TECHNICAL PAPERS
Jan 1, 2006

Simulation of Lead Ions Adsorption onto the Iron-Coated Medium: Dependent on Temperature and pH

Publication: Practice Periodical of Hazardous, Toxic, and Radioactive Waste Management
Volume 10, Issue 1

Abstract

Heat was employed to coat crystalline goethite onto a quartz sand surface so that the adsorbent properties of the coating could be utilized. Adsorption experiments were conducted to further demonstrate the adsorption of lead ions by goethite-coated medium under various temperatures and pH, respectively. The adsorption reaction between iron-coated medium and lead ions was simulated by a cation exchange model. Results indicated that the solution temperature and pH had a noticeable effect on the final adsorption capacity for lead ions. The pH-adsorption edges were shifted to lower pH values with increasing temperature. The adsorption reaction between lead ions and goethite-coated medium was an endothermic process. A cation exchange model applied to the regression model of experimental data was fitted very well. A high correlation coefficient (r2=0.91) and an extreme low p -value (7.02×1082) indicated that the variance of dependent variable, adsorption capacity of iron-coated medium could be firmly explained by independent variables such as [Pb+n] , temperature and [H+] .

Get full access to this article

View all available purchase options and get full access to this article.

Acknowledgments

The writers express their gratitude to the National Science Council of the Republic of China (Contract Nos. UNSPECIFIEDNSC 93-2211-E-242-009 and UNSPECIFIEDNSC 94-2211-E-242-007) for its financial support.

References

Adamson, W. (1982). Physical chemistry of surfaces, 4th Ed., Wiley, New York, 371.
Angove, M. J., Well, J. D., and Johnson, B. B. (1999). “The influence of temperature on the adsorption of cadmium and cobalt on goethite.” J. Colloid Interface Sci., 211, 218–290.
Baes, A. U., Okuda, T., Nishijima, W., Shoto, E., and Okada, M. (1997). “Adsorption and ion exchange of some groundwater anion contaminants in the amine modified coconut coir.” Water Sci. Technol., 35(7), 89–96.
Baker, H., and Khalili, F. (2004). “Analysis of the removal of lead(II) from aqueous solutions by adsorption onto insolubilized humic acid: Temperature and pH dependence.” Anal. Chim. Acta, 516, 179–186.
Benjamin, M. M., and Leckie, J. O. (1981). “Multiple site adsorption of Cd, Cu, Zn and Pb on amorphous iron oxyhydroxide.” J. Colloid Interface Sci., 79, 209–215.
Benjamin, M. M., Sletten, R. S., Bailey, R. P., and Bennett, T. (1996). “Sorption and filtration of metals using iron-oxide-coated sand.” Water Res. 30(11), 2609–2619.
Edwards, M., and Benjamin, M. M. (1989). “Adsorptive filtration using coated sand: A new approach for treatment of metal-bearing wastes.” J. Water Pollut. Control Fed., 61(9), 1523–1533.
Hillel, D. (1980). Fundamentals of soil physics, Academic, New York, 83.
Hsia, T. H., Lo, S. L., Lin, C. F., and Lee, D. Y. (1994). “Characterization of arsenate adsorption on hydrous iron oxide using chemical and physical methods.” Colloids Surf., A, 85, 1–7.
Joshi, A., and Chaudhuri, M. (1996). “Removal of arsenic from ground water by iron oxide-coated sand.” J. Environ. Eng., 122(8), 769–771.
Lai, C. H., and Chen, C. Y. (2001). “Removal of metal ions and humic acid from water by iron-coated filter media.” Chemosphere, 41, 1177–1184.
Lai, C. H., Chen, C. Y., Shih, P. H., and Hsia, T. H., (2000a). “Competitive adsorption of copper and lead ions on an iron-coated sand from water.” Water Sci. Technol., 42(3–4), 149–154.
Lai, C. H., Chen, C. Y., Wei, B. L., and Yeh, S. H. (2002). “Cadmium adsorption on the goethite-coated sand in the presence of humic acid.” Water Res., 36, 4943–4950.
Lai, C. H., Lo, S. L., and Chiang, H. L., (2000b). “Adsorption/desorption properties of copper ions on the surface of the iron-coated sand using BET and EDAX analyses.” Chemosphere, 41, 1249–1255.
Martins, R. J. E., Pardob, R., and Boaventurab, R. A. R. (2004). “Cadmium(II) and zinc(II) adsorption by the aquatic moss Fontinalis antipyretica: Effect of temperature, pH and water hardness.” Water Res., 38, 693–699.
McKenzie, R. M. (1980). “The adsorption of lead and other heavy metals on oxides of manganese and iron.” J. Soil Res., 18, 61–73.
Rodda, D. P., Jonson, B. B., and Well, J. D. (1993). “The effect of temperature and pH on the adsorption of copper, lead, and zinc onto goethite.” J. Colloid Interface Sci., 161, 57–62.
Schwertmann, U., and Taylor, R. M. (1989). “Iron oxides.” Minerals in soil environments, J. B. Dixon and S. B. Weed, eds., 2nd Ed., Soil Science Society America Journal, Madison, Wis., 379–428.
Sharma, Y. C. (2001). “Effect of temperature on interfacial adsorption of Cr(VI) on wollastonite.” J. Colloid Interface Sci., 233, 265–270.
Singh, D. B., Rupainwar, D. C., Prasad, G., and Jayaprakas, K. C. (1998). “Study on the Cd removal from water by adsorption.” J. Hazard. Mater., 60, 29–40.
Singh, D. K., Tiwari, D. P., and Saksena, D. N. (1993). “Removal of lead from aqueous solutions by chemically treated used tea leaves.” Indian J. Environ., 35(3), 169–177.
Sparks, D. L. (1995). Environmental soil chemistry, Academic, New York, 156.

Information & Authors

Information

Published In

Go to Practice Periodical of Hazardous, Toxic, and Radioactive Waste Management
Practice Periodical of Hazardous, Toxic, and Radioactive Waste Management
Volume 10Issue 1January 2006
Pages: 28 - 32

History

Received: Jul 25, 2005
Accepted: Jul 25, 2005
Published online: Jan 1, 2006
Published in print: Jan 2006

Permissions

Request permissions for this article.

Authors

Affiliations

Professor, Dept. of Environmental Engineering and Science, Fooyin Univ., Kaohsiung 831, Taiwan, Republic of China (corresponding author). E-mail: [email protected]
C. K. Gao
Associate Professor, Dept. of Environmental Engineering and Science, Fooyin Univ., Kaohsiung 831, Taiwan, Republic of China.
T. T. Lin
Associate Professor, Dept. of Civil Engineering, National Kaohsiung Univ. of Applied Science, Kaohsiung 807, Taiwan, Republic of China.
S. H. Yeh
Lecturer, Dept. of Healthcare Administration, Fooyin Univ., Kaohsiung 831, Taiwan, Republic of China.
C. Y. Chen
Associate Professor, Dept. of Environmental Engineering and Science, Fooyin Univ., Kaohsiung 831, Taiwan, Republic of China.
M. K. Wang
Professor, Dept. of Agricultural Chemistry, National Taiwan Univ., Taipei 106, Taiwan, Republic of China.

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share