TECHNICAL PAPERS
Dec 1, 2005

Influence of Wastewater Constituents on Hydrogen Sulfide Emission in Sewer Networks

Publication: Journal of Environmental Engineering
Volume 131, Issue 12

Abstract

Transport of wastewater in sewer networks causes potential problems associated with hydrogen sulfide in regard to odor nuisance, health risk, and microbially induced corrosion. To what extent these problems occur depends not only on the rate of sulfide formation but also on the rate of hydrogen sulfide emission into the sewer atmosphere. To gain understanding of the influence of wastewater constituents on the emission process, a number of batch experiments were conducted on domestic wastewater collected from sewer networks. The emission rate of hydrogen sulfide in the wastewater investigated was found to be approximately 60% of that in de-ionized water in terms of the overall mass-transfer coefficient, resulting in a correction factor (alpha) of 0.6. The alpha factor did not change significantly within the turbulence range studied (Froude numbers of 0.04–0.23). The Henry’s law constant for hydrogen sulfide in wastewater was observed to be close to that in de-ionized water, reflecting a correction factor (beta) of 1.0. By taking these results into account, modeling aspects of hydrogen sulfide emission in sewer networks are presented in this paper.

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References

Abdul-Talib, S. B. (2002). “In-sewer processes: Transformation of organic matter under anoxic conditions.” PhD thesis, Univ. Teknologi Malaysia, Malaysia.
Al-Haddad, A. A., Abdo, M. S. E., and Abdul-Wahab, S. A. (1989). “Evaluation of Henry’s constants for H2S in water and sewage effluents.” J. Environ. Sci. Health, Part A: Toxic/Hazard. Subst. Environ. Eng., A24(3), 207–227.
American Public Health Association, American Water Works Association, Water Environment Federation (APHA/AWWA/WEF). (1995). Standard methods for the examination of water and wastewater, 19th Ed., APHA, Washington, D.C.
Bates, R. L., Fondy, P. L., and Fenic, J. G. (1966). “Impeller characteristics and power.” Mixing: Theory and practice, V. W. Uhl and J. B. Gray, eds., Vol. 1, Academic, New York, 111–178.
Blain, W. A. (1969). “Discussion of ‘ammonia nitrogen losses from streams,’ by Stratton, F. E.” J. Sanit. Eng. Div., Am. Soc. Civ. Eng., 95, 974–978.
Boon, A. G., and Lister, A. R. (1975). “Formation of sulphide in rising main sewers and its prevention by injection of oxygen.” Prog. Water Technol., 7(2), 289–300.
Chern, J. M., and Chou, S. R. (2002). “Effects of surfactant on volatile organic compound emission rates in a diffused aeration system.” Ind. Eng. Chem. Res., 41, 5042–5048.
Chern, J. M., Chou, S. R., and Shang, C. S. (2001). “Effects of impurities on oxygen transfer rates in diffused aeration systems.” Water Res., 35, 3041–3048.
Clarke, E. C. W., and Glew, D. N. (1971). “Aqueous nonelectrolyte solutions. Part VIII. Deuterium and hydrogen sulfides solubilities in deuterium oxide and water.” Can. J. Chem., 49, 691–698.
Cline, J. D. (1969). “Spectrophotometric determination of hydrogen sulfide in natural waters.” Limnol. Oceanogr., 14, 454–458.
Cullen, E. J., and Davidson, J. F. (1956). “The effect of surface active agents on the rate of absorption of carbon dioxide by water.” Chem. Eng. Sci., 6(2), 49–56.
Downing, A. L., Bayley, R. W., and Boon, A. G. (1960). “The performance of mechanical aerators.” J. Proc. Inst. Sewage Purif., 231–242.
Eckenfelder, W. W., Jr., Raymond, L. W., and Lauria, D. T. (1956). “Effect of various organic substances on oxygen absorption efficiency.” Sewage Ind. Wastes, 28, 1357–1364.
Edwards, T. J., Maurer, G., Newman, J., and Prausnitz, J. M. (1978). “Vapor-liquid equilibria in multicomponent aqueous solutions of volatile weak electrolytes.” AIChE J., 24, 966–976.
Henze, M., Harremoës, P., la Cour Jansen, J., and Arvin, E. (1995). Wastewater treatment—biological and chemical processes, Springer, Berlin.
Howe, K. J., and Lawler, D. F. (1989). “Acid-base reactions in gas transfer: A mathematical approach.” J. Am. Water Works Assoc., 81(1), 61–66.
Hvitved-Jacobsen, T. (2002). Sewer processes—microbial and chemical process engineering for sewer networks, CRC, Boca Raton, Fl.
Hvitved-Jacobsen, T., Jütte, B., Nielsen, P. H., and Jensen, N. A. (1988). “Hydrogen sulphide control in municipal sewers.” Pretreatment in chemical water and wastewater treatment, H. H. Hahn and R. Klute, eds., Springer, Berlin, 239–247.
Jahani, F., Devinny, J. J., Mansfeld, F., Rosen, G., Sun, Z., and Wang, C. (2001). “Investigations of sulfuric acid corrosion of concrete. I: Modeling and chemical observations.” J. Environ. Eng., 127(7), 572–579.
Jensen, N. A. (1995). “Empirical modeling of air-to-water oxygen transfer in gravity sewers.” Water Environ. Res., 67, 979–991.
Kavanaugh, M. C., and Trussell, R. R. (1980). “Design of aeration towers to strip volatile contaminants from drinking water.” J. Am. Water Works Assoc., 72, 684–692.
Kehr, R. W. (1938). “Effect of sewage on atmospheric reaeration rates under stream flow conditions.” Sewage Works J., 10, 228–240.
Lewis, W. K., and Whitman, W. G. (1924). “Principles of gas absorption.” Ind. Eng. Chem., 16, 1215–1220.
Liss, P. S., and Slater, P. G. (1974). “Flux of gases across the air-sea interface.” Nature (London) 247, 181–184.
Mancy, K. H., and Okun, D. A. (1960). “Effects of surface active agents on bubble aeration.” J. Water Pollut. Control Fed., 32, 351–364.
Matos, J. S., and de Sousa, E. R. (1994). “Oxygen absorption in free-fall drops of small sewerage systems.” Proc., Hydrotop 94, Marseille, France, Vol. II, 161–166.
McKenna, S. P., and McGillis, W. R. (2002). “Surface divergence and air-water gas transfer.” Gas transfer at water surfaces, M. A. Donelan, W. M. Drennan, E. S. Saltzman, and R. Wanninkhof, eds., American Geophysical Union, Washington, D.C., 129–134.
Metcalf and Eddy Inc. (1991). Wastewater engineering: Treatment, disposal, and reuse, 3rd Ed., G. Tchobanoglous and F. L. Burton, eds., McGraw-Hill, New York.
Milde, K., Sand, W., Wolff, W., and Bock, E. (1983). “Thiobacilli of the corroded concrete walls of the Hamburg sewer system.” J. Gen. Microbiol., 129, 1327–1333.
Mood, A. M., Graybill, F. A., and Boes, D. C. (1974). Introduction of the theory of statistics, 3rd Ed., McGraw-Hill, New York.
Moore, W. A. (1938). “The solubility of atmospheric oxygen in sewage.” Sewage Works J., 10, 241–246.
Nielsen, P. H., Raunkjær, K., and Hvitved-Jacobsen, T. (1998). “Sulfide production and wastewater quality in pressure mains.” Water Sci. Technol., 37(1), 97–104.
O’Connor, D. J. (1963). “Effects of surface active agents on re-aeration.” J. Air Water Pollution, 5, 123–130.
O’Connor, D. J. (1998). “Chemical reactions and gas transfer in natural waters.” J. Environ. Eng., 124(2), 85–93.
Paris, D. F., Steen, W. C., and Baughman, G. L. (1978). “Role of physico-chemical properties of Aroclors 1016 and 1242 in determining their fate and transport in aquatic environments.” Chemosphere, 4, 319–325.
Parker, C. D. (1945). “The corrosion of concrete 2—the function of Thiobacillus concretivorous (nov. spec.) in the corrosion of concrete exposed to atmosphere containing hydrogen sulphide.” Aust. J. Exp. Biol. Med. Sci., 23, 91–98.
Parkhurst, J. D., and Pomeroy, R. D. (1972). “Oxygen absorption in streams.” J. Sanit. Eng. Div., Am. Soc. Civ. Eng., 98(1), 101–124.
Pomeroy, R. D., and Lofy, R. J. (1977). “Feasibility study on in-sewer treatment methods.” NTIS No. PB-271445, United States Environmental Protection Agency, Cincinnati.
Pomeroy, R. D., and Parkhurst, J. D. (1977). “The forecasting of sulfide build-up rates in sewers.” Prog. Water Technol., 9(3), 621–628.
Rathbun, R. E., Tai, D. Y., Shultz, D. J., and Stephens, D. W. (1978). “Laboratory studies of gas tracers for reaeration.” J. Environ. Eng. Div. (Am. Soc. Civ. Eng.), 104(2), 215–229.
Smith, J. H., Bomberger, D. C., Jr., and Haynes, D. L. (1980). “Prediction of the volatilization rates of high-volatility chemicals from natural water bodies.” Environ. Sci. Technol., 14, 1332–1337.
Stenstrom, M. K., and Gilbert, R. G. (1981). “Effects of alpha, beta and theta factor upon the design, specification and operation of aeration systems.” Water Res., 15, 643–654.
Stenstrom, M. K., and Hwang, H. J. (1979). “The effect of surfactants on industrial aeration systems.” Proc., 34th Industrial Waste Conf., Purdue University, West Lafayette, Ind., 902–909.
Steudel, R. (2000). “The chemical sulfur cycle.” Environmental technology to treat sulfur pollution: Principles and engineering, P. N. L. Lens and L. Hulshoffpol, eds., International Water Association, London, 1–31.
Stukenberg, J. R., Wahbeh, V. N., and McKinney, R. E. (1977). “Experiences in evaluating and specifying aeration equipment.” J. Water Pollut. Control Fed., 49, 66–82.
Tanaka, N., Hvitved-Jacobsen, T., and Horie, T. (2000). “Transformations of carbon and sulfur wastewater components under aerobic-anaerobic transient conditions in sewer systems.” Water Environ. Res., 72, 651–664.
Tewari, P. K., and Bewtra, J. K. (1982). “Alpha and beta factors for domestic wastewater.” J. Water Pollut. Control Fed., 54, 1281–1287.
Thistlethwayte, D. K. B., ed. (1972). The control of sulphides in sewerage systems, Butterworths, Sydney, Australia.
Tsivoglou, E. C., O’Connell, R. L., Walter, C. M., Godsil, P. J., and Logsdon, G. S. (1965). “Tracer measurements of atmospheric reaeration—I. laboratory studies.” J. Water Pollut. Control Fed., 37, 1343–1362.
United States Environmental Protection Agency (USEPA). (1974). “Process design manual for sulfide control in sanitary sewerage systems.” USEPA Technology Transfer, USEPA, Washington, D.C.
United States Environmental Protection Agency (USEPA). (1979). Proc.: Workshop Toward an Oxygen Transfer Standard, EPA-600/9-78-021, Office of Research and Development, Ohio.
Wagner, M., and Pöpel, H. J. (1996). “Surface active agents and their influence on oxygen transfer.” Water Sci. Technol., 34(3–4), 249–256.
Yongsiri, C., Hvitved-Jacobsen, T., Vollertsen, J., and Tanaka, N. (2003). “Introducing the emission process of hydrogen sulfide to a sewer process model (WATS).” Water Sci. Technol., 47(4), 85–92.
Yongsiri, C., Vollertsen, J., and Hvitved-Jacobsen, T. (2004a). “Effect of temperature on air-water transfer of hydrogen sulfide.” J. Environ. Eng., 130(1), 104–109.
Yongsiri, C., Vollertsen, J., and Hvitved-Jacobsen, T. (2004b). “Hydrogen sulfide emission in sewer networks: A two-phase modeling approach to the sulfur cycle.” Water Sci. Technol., 50(4), 161–168.
Yongsiri, C., Vollertsen, J., Rasmussen, M., and Hvitved-Jacobsen, T. (2004c). “Air-water transfer of hydrogen sulfide—an approach for application in sewer networks.” Water Environ. Res., 76, 81–88.
Zytner, R. G., Madani-Isfahani, M., and Corsi, R. L. (1997). “Oxygen uptake and VOC emissions at enclosed sewer drop structures.” Water Environ. Res., 69, 286–294.

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Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 131Issue 12December 2005
Pages: 1676 - 1683

History

Received: Jul 29, 2003
Accepted: Mar 9, 2005
Published online: Dec 1, 2005
Published in print: Dec 2005

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Chaturong Yongsiri, S.M.ASCE [email protected]
Chief Engineer, FGD Project Headquarters, Fujikasui Engineering Co., Ltd., 4-3, 1-Chome, Higashi-Gotanda, Shinagawa-Ku, Tokyo 141-0022, Japan; formerly, PhD Student, Dept. of Environmental Engineering, Aalborg Univ., Sohngaardsholmsvej 57, DK-9000 Aalborg, Denmark (corresponding author). E-mail: [email protected]
Jes Vollertsen [email protected]
Associate Professor, Dept. of Environmental Engineering, Aalborg Univ., Sohngaardsholmsvej 57, DK-9000 Aalborg, Denmark. E-mail: [email protected]
Thorkild Hvitved-Jacobsen [email protected]
Professor, Dept. of Environmental Engineering, Aalborg Univ., Sohngaardsholmsvej 57, DK-9000 Aalborg, Denmark. E-mail: [email protected]

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