TECHNICAL PAPERS
Jul 1, 1992

Softening by Fluidized Bed Crystallizers

Publication: Journal of Environmental Engineering
Volume 118, Issue 4

Abstract

Fluidized bed crystallizers (FBCs), also called pelletizers or pellet reactors, are an attractive alternative to conventional water softening. FBCs produce a coarse, spherically grained, easily dewatered, calcitic sand as the waste product, rather than a gelatinous sludge. Two operating full‐scale municipal FBCs used for softening in southern Florida were sampled and characterized. The study concludes that: (1) Calcium removal is very rapid within the reactor, leaving a large portion of the bed unused at any one time; (2) the calcium removal rate can be described by the Reddy‐Nancollas crystallization model; (3) high supersaturation levels due to poor mixing at the point of chemical mixing promotes microfloc production and solids carryover in the effluent; (4) classification of the pellets within the fluidized bed does not occur; (5) the sampling techniques appear to be adequate for characterizing FBC reactors; and (6) operation of FBCs would be aided by the installation of a pressure gauge on the FBC influent to monitor bed growth.

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References

1.
Graveland, A., van Dijk, J. C., de Moel, P. J., and Oomen, H. H. C. M. (1983). “Developments in water softening by means of pellet reactors.” J. AWWA, 75(12), 619–625.
2.
Harms, W. D. (1989). “Characterization of full‐scale operating lime‐driven conical water softening pelletizers in south Florida,” MS thesis, University of Tennessee, Knoxville, Tenn.
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Lieser, K. H. (1969). “Steps in precipitation reactions.” Angew Chem., Int. Ed., 8, 188–202.
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“Lime softening sludge treatment and disposal.” J. AWWA, 73(11), 600–608.
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Mullin, J. W. (1980). “Bulk crystallization.” Crystal growth, Brian Pamplin, ed., Pergamon Press, New York, N.Y.
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Stevens, J. D., and Schierholz, P. M. (1976). “Population balances in dilute impurity problems.” J. Envir. Engrg. Div., ASCE, 102(2), 337–346.
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van der Veen, C. and Graveland, A. (1988). “Central softening by crystallization in a fluidized bed process.” J. AWWA, 80(6), 51–58.
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Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 118Issue 4July 1992
Pages: 513 - 529

History

Published online: Jul 1, 1992
Published in print: Jul 1992

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Authors

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Willard D. Harms, Jr.
Project Mgr., Envir. Restoration, Westinghouse Envir. and Geotech. Services, Inc., 11931 Industriplex Blvd., Baton Rouge, LA 70809
R. Bruce Robinson, Member, ASCE
Assoc. Prof., Dept. of Civil. Engrg., 73 Perkins Hall, Univ. of Tennessee, Knoxville, TN 37996

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