419–427.
Flynn, H. C., Meharg, A. A., Bowyer, P. K., and Paton, G. I. (2003). “Antimony bioavailability in mine soils.” Environ. Pollut., 124(1), 93–100.
Fraga, C. G. (2005). “Relevance, essentiality, and toxicity of trace elements in human health.” Mol. Aspects Med., 26, 235–244.
Federal Remediation Technologies Roundtable (FRTR) (2005). Abstracts of remediation case studies, Vol. 9, FRTR, Washington, D.C.
Fu, F., Chen, R., and Xiong, Y. (2006). “Application of a novel strategy—Coordination polymerization precipitation to the treatment of Cu2+ -containing wastewaters.” Sep. Purif. Technol., 52(2), 388–393.
Fu, F., Chen, R., and Xiong, Y. (2007). “Comparative investigation of N, N -bis-(dithiocarboxy)piperazine and diethyldithiocarbamate as precipitants for Ni(II) in simulated wastewater.” J. Hazard. Mater., 140(1-2), 437–442.
Gaetke, L. M., and Chow, C. K. (2003). “Copper toxicity, oxidative stress, and antioxidant nutrients.” Toxicology, 189(1–2), 147–163.
Galvan-Arzete, S., and Santamaria, A. (1998). “Thallium toxicity.” Toxicol. Lett., 99(1), 1–13.
Galvin, R. M. (1996). “Occurrence of metals in waters: An overview.” Water SA, 22(1), 7–18.
Gans, P., Sabatini, A., and Vacca, A. (1996). “Investigation of equilibria in solution. Determination of equilibrium constants with the HYPERQUAD suite of programs.” Talanta, 43(10), 1739–1753.
Gardea-Torresdey, J. L., delaRosa, G., and PeraltaVidea, J. R. (2004). “Use of phytofiltration technologies in the removal of heavy metals: A review.” Pure Appl. Chem., 76(4), 801–813.
Gebel, T. (1997). “Arsenic and antimony: Comparative approach on mechanistic toxicology.” Chem. Biol. Interact., 107(3), 131–144.
Geckeler, K., and Volchek, K. (1996). “Removal of hazardous substances from water using ultrafiltration in conjunction with soluble polymers.” Environ. Sci. Technol., 30(3), 725–733.
Gitari, M. W., Petrik, L. F., Etchebers, O., Key, D. L., Iwuoha, E., and Okujeni, C. (2006). “Treatment of acid mine drainage with fly ash: Removal of major contaminants and trace elements.” J. Environ. Sci. Health, Part A: Toxic/Hazard. Subst. Environ. Eng., 41(8), 1729–1747.
Glaser, J. (1995). “Advances in thallium aqueous solution chemistry.” Adv. Inorg. Chem., 43, 1–78.
Goldhaber, S. B. (2003). “Trace element risk assessment: Essentiality versus toxicity.” Regul. Toxicol. Pharmacol., 38(2), 232–242.
Gomez del Rio, J., Sanchez, P., Morando, P. J., and Cicerone, D. S. (2006). “Retention of Cd, Zn, and Co on hydroxyapatite filters.” Chemosphere, 64(6), 1015–1020.
Guillard, D., and Lewis, A. E. (2002). “Optimization of nickel hydroxycarbonate precipitation using a laboratory pellet reactor.” Ind. Eng. Chem. Res., 41(13), 3110–3114.
Halim, C. E., Short, S. A., Scott, J. A., Amal, R., and Low, G. (2005). “Modeling the leaching of Pb, Cd, As, and Cr from cementitious waste using PHREEQC.” J. Hazard. Mater., 125(1-3), 46–61.
Hayes, P. C. (1985). Process selection in extractive metallurgy, Hayes, Brisbane, Australia.
Hendrickson, J. J., Benjamin, M. M., Ferguson, J. F., and Goebel, L. (1984). “Removal of silver and mercury from spent COD test solutions.” J. Water Pollut. Control Fed., 56(5), 468–473.
Henke, K. R. (1998). “Chemistry of heavy metal precipitates resulting from reactions with Thio-Red.” Water Environ. Res., 70(6), 1178–1185.
Henke, K. R., Hutchinson, A. R., Krepps, M. K., and Atwood, D. A. (2001). “The chemistry of 2,4,6-trimercapto-1,3,5-triazine (TMT): Acid dissolution constants and group 2 complexes.” Inorg. Chem., 40(17), 4443–4447.
HydroGeoLogic. (1998a). “Diffuse-layer sorption reactions for use in MINTEQA2 for HWIR metals and metalloids.” Rep., U.S. Environmental Protection Agency, National Exposure Research Laboratory, Ecosystem Research Division, Athens, Ga.
HydroGeoLogic. (1998b) “MINTEQA2/PRODEFA2, a geochemical assessment model for environmental systems: User manual supplement for version 4.0.” Rep. U.S. Environmental Protection Agency, National Exposure Research Laboratory, Ecosystem Research Division, Athens, Ga.
Islamoglu, S., Yilmaz, L., and Ozbelge, H. O. (2006). “Development of a precipitation-based separation scheme for selective removal and recovery of heavy metals from cadmium rich electroplating industry effluents.” Sep. Sci. Technol., 41(15), 3367–3385.
Jain, C. K., and Ali, I. (2000). “Arsenic: Occurence, toxicity and speciation techniques.” Water Res., 34(17), 4304–4312.
Jiang, J. Q. (2001). “Removing arsenic from groundwater for the developing world—A review.” Water Sci. Technol., 44(6), 89–98.
Juang, R. S., Lin, S. H., and Wang, T. Y. (2003). “Removal of metal ions from the complexed solutions in fixed bed using a strong acid ion exchange resin.” Chemosphere, 53(10), 1221–1228.
Juang, R. S., and Wang, S. W. (2000). “Electrolytic recovery of binary metals and EDTA from strong complexed solutions.” Water Res., 34(12), 3179–3185.
Jüttner, K., Galla, U., and Schmieder, H. (2000). “Electrochemical approaches to environmental problems in the process industry.” Electrochim. Acta, 45(15–16), 2575–2594.
Kabata-Pendias, A. (2001). Trace elements in soils and plants, 3rd Ed., A. Kabata-Pendias and H. Pendias eds., CRC, Boca Raton, Fla.
Kaksonen, A. H., Riekkola-Vanhanen, M. L., and Puhakka, J. A. (2003). “Optimization of metal sulphide precipitation in fluidized-bed treatment of acidic wastewater.” Water Res., 37(2), 255–266.
Kalin, M., Fyson, A., and Wheeler, W. N. (2006). “The chemistry of conventional and alternative treatment systems for the neutralization of acid mine drainage.” Sci. Total Environ., 366(2–3), 395–408.
Kamal, M., Ghaly, A. E., Mahmoud, N., and Côté, R. (2004). “Phytoaccumulation of heavy metals by aquatic plants.” Environ. Int., 29(8), 1029–1039.
Kapoor, A., and Viraraghavan, T. (1995). “Fungal biosorption—An alternative treatment option for heavy metal bearing wastewaters: A review.” Bioresour. Technol., 53(3), 195–206.
Kazantzis, G. (2000). “Thallium in the environment and health effects.” Environ. Geochem. Health, 22(4), 275–280.
Khan, D. H., and Frankland, B. (1983). “Chemical forms of Cd and lead in some contaminated soils.” Environ. Pollut. Ser. B., 6(1), 15–31.
Kharaka, Y. K., and Barnes, L. J. (1973). “SOLMNEQ: Solution-mineral equilibrium computations.” Rep. PB-215899, U.S. Geological Survey, Computer Contributions, National Technical Information Service, Washington, D.C.
Kharaka, Y. K., Gunter, W. D., Aggarwal, P. K., Perkins, E. H., and DeBraal, J. D. (1988). “SOLMNEQ.88: A computer program for geochemical modeling of water–rock interactions.” Rep. 88-4227, U.S. Geological Survey, Water Resources Investigations, Reston, Va.
Kim, B. M., and Amodeo, P. A. (1983). “Calcium sulphide process for treatment of metal-containing wastes.” Environ. Prog., 2, 175–180.
Kim, B. R., Gaines, W. A., Szafranski, M. J., Bernath, E. F., and Miles, A. M. (2002). “Removal of heavy metals from automotive wastewater by sulfide precipitation.” J. Environ. Eng., 128(7), 612–623.
Kobayashi, J. (1978). “Pollution by cadmium and the itai-itai disease in Japan.” Toxicity of heavy metals in the environment, F. W. Oehme, ed., Marcel Dekker, New York, 199–260.
Korfali, S. I., and Davies, B. E. (2004). “Speciation of metals in sediment and water in a river underlain by limestone: Role of carbonate species for purification capacity of rivers.” Adv. Environ. Res., 8(3–4), 599–612.
Kurniawan, T. A., Chan, G. Y. S., Lo, W. H., and Babel, S. (2006). “Comparisons of low-cost adsorbents for treating wastewaters laden with heavy metals.” Sci. Total Environ., 366(2-3), 409–426.
Lai, C. L., and Lin, K. S. (2006). “Sludge conditioning characteristics of copper chemical mechanical polishing wastewaters treated by electrocoagulation.” J. Hazard. Mater., 136(2), 183–187.
Lazaridis, N. K., Matis, K. A., and Webb, M. (2001). “Flotation of metal-loaded clay anion exchangers. Part I: The case of chromate.” Chemosphere, 42(4), 373–378.
Leist, M., Casey, R. J., and Caridi, D. (2000). “The management of arsenic wastes: Problems and prospects.” J. Hazard. Mater., 76(1), 125–138.
Leung, V. W. H., and Darvell, B. W. (1990). “The ramases algorithm for multiple equilibria. III: Acceleration and standardized formation constants (RAMASES II).” Talanta, 37(4), 425–429.
Levasseur, B., Blais, J. F., and Mercier, G. (2005). “Study of the metal precipitation from decontamination leachates of municipal wastes fly ash incinerators.” Environ. Technol., 26(4), 421–431.
Licskó, I. (1997). “Realistic coagulation mechanisms in the use of aluminium and iron(III) salts.” Water Sci. Technol., 36(4), 103–110.
Lin, S. H., Kao, H. C., Huang, S. H., and Juang, R. S. (2002). “Equilibrium and kinetic studies of the extraction of chelated copper(II) anions with Aliquat 336.” J. Chem. Technol. Biotechnol., 77(2), 168–174.
Lin, S. H., Lai, S. L., and Leu, H. G. (2000). “Removal of heavy metals from aqueous solution by chelating resin in a multistage adsorption process.” J. Hazard. Mater., 76(1), 139–153.
Lin, S. H., Wang, T. Y., and Juang, R. S. (2004). “Metal rejection by nanofiltration from diluted solutions in the presence of complexing agents.” Sep. Sci. Technol., 39(2), 363–376.
Lin, T. S., and Nriagu, J. O. (1998). “Speciation of thallium in natural waters.” Thallium in the environment., J. O. Nriagu, ed., Chap. 3, Wiley, New York, 31–43.
Lin, X., Burns, R. C., and Lawrance, G. A. (1998). “Effect of electrolyte composition, and of added iron(III) in the presence of selected organic complexing agents, on nickel(II) precipitation by lime.” Water Res., 32(12), 3637–3645.
Lippmann, M. (2000). Environmental toxicants. Human exposures and their health effects, Wiley, New York.
Liu, D. H. F., and Liptak, B. G. (1997). Environmental engineers’ handbook, CRC, Boca Raton, Fla.
Losi, M. E., Amrhein, C., and Frankenberger, W. T., Jr. (1994). “Bioremediation of chromate-contaminated groundwater by reduction and precipitation in surface soils.” J. Environ. Qual., 23(6), 1141–1150.
Mack, C., Burgess, J. E., and Duncan, J. R. (2004). “Membrane bioreactors for metal recovery from wastewater: A review.” Water SA, 30(4), 521–532.
Magalhaes, M. C. F. (2002). “Arsenic. An environmental problem limited by solubility.” Pure Appl. Chem., 74(10), 1843–1850.
Maine, M. A., Sune, N., Hadad, H., Sanchez, G., and Bonetto, C. (2006). “Nutrient and metal removal in a constructed wetland for wastewater treatment from a metallurgic industry.” Ecol. Eng., 26(4), 341–347.
Marchioretto, M. M., Bruning, H., and Rulkens, W. (2005). “Heavy metals precipitation in sewage sludge.” Sep. Sci. Technol., 40(16), 3393–3405.
Matlock, M. M., Henke, K. R., and Atwood, D. A. (2002). “Effectiveness of commercial reagents for heavy metal removal from water with new insights for future chelate designs.” J. Hazard. Mater., 92(2), 129–142.
Matlock, M. M., Henke, K. R., Atwood, D. A., and Robertson, D. (2001). “Aqueous leaching properties and environmental implications of cadmium, lead and zinc trimercaptotriazine (TMT) compounds.” Water Res., 35(15), 3649–3655.
Mavropoulos, E., Rossi, A. M., Costa, A. M., Perez, C. A. C., Moreira, J. C., and Saldanha, M. (2002). “Studies on the mechanisms of lead immobilization by hydroxyapatite.” Environ. Sci. Technol., 36(7), 1625–1629.
May, P. M., and Murray, K. (1991a). “JESS, a joint expert speciation system—I. Raison d’être.” Talanta, 38(12), 1409–1417.
May, P. M., and Murray, K. (1991b). “JESS, a joint expert speciation system—II. The thermodynamic database.” Talanta, 38(12), 1419–1426.
May, P. M., Murray, K., and Williams, D. R. (1985). “The use of glass electrodes for the determination of formation constants—II. Simulation of titration data.” Talanta, 32(6), 483–489.
McAnally, S., Benefield, L., and Reed, R. B. (1984). “Nickel removal from a synthetic nickel-plating waste water using sulphide and carbonate for precipitation and coprecipitation.” Sep. Sci. Technol., 19(11), 191–217.
McDuff, R. E., and Morel, E. M. (1973). “Description and use of the chemical equilibrium program REDEQL2.” Technical Rep. EQ-73-02, California Institute of Technology, Pasadena, Calif.
McGowen, S. L., Basta, N. T., and Brown, G. O. (2001). “Use of diammonium phosphate to reduce heavy metal solubility and transport in smelter-contaminated soil.” J. Environ. Qual., 30(2), 493–500.
McLaughlin, M. J., Zarcinas, B. A., Stevens, D. P., and Cook, N. (2000). “Soil testing for heavy metals.” Commun. Soil Sci. Plant Anal., 31(11–14), 1661–1700.
Meers, E., Unamuno, V. R., Du Laing, G., Vangronsveld, J., Vangroekhoven, K., Samson, R., Diels, L., Geebelen, W., Ruttens, A., Vandegehuchte, M., and Tack, F. M. G. (2006). “Zn in the soil solution of unpolluted soils as affected by soil characteristics.” Geoderma, 136(1–2), 107–119.
Mercier, G., Duchesne, J., and Carles-Gibergues, A. (2002). “A simple and fast screening test to detect soils polluted by lead.” Environ. Pollut., 118(3), 285–296.
Meunier, N., Blais, J. F., Lounes, M., Tyagi, R. D., and Sasseville, J. L. (2002). “Different options for metal recovery after sludge decontamination at the Montreal Urban Community wastewater treatment plant.” Water Sci. Technol., 46(10), 33–41.
Meunier, N., Drogui, P., Gourvenec, C., Mercier, G., Hausler, R., and Blais, J. F. (2004). “Removal of metals in leachate from sewage sludge using electrochemical technology.” Environ. Technol., 25(2), 235–245.
Meunier, N., Drogui, P., Montane, C., Hausler, R., Mercier, G., and Blais, J. F. (2006). “Comparison between electrocoagulation and chemical precipitation for metals removal from acidic soil leachate.” J. Hazard. Mater., 137(1), 581–590.
Mirbagheri, S. A., and Hosseini, S. N. (2004). “Pilot plant investigation on petrochemical wastewater treatment for the removal of copper and chromium with the objective of reuse.” Desalination, 171(1), 85–93.
Moller, A., Grahn, A., and Welander, U. (2004). “Precipitation of heavy metals from landfill leachates by microbially-produced sulphide.” Environ. Technol., 25(1), 69–77.
Mondal, B. C., and Das, A. K. (2004). “Functionalized chelating resins for selective sorption of metal ions: An overview.” J. Indian Chem. Soc., 81(2), 95–110.
Müller, B. (1996). CHEMEQL, version 2.0: User’s guide to application, Swiss Federal Institute of Environmental Sciences and Technology, Dübendorf, Switzerland.
Naeem, A., Mustafa, S., Dilara, B., Rehana, N., and Murtaza, S. (2003). “Effect of precipitation on the sorption of metal cations by AlPO4 .” J. Chem. Soc. Pakistan, 25(2), 98–103.
Navaro, R. R., Wada, S., and Tatsumi, K. (2005). “Heavy metal precipitation by polycation–polyanion complex of PEI and its phosphonomethylated derivative.” J. Hazard. Mater., 123, 203–209.
Nelson, A., Wang, W., Demopoulos, G. P., and Houlachi, G. (2000). “The removal of cobalt from zinc electrolyte by cementation: A critical review.” Miner. Process. Extr. Metall. Rev., 20(4), 325–356.
Nielsen, P. B., Christensen, T. C., and Vendrup, M. (1997). “Continuous removal of heavy metals from FGD wastewater in a fluidized bed without sludge generation.” Water Sci. Technol., 36(2-3), 391–397.
Nriagu, J. (1974). “Lead orthophosphates—IV. Formation and stability in the environment.” Geochim. Cosmochim. Acta, 38, 887–898.
Nriagu, J. (1996). “A history of global metal pollution.” Science, 272, 223–224.
Nriagu, J. O., and Pacyna, J. M. (1988). “Quantitative assessment of world-wide contamination of air, water, and soils by trace metals.” Nature (London), 333, 134–139.
Papadopoulos, A., Fatta, D., Parperis, K., Mentzis, A., Haralambous, K. J., and Loizidou, M. (2004). “Nickel uptake from a wastewater stream produced in a metal finishing industry combination of ion-exchange and precipitation methods.” Sep. Purif. Technol., 39(3), 181–188.
Papelis, C., Hayes, K. F., and Leckie, J. O. (1988). “HYDRAQL: A program for the computation of chemical equilibrium composition of aqueous batch systems including surface-complexation modeling of ion adsorption at the oxide/solution interface.” Technical Rep. 306, Dept. of Civil Engineering, Stanford Univ., Stanford, Calif.
Parkhurst, D., and Appelo, C. (1999). “User’s guide to PHREEQC (version 2.4.2). A computer program for speciation, batch reaction, one-dimensional transport and inverse geochemical calculations.” Rep. 99-4259, U.S. Geological Survey, Water Resources Investigations, Reston, Va.
Parkhurst, D. L., Thorstenson, D. C., and Plummer, L. N. (1980). “PHREEQE. A computer program for geochemical calculations.” Rep. 80-96, U.S. Geological Survey, Water Resources Investigations, Reston, Va.
Patterson, J. W. (1988). “Metal treatment and recovery.” Metal speciation: Theory, analysis and application, J. R. Kramer, and H. E. Allen, eds., Lewis, Chelsea, Mich., 333–345.
Pigaga, A., Juskenas, R., and Selkis, A. (2002). “Waste treatment of two electroplating solutions of Cu and Zn by mixing and precipitation.” Sep. Purif. Technol., 37(13), 3155–3168.
Plummer, L. N., Parkhurst, D. L., Fleming, G. W., and Dunkle, S. A. (1988). “A computer program incorporating Pitzer’s equations for calculation of geochemical reactions in brine.” Rep. 88-4153, U.S. Geological Survey, Water-Resources Investigations, Reston, Va.
Plummer, L. N., Prestemon, E. C., and Parkhurst, D. L. (1991). “An interactive code (NETPATH) for modeling net geochemical reactions along a flow path.” Rep. 91-4-78, U.S. Geological Survey, Water-Resources Investigations, Reston, Va.
Plummer, L. N., Prestemon, E. C., and Parkhurst, D. L. (1994). “An interactive code (NETPATH) for modeling net geochemical reactions along a flow path version 2.0.” Rep. 94-4169, U.S. Geological Survey, Water-Resources Investigations, Reston, Va.
Porter, S. K., Scheckel, K. G., Impellitteri, C. A., and Ryan, J. A. (2004). “Toxic metals in the environment: Thermodynamic considerations for possible immobilization strategies for Pb, Cd, As, and Hg.” Crit. Rev. Environ. Sci. Technol., 34(6), 495–604.
Preis, W., and Gamsjager, H. (2001). “Thermodynamic investigation of phase equilibria in metal carbonate-water-carbon dioxide systems.” Chem. Monthly, 132(11), 1327–1346.
Purcell, T. W., and Peters, J. J. (1998). “Sources of silver in the environment.” Envir. Toxicol. Chem., 17(4), 539–546.
Ratte, H. T. (1999). “Bioaccumulation and toxicity of silver compounds: A review.” Envir. Toxicol. Chem., 18(1), 89–108.
Robinson, A. K., and Sum, J. C. (1980). “Sulphide precipitation of heavy metals.” EPA/600/2-80/139, U.S. Environmental Protection Agency, Washington, D.C.
Romera, E., Gonzalez, F., Ballester, A., Blazquez, M. L., and Munoz, J. A. (2006). “Biosorption with algae: A statistical review.” Crit. Rev. Biotechnol., 26(4), 223–235.
Romero, R., and Joensson, J. A. (2005). “Determination of free copper concentrations in natural waters by using supported liquid membrane extraction under equilibrium conditions.” Anal. Bioanal. Chem., 381(7), 1452–1459.
Sankhesara, B. M., and Kamath, P. R. (1980). “Effluent treatment for pollutants management—Processing of beryl.” Chem. Eng. World, 15(7), 29–34.
Sasidhar, P., Ayengar, B., Anand Babu, C., Siriah, H. N., Lal, K. B., and Amalraj, R. V. (1991). “Coprecipitation of selenites from acidic effluents.” Indian J. Environ. Health, 33(4), 440–444.
Savage, D. (1986). “The geochemical interactions of simulated borosilicate waste glass, granite, and water at 100°350°C and 50MPa .” Nuclear Chem. Waste Manage., 6(1), 15–39.
Semerjian, L., and Ayoub, G. M. (2003). “High-pH-magnesium coagulation–flocculation in wastewater treatment.” Adv. Environ. Res., 7(2), 389–403.
Sharma, R. K., and Agrawal, M. (2005). “Biological effects of heavy metals: An overview.” J. Environ. Biol., 26(2), 301–313.
Sheoran, A. S., and Sheoran, V. (2006). “Heavy metal removal mechanism of acid mine drainage in wetlands: A critical review.” Minerals Eng., 19(2), 105–116.
Silva, J. E., Paiva, A. P., Soares, D., Labrincha, A., and Castro, F. (2005). “Solvent extraction applied to the recovery of heavy metals from galvanic sludge.” J. Hazard. Mater., 120(1-3), 113–118.
Smith, L. A., Means, J. L., Chen, A., Alleman, B., Chapman, C. C., Tixier, J. S., Brauning, S. E., Gavaskar, A. R., and Royer, M. D. (1995). Remedial options for metals-contaminated sites, Lewis, Boca Raton, Fla.
Sposito, G., and Coves, J. (1988). SOILCHEM: A computer program for the calculation of chemical speciation in soils, University of California, Riverside, Calif.
Sposito, G., and Matigod, S. (1977). GEOCHEM: A computer program for the calculation of chemical equilibria in soil solutions and other natural water systems.” University of California, Riverside, Calif.
Sposito, G., and Matigod, S. (1980). GEOCHEM: Computer program for the calculation of chemical equilibria in soil solutions and other natural water systems, University of California, Riverside, Calif.
Suarez, D. L., and Goldberg, S. (1994). “Modeling soil solution, mineral formation, and weathering.” Quantitative modeling of soil forming processes, Chap. 3, Soil Science Society of America, Madison, Wis., 37–60.
Sulzbacher, K., Ecke, H., Lagerkvist, A., and Calmano, W. (1997). “Anaerobic reduction of hexavalent chromium in filter sludge of an electrochemical process.” Environ. Technol., 18(3), 301–307.
Sun, J., and Huang, J. C. (2002). “Co-removal of hexavalent chromium during copper precipitation.” Water Sci. Technol., 46(4-5), 413–419.
Tandrus, M. E. (2000). “A review of metal precipitation chemicals for metal-finishing applications.” Met. Finish., 111, 20–23.
Tauler, R., and Casassas, E. (1988). “A simplex search for conditions giving maximal and/or minimal concentrations of species in distribution plots.” Anal. Chim. Acta, 206, 189–202.
Taylor, T. P., Ding, M., Ehler, D. S., Foreman, T. M., Kaszuba, J. P., and Sauer, N. N. (2003). “Beryllium in the environment: A review.” J. Environ. Sci. Health, Part A: Toxic/Hazard. Subst. Environ. Eng., 38(2), 439–469.
Terlecka, E. (2005). “Arsenic speciation analysis in water samples: A review of the hyphenated techniques.” Environ. Monit. Assess., 107(1–3), 259–284.
Thrailkill, J. (1970). “Solution geochemistry of the water of limestone terrains.” Rep. 19, Water Resources Institute of Research, Univ. of Kentucky, Lexington, Ky.
Tinggi, U. (2003). “Essentiality and toxicity of selenium and its status in Australia: A review.” Toxicol. Lett., 137, 103–110.
Tipping, E. (1998). “Humic ion-binding model VI: An improved description of the interactions of protons and metal ions with humic substances.” Aqueous Geochem., 4(1), 3–48.
Truesdell, A. H., and Jones, B. F. (1974). “WATEQ, a computer program for calculating chemical equilibria of natural waters.” J. Res. U.S. Geol. Surv., 2(2), 233–248.
Twidwell, L. G., and Williams-Beam, C. (2002). “Potential technologies for removing thallium from mine and process wastewater: An abbreviated annotation of the literature.” Eur. J. Min. Proc. Environ. Protect, 2(1), 1–10.
U.S. Environmental Protection Agency (USEPA). (1992). “Mercury and arsenic wastes. Removal, recovery, treatment, and disposal.” Pollution Technology Review No. 214, Noyes Data Corporation, Park Ridge, N.J.
U.S. Environmental Protection Agency (USEPA). (1993). “Constructed wetlands-based treatment.” EPA/540/R-93/523, USEPA, Agency, Washington, D.C.
U.S. Environmental Protection Agency (USEPA). (2000). “Chemical precipitation.” EPA/832/F-00/018, USEPA, Washington, D.C.
U.S. Environmental Protection Agency (USEPA). (2004). “Test methods for evaluating solid waste, physical/chemical methods.” EPA SW-846. USEPA, Washington, D.C.
Van der Lee, J., and De Windt, L. (2000). “CHESS tutorial and cookbook. User’s guide.” Rep. LHM/RD/99/05, CIG-École des Mines de Paris, Fontainebleau, France.
Vanbroekhoven, K., Dejonghe, W., and Diels, L. (2005). “Treatment of contaminated soil and groundwater: In situ immobilization of metals.” Soil and sediment remediation. Mechanisms, technologies, and applications, Chap. 13, P. Lens, T. Grotenhuis, G. Malina, and H. Tabak, eds., IWA, London, 248–263.
VanRoy, S., Vanbroekhoven, K., Dejonghe, W., and Diels, L. (2006). “Immobilization of heavy metals in the saturated zone by sorption and in situ bioprecipitation processes.” Inf. Technol. Manage., 83(1-4), 195–203.
Veeken, A. H. M., and Rulkens, W. H. (2003). “Innovative developments in the selective removal and reuse of heavy metals from wastewaters.” Water Sci. Technol., 47(10), 9–16.
Vesely, J., Norton, S. A., Skrivan, P., Majer, V., Kram, P., Navratil, T., and Kaste, J. M. (2002). “Environmental chemistry of beryllium.” Rev. Mineral. Geochem., 50, 291–317.
Viadero, R. C., Wei, X. C., and Buzby, K. M. (2006). “Characterization and dewatering evaluation of acid mine drainage sludge from ammonia neutralization.” Environ. Eng. Sci., 23(4), 734–743.
Vig, K., Megharaj, M., Sethunathan, N., and Naidu, R. (2003). “Bioavailability and toxicity of cadmium to microorganisms and their activities in soil: A review.” Adv. Environ. Res., 8(1), 121–135.
Wang, S., and Shi, X. (2001). “Molecular mechanisms of metal toxicity and carcinogenesis.” Mol. Cell. Biochem., 222(1–2), 3–9.
Wang, Y. H., Lin, S. H., and Juang, R. S. (2003). “Removal of heavy metal ions from aqueous solutions using various low-cost adsorbents.” J. Hazard. Mater., 102(2-3), 291–302.
Watts, R. J. (1998). Hazardous wastes. Sources, pathways, receptors, R. J. Watts, ed., Wiley, New York.
Westall, J. C. (1979). “MICROQL. 1. A chemical equilibrium program in BASIC. II. Computation of adsorption equilibria in BASIC.” Technical Rep., Swiss Federal Institute of Environmental Sciences and Technology, Dübendorf, Switzerland.
Westall, J. C. (1982). “FITEQL. A computer program for determination of equilibrium constants from experimental data.” Rep. 82-01, Department of Chemistry, Oregon State University, Corvallis, Ore.
Westall, J. C., Zachary, J. L., and Morel, F. M. N. (1976). “MINEQL: A computer program for the calculation of chemical equilibrium composition of aqueous systems.” Technical Note 18, Massachusetts Institute of Technology, Cambridge, Mass.
White, C., Sharman, A. K., and Gadd, G. M. (1998). “An integrated microbial process for the bioremediation of soil contaminated with toxic metals.” Nat. Biotechnol., 16(6), 572–575.
Wildeman, T., Gusek, J., Cevaal, J., Whiting, K., and Scheuering, J. (1995). Bioremediation of inorganics, R. E. Hinchee, J. L. Means, and D. R. Burris, eds., Battelle, Columbus, Ohio, 141–148.
Williams, J. W., and Silver, S. (1984). “Bacterial resistance and detoxification of heavy metals.” Enzyme Microb. Technol., 6, 530–537.
Windholz, M., Budavari, S., Blumetti, R. F., and Otterbein, E. S. (1983). The Merck index. An encyclopedia of chemicals, drugs, and biologicals, 10th Ed., Merck, Rahway, N.J.
Winge, D. R., and Mehra, R. K. (1990). “Host defenses against copper toxicity.” Int. Rev. Exp. Pathol., 31, 47–83.
Wingenfelder, U., Hansen, C., Furrer, G., and Schulin, R. (2005). “Removal of heavy metals from mine water by natural zeolites.” Environ. Sci. Technol., 39(12), 4606–4613.
Wolery, T. (1992). “EQ3NR, a computer program for geochemical aqueous speciation–solubility calculations: Theoretical manual, user’s guide and related documentation (version 7.0).” Rep. UCRL-MA-110662 PT III, Lawrence Livermore National Laboratory, Livermore, Calif.
Wolery, T., and Daveler, S. A. (1992). “EQ6, a computer program for reaction path modeling of aqueous geochemical systems: Theoretical manual, user’s guide and related documentation (version 7.0).” Rep. UCRL-MA-110662 PT IV, Lawrence Livermore National Laboratory, Livermore, Calif.
Wong, C. S. C., Li, X. D., and Thornton, I. (2006). “Urban environmental geochemistry of trace metals.” Environ. Pollut., 142(1), 1–16.
Ying, X., and Fang, Z. (2006). “Experimental research on heavy metal wastewater treatment with dipropyl dithiophosphate.” J. Hazard. Mater., 137(3), 1636–1642.
Zahir, F., Rizwi, S. J., Haq, S. K., and Khan, R. H. (2005). “Low-dose mercury toxicity and human health.” Environ. Toxicol. Pharmacol., 20(2), 351–360.
Zamboulis, D., Pataroudi, S. I., Zouboulis, A. I., and Matis, K. A. (2004). “The application of sorptive flotation for the removal of metal ions.” Desalination, 162(1–3), 159–168.
Zeng, Q. R., Sauvé, S., Allen, H. E., and Hendershot, W. H. (2005). “Recycling EDTA solutions used to remediate metal-polluted soils.” Environ. Pollut., 133(2), 225–231.
Zhou, P., Huang, J. C., Li, A. W. F., and Wei, S. (1999). “Heavy metal removal from wastewater in fluidized bed reactor.” Water Res., 33(8), 1918–1924.
Zimdahl, R. L., and Skogerboe, R. K. (1977). “Behavior of lead in soils.” Environ. Sci. Technol., 11(13), 1202–1207.
Zinck, J. M., and Aubé, B. C. (2000). “Optimization of lime treatment processes.” CIM Bull., 93(1043), 98–105.

Information & Authors

Information

Published In

Go to Practice Periodical of Hazardous, Toxic, and Radioactive Waste Management
Practice Periodical of Hazardous, Toxic, and Radioactive Waste Management
Volume 12Issue 3July 2008
Pages: 135 - 149

History

Received: May 1, 2007
Accepted: Jul 26, 2007
Published online: Jul 1, 2008
Published in print: Jul 2008

Permissions

Request permissions for this article.

Authors

Affiliations

J. F. Blais
Institut National de la Recherche Scientifique (INRS-ETE), Univ. du Québec, 490, Rue de la Couronne, Québec QC, Canada GIK 9A9 (corresponding author). E-mail: [email protected]
Z. Djedidi
Institut National de la Recherche Scientifique (INRS-ETE), Univ. du Québec, 490, Rue de la Couronne, Québec QC, Canada GIK 9A9.
R. Ben Cheikh
Ecole Nationale d’Ingenieurs de Tunis, B.P. 37, Le Belvedere, 1002 Tunis, Tunisie.
R. D. Tyagi
Institut National de la Recherche Scientifique (INRS-ETE), Univ. du Québec, 490, Rue de la Couronne, Québec QC, Canada GIK 9A9.
G. Mercier
Institut National de la Recherche Scientifique (INRS-ETE), Univ. du Québec, 490, Rue de la Couronne, Québec QC, Canada GIK 9A9.

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share