TECHNICAL PAPERS
Dec 1, 2000

Volatile Organic Compounds in Storm Water from a Parking Lot

Publication: Journal of Environmental Engineering
Volume 126, Issue 12

Abstract

A mass balance approach was used to determine the most important nonpoint source of volatile organic compounds (VOCs) in storm water from an asphalt parking lot without obvious point sources (e.g., gasoline stations). The parking lot surface and atmosphere are important nonpoint sources of VOCs, with each being important for different VOCs. The atmosphere is an important source of soluble, oxygenated VOCs (e.g., acetone), and the parking lot surface is an important source for the more hydrophobic VOCs (e.g., benzene). VOCs on the parking lot surface appear to be concentrated in oil and grease and organic material in urban particles (e.g., vehicle soot). Except in the case of spills, asphalt does not appear to be an important source of VOCs. The uptake isotherm of gaseous methyl tert-butyl ether on urban particles indicates a mechanism for dry deposition of VOCs from the atmosphere. This study demonstrated that a mass balance approach is a useful means of understanding non-point-source pollution, even for compounds such as VOCs, which are difficult to sample.

Get full access to this article

View all available purchase options and get full access to this article.

References

1.
Baehr, A. L., Stackelberg, P. E., and Baker, R. J. ( 1999). “Evaluation of the atmosphere as a source of volatile organic compounds in shallow groundwater.” Water Resour. Res., 35, 127–136.
2.
Ciccioli, P. ( 1993). “VOCs and air pollution.” Chemistry and analysis of volatile organic compounds in the environment, H. J. Th. Bloemen and J. Burns, eds., Blackie Academic and Professional, New York, 92–174.
3.
Connor, B. F., Rose, D. L., Noriega, M. C., Murtagh, L. K., and Abney, S. R. ( 1998). “Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory—Determination of 86 volatile organic compounds in water by gas chromatography/mass spectrometry, including detections less than reporting limits.” USGS Open-File Rep. OFR 97-829, U.S. Geological Survey, Reston, Va.
4.
Delzer, G. C., Zogorski, J. S., Lopes, T. J., and Bosshart, R. L. ( 1996). “Occurrence of the gasoline oxygenate MTBE and BTEX compounds in urban stormwater in the United States, 1991–95.” USGS Water Resour. Investigations Rep. WRIR 96-4145, U.S. Geological Survey, Reston, Va.
5.
Ferronato, C., Kaluzny, P., Jacob, V., Laffond, M., and Panayotis, F. ( 1998). “Study of TEX (toluene, ethylbenzene, xylenes) scavaging by raindrops.” Fresenius Envir. Bull., FRG (Federal Republic of Germany), 7, 246–253.
6.
Gregg, S. J., and Sing, K. S. W. ( 1982). Adsorption, surface area, and porosity, Academic, Newark, N.J.
7.
Hiatt, M. H. ( 1995). “Vacuum distillation coupled with gas chromatography/mass spectrometry for the analysis of environmental samples.” Analytical Chem., 67, 4044–4052.
8.
Hoffman, E. J., and Quinn, J. G. ( 1987). “Chronic hydrocarbon discharges into aquatic environments: II—Urban runoff and combined sewer overflows.” Oil in freshwater: Chemistry, biology, countermeasure technology, J. H. Vandermeulen and S. E. Hrudey, eds., Pergamon, New York, 114–137.
9.
Kirchstetter, T. W., Singer, B. C., Harley, R. A., Kendall, G. R., and Chan, W. ( 1996). “Impact of oxygenated gasoline use on California light-duty vehicle emissions.” Envir. Sci. and Technol., 30, 661–670.
10.
Ligocki, M. P., Leuenberger, C., and Pankow, J. F. ( 1985). “Trace organic compounds in rain—II. Gas scavenging of neutral organic compounds.” Atmospheric Envir., 19, 1609–1617.
11.
Lopes, T. J., and Bender, D. A. ( 1998). “Nonpoint sources of volatile organic compounds in urban areas—relative importance of land surfaces and air.” Envir. Pollution, England, 101, 221–230.
12.
Lopes, T. J., Fallon, J. D., and Maluk, T. L. ( 2000). “Compositing water samples for analysis of volatile organic compounds.” Envir. Engrg., 126, 769–773.
13.
Lundgren, R. F., and Lopes, T. J. ( 1999). “Occurrence, distribution, and trends of volatile organic compounds in the Ohio River, 1987–96.” USGS Water Resour. Investigations Rep. WRIR 99-4257, U.S. Geological Survey, Reston, Va.
14.
Mackay, D., Shiu, W. Y., and Ma, K. C. ( 1992). Illustrated handbook of physical-chemical properties and environmental fate for organic chemicals, Vols. I and III, Lewis, Ann Arbor, Mich.
15.
Novotny, V. ( 1995). “Hydrologic aspects of nonpoint pollution.” Nonpoint pollution and urban storm water management, V. Novotny, ed., Technomic Publishing Co., Lancaster, Pa., 73–109.
16.
Pankow, J. F., Thomson, N. R., Johnson, R. L., Baehr, A. L., and Zogorski, J. S. ( 1997). “The urban atmosphere as a non-point source for the transport of MTBE and other volatile organic compounds (VOCs) to shallow groundwater.” Envir. Sci. and Technol., 31, 2821–2828.
17.
Plummer, L. N., Michel, R. L., Thurman, E. M., and Glynn, P. D. ( 1993). “Environmental tracers for age dating young ground water.” Regional ground-water quality, W. M. Alley, ed., Van Nostrand Reinhold, New York, 255–294.
18.
Reiser, R. G., and O'Brien, A. K. ( 1998). “Occurrence and seasonal variability of volatile organic compounds in seven New Jersey streams.” USGS Water Resour. Investigations Rep. WRIR 98-4074, U.S. Geological Survey, Reston, Va.
19.
Rutherford, D. W., Chiou, C. T., and Eberl, D. D. ( 1997). “Effects of exchanged cation on the microporosity of montmorillonite.” Clays and Clay Minerals, 45, 534–543.
20.
Schauer, J. J., Kleeman, M. J., Cass, G. R., and Simoneit, B. R. T. ( 1999). “Measurement of emissions from air pollution sources. 2. C1 through C30 organic compounds from medium duty diesel trucks.” Envir. Sci. and Technol., 33, 1578–1587.
21.
Slinn, W. G. N., et al. ( 1978). “Some aspects of the transfer of atmospheric trace constituents past the air-sea interface.” Atmospheric Envir., 12, 2055–2087.
22.
Squillace, P. J., Moran, M. J., Lapham, W. W., Price, C. V., Clawges, R. M., and Zogorski, J. S. ( 1999). “Volatile organic compounds in untreated ambient groundwater of the United States, 1985–95.” Envir. Sci. and Technol., 33, 4176–4187.
23.
Squillace, P. J., Zogorski, J. S., Wilber, W. G., and Price, C. V. ( 1996). “Preliminary assessment of the occurrence and possible sources of MTBE in groundwater in the United States, 1993–94.” Envir. Sci. and Technol., 30, 1721–1730.
24.
Stackelberg, P. E., Hopple, J. A., and Kauffman, L. J. ( 1997). “Occurrence of nitrate, pesticides, and volatile organic compounds in the Kirkwood-Cohansey aquifer system, southern New Jersey.” USGS Water Resour. Investigations Rep. WRIR 97-4241, U.S. Geological Survey, Reston, Va.
25.
U.S. Environmental Protection Agency (U.S. EPA). ( 1997a). “State source water assessment and protection programs.” EPA 816-R-97-009, Office of Water, Washington, D.C.
26.
U.S. Environmental Protection Agency (U.S. EPA). ( 1997b). “Community water system survey. Vol. 1: Overview.” EPA 815-R-97-001a, Office of Water, Washington, D.C.
27.
Westrick, J. J., Mello, J. W., and Thomas, R. F. ( 1984). “The groundwater supply survey.” J. AWWA, 76, 52–59.

Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 126Issue 12December 2000
Pages: 1137 - 1143

History

Received: Jan 31, 2000
Published online: Dec 1, 2000
Published in print: Dec 2000

Permissions

Request permissions for this article.

Authors

Affiliations

Hydro., U.S. Geological Survey, 333 W. Nye Lane, Carson City, NV 89706.
Hydro., U.S. Geological Survey, 2280 Woodale Dr., Mounds View, MN 55112.
Res. Chemist, U.S. Geological Survey Nat. Water Quality Lab., Box 25046, Denver Fed. Ctr., M/S 408, Denver, CO 80225-0046.
Res. Chemist, U.S. Envir. Protection Agency, Nat. Exposure Res. Lab., Envir. Sci. Div., P.O. Box 93478, Las Vegas, NV 89193-3478.

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share