TECHNICAL PAPERS
Apr 1, 1986

Multi‐Stage Air Flotation of Tar Sand Wastewater

Publication: Journal of Energy Engineering
Volume 112, Issue 1

Abstract

In 1980, the Department of Energy's Laramie Energy Technology Center conducted a steam‐driven tar sand recovery experiment near Vernal, UT. This experiment yielded 1,150 barrels of bitumen and 6,250 barrels of process water, which was highly contaminated with emulsified oils and dissolved organics. The process waters were successfully treated by bench‐scale, continuous‐flow air flotation (AF), but significant amounts of very dilute sludge were generated. The present study investigated the effects of adding a second flotation stage to the AF system to thicken stage I sludge, produce a clean effluent suitable for recycling, and thereby increase the hydraulic efficiency of the system. Key stage II operating variables were polymer dose, air flowrate, and liquid residence time. These were optimized to minimize sludge volume and maximize effluent quality and volume. Total organic carbon and total suspended solids removals in the stage II system were 96 and 99%, respectively. Overall sludge production equalled about 2% of the total influent flow.

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References

1.
Boardman, G. D., Nolan, B. T., and Vanleigh, L., “Application of Gas Flotation and Foam Separation for the Treatment of Tar Sand Wastewaters,” Technical Information Center Report DOE/LC/10639‐T1, 1983.
2.
Churchill, R. J., and Tacchi, K. J., “A Critical Analysis of Flotation Performance,” American Institute of Chemical Engineering Journal, Vol. 74, 1978, pp. 290–299.
3.
King, P. H., “Physical‐Chemical Treatment of Tar Sand Processing Wastewater,” US Department of Energy Report DOE/LC/10678‐2, Task No. 2‐Sludge Management Studies, 1983.
4.
King, P. H., “Physical‐Chemical Treatment of Tar Sand Processing Wastewater,” US Department of Energy Report DOE/LC/10678‐1563, Tasks No. 3–5, 1983.
5.
Lemlich, R., “Introduction,” Adsorptive Bubble Separation Techniques, R. Lemlich, Ed., Academic Press, Inc., New York, NY, 1972, pp. 1–4.
6.
LaSasso, R. A., Hart, W. L., and Raman, M. S., “Polymers Help Industry Clean Up Its Water,” Industrial Water Engineering, 15, 1978, pp. 14–21.
7.
Luthy, R. G., Selleck, R. E., and Galloway, T. R., “Removal of Emulsified Oil with Organic Coagulants and Dissolved Air Flotation,” Journal of the Water Pollution Control Federation, Vol. 50, 1978, pp. 331–346.
8.
Maas, K., “Adsorptive Bubble Separation Methods,” Methodicum Chimicum, F. Korte, Ed., Academic Press, Inc., New York, NY, 1974, pp. 165–166.
9.
Rosain, R. M., and Mavid, J. D., “Water Reuse in Steam Generation Systems for Oil Shale Plants,” Proceedings of the 14th Oil Shale Symposium, Colorado School of Mines, Golden, CO, 1981.
10.
Standard Methods for the Examination of Water and Wastewater, American Public Health Association, 15th ed., 1980.
11.
Steiner, J. L., Bennet, G. F., Mohler, E. F., and Clere, L. T., “Air Flotation Treatment of Refinery Wastewater,” Chemistry Engineering Progress, Vol. 74, 1978, pp. 39–45.
12.
Voleski, B., and Agathos, S., “Oil Removal from Refinery Wastes by Air Flotation,” Water Pollution Research Canada, Vol. 9, 1974, pp. 328–339.

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Go to Journal of Energy Engineering
Journal of Energy Engineering
Volume 112Issue 1April 1986
Pages: 14 - 24

History

Published online: Apr 1, 1986
Published in print: Apr 1986

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Authors

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Bernard T. Nolan
Research Engr., Div. of Environ. Engrg., Western Research Inst., Laramie, WY 82071
William F. McTernan, A. M. ASCE
Assoc. Prof., School of Civ. Engrg., Stillwater, OK 74076
Chris J. Laya
Sr. Lab. Technician, Div. of Environ. Engrg., Western Research Inst., Laramie, WY 82071

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