TECHNICAL PAPERS
Jan 1, 2009

Effectiveness of Fly Ash and Slag in Mitigating Alkali–Silica Reaction Induced by Deicing Chemicals

Publication: Journal of Materials in Civil Engineering
Volume 21, Issue 1

Abstract

Recent studies have shown that potassium acetate based deicers are capable of triggering deleterious expansion and cracking in concrete specimens containing alkali–silica reactive (ASR) aggregates. This paper presents the results and analysis from a research study conducted to evaluate the effectiveness of fly ash and ground granulated blast furnace slag (slag) in mitigating expansions induced by ASR in the presence of a potassium acetate based deicer. Standard and modified ASTM C 1260 and 1567 tests were conducted on mortar specimens prepared with five aggregates to study the mitigation behavior of fly ashes and slag. In this study, fly ash was evaluated at 15, 25, and 35%, and slag at 40 and 50% by mass replacement of cement. Changes in length, dynamic elastic modulus, and microstructure of the mortar bars were studied. Results from these studies indicate that low- and intermediate-lime fly ashes were more effective than high-lime fly ash at 25 and 35% cement replacement levels. High-lime fly ash was ineffective even at a replacement level of 35%. Slag at 50% cement replacement was more effective in mitigating expansions compared to 40% dosage level.

Get full access to this article

View all available purchase options and get full access to this article.

Acknowledgments

The support of Innovative Pavements Research Foundation (IPRF) and FAA for this project is gratefully acknowledged. Thanks are also extended to ISG Resources, Inc. and Holcim, Inc. for providing the SCMs.

References

American Concrete Pavement Association (ACPA). (2005). “Alkali-silica reaction: Old issue, new cause” R & T Update, ACPA, Skokie, Ill.
ASTM. (2001a). “Standard test method for determination of length change of concrete due to alkali-silica reaction.” ASTM book of standard volumes 04.02, ASTM C 1293-01, West Conshohocken, Pa.
ASTM. (2001b) “Standard test method for dynamic Young’s modulus, shear modulus, and Poisson’s ratio by impulse excitation of vibration.” ASTM book of standard volumes 03.01, ASTM E 1876-01, West Conshohocken, Pa.
ASTM. (2003). “Standard guide for petrographic examination of aggregates for concrete.” ASTM book of standard volumes 04.02, ASTM C 295-03, West Conshohocken, Pa.
ASTM. (2004a) “Standard test method for determining the potential alkali-silica reactivity of combination of cementitious materials and aggregates (accelerated mortar-bar method).” ASTM book of standard volumes 04.02, West Conshohocken, Pa.
ASTM. (2004). “Standard test method for potential alkali reactivity of aggregates (mortar bar method).” ASTM book of standard volumes 04.02, West Conshohocken, Pa., 680–684.
Barringer, W. L. (2000). “Application of accelerated mortar bar tests to New Mexico aggregates.” Proc., 11th Int. Conf. on Alkali-Aggregate Reactions in Concrete, M. A. Berube, B. Fournier, and B. Durand, eds., Center de Recherche Interuniversitaire sur le Beton (CRIB), Department de genie civil, Universite Laval, Sainte-Foy, Quebec, Canada, 563–572.
Detwiler, R. J. (2003). “PCA’s guide specification for concrete subject to alkali-silica reaction: mitigation measures.” R&D Serial No. 2407, Portland Cement Association, Skokie, Ill.
Duschene, J., and Berube, M. A. (2001). “Long term effectiveness of supplementary cementing materials against alkali-silica reaction.” Cem. Concr. Res., 31(7), 1057–1063.
Folliard, K. J., Thomas, M. D. A., and Kurtis, K. E. (2003). “Guidelines for the use of lithium to mitigate or prevent ASR.” Rep. No. FHWA-RD-03-047, Federal Highway Administration, Washington, D.C.
Joel, R. (2005). “Accelerated alkali-silica reactivity in Portland cement concrete pavements exposed to runway deicing chemicals.” Engineering Brief No. 70, Federal Aviation Administration, Washington, D.C.
Johnson, C. (2001). “I-35W and Mississippi River Bridge anti-icing project: Operational evaluation report.” Rep. No. 2001-22, Minnesota DOT, Office of Metro Maintenance Operations, Minneapolis.
Johnston, D. P., Surdahl, R., and Stokes, D. B. (2000). “A case study of a lithium-based treatment on an ASR-affected pavement.” Proc., 11th Int. Conf. on Alkali-Aggregate Reactions in Concrete, M. A. Berube, B. Fournier, and B. Durand, eds., Center de Recherche Interuniversitaire sur le Beton (CRIB), Department de genie civil, Universite Laval, Sainte-Foy, Quebec, Canada, 1149–1158.
Leming, M. L., Mitchell, J. F., and Ahmad, S. H. (1996). “Investigation of alkali-silica reactivity in North Carolina highway structures.” Center for Transportation Engineering Studies/NCDOT Rep. No. 23241-94-6, Raleigh, N.C.
Minnesota Dept. of Transportation (MnDOT). (2006). “New anti-icing system planned for Interstate 35E Lexington Bridge spanning the Mississippi River in St. Paul.” Press release, June 30, 2005, ⟨http://www.dot.state.mn.us/metro/news/05/06/30i35e.html⟩ (May 16, 2007).
Rangaraju, P. R. (2000). “A lab study on alkali-silica reactivity of quartzites used in concrete pavements of Minnesota.” Proc., 11th Int. Conf. on Alkali-Aggregate Reactions in Concrete, M. A. Berube, B. Fournier, and B. Durand, eds., Center de Recherche Interuniversitaire sur le Beton (CRIB), Department de genie civil, Universite Laval, Sainte-Foy, Quebec, Canada, 453–462.
Rangaraju, P. R. (2007). “Mitigation of ASR in presence of pavement deicing chemicals.” Research Rep. No. IPRF 01-G-002-04-8, Innovative Pavement Research Foundation, Skokie, Ill.
Rangaraju, P. R., and Olek, J. (2007). “Potential for acceleration of ASR in presence of pavement deicing chemicals.” Research Rep. No. IPRF 01-G-002-03-9, Innovative Pavement Research Foundation, Skokie, Ill.
Rangaraju, P. R., Sompura, K. R., and Olek, J. (2006). “Investigation into potential of alkali-acetate based deicers in causing alkali-silica reaction” J. Transportation Research Board, 1979, 69–79.
Rangaraju, P. R., Sompura, K. R., Olek, J., Diamond, S., and Lovell, J. (2005). “Potential for development of alkali-silica reaction in presence of airfield deicing chemicals.” Proc., 8th Int. Conf. on Concrete Pavements, International Society of Concrete Pavements (ISCP), Colorado Springs, Colo.
Rogers, C. (1999). “Multi-laboratory study of accelerated mortar bar test (ASTM C 1260) for alkali-silica reaction.” Cem., Concr., Aggregates, 21(2), 191–200.
Shayan, A., Diggins, R., and Ivanusec, I. (1996). “Long-term effectiveness of fly ash in preventing deleterious expansion due to alkali-silica reaction in concrete.” Proc., 10th Int. Symp. on Alkali-Aggregate Reactions, A. Shayan, ed., ARRB Transport Research, Vermont South, Victoria, Australia.
Shehata, M. H., and Thomas, M. D. A. (2000). “The effect of fly ash composition on the expansion of concrete due to alkali-silica reaction.” Cem. Concr. Res., 30(7), 1063–1072, 2000.
Touma, E. T., Fowler, D. W., and Carasquillo, R. L. (2001). “Alkali-silica reaction in portland cement concrete: Testing methods and mitigation alternatives.” Technical Rep. No. ICAR 301-1F, International Center for Aggregate Research (ICAR), Univ. of Texas, Austin, Tex.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 21Issue 1January 2009
Pages: 19 - 31

History

Received: Oct 24, 2006
Accepted: Oct 18, 2007
Published online: Jan 1, 2009
Published in print: Jan 2009

Permissions

Request permissions for this article.

Notes

Note. Associate Editor: Maria C. G. Juenger

Authors

Affiliations

Prasada Rao Rangaraju, A.M.ASCE [email protected]
P.E.
Associate Professor, Dept. of Civil Engineering, Clemson Univ., 220 Lowry Hall, Clemson, SC 29634-0911. E-mail: [email protected]
Jigar Desai [email protected]
Graduate Research Assistant, Dept. of Civil Engineering, Clemson Univ., 131 Lowry Hall, Clemson, SC 29634-0911. E-mail: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share