Application of Fenton’s Reagent to Remediate Diesel Contaminated Soils
Publication: Practice Periodical of Hazardous, Toxic, and Radioactive Waste Management
Volume 10, Issue 1
Abstract
This paper presents the results of an experimental investigation into usage of Fenton’s reagent (a mixture of ferrous salts and hydrogen peroxide) to remediate diesel-impacted soils. A number of process variables such as the presence of iron salts, comparison between ferrous and ferric salts, amount of diesel washed out and mineralized and the use of surfactant to augment the treatment were investigated. Additionally, studies were conducted to evaluate the in-situ injection technique for remediation of diesel-impacted soil using and also its effect on the hydraulic conductivity of the soil. The results indicate that external amendment of iron is not necessary in soils containing iron, and that concentration and volume of were important process variables in modified Fenton’s reaction. The hydraulic conductivity of the soil for was significantly lower than that of water due to generation of gas and other reaction products, which blocked the pores. In some experiments, injection of into the soil matrix met with resistance due to gas generation and the moved up along the sides of the injector.
Get full access to this article
View all available purchase options and get full access to this article.
Acknowledgment
The writers would like to thank NSERC for providing financial assistance in conducting this research.
References
American Petroleum Institute (API. (2002). “Monthly petroleum fact at a glance.” API statistics, ⟨http://api-ec.api.org/industry⟩ (Nov. 2002).
Bishop, D. F., Stern, G., Fleischman, M., and Marshall, L. S. (1968). “Hydrogen peroxide catalytic oxidation of refractory organics in municipal waste waters.” I&EC Process Des. Dev., 7(1), 110–117.
Chen, C. T., Tafuri, A. N., Rahman, M., and Forest, M. B. (1998). “Chemical oxidation treatment of petroleum contaminated soil using Fenton’s reagent.” J. Environ. Sci. Health, 33, 987–1008.
Gabr, M. A., Chen, J., and Thomas, R. (1998). “Soil clogging during surfactant-enhanced flushing of naphthalene-contaminated sand-kaolinite.” Can. Geotech. J., 35, 976–985.
Huling, S. G., Arnold, R. G., Jones, P. K., and Sierka, R. A. (2000). “Predicting Fenton-driven degradation using contaminant analog.” J. Environ. Eng., 126(4), 348–353.
Kolthoff, I. M., Sandell, E. B., Meehan, E. J., and Bruckenstein, S. (1969). Quantitative chemical analysis, 4th Ed., MacMillan, London.
Lou, J. C., and Lee, S. S. (1995). “Chemical oxidation of BTX using Fenton’s reagent.” Hazard. Waste Hazard. Mater., 2(2), 185–193.
Lyman, W. J., Noonan, D. C., and Reidy, P. J. (1990). Cleanup of petroleum contaminated soils at underground storage tanks, Noyes Data Corporation, Park Ridge, N.J.
Mahmoud, M., McCormick, M., Dickie, R. W., McClymont, G., and Stokes-Rees, P. (2000). “Hydrogen peroxide in cleanup of residual hydrocarbons adjacent to structures with restricted access.” Proc., 53rd Canadian Geotechnical Conf., Vol. 1, Montreal, 575–584.
Nesheiwat, F. K., and Swanson, A. G. (2000). “Cleaning contaminated sites using Fenton’s reagent.” Chem. Eng. Prog., 61–66.
Paya-Perez, M. S., Rahman, H., Skejo-Andresen, X., and Larsen, B. R. (1996). “Surfactant solubilization of hydrophobic compounds in soil and water.” Environ. Sci. & Res., 3(4), 183–188.
Sedlak, D. L., and Andren, A. W. (1991). “Oxidation of chlorobenzene with Fenton’s reagent.” Environ. Sci. Technol., 25(4), 777–182.
Tang, W. Z., and Huang, C. P. (1996). “2,4-Dichlorophenol oxidation kinetics by Fenton’s reagent.” Environ. Technol., 17, 1371–1378.
Tyre, B. W., Watts, R. J., and Miller, G. C. (1991). “Treatment of four biorefractory contaminants in soils using catalyzed hydrogen peroxide.” J. Environ. Qual., 20, 832–838.
Walling, C. (1975). “Fenton’s reagent revisited.” Acc. Chem. Res., 8, 125–131.
Watts, R. J. (1992). “Hydrogen peroxide for physiochemically degrading petroleum-contaminated soils.” Remediation, Autumn, 413–425.
Watts, R. J., and Dilly, S. E. (1996). “Evaluation of iron catalysts for the Fenton-like remediation of diesel-contaminated soils.” J. Hazard. Mater., 51, 209–224.
Watts, R. J., and Dilly, S. E. (1999). “Fenton-like remediation catalyzed by naturally occurring iron minerals.” Environ. Eng. Sci., 16(1), 93–103.
Wisconsin Department of Natural Resource (DNR. (1995). “Modified DRO method for determining diesel range organics.” PUBL-SW-141, Wis.
Information & Authors
Information
Published In
Copyright
© 2006 ASCE.
History
Received: Jun 29, 2004
Accepted: Jul 4, 2005
Published online: Jan 1, 2006
Published in print: Jan 2006
Authors
Metrics & Citations
Metrics
Citations
Download citation
If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.