Removal of Methyl Isobutyl Ketone From Contaminated Air by Trickle-Bed Air Biofilter
Publication: Journal of Environmental Engineering
Volume 131, Issue 9
Abstract
A laboratory-scale trickle-bed air biofilter was evaluated for the removal of methyl isobutyl ketone (MIBK) from a waste gas stream. Six-millimeter Celite pellets (R-635) were used as the biological attachment medium. Effects of MIBK volumetric loading rates on removal efficiency, biofilter reacclimation, biomass growth, and removal kinetics were studied under three different operating conditions, namely, backwashing and two intermittent periods (off chemical—no MIBK input; and off flow-no flow input). Backwashing of the biofilter once a week with full-medium fluidization removed the excess biomass and attained stable long-term performance with over 99% removal efficiency for loading rates less than chemical oxygen demand . The two intermittent periods could also sustain high removal efficiency for loading rates up to without any backwashing. The recovery time increased with an increase in loading rates. Furthermore, the intermittent operations required a longer time to recover than backwashing. The pseudo-first-order removal rate constant decreased with an increase in volumetric loading rate. The removal kinetics showed an apparent dependency on the experimental operating conditions.
Get full access to this article
View all available purchase options and get full access to this article.
Acknowledgment
This research was supported by the National Science Foundation under Award No. BES 0229135. The findings and conclusions expressed in this publication are solely those of the writers and do not necessary reflect the views of the Foundation. Special thanks are given to Mr. Steven Mallin and Miss Rachel Rhodes, the cooperative undergraduate students from the University of Cincinnati, for their dependable skilled technical assistance. The writers also extend their sincere gratitude to Dr. Makram T. Suidan and his research assistants at the University of Cincinnati for their consistent assistance during this phase of our research.
References
Aizpuru, A., Malhautier, L., Roux, J. C., and Fanlo, J. L. (2001). “Biofiltration of a mixture of volatile organic emissions.” J. Air Waste Manage. Assoc., 51(12), 1662–1670.
Alonso, C. et al. (1997). “Gas treatment in trickle-bed biofilters: Biomass, how much is enough?” Biotechnol. Bioeng., 54(6), 583–594.
Alonso, C., Suidan, M. T., Kim, B. R., and Kim, B. J. (1998). “Dynamic mathematical model for the biodegradation of VOCs in a biofilter: Biomass accumulation study.” Environ. Sci. Technol., 32(20), 3118–3123.
Alonso, C., Zhu, Y., Suidan, M. T., Kim, B. R., and Kim, B. J. (1999). “Mathematical model for the biodegradation of VOCs in trickle bed biofilters.” Water Sci. Technol., 39(7), 139–146.
Alonso, C., Zhu, X. Q., Suidan, M. T., Kim, B. R., and Kim, B. J. (2000). “Parameter estimation in biofilter systems.” Environ. Sci. Technol.,34(11), 2318–2323.
Alonso, C., Zhu, X. Q., Suidan, M. T., Kim, B. R., and Kim, B. J. (2001). “Mathematical model of biofiltration of VOCs: Effect of nitrate concentration and backwashing.” J. Environ. Eng., 127(7), 655–664.
American Public Health Administration, American Water Works Association, and Water Environment Federation (APHA/AWWA/WEF). (1998). Standard methods for the examination of water and wastewater, 20th Ed., APHA, AWWA, and WEF, Washington, D.C.
Arulneyam, D., and Swaminathan, T. (2003). “Biodegradation of methanol vapor in a biofilter.” J. Environ. Sci. (China), 15(5), 691–696.
Chou, M. S., and Huang, J. J. (1997). “Treatment of methylethylketone in air stream by biotrickling filters.” J. Environ. Eng., 123(6), 569–576.
Deshusses, M. A. (1997). “Transient behavior of biofilters: Start-up, carbon balances, and interactions between pollutants.” J. Environ. Eng., 123(6), 563–568.
Deshusses, M. A., Hamer, G., and Dunn, I. J. (1995a). “Behavior of biofilters for waste air biotreatment.1: Dynamic-model development.” Environ. Sci. Technol., 29(4), 1048–1058.
Deshusses, M. A., Hamer, G., and Dunn, I. J. (1995b). “Behavior of biofilters for waste air biotreatment.2: Experimental evaluation of a dynamic model.” Environ. Sci. Technol., 29(4), 1059–1068.
Deshusses, M. A., Hamer, G., and Dunn, I. J. (1996). “Transient-state behavior of a biofilter removing mixtures of vapors of MEK and MIBK from air.” Biotechnol. Bioeng., 49(5), 587–598.
Deshusses, M. A., and Johnson, C. T. (2000). “Development and validation of a simple protocol to rapidly determine the performance of biofilters for VOC treatment.” Environ. Sci. Technol., 34(3), 461–467.
Don, J. A., and Feenstra, L. (1984). “Ordor abatement through biofiltration.” Proc., Symp. on Characterization and Control of Odoriferous Pollutants in Process Industries, Le Neuve, Belgium.
Jorio, H., Bibeau, L., and Heitz, M. (2000). “Biofiltration of air contaminated by styrene: Effect of nitrogen supply, gas flow rate, and inlet concentration.” Environ. Sci. Technol., 34(9), 1764–1771.
Kawai, T. et al. (2003). “Methyl isobutyl ketone and methyl ethyl ketone in urine as biological markers of occupational exposure to these solvents at low levels.” Int. Arch. Occup. Environ. Health, 76(1), 17–23.
Kong, Z., Farhana, L., Fulthorpe, R. R., and Allen, D. G. (2001). “Treatment of volatile organic compounds in a biotrickling filter under thermophilic conditions.” Environ. Sci. Technol., 35(21), 4347–4352.
Lee, B. (1991). “Highlights of the clean air act amendments of 1990.” J. Air Waste Manage. Assoc., 41(1), 16–19.
Martin, F. J., and Loehr, R. C. (1996). “Effect of periods of non-use on biofilter performance.” J. Air Waste Manage. Assoc., 46(6), 539–546.
Ottengraf, S. P. P. (1986). “Exhaust gas purification.” Biotechnology, H. J. Rehm and G. Reed, eds., VCH Verlagsgesellsch, Weinheim, Germany, 8, 425–452.
Pedersen, A. R., and Arvin, E. (1997). “Toluene removal in a biofilm reactor for waste gas treatment.” Water Sci. Technol., 36(1), 69–76.
Phillips, R. D. et al. (1987). “A vapor inhalation toxicity study of methyl isobutyl ketone.” Fundam. Appl. Toxicol., 9(3), 380–388.
Seignez, C., Atti, A., Adler, N., and Peringer, P. (2002). “Effect of biotrickling filter operating parameters on chlorobenzenes degradation.” J. Environ. Eng., 128(4), 360–366.
Smith, F. L. et al. (1996). “Development of two biomass control strategies for extended, stable operation of highly efficient biofilters with high toluene loadings.” Environ. Sci. Technol., 30(5), 1744–1751.
Smith, F. L. et al. (1998). “Evaluation of trickle bed air biofilter performance as a function of inlet VOC concentration and loading, and biomass control.” J. Air Waste Manage. Assoc., 48(7), 627–636.
Smith, F. L., Sorial, G. A., Suidan, M. T., Biswas, P., and Brenner, R. C. (2002). “Development and demonstration of an explicit lumped-parameter biofilter model and design equation incorporating Monod kinetics.” J. Air Waste Manage. Assoc., 52(2), 208–219.
Sorial, G. A. et al. (1993a). “Development of aerobic biofilter design criteria for treating VOCs.” Proc., 86th Annual Meeting and Exhibition of the Air and Waste Management Asociation.
Sorial, G. A. et al. (1993b). “Evaluation of biofilter media for treatment of air streams containing VOCs.” Proc., Water Environment Federation 66th Annual Conf. and Exposition, 429–439.
Sorial, G. A. et al. (1994). “Evaluation of performance of trickle bed biofilter-impact of periodic removal of accumulated biomass.” Proc., 87th Annual Meeting and Exhibition of the Air and Waste Management Association.
Sorial, G. A., Smith, F. L., Suidan, M. T., Biswas, P., and Brenner, R. C. (1995). “Evaluation of trickle-bed biofiltermedia for toluene removal.” J. Air Waste Manage. Assoc., 45(10), 801–810.
Sorial, G. A. et al. (1998). “Evaluation of trickle-bed air biofilter performance for styrene removal.” Water Res., 32(5), 1593–1603.
Togna, A. P., and Frisch, S. (1993). “Field-pilot study of styrene biodegradation using biofiltration.” Proc., 86th Annual Meeting and Exhibition of the Air and Waste Management Association.
Zhu, X., Rihn, M. J., Suidan, M. T., Kim, B. J., and Kim, B. R. (1996). “The effect of nitrate on VOC removal in trickle bed biofilters.” Water Sci. Technol., 34(3–4), 573–581.
Information & Authors
Information
Published In
Copyright
© 2005 ASCE.
History
Received: May 24, 2004
Accepted: Feb 3, 2005
Published online: Sep 1, 2005
Published in print: Sep 2005
Authors
Metrics & Citations
Metrics
Citations
Download citation
If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.