TECHNICAL PAPERS
Aug 1, 1997

Multiresponse Parameter Estimation of SVOCs in Activated Sludge Process

Publication: Journal of Environmental Engineering
Volume 123, Issue 8

Abstract

Semivolatile organic chemicals (SVOCs) in a treatment system may be dissolved in the liquid phase, adsorbed into the solid phase, become part of the gaseous phase, or be biologically degraded. Experiments on discovering their fate should examine these phases simultaneously. As a result, the experiments produce multiple responses relating the liquid, solid, and gaseous phases of the system. These data are used to estimate parameters (e.g., rate constants) for biodegradation, volatilization, adsorption, and perhaps desorption. This paper explains how data were collected in unsteady-state experiments and how the multiple-response nonlinear least-squares parameter estimation was done on a set of simultaneous differential equations. Some aspects of the model building process, parameter significance and consistency, and model simplification are also discussed.

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References

1.
Armenante, P. M., Kafkewitz, D., Lewandowski, G., and Kung, C. M.(1992). “Integrated anaerobic-aerobic process for biodegradation of chlorinated aromatic compounds.”Envir. Progress, 11(2), 113–122.
2.
Baillod, C. R., et al. (1990). “Critical evaluation of the state of technologies for predicting the transport of toxic compounds in wastewater facilities.”WPCF Res. Found. Proj. 90-1, Water Environment Federation, Alexandria, Va.
3.
Barton, D. A.(1987). “Intermedia transport of organic chemicals in biological treatment processes.”Envir. Progress, 6, 246–256.
4.
Bates, D. M., and Watts, D. G. (1988). Nonlinear regression analysis and its applications. John Wiley & Sons, Inc., New York, N.Y.
5.
Berthouex, P. M., and Brown, L. C. (1994). Statistics for environmental engineers. Lewis Publishers, Boca Raton, Fla.
6.
Berthouex, P. M., and Hunter, W. G.(1971). “Statistical experimental design: BOD tests.”J. Sanit. Engr. Div., ASCE, 97, 393–407.
7.
Bogus, S. M. (1992). “Modeling of fate of semi-volatile organic compounds during activated sludge treatment and anaerobic digestion,”MS Res. Rep., Univ. of Wisconsin-Madison, Madison, Wis.
8.
Buisson, R. S. K., Kirk, P. W., and Lester, J. N.(1987). “The behavior of selected chlorinated organic micropollutants in the activated sludge process: a pilot plant study.”Water Air and Soil Pollution, 37, 419–432.
9.
Dobbs, R.(1989). “Sorption of toxic organic compounds on wastewater solids: correlation with fundamental properties.”Envir. Sci. Technol., 23, 1092.
10.
Dull, T. C. (1991). “The development of a mathematical model to predict the fate of semivolatile organic chemicals in an activated sludge bioreactor,” MS thesis, Univ. of Wisconsin-Madison, Madison, Wis.
11.
Edgehill, R. U., and Finn, R. K.(1983). “Activated sludge treatment of synthetic wastewater containing pentachlorophenol.”Biotechnol. and Bioengrg., 25, 2165–2176.
12.
Govind, R., and Dobbs, R.(1991). “Integrated model for predicting the fate of organics in wastewater treatment plants.”Envir. Progress, 10(1), 13–23.
13.
Grady, C. P. I. Jr.(1983). “Biodegradation of toxic organics: status and potential.”J. Envir. Engrg., ASCE, 116(5), 805–828.
14.
Grimm, R. (1991). “Development of techniques for analyzing semivolatile organic chemicals in an activated sludge bioreactor,” MS thesis, Univ. of Wisconsin-Madison, Madison, Wis.
15.
Hawkins, E. F., and Steiner, R. (1991). Scintillation supplies and sample preparation guide. Beckman Instruments, Inc., Fullerton, Calif.
16.
Jacobsen, B. N., Nyholm, N., Pedersen, B. M., Poulson, O., and Ostfeldt, P.(1991). “Microbial degradation of pentachlorophenol and lindane in laboratory-scale activated sludge reactors.”Water Sci. and Technol., 23, 349–356.
17.
Jaffe, P. R., and Ferrara, R. A.(1983). “Desorption kinetics in modeling of toxic chemicals.”J. Envir. Engrg., ASCE, 109(4), 859–867.
18.
Kennedy, K. J., Lu, J., and Mohn, W. W.(1992). “Biosorption of chlorophenols to anaerobic granular sludge.”Water Res., 26, 1085–1092.
19.
Ko, K. B. (1987). “A mathematical model for the prediction of the distribution, transport and fate of polycyclic aromatic hydrocarbons in activated sludge processes,” PhD thesis, Univ. of Wisconsin-Madison, Madison, Wis.
20.
Ko, K. B., and Berthouex, P. M.(1990). “A mathematical model for the fate of polycyclic aromatic hydrocarbons in activated sludge processes: steady state and dynamic simulations.”Korean J. Civ. Engrg., 10, 173–184.
21.
Lee, L. S., Rao, P. S., and Brusseau, M. L.(1991). “Nonequilibrium sorption and transport of neutral and ionized chlorophenols.”Envir. Sci. Technol., 25, 722–729.
22.
Matter-Muller, C., Gujer, W., and Giger, W.(1981). “Transfer of volatile substances from water to the atmosphere.”Water Res., 15, 1271–1279.
23.
Melcer, H., and Bedford, W. K.(1988). “Removal of pentachlorophenol in municipal activated sludge systems.”J. Water Pollution Control Fedn., 60, 622.
24.
Moretti, C. J., and Neufield, R. D.(1989). “PAH partitioning mechanisms with activated sludge.”Water Res., 23(1), 93–102.
25.
Namkung, E., and Rittman, B. E.(1987). “Estimating volatile organic compound emissions from publicly owned treatment works.”J. Water Pollution Control Fedn., 59(7), 670–678.
26.
Nutting, E. (1993). “Determination of the fate of semivolatile organic compounds in activated sludge biological treatment,” MS thesis, Univ. of Wisconsin-Madison, Madison, Wis.
27.
Nyholm, N., Jacobsen, B. N., Pedersen, B. M., Poulsen, O., Damborg, A., and Schultz, B.(1992). “Removal of organic micropollutants at PPB levels in laboratory activated sludge reactors under various operating conditions: biodegradation.”Water Res., 26, 339–353.
28.
Parker, W. J., Bell, J. P., and Melcer, H.(1994). “Modelling the fate of chlorinated phenols in wastewater treatment plants.”Envir. Progress, 13, 98–104.
29.
Rathbun, R. E., and Tai, D. Y.(1981). “Volatilization of organic compounds from streams.”Envir. Engrg. Div., ASCE, 108(5), 973–989.
30.
Roberts, P. V., Hopkins, G. D., and Munz, C.(1985). “Evaluating two-resistance models for air-stripping of volatile organic contaminants in a countercurrent packed column.”Envir. Sci. and Technol., 19(2), 164–173.
31.
Stewart, W. E. (1991). GREG software package documentation. Dept. of Chemical Engrg., Univ. of Wisconsin-Madison, Madison, Wis.
32.
Tsezos, M., and Bell, J. P.(1989). “Comparison of the biosorption and desorption of hazardous organic pollutants by live and dead biomass.”Water Res., 23, 561–569.
33.
U.S. Environmental Protection Agency (EPA). (1990a). “Method 604, phenols.”40 CFR chapter 1, 7-1-90 Ed., Washington, D.C.
34.
U.S. Environmental Protection Agency (EPA). (1990b). “Method 610, polynuclear aromatic hydrocarbons.”40 CFR chapter 1, 7-1-90 Ed., Washington, D.C.
35.
Wang, L., Govind, R., and Dobbs, R. A.(1993). “Sorption of toxic organic compounds on wastewater solids: mechanism and modeling.”Envir. Sci. and Technol., 27(1), 152–158.
36.
Wang, X., and Grady, C. P. L.(1994). “Comparison of biosorption isotherms for di-n-butyl phthalate by live and dead bacteria.”Water Res., 28, 1247–1251.

Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 123Issue 8August 1997
Pages: 767 - 775

History

Published online: Aug 1, 1997
Published in print: Aug 1997

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Authors

Affiliations

L. C. Brown
Prof., Dept. of Civ. and Envir. Engrg., Tufts Univ., Medford, MA 02155.
P. M. Berthouex, Associate Members, ASCE
Prof., Dept. of Civ. and Envir. Engrg., Univ. of Wisconsin-Madison, Madison, WI 53706.

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